CS248287B1 - Method of battery acid preparation - Google Patents

Method of battery acid preparation Download PDF

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Publication number
CS248287B1
CS248287B1 CS832022A CS202283A CS248287B1 CS 248287 B1 CS248287 B1 CS 248287B1 CS 832022 A CS832022 A CS 832022A CS 202283 A CS202283 A CS 202283A CS 248287 B1 CS248287 B1 CS 248287B1
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CS
Czechoslovakia
Prior art keywords
acid
sulfuric acid
distilled water
heat exchanger
acid preparation
Prior art date
Application number
CS832022A
Other languages
Czech (cs)
Other versions
CS202283A1 (en
Inventor
Margit Baltrusch
Erich Gossgebauer
Karl-Peter Guenzel
Eberhard Link
Gerhard Uhlig
Ullrich Kritschill
Original Assignee
Margit Baltrusch
Erich Gossgebauer
Guenzel Karl Peter
Eberhard Link
Gerhard Uhlig
Ullrich Kritschill
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Margit Baltrusch, Erich Gossgebauer, Guenzel Karl Peter, Eberhard Link, Gerhard Uhlig, Ullrich Kritschill filed Critical Margit Baltrusch
Publication of CS202283A1 publication Critical patent/CS202283A1/en
Publication of CS248287B1 publication Critical patent/CS248287B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/69—Sulfur trioxide; Sulfuric acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40—Mixing liquids with liquids; Emulsifying
    • B01F23/49—Mixing systems, i.e. flow charts or diagrams
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/06—Lead-acid accumulators
    • H01M10/08—Selection of materials as electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Secondary Cells (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Description

11

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Hepe3 pacxoflOMep c npeflsapHTeJibHbíM peryjiHTopoM o6beMHoro noTOKa b Tpy6e3 oflHH hjih HecKOJibKo pacxonHo—cMecHTejibHbix cocyflOB 4 3anojiHHi0TCH onpeflejieH--HblM KOJIHneCTBOM flHCTHJTJIHpOBaHHOH BOffbl. 2482.87 3Hepe3 pacxoflOMep c npeflsapHTeJibHbM peryjiHTopoM o6beMHoro noTOKa b Tpy6e3 oflHH hjKOHibKO 4 panojHHi0TCH onpeflejieH - HblM KOJIHneCTBOM flHCTHJTJIHpOBaHHOH BOffbl. 2482.87 3

Ilocjie bxjhohghhh pHpxyjiHUHOHHoro Hacoca 7 προη3βο^ητοβ περεχβΗχε ahcthiijih-poBaHHoň Boflbí ηερεβ τειυιοοβΜεκΗΗχ 6 oÓpaTHo b pacxopHo-CMecHTejibHbiH co-cy« 4.Ilocjie bxjhohghhh pHpxyjiHUHOHHoro Hacoca 7 προη3βο ^ ητοβ περεχβΗχε ahcthiijih-poBaHHoň Boflbí ηερεβ τειυιοοβΜεκΗΗχ 6 oÓpaTHo b pacxopHo-CMecHTejibHbiH co-cy «4.

Ilepefl flOČaBJíeHneM xoHijeHTpHpoBaHHOH cepHoň xhcjiotm 2 κ RHCTHJiJiHpoBaHHoňBone flO3HpyromnM wacocoM 13 κ TenjiooÓMeHHHxy 6 nonacHa 6μτβ no^aHa oxnaxnaio-maa eopa 1. flo6aBjieHHe xoHueHTpHpoBaHHoň cepHoň xhcjiotm npoH3BORHTCH BnjioTb flo flocraace-HHH ΜβΤΧΗ ypOBHH Ha BOflOMepHOH Tpy6xe paCXOflHO-CMeCHTejIbHOrO cocyfla 4. lípufloCTiraceHHH 3ap,aHHoň npeflejibHoň TeMnepaTypu τερΜΟΜετρω ro TennooČMeHHHxa 6 h 3ahhm BbiKnrouaioT 303HpyjomHň Hacoc 13 h 3aKpbiBaioT 3JiaKTpoMarHHTHbiň KJianaH b TpySa2 flJIH HCXJIIOneHHH OÓpaTHOrO ΠΟΤΟΧε flHCTHJIJIHpOBaHHOň BOflbl X KOHIíBHTpupOBaH-Hoň xncjioTe. TaMnepaTypbi cmbch flo TeiuiooBMeHHHxa 6 h nocne Hero (noxa3bi-BaioTcn Ha τερΜΟΜετρεχ 8) mohcho oTperynHpoBaTb Ha onTHManbHbie 3HaneHHH (bm-coxne TBMnapaTypbi pna ycKopeHna TennonepeflanH b τεπηοοβΜθΗΗΗκε 6) nyTeMH3M8H8HHH nOflaHH OXnajKflaKMUeň BOflbl 1 HJIH flo6aBJI8HHH KOHH8HTpHpOBaHHOň khcjio-Tbi jih6o nyTeM HanpaBJíeHHH nacranHoro noToxa nepe3 oSBOflHyio Tpy6y 14. Πο 33ΒερΐΠεΗΗΗ floGaBJíeHHH XOHH8HTpHpOBaHHOň XHCJIOTbl pa36aBJI8HHaH XHCJlOTaflanee napaxanHBaeTCH hscocom 7 po flocTHweHHH HeoĎxoflHMoň TeMnepaTypbi.CorJiaCHO nOXa3aHHHM H3M8PHT8JIH nflOTHOCTH 11 HJIH p83yjIbTaTaM Η3Μ8Ρ8ΗΗΗ ΠΠΟΤ-HOCTH B3HTMX Πρθ6 flO6HBai0TCH HOMHHaJIbHOH njIOTHOCTH CM8CH nyTeM flO6aBJI8HHHXOHIÍ8HTpHpOBaHHOft XHCJIOTbl HJIH flHCTHJIJIHpOBaHHOií BOflbl.Ilepefl flOČaBJíeHneM xoHijeHTpHpoBaHHOH cepHoň xhcjiotm RHCTHJiJiHpoBaHHoňBone 2 κ κ flO3HpyromnM wacocoM 13 TenjiooÓMeHHHxy 6 nonacHa 6μτβ NOx oxnaxnaio Aha-MAA eopa first flo6aBjieHHe xoHueHTpHpoBaHHoň cepHoň xhcjiotm npoH3BORHTCH BnjioTb flocraace flo-HHH ΜβΤΧΗ ypOBHH Ha BOflOMepHOH Tpy6xe paCXOflHO-CMeCHTejIbHOrO cocyfla fourth lípufloCTiraceHHH 3a, aHHoň npeflejibHoň TeMnepaTypu τερΜΟΜετρω ro TennooČMeHHHxa 6h 3ahhm BbiKnrouaioT 303HpyjomHň Hacoc 13h 3aKpbiBaioT 3JiaKTpoMarHHTHbiň KJianaH b TpySa2 flJIH HCXJIIOneHHH OÓpaTHOrO ΠΟΤΟΧε flHCTHJIJIHpOBaHHOň BOflbl KOHIíBHTpupOBaH X-hon xncjioTe. TaMnepaTypbi cmbch flo TeiuiooBMeHHHxa 6h nocne Hero (noxa3bi-BaioTcn Ha τερΜΟΜετρεχ 8) mohcho oTperynHpoBaTb Ha onTHManbHbie 3HaneHHH (BM-coxne TBMnapaTypbi PNA ycKopeHna TennonepeflanH b τεπηοοβΜθΗΗΗκε 6) nyTeMH3M8H8HHH nOflaHH OXnajKflaKMUeň BOflbl 1 HJIH flo6aBJI8HHH KOHH8HTpHpOBaHHOň khcjio-TBI jih6o rivet HanpaBJíeHHH nacranHoro NOTOX nepe3 oSBOflHyio Tpy6y 14th Πο 33ΒερΐΠεΗΗΗ floGaBJíeHHH XOHH8HTpHpOBaHHOň XHCJIOTbl pa36aBJI8HHaH XHCJlOTaflanee napaxanHBaeTCH hscocom 7 after flocTHweHHH HeoĎxoflHMoň TeMnepaTypbi.CorJiaCHO nOXa3aHHHM H3M8PHT8JIH nflOTHOCTH 11 HJIH p83yjIbTaTaM Η3Μ8Ρ8ΗΗΗ ΠΠΟΤ-HOCTH B3HTMX Πρθ6 flO6HBai0TCH HOMHHaJIbHOH njIOTHOCTH CM8CH rivet flO6aBJI8HHHXOHIÍ8HTpHpOBaHHOft XHCJIOTbl HJIH flHCTHJIJIHpOBaHHOií BOflbl.

OopMyna Η3θ6ρετ8ΗΗΗ 1. Cnoco6 fljiH npnroTOBJíeHHH axxyMyjiHTopHoň xhojiotm, b nacTHocTH, flnu cmc-ΠΙΗΒΗΗΗΗ, C8PHOH XHCJIOTbl H flHCTHJIJIHpOBaHHOií BOflbl, ΠρΗΗβΜ npOfleCC CM8HIHBaHHHnpoTexacT c BbifleneHHeM Tenna, OTJiHnaiomaccH τεΜ, ητο CMeniHBaeMbie jkhaxocthπερεβ nOCTynJI8HH8M B paCXOflHO-CMeCHTenbHblň COCyfl (4) nponyexaiOTCH H8P83T8nJIOO6M8HHyW 6aTap8IO (6), Η HTO flO3HpOBaHHOe ΧΟΙΙΗΗεΟΤΒΟ XOHUBHTpHpOBaH-HOÍÍ CCpHOH XHCJIOTbl, flo6aBJIH8MOH HpHMblM BnpbICXOM, H3M8HH8TCH HpH ΠρεΒΜΙΠε-HHH npCflCJIbHOrO 3HaHCHHH TCMnCpaTypbl p8ryjIHpyi0m(HMH TCpMOMCTpaMH (8), CJiy-KamHMH flJIH ΗεπρερΗΒΗΟΓΟ XOHTPOJIH CM8CH H paCnOflOHCeHHblMH flO τειυιοοβΜβΗΗοήCaTapen (6) h 3a hch. 2. Cnoco6 fljia npHroTOBjíGHHH axxyMyjiHTopHOH xhcjioth, corjiacHO nyHKTy 1 ,OTJIHHaiOmHňCH T8M, HTO npOfleCC CMeilIHBaHHH flHCTHJIJIHpOBaHHOň BOflbl H CGpHOňXHCJIOTbl npoTexacT npeflnoHTHTenbHo b flHanaaóHG TeMncpaTyp +20°C .,,+90 C.IIpHJioaccHHc: Φηγ. Ha 1 jihctcOopMyna Η3θ6ρετ8ΗΗΗ first Cnoco6 fljiH npnroTOBJíeHHH axxyMyjiHTopHoň xhojiotm b nacTHocTH, flnu CMC-ΠΙΗΒΗΗΗΗ, C8PHOH XHCJIOTbl H flHCTHJIJIHpOBaHHOií BOflbl, ΠρΗΗβΜ npOfleCC CM8HIHBaHHHnpoTexacT c BbifleneHHeM Tenna OTJiHnaiomaccH τεΜ, ητο CMeniHBaeMbie jkhaxocthπερεβ nOCTynJI8HH8M paCXOflHO B-CMeCHTenbHblň COCyfl (4) nponyexaiOTCH H8P83T8nJIOO6M8HHyW 6aTap8IO ( 6) Η HTO flO3HpOBaHHOe ΧΟΙΙΗΗεΟΤΒΟ XOHUBHTpHpOBaH-hoiii CCpHOH XHCJIOTbl, flo6aBJIH8MOH HpHMblM BnpbICXOM, H3M8HH8TCH HpH ΠρεΒΜΙΠε-HHH npCflCJIbHOrO 3HaHCHHH TCMnCpaTypbl p8ryjIHpyi0m (HMH TCpMOMCTpaMH (8) CJiy-KamHMH flJIH ΗεπρερΗΒΗΟΓΟ XOHTPOJIH CM8CH H paCnOflOHCeHHblMH FLO τειυιοοβΜβΗΗοήCaTapen (6) H 3A HCH 2. Cnoco6 fljia npHroTOBjíGHHH axxyMyjiHTopHOH xhcjioth, corjiacHO nyHKTy 1 OTJIHHaiOmHňCH T8M, HTO npOfleCC CMeilIHBaHHH flHCTHJIJIHpOBaHHOň BOflbl H CGpHOňXHCJIOTbl npoTexacT npeflnoHTHTenbHo flHanaaóHG TeMncpaTyp b + 20 ° C. ,, + 90 C.IIpHJioaccHHc: 1ηγ

AHHOTaflHHAHHOTaflHH

Cnoco6 ΡΠΒ npHrOTOBJIGHHH aXXyMyjIHTOpHOft XHCJIOTbl Μ3θ6ρεΤ8ΗΗε OTHOCHTCH X CM8DIHBΒΗΗΚ) JKHflXOCTeň C JKHflXOCTHMH. H3O6p8TCHHCnpHM8HH8TCH, B HHCTHOCTH, flJIH ΠρΗΓΟΤΟΒϋεΗΗΗ aXXyMyjIHTOpHOň XHCJIOTbl. UGJIb Η3θ6ρετεΗΗΗ 3aXJII0Ha8TCH B CO3flaHHH CnOCOČa, nO3BOJIH10q8ro npHrOTOBJIHTb'B TGHGHHG OTHOCHTCJIbHO ΧΟρΟΤΧΟΓΟ BpGMCHH 6OJIbfflO8 XOJIHH8CTBO axxyMyjiHTopHoňXHCJIOTbl.Cnoco6 ΡΠΒ npHrOTOBJIGHHH aXXyMyjIHTOpHOft XHCJIOTbl Μ3θ6ρεΤ8ΗΗε OTHOCHTCH X CM8DIHBΒΗΗΚ) JKHflXOCTen C JKHflXOCTHMH. H3O6p8TCHHCnpHM8HH8TCH, B HHCTHOCTH, flJIH ΠρΗΓΟΤΟΒϋεΗΗΗ aXXyMyjIHTOpHO XHCJIOTbl. UGJIb Η3θ6ρετεΗΗΗ 3aXJII0Ha8TCH B CO3flaHHH CnOCOČa, nO3BOJIH10q8ro npHrOTOBJIHTb'B TGHGHHG OTHOCHTCJIbHO ΧΟρΟΤΧΟΓΟ BpGMCHH 6OJIbfflO8 XOJIHH8CTBO axxyMyjiHTopNoXHCJIOTbl.

TexHHHecxan 3aflana H3o6pgtghhh coctoht b tom, htoSh coaflan cnocofi h ycTpoň-CTBOflHH CMGDIHBaHHH ΚΟΗΗ8ΗΤρΗρθΒ3ΗΗθβ CGpHOň XHCJIOTbl C flHCTHJIJIHpOBaHHOň BO“ΡθΆ Ρ,Ο flOCTHHCCHHfl HeoSxOflHMOň njIOTHOCTH npH Onp8flGJI8HHOM BbWCJIGHHH TCnjia,a Tax»G c npoMexyTowHMM xphhchhcm totoboíí axxyMyjiHTopHoň xhcjiotm. 248287 4 CMemnBaeMbie jkhakocth προχοαητ nepe3 Tenjioo6MeHHyw OaTapeio w flO3HpoBKaHjSt^ npoH3BOflHTC.H c πομοπ?βη) peryjiMpyiomero TspMOMeTpa. 06naCTb npHMeH6HH3 OrpaHHWHBaeTCH ΠρΗΓΟΤΟΒΠβΗΗβΜ aKKyMyjIBTOpHOÍil KHCJlOTbl. IIpH3HaHO Η3θ6ρβΤΘΗΗβΜ ΠΟ pe3yJIbTaTaM 3KCnepTH3bl, OCymeCTBJíeHHOň BeflOMCTBOMno flenaM H3OÓpeTeHHft η naTeHTOB TOP. 1 nepTeac 248287TexHHHecxan 3aflana H3o6pgtghhh coctoht b that htoSh coaflan cnocofi h ycTpoň-CTBOflHH CMGDIHBaHHH ΚΟΗΗ8ΗΤρΗρθΒ3ΗΗθβ CGpHOň XHCJIOTbl C flHCTHJIJIHpOBaHHOň BO "ΡθΆ Ρ, Ο flOCTHHCCHHfl HeoSxOflHMOň njIOTHOCTH NPH Onp8flGJI8HHOM BbWCJIGHHH TCnjia and Tax» G c npoMexyTowHMM xphhchhcm totoboíí axxyMyjiHTopHoň xhcjiotm. 248287 4 CMemnBaeMbie jkhakocth προχοαητ nepe3 Tenjioo6MeHHyw OaTapeio w flO3HpoBKaHjSt ^ npoH3BOflHTC.H c πομοπ? Βη) peryjiMpyiomero TspMOMeTpa. 06naCTb npHMeH6HH3 OrpaHHWHBaeTCH ΠρΗΓΟΤΟΒΠβΗΗβΜ aKKyMyjIBTOpHOIL KHCJlOTbl. IIpH3HaHO Η3θ6ρβΤΘΗΗβΜ ΠΟ pe3yJIbTaTaM 3KCnepTH3bl, OCymeCTBJ e ň ň ef ef BeflOMCTBOMno flenaM H3OÓpeTeHHft η naTeHTOB TOP. 1 nepTeac 248287

Claims (2)

248 28? pRbdmSt vynálezu248 28? pRbdmSt of the invention 1. Způsob přípravy akumulátorové kyseliny, zvláště míšeníkyseliny sírové a destilované vody, přičemž proces míšeníprobíhá za současného uvolňování tepla, vyznačující setím, Že se míšené kapaliny před přivedením do průtokovémísící nádoby vedou přes výměník tepla, a že dávkovanémnožství koncentrované kyseliny sírové, přiváděné přímýmvstřikováním, se mění při překročení hodnoty limitní tep-loty regulačními teploměry, které jsou určeny pro nepřetr-žitou kontrolu směsi, a jsou umístěny ve výměníku tepla a za ním.CLAIMS 1. A process for the preparation of accumulator acid, in particular sulfuric acid and distilled water, wherein the mixing process is carried out with the simultaneous release of heat, wherein the mixed liquids are passed through a heat exchanger prior to introduction into the flow vessel and that the amount of concentrated sulfuric acid fed by direct injection is it changes when the limit temperature is exceeded by the control thermometers that are intended for continuous monitoring of the mixture and are placed in and behind the heat exchanger. 2. Způsob přípravy akumulátorové kyseliny podle bodu 1, vyzna-čující se tím, že proces míšení destilované vody a kyselinysírové probíhá zejména v rozmezí teplot 20 °C až 90 °C.2. A process for preparing the battery acid according to claim 1, wherein the process of mixing distilled water and acid sulfuric acid takes place in particular at a temperature range of 20 ° C to 90 ° C.
CS832022A 1982-04-08 1983-03-24 Method of battery acid preparation CS248287B1 (en)

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DD82238929A DD220485A3 (en) 1982-04-08 1982-04-08 METHOD FOR PRODUCING BATTERY ACID

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CS248287B1 true CS248287B1 (en) 1987-02-12

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DE (1) DE3310119A1 (en)
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DE4118961C2 (en) * 1991-06-08 1995-09-28 Kodak Ag Method and device for supplying additional liquid, in particular additives to a photographic treatment liquid

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD111624A3 (en) * 1972-11-03 1975-03-12
SE422007B (en) * 1976-07-02 1982-02-15 Nordiska Ackumulator Fabriker DEVICE FOR PREPARING A MIXTURE OF SULFURIC ACID AND WATER

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DE3310119A1 (en) 1983-10-20
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DE3310119C2 (en) 1990-04-26
HU189258B (en) 1986-06-30

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