DE10142746A1 - Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen - Google Patents

Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen

Info

Publication number
DE10142746A1
DE10142746A1 DE10142746A DE10142746A DE10142746A1 DE 10142746 A1 DE10142746 A1 DE 10142746A1 DE 10142746 A DE10142746 A DE 10142746A DE 10142746 A DE10142746 A DE 10142746A DE 10142746 A1 DE10142746 A1 DE 10142746A1
Authority
DE
Germany
Prior art keywords
weight
metal cyanide
catalyst
butanol
crown
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE10142746A
Other languages
German (de)
English (en)
Inventor
Walter Schaefer
Joerg Hofmann
Pieter Ooms
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Priority to DE10142746A priority Critical patent/DE10142746A1/de
Priority to DE50203464T priority patent/DE50203464D1/de
Priority to PT02754999T priority patent/PT1425333E/pt
Priority to CNB028169034A priority patent/CN1289569C/zh
Priority to MXPA04001907A priority patent/MXPA04001907A/es
Priority to PL02367706A priority patent/PL367706A1/xx
Priority to BR0212156-5A priority patent/BR0212156A/pt
Priority to CA002458530A priority patent/CA2458530A1/en
Priority to PCT/EP2002/009245 priority patent/WO2003020796A1/de
Priority to ES02754999T priority patent/ES2242872T3/es
Priority to HU0401744A priority patent/HUP0401744A2/hu
Priority to AT02754999T priority patent/ATE298354T1/de
Priority to HK06103179.1A priority patent/HK1083222B/xx
Priority to JP2003525063A priority patent/JP2005501947A/ja
Priority to KR10-2004-7002927A priority patent/KR20040029086A/ko
Priority to EP02754999A priority patent/EP1425333B1/de
Priority to TW091119472A priority patent/TW592814B/zh
Priority to US10/229,442 priority patent/US6586564B2/en
Publication of DE10142746A1 publication Critical patent/DE10142746A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyethers (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
DE10142746A 2001-08-31 2001-08-31 Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen Withdrawn DE10142746A1 (de)

Priority Applications (18)

Application Number Priority Date Filing Date Title
DE10142746A DE10142746A1 (de) 2001-08-31 2001-08-31 Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE50203464T DE50203464D1 (de) 2001-08-31 2002-08-19 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen
PT02754999T PT1425333E (pt) 2001-08-31 2002-08-19 Catalisadores de cianetos bimetalicos usados para a producao de polieter-polialcoois
CNB028169034A CN1289569C (zh) 2001-08-31 2002-08-19 用于制备聚醚型多元醇的双金属氰化物催化剂
MXPA04001907A MXPA04001907A (es) 2001-08-31 2002-08-19 Catalizadores de cianuro de metal doble para preparacion de polioles poliester.
PL02367706A PL367706A1 (en) 2001-08-31 2002-08-19 Double metal cyanide catalysts for producing polyether polyols
BR0212156-5A BR0212156A (pt) 2001-08-31 2002-08-19 Catalisadores de cianeto de metal duplo para a preparação de poliéter-polióis
CA002458530A CA2458530A1 (en) 2001-08-31 2002-08-19 Double metal cyanide catalysts for producing polyether polyols
PCT/EP2002/009245 WO2003020796A1 (de) 2001-08-31 2002-08-19 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen
ES02754999T ES2242872T3 (es) 2001-08-31 2002-08-19 Catalizadores de cianuro bimetalico para la preparacion de polioleteres.
HU0401744A HUP0401744A2 (hu) 2001-08-31 2002-08-19 Kettős fém-cianid (DMC) katalizátor poliéter-poliolok előállításához és eljárás ennek előállítására
AT02754999T ATE298354T1 (de) 2001-08-31 2002-08-19 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen
HK06103179.1A HK1083222B (en) 2001-08-31 2002-08-19 Double metal cyanide catalysts for producing polyether polyols
JP2003525063A JP2005501947A (ja) 2001-08-31 2002-08-19 ポリエーテルポリオールを製造するための複金属シアン化物触媒
KR10-2004-7002927A KR20040029086A (ko) 2001-08-31 2002-08-19 폴리에테르 폴리올을 제조하기 위한 이중 금속 시안화물촉매
EP02754999A EP1425333B1 (de) 2001-08-31 2002-08-19 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen
TW091119472A TW592814B (en) 2001-08-31 2002-08-28 Double-metal cyanide catalysts for preparing polyether polyols
US10/229,442 US6586564B2 (en) 2001-08-31 2002-08-28 Double-metal cyanide catalysts for preparing polyether polyols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10142746A DE10142746A1 (de) 2001-08-31 2001-08-31 Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen

Publications (1)

Publication Number Publication Date
DE10142746A1 true DE10142746A1 (de) 2003-03-20

Family

ID=7697294

Family Applications (2)

Application Number Title Priority Date Filing Date
DE10142746A Withdrawn DE10142746A1 (de) 2001-08-31 2001-08-31 Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
DE50203464T Expired - Lifetime DE50203464D1 (de) 2001-08-31 2002-08-19 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE50203464T Expired - Lifetime DE50203464D1 (de) 2001-08-31 2002-08-19 Doppelmetallcyanid-katalysatoren für die herstellung von polyetherpolyolen

Country Status (16)

Country Link
US (1) US6586564B2 (enExample)
EP (1) EP1425333B1 (enExample)
JP (1) JP2005501947A (enExample)
KR (1) KR20040029086A (enExample)
CN (1) CN1289569C (enExample)
AT (1) ATE298354T1 (enExample)
BR (1) BR0212156A (enExample)
CA (1) CA2458530A1 (enExample)
DE (2) DE10142746A1 (enExample)
ES (1) ES2242872T3 (enExample)
HU (1) HUP0401744A2 (enExample)
MX (1) MXPA04001907A (enExample)
PL (1) PL367706A1 (enExample)
PT (1) PT1425333E (enExample)
TW (1) TW592814B (enExample)
WO (1) WO2003020796A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003093888A (ja) * 2001-09-27 2003-04-02 Asahi Glass Co Ltd 複合金属シアン化物錯体触媒およびその製造方法
CN100549063C (zh) * 2003-10-10 2009-10-14 国际壳牌研究有限公司 制备聚醚多元醇的方法
DE602004010482T2 (de) * 2004-02-27 2009-01-08 Repsol Quimica S.A. Doppelmetallcyanidkatalysatoren (DMC) mit Kronenethern, Prozess zu ihrer Herstellung und Verwendungen
US20060058182A1 (en) * 2004-09-13 2006-03-16 Combs George G Processes for the preparation of double metal cyanide (DMC) catalysts

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1063525A (en) 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3829505A (en) 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
US3941849A (en) 1972-07-07 1976-03-02 The General Tire & Rubber Company Polyethers and method for making the same
JP2653236B2 (ja) 1990-10-05 1997-09-17 旭硝子株式会社 ポリエーテル化合物の製造方法
US5158922A (en) 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5712216A (en) 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5470813A (en) 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US5482908A (en) * 1994-09-08 1996-01-09 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5545601A (en) 1995-08-22 1996-08-13 Arco Chemical Technology, L.P. Polyether-containing double metal cyanide catalysts
US5627120A (en) 1996-04-19 1997-05-06 Arco Chemical Technology, L.P. Highly active double metal cyanide catalysts
US5714428A (en) 1996-10-16 1998-02-03 Arco Chemical Technology, L.P. Double metal cyanide catalysts containing functionalized polymers
DE19906985A1 (de) * 1999-02-19 2000-08-31 Bayer Ag Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen

Also Published As

Publication number Publication date
PL367706A1 (en) 2005-03-07
EP1425333A1 (de) 2004-06-09
DE50203464D1 (de) 2005-07-28
CN1289569C (zh) 2006-12-13
CN1671768A (zh) 2005-09-21
HUP0401744A2 (hu) 2004-12-28
MXPA04001907A (es) 2005-03-07
BR0212156A (pt) 2004-07-13
WO2003020796A1 (de) 2003-03-13
HK1083222A1 (en) 2006-06-30
CA2458530A1 (en) 2003-03-13
US20030050186A1 (en) 2003-03-13
ATE298354T1 (de) 2005-07-15
ES2242872T3 (es) 2005-11-16
US6586564B2 (en) 2003-07-01
TW592814B (en) 2004-06-21
JP2005501947A (ja) 2005-01-20
EP1425333B1 (de) 2005-06-22
PT1425333E (pt) 2005-10-31
KR20040029086A (ko) 2004-04-03

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Legal Events

Date Code Title Description
8127 New person/name/address of the applicant

Owner name: BAYER MATERIALSCIENCE AG, 51373 LEVERKUSEN, DE

8139 Disposal/non-payment of the annual fee