CS249773B1 - System of corrosion-resistant reflecting layers on substrates especially on glass - Google Patents
System of corrosion-resistant reflecting layers on substrates especially on glass Download PDFInfo
- Publication number
- CS249773B1 CS249773B1 CS828793A CS879382A CS249773B1 CS 249773 B1 CS249773 B1 CS 249773B1 CS 828793 A CS828793 A CS 828793A CS 879382 A CS879382 A CS 879382A CS 249773 B1 CS249773 B1 CS 249773B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- cjioh
- hjih
- glass
- cnoeb
- corrosion
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract 4
- 239000000758 substrate Substances 0.000 title claims abstract 4
- 230000007797 corrosion Effects 0.000 title claims 2
- 238000005260 corrosion Methods 0.000 title claims 2
- 229910052751 metal Inorganic materials 0.000 claims abstract 2
- 239000002184 metal Substances 0.000 claims abstract 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims 1
- 238000004157 plasmatron Methods 0.000 claims 1
- 239000010409 thin film Substances 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 229910000765 intermetallic Inorganic materials 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 238000004544 sputter deposition Methods 0.000 abstract 1
- 101100462378 Danio rerio otpb gene Proteins 0.000 description 4
- 101100066898 Mus musculus Flna gene Proteins 0.000 description 2
- UJCHIZDEQZMODR-BYPYZUCNSA-N (2r)-2-acetamido-3-sulfanylpropanamide Chemical compound CC(=O)N[C@@H](CS)C(N)=O UJCHIZDEQZMODR-BYPYZUCNSA-N 0.000 description 1
- 229910018575 Al—Ti Inorganic materials 0.000 description 1
- 229910002482 Cu–Ni Inorganic materials 0.000 description 1
- 229910017945 Cu—Ti Inorganic materials 0.000 description 1
- 241001669680 Dormitator maculatus Species 0.000 description 1
- 241000751119 Mila <angiosperm> Species 0.000 description 1
- 241001454372 Onoba Species 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 231100001143 noxa Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
- C23C14/185—Metallic material, boron or silicon on other inorganic substrates by cathodic sputtering
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/40—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal all coatings being metal coatings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
- G02B5/0816—Multilayer mirrors, i.e. having two or more reflecting layers
- G02B5/085—Multilayer mirrors, i.e. having two or more reflecting layers at least one of the reflecting layers comprising metal
- G02B5/0858—Multilayer mirrors, i.e. having two or more reflecting layers at least one of the reflecting layers comprising metal the reflecting layers comprising a single metallic layer with one or more dielectric layers
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Physical Vapour Deposition (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Testing Resistance To Weather, Investigating Materials By Mechanical Methods (AREA)
Abstract
Description
-1--1-
HaaBaHHe Η3ο6ρβτβΗΗΗ Internes Az.: 1/16 CHCTeMa BbicoKOKoppo3HOHHOCTOiiKHx oTpaxaiomHX cjioeB Ha cyčcTpaTaxHaaBaHHe ο3ο6ρβτβΗΗΗ Internes Az .: 1/16 CHCTeMa BbicoKOKoppo3HOHHOCTOiiKHx oTpaxaiomHX cjioeB Ha ctpaTax
QgjiaCTb ΠρΗΜβΗβΗΗΗ Η3θ6ρβΤβΗΗΗ » H3o6peTeHHe KacaeTCH CHCTeMH3 BbICOKOKOppO3HOHHOCTÓňKHX OTpaxaiomHX CJIOeBHa CTexjie hhh στβκποπορ,οδΗΗΧ cyScTpaTax. Cy6cTpaTbi, cHa6xeHHbie OTpasaiouuíMcjioeM, npHMeHjnoTCH, HanpHMep, KaK 3epxana b MeSentHoň HHflycTpHH, b 6wTy,b TpaHcnopTHOM flene, b HaynHOM npn6opocTpoeHnn hjih b xanecTBe nojiynpoHHijae-MblX 3βρΚΗΛ.QgjiaCTb ΠρΗΜβΗβΗΗΗ θ3θ6ρβΤβΗΗΗ »H3o6peTeHHe KacaeTCH CHCTeMH3 BbICOKOKOppO3HOHHOCTÓnKHX OTpaxaiomHX CJIOeBHa CTexjie hhh στβκποπορ, οδΗΗΧ cyScTpaTax. Cy6cTpaTbi, cHa6xeHHbie OTpasaiouuíMcjioeM, npHMeHjnoTCH, HanpHMep, KaK 3epxana b MeSentHoň HHflycTpHH, b 6wTy, b TpaHcnopTHOM flene, b HaynHOM npn6opocTpoeHnn hjih b xanecTBe nojiynpoHHijae-MblX 3βρΚΗΛ
XapaKTepHCTHxa HáBecTHbix TexHHHecKHX peiueHHftXapaKTepHCTHxa HábecTHbix TexHHHecKHX peiueHHft
HsBecTHo, hto MeTanjiHHecKHe oTpajKaromHe cjioh, očjiaflaroujHe CBoňcTBaMH caMO-IiaCCHBHpOBaHHH HJIH Ηβ OÓJia^aiOmHe THKHMH CBOÍÍCTBaMH, 3aiUHmaiOTCH OT ΚΟΡΡΟ3ΗΗHaHeceHHeM nonojiHHTejibHoro τοηκογο cjioh MeTajma h/hjih cjioh opraHHnecKoronojiHMepa, κοτορωή Taxace MoaceT coctohtb H3 HecxojibXHx cjioeB. 3φφβκτΗΒΗοοτι>3TOň 3aiUHTbI 3aBHCHT, KpOMe Bcero nponero, OT TOJHUHHbl, IIJ1OTHOCTH H nOpHCTOC-th 3thx cjioeB, a Táxke ot προηηοοτη a,nre3HH τοηκογο MeTajunmeCKoro cjioh cOTpawaioinHM cjioeM hjih, cooTBeTcTBeHHo, npoHHocTH aflreaHH cjioh opraHHHecxoronojiHMepa c tohkhm MeTajiJiHqecKHM cjioeM. IIocKOJibKy sainHTHoe fleftcTBHe τοηκογοMeTajuiHHecKoro cjioh no οτΗοηιβΗΗΐο κ oTpaacatomeMy cjioio onpeflěJineTCH npeHMyqe-CTBeHHo rajibBaHHuecKHM B3aHMop,eňcTBHfiM Meacfly o6ohmh cjiohmh MeTajma, tohkhiíMeTajuiHHecKHH cjioh ποητη Bcer^a coctoht He MeTaJiJia, κοτρρωή 3ηΗημηθτ b pa-ny 3JieKTpoxHMH«ecKHX HanpHHceHHň 6oJiee HH3xoe nojioaceHHe, ηθμ MeTajui oTpa-acaramero cjioh. ToHKHň MeTaJiJiHnecKHň cjioň, coctohiíi;hh b ochobhom H3 ηηοτογοMeTaJiJia, hhhocht npeflnoHTHTeJibHO nyTeM "μοκρογο" χημηηθοκογο cnoco6a hjihHanbuiHBáHHeM b BaxyyMe. OTpa»aroqHÉ cjioh 3ainHiuaeTCH tohkhm MeTajuiHnecKHMcjioeM TOJibKo flo τεχ nop, noxa He noflBepraeTCH aHOflHOMy pacTBopeHHio. BoJib-íliaH ftOJIH 3aiUHTHOrO fleňCTBHH npHXOflHTCH Ha CJIOH OpraHHHeCKOrO nojiHMepa, no-CKOJibKy nepnofl BpeMeHH «o aHOflHoro pacTBopeHHH τοηκογο MeTaJunroecKoro cjiohcjihiukom Man no cpaBHeHHío co BpeMeneM npoHHKHOBeHHw b cjioň opraHHnecKoro no- 249773 -2- JIHMepa 3TM0C(J)6pHbIX 3ΓΘΗΤ0Β (BOflS, KHCJlOpon H T.fl.), ΠρΗΗΘΜ K CJIOK) OpraHH-necKoro nojiHMepa npeflbHBJíHioTCH cpejiH npoHHx ocoSeHHo crporne TpečoBaHHHoTHocHTejibHo cTeneHH ciuhbkh. 06hhho cjioh opraHHHecKoro nojiHMepa αοτβκθη bu-cyuiHBaTbcn b BHeproeMKOM npopecce. .HsBecTHo, hto MeTanjiHHecKHe oTpajKaromHe cjioh, očjiaflaroujHe CBoňcTBaMH Camo-IiaCCHBHpOBaHHH HJIH Ηβ OÓJia ^ aiOmHe THKHMH CBOÍÍCTBaMH, 3aiUHmaiOTCH OT ΚΟΡΡΟ3ΗΗHaHeceHHeM nonojiHHTejibHoro τοηκογο cjioh MeTajma h / hjih cjioh opraHHnecKoronojiHMepa, κοτορωή Taxation MoaceT coctohtb H3 HecxojibXHx cjioeB. 3φφβκτΗΒΗοοτι> 3ton 3aiUHTbI 3aBHCHT, KpOMe Bcero nponero OT TOJHUHHbl, IIJ1OTHOCTH nOpHCTOC H-th 3thx cjioeB and Táxke προηηοοτη and OT, nre3HH τοηκογο MeTajunmeCKoro cjioh cOTpawaioinHM cjioeM hjih, cooTBeTcTBeHHo, npoHHocTH aflreaHH cjioh opraHHHecxoronojiHMepa c tohkhm MeTajiJiHqecKHM cjioeM. IIocKOJibKy sainHTHoe fleftcTBHe τοηκογοMeTajuiHHecKoro cjioh well οτΗοηιβΗΗΐο κ oTpaacatomeMy cjioio onpeflěJineTCH npeHMyqe-CTBeHHo rajibBaHHuecKHM B3aHMop, eňcTBHfiM Meacfly o6ohmh cjiohmh MeTajma, tohkhiíMeTajuiHHecKHH cjioh ποητη Bcer ^ and coctoht He MeTaJiJia, κοτρρωή 3ηΗημηθτ b pa-ny 3JieKTpoxHMH «ecKHX HanpHHceHHň 6oJiee HH3xoe nojioaceHHe, ηθμ MeTajui otPA -acaramero cjioh. ToHKHn MeTaJiJiHnecKHn cjioň, coctohiíi; hh b ochobhom H3 ηηοτογοMeTaJiJia, hhhocht npeflnoHTHTeJibHO nyTeM "μοκρογο" χημηηθοκογο cnoco6a hjihHanbuiHBáHHeM b BaxyyMe. OTpa »aroqHÉ cjioh 3ainHiuaeTCH Tohkhm MeTajuiHnecKHMcjioeM TOJibKo flo τεχ nop, noxa He noflBepraeTCH aHOflHOMy pacTBopeHHio. BoJib-Iliahi ftOJIH 3aiUHTHOrO fleňCTBHH npHXOflHTCH Ha CJIOH OpraHHHeCKOrO nojiHMepa no-CKOJibKy nepnofl BpeMeHH «on aHOflHoro pacTBopeHHH τοηκογο MeTaJunroecKoro cjiohcjihiukom Man cpaBHeHHío well as BpeMeneM npoHHKHOBeHHw b cjioň opraHHnecKoro O- 249,773 JIHMepa 3TM0C -2- (J) 6pHbIX 3ΓΘΗΤ0Β (BOflS, KHCJlOpon H T.fl.), ΗΗΘΜ ΗΗΘΜ J J K ra ra ra ra ra ra ra ra ra ra T T T T T T T T T T T T T T T T T T T T 06hhho cjioh opraHHHecKoro nojiHMepa αοτβκθη bu-cyuiHBaTbcn b BHeproeMKOM npopecce. .
OflHaKO B MHOIOHHCJieHHblX CJiyHaHX ΠρΗΜθΗβΗΗΗ, HecMOTpH Ha floporocTOHiípie cno-co6bi noJiyueHHH, HanpHMep, oca3Kp,eHneM npn πομοιιιη ŤepMHHecKoro hjih ΒπεκτροΗ-HOJiyneBoro HamneHHH b BanyyMe hjih njia3MeHHbix npopeccoB na BO3flyxe, HeHOCTHraeTCH HeoSxOHHMblH CPOK CJiy>K0bI H3-3a MaJIOH KOppO3HOHHO~XHMHHeCKOHctohkocth. B cnynae μοκρογο χημηηθοκογο ocaayieHHH npep;bHBJiHioTC.H ποβηιπθηημθTpeSoBaHHH no οτηοπιθηηιο k oxpaHe Tpypa u 3auiHTe ojcpyjtcaioineH cpenbi BCjiencT-Bue Hcnojib3OBaHHH HflOBHTbix 3JieKTpoJiH3HHx bhhh. noJiyneHHe Ha oTpascaioineMcjioe Koppo3noHHo-3amnTHoro cjioh npH πόΜοηρι aHOflHoro OKHCJieHHH, HanpHMep,aHOflHpOB ΗΗΗΘΜ C ΠρΗΜβΗΘΗΗβΜ ajIIOMHHHH B KaneCTBe OTpawaiOmerO CJIOH, CBH3aHOK3K CO 3HaHHTeJIhHbIMH ΤΘΧΗΟΙΙΟΓΗΗΘΟΚΗΜΗ 3ΒΤρ£ΙΤ3ΜΗ, TaK H C o6pa3OBaHHeMMHOrOHHCJieHHblX flbip B OTpa5KaKM(eM CJIOe, npHBOflHIHHM K yxyflUieHHIO CTeneHH OTpa-«eHHH.OflHaKO B MHOIOHHCJieHHblX CJiyHaHX ΠρΗΜθΗβΗΗΗ, HecMOTpH Ha floporocTOHiípie cno-co6bi noJiyueHHH, HanpHMep, oca3Kp, eHneM npn πομοιιιη ŤepMHHecKoro hjih ΒπεκτροΗ-HOJiyneBoro HamneHHH b BanyyMe hjih njia3MeHHbix npopeccoB to BO3flyxe, HeHOCTHraeTCH HeoSxOHHMblH CPOK CJiy> K0bI H3-3a MaJIOH KOppO3HOHHO ~ XHMHHeCKOHctohkocth. B cnynae μοκρογο χημηηθοκογο ocaayieHHH npep; bHBJiHioTC.H ποβηιπθηημθTpeSoBaHHH no οτηοπιθηηιο to oxpaHe Tpypa u 3auiHTe ojcpyjtcaioineH cpenbi BCjiencT-Bue Hcnojib3OBaHHH HflOBHTbix 3JieKTpoJiH3HHx bhhh. noJiyneHHe Ha oTpascaioineMcjioe Koppo3noHHo-3amnTHoro cjioh NPH πόΜοηρι aHOflHoro OKHCJieHHH, HanpHMep, aHOflHpOB ΗΗΗΘΜ C ΠρΗΜβΗΘΗΗβΜ ajIIOMHHHH B KaneCTBe OTpawaiOmerO CJIOH, CBH3aHOK3K CO 3HaHHTeJIhHbIMH ΤΘΧΗΟΙΙΟΓΗΗΘΟΚΗΜΗ 3ΒΤρ £ ΙΤ3ΜΗ and HC o6pa3OBaHHeMMHOrOHHCJieHHblX flbip OTpa5KaKM B (EM CJIOe, npHBOflHIHHM K yxyflUieHHIO CTeneHH OTpa- «ehhh .
HsBecTHo, hto npH HaHeceHHH MeTajnia Ha MeTajui πρκ πομοιιιη nJia3MeHHbix npo-peccoB Ha BO3,n;yxe pap MeTanjioB (HanpHMep Ag-Al, Cu-Ni) BCTynaer b χημηηθο-Koe B3anMOfleHCTBHe, hto ÉJiHaeT Ha onTHnecKHe H apre3HOHHbie cnocoóHocTH(KyflmoB h flp: Onraxa nna3MeHHbix ποκρωτΗή, H3p. Hayxa, MocKBa 1981). Πο-noSHbie xHMHHecKHe B3aHMofleňcTBHH Meacpy MeTajuiaMH CBHaaHbí c onpepeJieHHbíMHKOMČHHapHHMH MeTaHJIOB . 3TH XHMHHecKHe B3aHMOfleHCTBHH H CBH33HHbie C 3THMH3MeHeHHH cboHctb He HaSjíiopaioTCH, HanpHMep, npH κομ6ηηβρηηχ MeTanjioB Al-Tí,Cu-Ti.HsBecTHo, hto NPH HaHeceHHH MeTajnia Ha MeTajui πρκ πομοιιιη nJia3MeHHbix NPO-peccoB Ha BO3 n; YXE PAP MeTanjioB (HanpHMep Ag-Al, Cu-Ni) BCTynaer b χημηηθο-Koe B3anMOfleHCTBHe, HTO ÉJiHaeT Ha onTHnecKHe H apre3HOHHbie cnocoóHocTH (KyflmoB h FLP : Onraxa nna3MeHHbix ποκρωτΗή, H3p., Hayxa, MocKBa 1981). Π-no bie bie Π Π Π Π a Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π Π 3 3 3 3 3 3 3 3 3 3. 3TH XHMHHecKHe B3aHMOfleHCTBHH CBH33HHbie C 3THMH3MeHeHHH cboHctb He HaSjiiopaioTCH, HanpHMep, npH κομ6ηηβρηηχ MeTanjioB Al-Ti, Cu-Ti.
Uenb H306peTCHHHUenb H306peTCHHH
IlpepnojiaraeTCH pa3pa6oTaTb pap bmcokokóppo3hohhoctohkhx CHCTeM OTpaacaiomHxcnoeB Ha creKJie hjih cTeKJionopoóHbix cyÓCTpaTax, κοτορωε mojkho η3γοτοβητβTexHojioranecKH npocTbiM cnocoSoM h 6e3 6ojihiuHX 3aTpaT η κοτορΗβ He yxypniaioTCTeneHH oTpaxatomeň cnocoSHocTH, a npeHMymecTBeHHo CTeneHH OTpaaceHHH CBeTa,HH ΠΡΗ ero Η3ΓΟΤΟΒηθΗΗΗ, HH npH nOCJiepyiOmeM HCnOJIb3OBaHHH.IlpepnojiaraeTCH pa3pa6oTaTb pap bmcokokóppo3hohhoctohkhx CHCl OTpaacaiomHxcnoeB Ha creKJie hjih cTeKJionopoóHbix cyÓCTpaTax, κοτορωε mojkho η3γοτοβητβTexHojioranecKH npocTbiM cnocoSoM h 6E3 6ojihiuHX 3aTpaT η κοτορΗβ He yxypniaioTCTeneHH oTpaxatomeň cnocoSHocTH and npeHMymecTBeHHo CTeneHH OTpaaceHHH CBet HH ΠΡΗ ero Η3ΓΟΤΟΒηθΗΗΗ HH NPH nOCJiepyiOmeM HCnOJIb3OBaHHH.
H3JioaceHne cyiqHOCTH H3o6peTeHHH H3o6peTeHHe pemaeT 3apany pa3paSoTKH bi>icokokoppo3hohhoctohkhx CHCTeM H3oTpaacawinHx cjioes Ha ετεκηε hjih CTeKJionopóĎHbix cyĎCTpaTax, npH η3γοτοβηθηηηh flajibHeňiueM ynoTpeSneHHH κοτορωχ He yxypinaeTca CTeneHb OTpaaceHHH, npep-ποητητθιιβηο CTeneHb OTpaaceHHH CBeTa, η npH η3γοτοβρθηηη κοτορΜΧ pna pocth-JKeHHH fíOJirOBpeMeHHOÍI KOPPO3HOHHOH 3aqHTbI He HCnOJIb3yeTCH CJIOft OpraHHHeCKO-ro nojiHMepa. 'H3JioaceHne cyiqHOCTH H3o6peTeHHH H3o6peTeHHe pemaeT 3apany pa3paSoTKH bi> icokokoppo3hohhoctohkhx CHCl H3oTpaacawinHx cjioes Ha ετεκηε hjih CTeKJionopóĎHbix cyĎCTpaTax, NPH η3γοτοβηθηηηh flajibHeňiueM ynoTpeSneHHH κοτορωχ He yxypinaeTca CTeneHb OTpaaceHHH, npep-ποητητθιιβηο CTeneHb OTpaaceHHH CBet, η NPH η3γοτοβρθηηη κοτορΜΧ PNA pocth-JKeHHH fíOJirOBpeMeHHOÍI KOPPO3HOHHOH 3aqHTbI He HCnOJIb3yeTCH CJIOft OpraHHeCKO-ro nojiHMepa. '
HeoampaHHo 6bino naňpeHo, hto sahana pentaeTCH Torpa, ecJiH Hcnojib3yioT cncTe-Mbi oTpaacaiomHX cnoeB, coctohiuhx H3 oTpaacaioiuero cjioh H3 aJHOMHHHH hjih MepH hjihHHHKa hjih MeflH h HHHKa hjih Me«H h onoBa h TOHKoro cjioh MeTaJiJia THTaHa, ko-Topbie ηηηοοητοη Ha CTeKJio hjih CTeKJionofloSHbiH cy6cTpaT πρκ noMoqH tohkocjioH-ηογο nna3MaTpoHHoro ycKopHTenH b BaKyyMHoň nocjieflOBaTeJibHocTH.HeoampaHHo 6bino naňpeHo, HTO Sahana pentaeTCH Torpa ecJiH Hcnojib3yioT cncTe-MBi oTpaacaiomHX cnoeB, coctohiuhx H3 oTpaacaioiuero cjioh H3 aJHOMHHHH hjih Meph hjihHHHKa hjih MeflH h HHHKa hjih Me «H H onoBa h TOHKoro cjioh MeTaJiJia THTaHa co-TopBio ηηηοοητοη Ha CTeKJio hjih CTeKJionofloSHbiH cy6cTpaT πρκ noMoqH tohkocjioH-ηογο nna3MaTpoHHo ycKopHTenH b BaKyyMHoň nocjieflOBaTeJibHocTH.
CooTBeTCTByioniaH H3o6peTéHHW BbicoKOKopposHOHHocTofíKaH CHCTeMa oTpaacaiomHxcjioeB, nojiyneHHaH no TaKon npocToň τθχηοιιογηη h 6e3 SoJibiuHx 3aTpaT, oĎJiapa-βτ npH coxpaHeHHH HeH3MeHHoň CTeneHH OTpaaceHHH, b ocoSennocTH CTeneHH OTpa-®eHHH CBeTa, TaKOň POJITOBpeMeHHOH KOppO3HOHHOÍÍ 3aiUHTOH, HTO H3 3THX coo6pa-aceHHň Ha stom cnoe 6ojibme He TpeSyeTca cjioh opraHHHecKoro nojiHMepa. B cjiy-nae HeoBxouHMocTH KaHeeTBeHHO MeHee xopomHH cjioh opraHHHecKoro nojiHMepa bh- 249773 -3- ΠΟΛΗΗβΤ TOflbKO φΥΗΚίχΗΚ) 3βΠ|ΗΤΗ ΟΤ CHJIbHhlX MexaHHHeCKHX BO3fleňcTBHft Ha OTpa-acawiUHň cnoft MaTepnana.CooTBeTCTByioniaH H3o6peTéHHW BbicoKOKopposHOHHocTofíKaH CHCTeMa oTpaacaiomHxcjioeB, but nojiyneHHaH TaKon npocToň τθχηοιιογηη h 6E3 SoJibiuHx 3aTpaT, oĎJiapa-βτ NPH coxpaHeHHH HeH3MeHHoň CTeneHH OTpaaceHHH b ocoSennocTH CTeneHH otPA-®eHHH CBet, TaKOň POJITOBpeMeHHOH KOppO3HOHHOÍÍ 3aiUHTOH, HTO H3 3THX coo6pa-Ha aceHHň one hundred meters cnoe He 6ojibme TpeSyeTca cjioh opraHHHecKoro nojiHMepa. B cjiy-nae HeoBxouHMocTH KaHeeTBeHHO MeHee xopomHH cjioh opraHHHecKoro nojiHMepa bh- 249773 -3- ΠΟΛΗΗβΤ TOflbKO φΥΗΚίχΗΚ) 3βΠ | ΗΤΗ ΟΤ
HaňfleHHoe cymecTBeHHoe noBbiuieHne flonroBpeMeHHoft κορρο3ΗθΗΗοή aamHTbi mojkhoo6t>HCHHTh o6pa3OBaHneM cneiíH<i>HqecKoro nepexóflHoro cnon. Cnein«l)HHecKHň ne-pexoflHbiň cnoft oneBHflHo cnocočcTByeT cymecTBeHHO 6onbmeň ciiocoShocth k caMo-nacČHBHsaitHH, neM nncTbift MeTami η thkhm o6pa3OM o6pa3yeT ochoby flnH bmcoko-KOppO3HOHHOCTOftKOft CHCTeMbi OTpaxaKMItflX cnoefi.HanfleHHoe cymecTBeHHoe noBbiuieHne flonroBpeMeHHoft κορρο3ΗθΗΗοή aamHTbi mojkhoo6t> HCHHTh o6pa3OBaHneM cneiíH <i> HqecKoro nepexóflHoro cnon. Cnein «lhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhhmnhhhhhmhmhmhmhmhmhmhnmhnmhnmhnmhcmnn
JlerHpoBaHHeM noflxoflHmHX ΜβτβηηοΒ, HanpHMep, HHKenn, c MeTannoM oTpaxaiome-ΓΟ CHOH npH COXpaHeHHH flOnrOCpOHHOft 3amHTbl ΟΤ KOppO3HH MO3KHO H3TOTOBHTbpaaHbie BapHaHTbi pacflBeTOK «nn fleKOpaTHBHbix peneft. ΠρΗΜβρ OCyměCTBJíeHHH Η3θ6ρβΤβΗΗΗ ΠρΗΜβρ 1Ler τ τ τ OH of OH OH OH OH OH OH OH OH OH pp pp pp pp pp c T no o 3 3 3 3 3 3 3 3 3 n n n n n n n ΠρΗΜβρ OCyměCTBJíeHHH Η3θ6ρβΤβΗΗΗ ΠρΗΜβρ 1
Ha TmarejibHO onraneHHyio npo6y H3 Φποτβαηοηηογο CTenna pa3MepoM 10 cm x 10 cmb BaKyyMe npH ο6μηηομ pafíoneM flaBneHHH b 133,32 Míla (aproH) npH noMoupi toh-KOCJioňHoro nna3MaTpoHHoro ycKopHTejiH nocneflOBaTenbHo b oahom npouecce ηβηο-cht oTpaxcawinyio CHCTeMy aJHOMHHHft/THTaH, πρΗΗβΜ cnanána HaHocHT cnoft anioMHHHHTOJimHHoň οκοπο 110 hm, 3aTeM cnoft τητβηβ TojrapiHoň 20 hm. fljia cpaBHeHHH naflBe aHaJioruHHo omnueHHbie npo6bi H3 φηοτβηΗΟΗΗΟΓΟ ςτεκηβ pa3Mepoe b IO cmxx 10 cm HaHocHT OTpawaromyio CHCTeMy anioMHHHň/THTaH co chohmh τοή sce τοππιηημ,ho ΜβτοΑοΜ TepMHHecKoro HanbineHHH b BaKyyMe npH o6bWHÓM paóoneM flaBneHHH2,67 Míla. flanee Ha oflHy H3 sthx flByx npo6 HaHocHT cnoft opraHHnecKoro nonft-Mepa, a ημθηηο ο6ηηηογο aepKanbHoro nana. Bce τρΗ προβω noflBepraioTCH Hcnbi-TaHHio Ha sjíeKTpoxnMHHecKyio ctohkoctb, npH kotopom nokašaTeneM ctohkocth hπρκ 3TOM cpoKa cnyxčbi HaHeceHHoň OTpaacaromeň CHCTeMbi ΗΒΠΗβτοΗ χορ, προτβκβ-HHH KOPPO3HH BO ΒρβΜβΗΗ, Η3ΜβρΗβΜΒΠι ΠΟ ΟΤΗΟΙΠΘΗΗΚ) K OMblBaeMOMy KHCHOpOflOMitnaTHHOBOMy ajieKTpofly b 0,5 h HNOj .Ha TmarejibHO onraneHHyio npo6y H3 Φποτβαηοηηογο CTenna pa3MepoM 10 cm x 10 cmb BaKyyMe NPH ο6μηηομ pafíoneM flaBneHHH b MIIa 133.32 (aproH) NPH noMoupi toh-KOCJioňHoro nna3MaTpoHHoro ycKopHTejiH nocneflOBaTenbHo b oahom npouecce ηβηο-CHT oTpaxcawinyio CHCTeMy aJHOMHHHft / THTaH, πρΗΗβΜ cnanána HaHocHT cnoft anioMHHHHTOJimHHoň 110 hm, 3aTeM cnoft τητβηβ TojrapiHoň 20 wt. fljia cpaBHeHHH naflBe aHaJioruHHo omnueHHbie npo6bi H3 φηοτβηΗΟΗΗΟΓΟ ςτεκηβ pa3Mepoe CMXX b IC 10 cm HaHocHT OTpawaromyio CHCTeMy anioMHHHň / THTaH what chohmh τοή SCE τοππιηημ him ΜβτοΑοΜ TepMHHecKoro HanbineHHH b BaKyyMe NPH o6bWHÓM paóoneM flaBneHHH2,67 nice. flanee Ha oflHy H3 sthx flByx npo6 HaHocHT cnoft opraHHnecKoro nonft-Mepa, and ημθηηο ο6ηηηογο aepKanbHoro nana. BCE τρΗ προβω noflBepraioTCH HCNB TaHHio-Ha sjíeKTpoxnMHHecKyio ctohkoctb, NPH kotopom nokašaTeneM ctohkocth hπρκ 3TOM cpoKa cnyxčbi HaHeceHHoň OTpaacaromeň CHCTeMbi ΗΒΠΗβτοΗ χορ, προτβκβ-HHH KOPPO3HH BO ΒρβΜβΗΗ, Η3ΜβρΗβΜΒΠι ΠΟ ΟΤΗΟΙΠΘΗΗΚ) To OMblBaeMOMy KHCHOpOflOMitnaTHHOBOMy ajieKTpofly b 0.5h manure.
Ha p«c. 1 npencTaBJíeH xofl προτβκβΗΗΗ kopposhh Ha Tpex npofiax b 3aBHCHMoc-th ot BpeMeHH. KpHBaH í othocHtch k. npo6e, nonyneHHoň TepMHnecKHM Hanbine-ΗΗβΜ 6e3 cjioh opraHHHecKoro nojiHMepa; κρκΒβα 2 npeflCTaBnneT npo6y, nony-neHHyio TepMHnecKHM ΗβπωπβΗΗβΜ, co cnoeM opraHHnecKoro nonHMepa, a KpHBaH 3rtpeflcTaBJíHeT npoóy nonyneHHyio πρκ πομοειη TOHKOcnoňHoro nna3MaTpoHHoro yc-ΚΟρΗΤβΠΗ. IIpo6a TepMHvécKoro HanbineHHH 6e3 cjioh opraHHnecicoro nonHMepa ysce nočně TpexnacoB noKaabiBaeT nepBbie BH3yanbHo HaČmonaeMbie ηέφεκτω (nanpHMep, flbipbi),ηβρβ3 20 nacoB CHčTeMa oTpaacaioiiiHx cnoeB npoxoflHT MaKCHMyM Ha KpHBoň. XapaK-TepHblMH HBJIHIOTCH OCTpblft ΠΗΚ H ΚΡΥΤΟβ ΠβΑβΗΗβ KpHBOH XOfla ΠρθΤβΚ3ΗΗΗ κορρο-3HH c BblCOKHM MaKCHMyMOM. (KpHBaH 1) .Ha p «c. 1 npencTaBJíeH xofl προτβκβΗΗΗ kopposhh Ha Tpex npofiax b 3aBHCHMoc-th ot BpeMeHH. KpHBaH í othocHtch k. Npo6e, nonyneHHoM TepMHnecKHM Hanbine-ΗΗβΜ 6e3 cjioh opraHHHecKoro nojiHMepa; κρκΒβα 2 npeflCTaBnneT npo6y, nony-neHHyio TepMHnecKHM ΗβπωπβΗΗβΜ, what cnoeM opraHHnecKoro nonHMepa, and KpHBaH 3rtpeflcTaBJiHeT npoo nonyneHHiio πρκ πομοειη TOHKOcnoňHoro nna3MaTpoHHoro yc-ΚΟρΗΤβΠΗ. IIpo6a TepMHvécKoro HanbineHHH 6e3 cjioh opraHHnecicoro nonHMepa ysce nighttime TpexnacoB noKaabiBaeT nepBbie BH3yanbHo HaCmonaeMbie ηέφεκτω (nanpHMep, flbipbi), ηβρβ3 20 nacoB CHCTeMa oTpaacaioiiiHx cnoeB npoxoflHT MaKCHMyM Ha KpHBoň. XapaK-TepHblMH HBJIHIOTCH OCTpblft ΠΗΚ H ΚΡΥΤΟβ ΠβΑβΗΗβ KpHBOH XOfla ΠρθΤβΚ3ΗΗΗ κορρο-3HH c BblCOKHM MaKCHMyMOM. (KpHBaH 1).
Xofl npoTeKaHHH κορρο3ΗΗ Ha προβε, nonyneHHoň TepMHneckHM HanbiJieHneM co čno-eM opraHinecKoro nonHMepa (κρηβηη 2) no cpaBfieHHio c κρΗΒοή 1 6oJiee poBHbiňc 6onee hh3khm MaKCHMyMOM, hto cBHfleTenbCTByeT 06 onpefleneHHOM 3anpiTHOMneňCTBHH cjioh opraHunecKoro nonnMepa. 3flécb neppbie ρβφβκτώ HaSntoflaioTCHnocne 20 nacoB, nepea 60 nacoB cncTeMa OTpaxcaiomHX cnoeB npoxoflHT uepe3 MaK-CHMyM KpHBOft. B cnynae προβω, nonyneHHoft πρκ ποΜοημί TOHKocnoftHoro nna3MaTpoHHoro ycKo- iρΗΤβΠΗ, (KpHBaH 3) B npOTHBOnOJIOKHOCTb BbnnenpHBeneHHOMy MOJKHO HaSjHOflaTbnepBbie Αβφβκτω He panee, neM npH6nH3HTenbHo nepe3 200 nacoB. DKCTpeMajibHoHHSKoe προτεκβΗΗβ κορρο3ΗΗ, a τβκκβ ποητη nocTOHHHbiň xapaKTep xona κορρο-3HH 6ea BbipaaceHHoro MaKCHMyMa bo BpeMeHH - flašce nocne 480 nacoB - flOKa3bi-eaeT, hto b naHHOM cnýnae npoTeKaeT τοηπκο BecbMa cna6biň nponecc κορρο3ΗΗh mm HMeeM fleno c BecbMa ΒΜθοκοκορρο3ΗθΗΗοοτοήκοή cHCTeMoň oTpawawmHxcjioeB. ' ' 249773 -4- H3MepeHne cTeneHH oTpa«eHHH CBeTa oTpaacaiomHx cnoeB Bcex τρεχ npo6 Kenocpefl*CTB6HHO nOCJie H3 rOTOBJ16HHJI COCTaBJIHeT BenHHHHy 86!?. H3MepeHHH B XOfle Hcnbl-T3HHH Ha 3JieKTpoxnMHwecKyio CToňxocTb flaioT BejiHHHHy 9% nocne 20 qacoB ncm>i-T3HHH npoBbi, nonyqeHHoň TepMHnecKHM HanwneHHeM 6e3 cnoa opraHHnecKorononHMepa, 12% nepe3 20 qacoB ηοπμτηηηη flna npoSbi, nonyqeHHoň TepMHnecKHMHanbLneHHeM co cjioeM opraHunecKoro nonHMepa, h 9% nepe3 60 uacoB ηοπμτ3ηηη,85% wepe3 200 nacoB h 480 nacóB ηοπβιτηηηη pjia προ6ω, nonyneHHoň πρκ πομο-mn TOHKOcjioííHoro ,njia3MaTpoHHoro ycKopHTenn. fljIH OČbHCHeHHH npHpOflbl o6Hapy®eHHOH BblCOKOH KOPPO3HOHHOH CTO&KOCTH flaJieeHccJieflOBaJiH cucTeMy oTpaacaioinHx cnoeB πρκ noMomu BTopHWHoň hohhoíí Macc-cneKTpocKonHH (BHMC). Ha pne. 2 npefíCTaBJíeHa BHMC-xapaKTepHCTHKa (κοηκηεοτ-BO HMnyjlbCOB 3a eflHHHHy ΒΡΟΜΘΗΗ - HHTeHCHBHOCTb - B 3aBHCHMOCTH OT BpeMeHHH3MepeHHfl) npo6bi oTpaxaromnx cnoeB, nonyneHHbix TepMnwecKHM ηθπμπθηηθμ, hHa pne. 3 - BHMC - xapaKTepHCTHKa προδω oTpaáfawipHx cnoeB, nonyqeHHbix πρκnoMomH TOHKOcnoňHoro nna3MaTpoHHoro ycKopuTena. B το BpeMa kbk Ha npo6e,nonyneHHoň TepMHnecKHM HanuneHneM, HaSnronaeTcn ηετκοε pa3fleneHHe cnoeB anio-mhhhh h THTana (kpHBbie Ha pne. 2), b CHCTeMe OTpaacaiomHX cnoeB, nonyneHHoňnpH noMOinn TOHKocnoftHoro nna3MaTpoHHoro ycKopHTenn npo6bi, Hapnny co 3Ha-HHTenbHbíM cMeiuaHHeM cnoeB anioMriHHH. n THTaHa Ha6raoflaeTCH 3aMeTHoe H3MeHe-Hne o6enx xapaKTepHCTHK c ποηΒηβΗΗβΜ cennoBHH Ha κρηβμχ (τ.θ, κρηβμθ ημθιοτflByropSyro $opMy). Kax 3HanHTenbHoe cMemaHne cnoeB, Tax h flByropčocTb kph-Bbix (ceflnoBHH Ha κρηβμχ) HBnHMTcn noKa3aTenbCTBOM oGpaaoBaHHH nepexoflHorocnon, KOTOPMH OqeBHflHO HBnHeTCH OTBeTCTBeHHblM 3a BblCOKyiO KOppO3HOHHyK)CTOťlKOCTb. IIpHMep 2 AHanornnHo npuMepy 1 Ha npo6e H3 $noTanHoHHoro CTexna b BaxyyMe πρκ pa6o- neM naBneHHH b 133,32 Míla (aproH) πρκ πομοιιιη TOHKocnoftHoro nna3MaTpoHHoroycKopHTenn nocnenoBaTenbHo b ορ,ηομ npoijecce HaHocnT CHCTeMy oTpaacaionuix cno-eB Menb/THTaH, cocTOHHjyro H3 cnoa Menu tojiihhhoh npn6nH3HTenhHo b 100 ημ η H3'cnoa THTaHa TonmuHoíi npHMepHo b 20 hm. flna cpaBHeHHa b BaxyyMe npH paSon^MflaBneHHH b 2,67 Míla b οη,ηομ pa6oneM nponecce nocnenoBaTenbHo πρκ ποΜοπριTepMHnecKoro HanbineHHa Ha npo6y H3 (JmoTannoHHoro CTexna HaHocaT CHCTeMyoTpajKaromHx cnoeB μθπβ/τητηη c aHanorHHHoň tojiihhhoh cnoeB. 06e προδω noflBepraiOT hciimthhhio Ha sneKTpoxHMHHěcKyio CToiÍKocTb οοοτβθτοτ-BeHHO npHMepy 1. Ha pne. 1 npeflCTaBneH χορ, προτεκΗΗΗΗ κορρθ3ΗΗ bo βρθμθηη.y»e nocne οηηογο naca Ha TepMHqecKHM nyTeM HanbineHHoťí npo6e (xpuBan 4) norHBnnioTCH BH3yanbHo pa3nnnaeMbte Ηβφβκτω, a npHMepHo nocne 35 nacoB CHCTeMaOTpaacaroiuHx cnoeB προχοπκτ MaxcHMyM Ha kphboh. XapaKTepHbíM Ha stom npHMepeaBnaeTca Taxace octpmíí πηκ h kpyToe naneHHe KpHBoň xofla προτβΚΗΗΗΗ κορρο3ΗΗC BblCOKHM MaKCHMyMOM.Xofl npoTeKaHHH κορρο3ΗΗ Ha προβε, nonyneHHoň TepMHneckHM HanbiJieHneM what CNO-eM opraHinecKoro nonHMepa (κρηβηη 2) n C cpaBfieHHio κρΗΒοή 1 6oJiee poBHbiňc 6onee hh3khm MaKCHMyMOM, HTO cBHfleTenbCTByeT 06 onpefleneHHOM 3anpiTHOMneňCTBHH cjioh opraHunecKoro nonnMepa. 3flcb neppbie ρβφβκτώ HaSntoflaioTCHnocne 20 nacoB, nepea 60 nacoB cncTeMa OTpaxcaiomHX cnoeB npoxoflHT uepe3 MaK-CHMyM KpHBOft. B cnynae προβω, nonyneHHoft πρκ ποΜοημί TOHKocnoftHoro nna3MaTpoHHoro ycKo- iρΗΤβΠΗ, (KpHBaH 3) B npOTHBOnOJIOKHOCTb BbnnenpHBeneHHOMy MOJKHO HaSjHOflaTbnepBbie Αβφβκτω He panee, neM npH6nH3HTenbHo nepe3 200 nacoB. DKCTpeMajibHoHHSKoe προτεκβΗΗβ κορρο3ΗΗ and τβκκβ ποητη nocTOHHHbiň xapaKTep Xona κορρο-3HH 6ea BbipaaceHHoro MaKCHMyMa BpeMeHH bo - flašce nocne 480 nacoB - flOKa3bi-eaeT, hto b naHHOM cnýnae npoTeKaeT τοηπκο BecbMa cna6biň nponecc κορρο3ΗΗh mm HMeeM FLEN c BecbMa ΒΜθοκοκορρο3ΗθΗΗοοτοήκοή cHCTeMoň oTpawawmHxcjioeB. '' 249773 -4- H3MepeHne cTeneHH oTpa «eHHH CBeTa oTpaacaiomHx cnoeB Bcex τρεχ npo6 Kenocpefl * CTB6HHO nOCJie H3 rOTOBJ16HHJI COCTaBJIHeT BenHHHHy 86! H3MepeHHH B XOfle Hcnbl-T3HHH Ha 3JieKTpoxnMHwecKyio CToňxocTb flaioT BejiHHHHy 9% Nighttime 20 qacoB Ncm> i-T3HHH npoBbi, nonyqeHHoň TepMHnecKHM HanwneHHeM 6E3 cnoa opraHHnecKorononHMepa 12% nepe3 20 qacoB ηοπμτηηηη flna npoSbi, nonyqeHHoň TepMHnecKHMHanbLneHHeM what cjioeM opraHunecKoro nonHMepa h 9% nepe3 60 uacoB ηοπμτ3ηηη, 85% wepe3 200 nacoB h 480 nacóB ηοπβιτηηηη pjia προ6ω, nonyneHHoň πρκ πομο-mn TOHKOcjioííHoro, njia3MaTpoHHoro ycKopHTenn. flcIH OCbHCHeHHOH BblCOKOH KOPPO3HOHHOH CTO & Ha pne. BHMC-xapaKTepHCTHKa (κοηκηεοτ-BO HMnyjlbCOB 3a eflHHHy ΒΡΟΜΘΗΗ - HHTeHCHBHOCTb - B 3aBHCHMOCTH OT BpeMeHHH3MepeHHfl) npo6bi oTpaxaromnx cnoeB, nonyneHHbix TepMnwecKHM ηθπμπθηηθμ, hHa pne. 3 - BHMC - xapaKTepHCTHKa προδω oTpaáfawipHx cnoeB, nonyqeHHbix πρκnoMomH TOHKOcnoňHoro nna3MaTpoHHoro ycKopuTena. B το BpeMa CSC Ha npo6e, nonyneHHoň TepMHnecKHM HanuneHneM, HaSnronaeTcn ηετκοε pa3fleneHHe cnoeB of anionic mhhhh h THTana (PNE kpHBbie IIa. 2), b CHCl OTpaacaiomHX cnoeB, nonyneHHoňnpH noMOinn TOHKocnoftHoro nna3MaTpoHHoro ycKopHTenn npo6bi, what Hapnny 3 ha-HHTenbHbíM cMeiuaHHeM cnoeB anioMriHHH. n THTaHa Ha6raoflaeTCH 3aMeTHoe H3MeHe-Hne o6enx xapaKTepHCTHK c ποηΒηβΗΗβΜ cennoBHH Ha κρηβμχ (τ.θ, κρηβμθ ημθιοτflByropSyro $ opMy). Kax 3HanHTenbHoe cMemaHne cnoeB, Tax h flBrOcTb kph-Bbix (ceflnoBHH Ha κρηβμχ) HBnHMTcn noKa3aTenbCTBOM oGpaaoBaHHH nepexoflHorocnon, KOPOPHMHbHHlTCH OTBeTCTBeHHblM 3a BblCOKyiO KOppO3HOHHyK) CTOtKKiOO KOppO3HOHHyK) CTOtKKiTO. IIpHMep 2 AHanornnHo npuMepy 1 Ha npo6e H3 $ noTanHoHHoro CTexna b BaxyyMe πρκ pa6o- therein naBneHHH b MIIa 133.32 (aproH) πρκ πομοιιιη TOHKocnoftHoro nna3MaTpoHHoroycKopHTenn nocnenoBaTenbHo b ορ, ηομ npoijecce HaHocnT CHCTeMy oTpaacaionuix cno-MenB eB / THTaH, cocTOHHjyro H3 cnoa Menu tojiihhhoh npn6nH3HTenhHo b 100 ημ η H3'cnoa THTaHa TonmuHoíi npHMepHo b 20 wt. flna cpaBHeHHa b BaxyyMe NPH paSon MflaBneHHH ^ b 2.67 b οη Mila, ηομ pa6oneM nponecce nocnenoBaTenbHo πρκ ποΜοπριTepMHnecKoro HanbineHHa npo6y Ha H3 (JmoTannoHHoro CTexna HaHocaT CHCTeMyoTpajKaromHx cnoeB μθπβ / c τητηη aHanorHHHoň tojiihhhoh cnoeB. 06E προδω noflBepraiOT hciimthhhio Ha sneKTpoxHMHHěcKyio CToiÍKocTb οοοτβθτοτ-BeHHO Ha npHMepy first pole. 1 npeflCTaBneH χορ, προτεκΗΗΗΗ κορρθ3ΗΗ βρθμθηη.y bo »e Night οηηογο NACA Ha TepMHqecKHM rivet HanbineHHoťí npo6e (xpuBan 4) norHBnnioTCH BH3yanbHo pa3nnnaeMbte Ηβφβκτω and npHMepHo nocne 35 nacoB CHCTeMaOTpaacaroiuHx cnoeB προχοπκτ MaxcHMyM kphboh Ha. Ha XapaKTepHbíM one hundred meters npHMepeaBnaeTca Taxace octpmii πηκ h kpyToe naneHHe KpHBo xofla προτβΚΗΗΗΗ κορρο3ΗΗC BblCOKHM MaKCHMyMOM.
Ha npo6e,. Η3ΓοτοΒηβΗΗοίί npH noMomu τοηκοοποϊιηογο nna3MaTpoHHoro yCKopHTe·’·na (KpHBaa 5) nepBbie Ηβφβκτω HaSmoflaioTCH He paHbine neM nepee 150 nacoB.KpaňHe HH3Koe προτβκβΗκε κορρο3ΗΗ xax η ποητη nocToaHHbiň χοη προτθκηηηηbo BpeMeHH 6e3 MaxcHMyMa n;oKa3biBaioT, hto προτεκββτ τοηβκο BecbMa cnaGbiňnponecc KOppO3HH H Mbl ΗΜββΜ fleno c BecbMa BMCOKOKOppO3HOHHOCTOHKOň CHCTe-Moň oTpawaromHx cnoeB. IIpHMep 3. AHanoranHo npHMepy 1 Ha npo6y H3 cbnoTaijHOHHoro cTexna b BaxyyMe πρκ paóo- neM p,aBneHHH b 133,32 Míla (aproH) npn noMoqn TOHKocnoňHoro nna3MaTpoHHoro ycKopHTenn nocnenoBaTenbHo b oahom nponecce HaHocnT CHCTeMy OTpaxtaiomHx cnoeB Menb/onoBo/raTaH, cocTomnyra H3 cnon Meflb/onoSo, τοηπρίΗΟΙί npn6nH3H-Ha npo6e ,. Η3ΓοτοΒηβΗΗοίί NPH prefecture τοηκοοποϊιηογο nna3MaTpoHHoro yCKopHTe · '· on (KpHBaa 5) nepBbie Ηβφβκτω HaSmoflaioTCH He paHbine therein NEP 150 nacoB.KpaňHe HH3Koe προτβκβΗκε κορρο3ΗΗ XAX η ποητη nocToaHHbiň χοη προτθκηηηηbo BpeMeHH 6E3 MaxcHMyMa N oKa3biBaioT, HTO προτεκββτ τοηβκο BecbMa cnaGbiňnponecc KOppO3HH H Mbl ΗΜββΜ fleno c BecbMa BMCOKOKOppO3HOHHOCTOHKOch CHCTe -May oTpawaromHx cnoeB. IIpHMep third AHanoranHo npHMepy 1 Ha H3 npo6y cbnoTaijHOHHoro cTexna b BaxyyMe πρκ paóo- NEM p, b aBneHHH MIIa 133.32 (aproH) npn noMoqn TOHKocnoňHoro nna3MaTpoHHoro ycKopHTenn nocnenoBaTenbHo b oahom nponecce HaHocnT CHCTeMy OTpaxtaiomHx cnoeB MenB / onoBo / raTaH, cocTomnyra H3 cNon = Meflb / onoSo, τοηπρίΗΟΙί npn6nH3H-
TenhHo b 90 hm h cnoa THTaHa, TonmHHoří b 20 hm. 249773 - 5 -TenhHo b 90 wt h cnoa THTaHa, TonmHHorea b 20 wt. 249773 - 5 -
CooTBeTCTBeHHo npHMepy 1 npo6a noflBepraeTCH ηοπμτβηηιο Ha sjíeKTpo-xHMHqec-·KyiO CTOftKOCTh. XOfl ΠρΟΤβΚβΗΗΗ KOPPO3HH BO ΒρβΜβΗΗ npeflCTaBJíeH Ha pHC. 1KSK KpHBaH 6. AHajioruHHafl KpHBaH CHCTeM OTpaacaioiHHx cjioeB ajiioMHHHfí/THTaH η Meflb/THTaH hB ňaHHOM npHMepe AOKa3bIBaiOT HaJIHHHe BbICOKOKOpp03HOHHOCTOÍÍKOň CHCTeMbl OT-paxaioniHx cjioeB. ΦορΜγΧΙβ Η3θ6ρβΤβΗΗΗCooTBeTCTBeHHo npHMepy 1 npo6a noflBepraeTCH ηοπμτβηηιο Ha sjíeKTpo-xHMHqec- · KyiO CTOftKOCTh. XOfl ΠρΟΤβΚβΗΗΗ KOPPO3HH BO ΒρβΜβΗΗ nPeflCTaBJiHH pHC. 1KK KpHBaH 6HHIHHHFlHHHHHHI / THTaH η Meflb / THTaH hBHnHHOM npHMepe AOKa3bIBaiOT HaJIHHHe BbICOKOKOpp03HOHHOCTOOLINE CHCTeMbl OT-paxaioniHx cjioeB. ΦορΜγΧΙβ Η3θ6ρβΤβΗΗΗ
BbicoKOKoppo3HOHHočToiíKaH CHCTeMa OTpajKaiomHx cjioeB Ha cy6cTpaTax, b qacT-hocth, Ha CTeKJie hjih CTeKJionaflo6Hbix cyčcTpaTax, oTJiHnaiomaHCH τβΜ, hto chc-TeMa OTpaxaroniHX cjioee coctoht H3 oTpaxaiomero cjioh h3 sjikimhhhh hjih μθ«ηhjih i|HHKa hjih MeflH h UHHKa hjih MeflH h oji ob a, HaHeceHHoro b BaxyyMHoň nocjie-flOBaTejIBHOCTH ΠΡΗ ΠΟΜΟΠίΗ TOHKOCJIOftHOrO nJia3MaTpOHHOrO yCKOpHTSJIH Η ΤΟΗΚΟΓΟMéTaJIJIHHecKOrO CJIOH H3 THTHHa.BbicoKOKoppo3HOHHočToiíKaH CHCTeMa OTpajKaiomHx cjioeB Ha cy6cTpaTax b Qact-hocth Ha CTeKJie hjih CTeKJionaflo6Hbix cyčcTpaTax, oTJiHnaiomaHCH τβΜ, HTO CHC-topic OTpaxaroniHX cjioee coctoht H3 oTpaxaiomero cjioh h3 sjikimhhhh hjih μθ «ηhjih i | HHKa hjih MeflH h UHHKa hjih MeflH h drawbar ob , HaHeceHHoro b BaxyyMHoň nocjie-flOBaTejIBHOCTH ΠΡΗ ΠΟΜΟΠίΗ TOHKOCJIOftHOrO nJia3MaTpOHHOrO yCKOpHTSJIH Η éMéTaJIJIHHecKOrO CJIOH H3 THTHHa.
AHHOTaUHH Η3θ6ρβΤβΗΗβ KHCaeTCH BbICOKOKOppO3HOHHOCT0ňKOH CHCTeMbl OTpawaiOIUHX CjioeB HacyScTpaTax, b nacTHocTH, Ha cTexjie hjih CTeKJiottofloSHbrx cyScTpaTax. CyScTpa-Tbi, CHa6jKeHHbie CHCTeMoft oTpaacaiomHX cnoeB, npHMeHHioTCH, HanpHMep, Kax 3ep-xajia b Me6ejiBHoií HHflycTpHH, b 6brry, b TpaHcnopTHOM jiene, b HaynHOM πρκβο-pocTpoeHHH hjih Kax nojtynp03paHHbie BepKana. 3aflana Η3θ6ρβΤβΗΗΗ - CO3flaTb BbICOKOKOppO3HOHHOCTOfÍKyi0 CHCTeMy OTpa»aK«UHXcjioeB, coxpaHHH cTeneHB oTpameHHH,AHHOTaUHH Η3θ6ρβΤβΗΗβ KHCaeTCH BbICOKOKOppO3HOHHOCT0ňOKOH CHCTeMbl OTpawaiOIUHX CjioeB HacyScTpaTax, b nacTHocTH, Ha cTexjie hjih CTeKJiottofloSHbrx cyScTpaTax. CHCTeMoft oTpaacaiomHX cnoeB, npHMeHHioTCH, HanpHMep, Kax 3ep-xajia b Me6ejiBHoii HHflycTpHH, b 6brry, b TpaHcnopTHOM jiene, b HaynHOM πρκβο-pocTpoeHHH hjih Kax nojtynp03paHHbie BepKana. 3aflana Η3θ6ρβΤβΗΗΗ - CO3flaTb BbICOKOKOppO3HOHHOCTOFINO CHCTeMy OTpa »UHXcjioeB, coxpaHHH cTeneHB oTpameHHH,
CorjiacHo Η3θ6ρβτβΗΗΚ> CHCTeMa oTpaxaromHx cjioeB coctoht H3 oTpaataiomero cjiohH3 AI hjih Cu hjih Zn, KáK h Cu h Zn hjih Sn, HaHeceHHoro b BaxyyMHoH nocne-HOBaTejibHoCTH πρκ πομοπιη iuiaaMaTpoHHoro TOHKOcjioňHoro ycKopHTejiH,. η tohko-ro cjioh MeTaJUia Ti. ΠρΗ3ΗΒΗθ H3o6peTeHHeM no peayjibTaTaM 3KcnepTH3bi, ocymecTBJíeHHoň BenoMCT-bom no flejiaM Η3οδρβτβΗΗή h naTeHTOB TflP. 2 qepTewa 249773CorjiacHo j3θ6ρβτβΗΗΚ> CHCTeMa oTpaxaromHx cjioeB coctoht H3 oTpaataiomero cjiohH3 Al hjih Cu hjih Zn, khc h Cuh Zn hjih Sn, HaHeceHHoro b BaxyyMHoH nocne-HOBaTejibHoCTH πρκ πομοπιη iuiaaMaTpoHHoro η tohko-ro cjioh MeTaJUia Ti. Π Η 3 3 3 no 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 eno eno eno eno eno eno eno eno eno eno eno eno eno ο ο ο 2 qepTewa 249773
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD23587281A DD216839A3 (en) | 1981-12-17 | 1981-12-17 | HIGHLY CORROSION-RESISTANT REFLECTION LAYER SYSTEM ON SUBSTRATES |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS879382A1 CS879382A1 (en) | 1985-06-13 |
| CS249773B1 true CS249773B1 (en) | 1987-04-16 |
Family
ID=5535508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS828793A CS249773B1 (en) | 1981-12-17 | 1982-12-06 | System of corrosion-resistant reflecting layers on substrates especially on glass |
Country Status (9)
| Country | Link |
|---|---|
| BE (1) | BE895376A (en) |
| BG (1) | BG47853A1 (en) |
| CS (1) | CS249773B1 (en) |
| DD (1) | DD216839A3 (en) |
| DE (1) | DE3244416A1 (en) |
| DK (1) | DK551982A (en) |
| FR (1) | FR2518761B1 (en) |
| GB (1) | GB2112815B (en) |
| SE (1) | SE8207195L (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5931147A (en) * | 1982-08-17 | 1984-02-20 | 株式会社豊田中央研究所 | Visible light transmitting heat ray shielding film and its manufacturing method |
| DE3902596A1 (en) * | 1989-01-28 | 1990-08-02 | Flachglas Ag | METHOD FOR PRODUCING A TEMPERED OR CURVED GLASS DISC WITH COVER ON THE BACK, THEREFORE PRODUCED GLASS DISC AND THE USE THEREOF |
| DE4204763C1 (en) * | 1992-02-18 | 1993-06-03 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung Ev, 8000 Muenchen, De | |
| DE19732978C1 (en) * | 1997-07-31 | 1998-11-19 | Ver Glaswerke Gmbh | Low emissivity layer system especially for glass |
| DE19739046C2 (en) * | 1997-09-05 | 2001-10-25 | Schott Desag Ag | Color-neutral rearview mirror, especially for vehicle mirrors |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE930428C (en) * | 1941-04-11 | 1955-07-14 | Georg Dr Hass | Process for the production of highly reflective, adhesive surface mirrors on a metal base |
| GB842886A (en) * | 1956-03-31 | 1960-07-27 | Heraeus Gmbh W C | Improvements in or relating to heat insulated splinter-proof laminated glass |
| DE2065363A1 (en) * | 1969-07-28 | 1973-04-19 | Gillette Co | Surface treatment of razor blades |
| GB1309881A (en) * | 1970-01-06 | 1973-03-14 | Nippon Sheet Glass Co Ltd | Transparent heat ray reflecting glass and process for manufacturing the same |
| US4046659A (en) * | 1974-05-10 | 1977-09-06 | Airco, Inc. | Method for coating a substrate |
| GB1524393A (en) * | 1976-05-27 | 1978-09-13 | Pilkington Brothers Ltd | Heat-reflecting glass sheets |
| DE3040300A1 (en) * | 1979-10-30 | 1981-05-14 | Mitsubishi Keikinzoku Kokyo K.K., Tokyo | MIRROR AND METHOD FOR PRODUCING THE SAME |
| JPS6047562B2 (en) * | 1980-04-23 | 1985-10-22 | 日産自動車株式会社 | Synthetic resin mirror |
-
1981
- 1981-12-17 DD DD23587281A patent/DD216839A3/en not_active IP Right Cessation
-
1982
- 1982-11-25 BG BG5871182A patent/BG47853A1/en unknown
- 1982-12-01 DE DE19823244416 patent/DE3244416A1/en active Granted
- 1982-12-06 CS CS828793A patent/CS249773B1/en unknown
- 1982-12-08 GB GB08234962A patent/GB2112815B/en not_active Expired
- 1982-12-13 DK DK551982A patent/DK551982A/en not_active Application Discontinuation
- 1982-12-15 FR FR8221033A patent/FR2518761B1/en not_active Expired
- 1982-12-16 BE BE0/209751A patent/BE895376A/en not_active IP Right Cessation
- 1982-12-16 SE SE8207195A patent/SE8207195L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE3244416C2 (en) | 1990-02-15 |
| SE8207195L (en) | 1983-06-18 |
| DD216839A3 (en) | 1984-12-19 |
| DK551982A (en) | 1983-06-18 |
| FR2518761B1 (en) | 1987-01-09 |
| GB2112815A (en) | 1983-07-27 |
| DE3244416A1 (en) | 1983-07-14 |
| BE895376A (en) | 1983-04-15 |
| CS879382A1 (en) | 1985-06-13 |
| FR2518761A1 (en) | 1983-06-24 |
| SE8207195D0 (en) | 1982-12-16 |
| BG47853A1 (en) | 1990-10-15 |
| GB2112815B (en) | 1986-06-18 |
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