CS233336B1 - Stabilizing method of optical systems' binders and adhesives on base of epoxy resins of esters of metacrylic or of polyester resins ans their mixtures with vinyl monomers against efects of short-term radiation and heat shocking treatment - Google Patents
Stabilizing method of optical systems' binders and adhesives on base of epoxy resins of esters of metacrylic or of polyester resins ans their mixtures with vinyl monomers against efects of short-term radiation and heat shocking treatment Download PDFInfo
- Publication number
- CS233336B1 CS233336B1 CS813373A CS337381A CS233336B1 CS 233336 B1 CS233336 B1 CS 233336B1 CS 813373 A CS813373 A CS 813373A CS 337381 A CS337381 A CS 337381A CS 233336 B1 CS233336 B1 CS 233336B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- adhesives
- mixtures
- optical systems
- binders
- vinyl monomers
- Prior art date
Links
- 239000011230 binding agent Substances 0.000 title claims 6
- 239000000203 mixture Substances 0.000 title claims 3
- 239000000178 monomer Substances 0.000 title claims 3
- 239000000853 adhesive Substances 0.000 title claims 2
- 230000001070 adhesive effect Effects 0.000 title claims 2
- 239000003822 epoxy resin Substances 0.000 title claims 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 title claims 2
- 238000000034 method Methods 0.000 title claims 2
- 230000003287 optical effect Effects 0.000 title claims 2
- 229920000647 polyepoxide Polymers 0.000 title claims 2
- 229920001225 polyester resin Polymers 0.000 title claims 2
- 239000004645 polyester resin Substances 0.000 title claims 2
- 230000005855 radiation Effects 0.000 title claims 2
- 230000000087 stabilizing effect Effects 0.000 title claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims 2
- 229920002554 vinyl polymer Polymers 0.000 title claims 2
- 150000002148 esters Chemical class 0.000 title 1
- 125000000007 metacrylic acid group Chemical group 0.000 title 1
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims 3
- 241001446467 Mama Species 0.000 claims 1
- 235000019445 benzyl alcohol Nutrition 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 238000000265 homogenisation Methods 0.000 claims 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 241001553014 Myrsine salicina Species 0.000 description 2
- NKRVGWFEFKCZAP-UHFFFAOYSA-N 2-ethylhexyl nitrate Chemical compound CCCCC(CC)CO[N+]([O-])=O NKRVGWFEFKCZAP-UHFFFAOYSA-N 0.000 description 1
- 101100059139 Bacillus subtilis (strain 168) carB gene Proteins 0.000 description 1
- 235000017399 Caesalpinia tinctoria Nutrition 0.000 description 1
- 229910018979 CoPt Inorganic materials 0.000 description 1
- 241001669680 Dormitator maculatus Species 0.000 description 1
- 101100352023 Synechocystis sp. (strain PCC 6701) cpeB gene Proteins 0.000 description 1
- 241000375392 Tana Species 0.000 description 1
- 241000388430 Tara Species 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- HESCAJZNRMSMJG-HGYUPSKWSA-N epothilone A Natural products O=C1[C@H](C)[C@H](O)[C@H](C)CCC[C@H]2O[C@H]2C[C@@H](/C(=C\c2nc(C)sc2)/C)OC(=O)C[C@H](O)C1(C)C HESCAJZNRMSMJG-HGYUPSKWSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
- C08L2666/34—Oxygen-containing compounds, including ammonium and metal salts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Description
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UeJiL HacTOíánero z3odpeTeH2H coctoht b cnocode no CTsdHAH—saiUíK οπτηήθοκηχ καθκακχ MaTepnajioB h CKJieeK κοκ προτκΒBOSAeficTBKH κοροτκΟΒΟΛΗΟΒΟΓο H3AyqeK2H, tok a , Hanprazep,ΠρΟΤΗΒ raMMa-íUI2 ρβΗΤΓβΗΟΒΟΚΟΓΟ 23ΛγΉΘΗΗΗ, a Tanae ΠρΟΤΗΒoópaóoTKK TeMiiepaTypHHM uiokom. Πριι θτομ Apyrne OKCiuiyaTa-UKOHKae cBoficTBa, KaK HanpHMep, K23HecnocodHOCTB, ycAOBnaoTBepAesanM, BpeMeHHan xapaKTepKGTKKa b23kocth, pacTBopn-moctl KJieíomero οοθαηηθηηη h $23HOJiorHnecK2e οβο2οτββ Taxne,ÓTcyrcTBíie MexaHnnecKHX 2 οπτΗΗβοκΗΧ HanpHxeHirií, cneKTpaAB-Hoe nponycKaHBe z κλημοτζηθοκοη ycTofínzBOCTB He aojlkhh npe-TepneBaTL OTpznaTeABHoro bazhhhh. 3tzm aojekhh odecnenHBaTB-ch CKJieÉKH hjih Aep^aHze οιιτζηθοκζχ 3JieMeKT0B 2 οποτθμ cHaHJiy2III2M2 230Ópa?KaiOIHHMH CBOSCTBaMZ np2 BLWepmíBaHH2 T02H0C·τη noBepxHocTH I KOJima ajih Bcex οοοτηοιπθη23 cepeA2HH0ŽT0JHH2HH κ ΛΗΟΜβτργ 1:15.
H3JI0KeH2e'. C,VH1HOCT2 HSOdpeTeHHH
CoiviacHo nocTaBJíeHHoS penz sahana HacTonmero 23odpeTeHZ2coctoht b pa3padoTKe cnocoda, c πομοιπβιο κοτοροΓΟ Ó&3 αοποα-ΗΗΤβηΒΗΗΧ ΤΘΧΗΟΑΟΓΖΗΘΟΚΗΧ 3aTpaT 2 ΑΘΓΚΟ AOCTyTIHHMZ CpeA“ΟΤΒΗΜΖ ÓyHeT B03M0JKH0 00Θ0ΠΘΗ2ΤΒ yCTOfiHZBOCTL· ΟΠΤΖΗβΟΚΖΧKnengzx MaTepnaAOB 2 czneeK Ha pa3nznHo3 ochobc οτΗοοπτεηΒ-HO B03A62CTB22 ΓΗΜΜΟ—ΚΑΖ ρθΗΤΓΘΗΟΒΟΚΟΓΟ H3JiyneHK2 C A0302ao 5 . IO^G-y /ao 5 · 10 rJ /. K 3aAaHino othocztch TazxeOAHOBpeMeHHO CTaÓHAH3ZpOBaH2e ΟΚΑβδΚΗ ΟΤΗΟΟΖΤβΑΒΗΟ pKeCTO-hchhoSí odpaóOTKZ, TeMnepaTypraai uiokom ποορθαοτβομ, no Kpa3-Heft Mepe, 5~TZKpaTHo3 CMeHU TeMnepaTypu c -40°C Ha +55°CC 2~HaC0BHM.ΟΜΘΗΗΗΜ ΡΖΚΑΟΜ. 3631
HpH 3T0M £OJDKHH COXpaHHTBCH ΟΠρΒΒΑΗΒΠΙΖβ· CedH CZCTeMH ΜΗΤθ-pzaJiOB ajih οπτζπβοκζχ KJiennzx BemecTB, a xpyrze CBoficTBa znapaweTpH ne aojixhn noABepraTBCH oTpzpaTejiBHOMy bjizhhiw.CoiviacHO K3odpeTemw 3Ta ueJiB AOCTzraeTCH c iiomoiw cnoco-<5a no cTadzJiH3aipiK οπτζΗβοκζχ KJierapxx MaTepzajioB z cmíeeKHa OCHOBe 3H0KCZAHUX CMOJI, CJIO3KHHX θφζρΟΒ MCTZJiaKpZJIOBOlíKZCJIOTH OH H0JIZ3$ZpHHX CMOJI Η ZX ΟΟβΑΖΗΘΗΖΚ C BZHZJIOBHMZMOHOMepaMZ OT B03B.6ÍÍCTB2H KOpOTKOBOJIHOBOrO Z3JiyaeHZH Z OTodpadoTKZ TeMnepaTypHHM ihokom AodaBJíeHzeM cTadHJiZ3aTopa,OTjnnaioinerocH τθμ, hto k zcxoahož CMecz nocjie roMoreHZsa-miH MOHOMepHiix KOMnoHeHTOB KJieonero MaTepzajia z ao npzdaB-ji6hzh oTBepAZTejiH miz paAZKajiBHoro CBH3yiomero/cKCTeMií yczo-pzTejieň AodaBJíaeTCH b KaaecTBe CTadzJiZ3aTopa óeH3ZJiOBKÍí ·"οπζρτ b KOJiznecTBe οτ I ao 10 BecoBHX προηβΗτοΒ b paczeTeHa odmee KOJizzecTBO hcxoahoS CMecz mieioinero MaTepzaJia.
TaKoe penieHze corJiacHO Z3odpeTeHzio hbjlhotch HeoszAaHHHM,
Taž Kan b oTJizzze οτ HacTOzqero Z3odpeTeHza deH3iuioBKz οπκρτdHJI H3B6CT6H JIZHIB ΚΗΚ ΗθρβΒΚΤΗΒΗΒΗ pa3daBZTeJIBHafl Z paCT-BOpZTCJIBHaH npZMeCB .AJIH ΤΟΓΟ, HTOdtl yMeHBHIZTL BH3K0CTB OT—BepfleBWKX cweceií cmoji η πρζαβτβ οτΒβρΑβΒπιζΜ npoAyzTaM aoc-TaTOHHyra MexaHzaecKyx) ynpyrocTB /BHKJiaAHoe onzcazze Z3odpe-ΤΘΗΖΗ K AO3KCnepTZ3HOÍÍ 3βΗΒΚΘ ΦΡΓ - 2460690/. KpOMe ΤΟΓΟ, 3TO ΠρΖΜβΗΘΗΗβ OrpaHZHZBaJIOCB A O CHX ΠΟρ JIZHIB CZCTeMaMHanoKczuHHX cmoji. npzMeHeHze οπτζζβοκζχ KJie»mzx MaTepzajioB corJiacHO H3odpeTe-HZK) AaeT B03M0JKH0CTB AOCTZHB CTadZJIZ3aiTZZ CKJiefíKZ HJIZ Aep-khhzh onTznecKZX AeTaJiefi, κοτορκβ noABepraioTCH £ose z3Jiy-H6HZH 5*I04^y ./no δΊΟθΓί)/ z, no KpaifoieS wepe, 5~KpaTHOiíodpadoTKe TeMnepaTypHHM idokom c -40°C Ha +55°G c 2-zacOBHMCMeHHHM nZKJIOM*
JlaiKe Ha οηθηβ zyBCTBZTejiBHHX οπτζηβοκζχ ACTaJLzx c tohhoctbioodpadoTKZ noBepxHoeiz ál KOJima z c οοοτηοιπθηκθμ. cepeAZH-hoíí tojiihzhu K AzaMeTpy, HazzHaz c 1:15, He B03HZKai0T npz '3tom HanpwKeHza, KOTopue-npesmnaioT omzdny Z3MepeHZH ΖΗτβρ—$epoMeTpa MazKejiBcoHa 0,2 KOJima Ηβκτοηβ. 3631
HpH 3T0M pa3J!ITCKH ΚΟθφφϊΠΧΠθΗΤΟΒ paCIHHp6HKH CKJieeHHUX ΛΘΤ&-jiežt MoryT οοοτββοιητβ = 6 · ΙΟ”6. IIpKÓaBJíemie óeH3iuio-Boro cnnpTa npKBOflHT, κροΜβ τογο, κ 3Ha^KTejiLHOMy yMeHLine-HIOT nOTepL nponyCEaHHfl B .BIíHHMOfi OÓJiaCTH, B03HHKaromHX πρκoÓJiyaeHBK raMMa-mra peHTreHOBCKHMH JiyaaMH ηθ b οοοτβθτοτ-BHH C Η300ρβΤ6ΗΖ6Μ CTaÓHJIH3HpOBaHHiIX ΟΠΤΗΉβΟΚΗΧ KJieWLX Ma·TepnaJioB hjiíí CK7ieeKe .
JlajiLHeftuiHM npexMynecTBOM ηβληθτοη to, hto bO3MOžchocthOTBepAeBaHUH οπτκΉβοκηχ KJieroiuHX MaTepnajioB. πρκ κομηβτηοζTewnepaType, npn noBHineHHofi TeMnepaType íltih ÓJiaroAapa khh-íumpoBaHíTO ΥΦ-οβθτομ H6 yxyniiiaioTCH· OTBepseBnme KJieKwieBSLqecTBa b 3Ββηοεμοοτζ ot ochobu BeqecTBa π pejien npuMeHe-KKH paCTBOpEMH B BHtípaHHHX OpraHHHeCKHX paCTBOpHTeJIBX HJIHTepMjraecKHM nyTěM. ΠρΚΜθρυ ΒΗΠΟΙΕΗβΗΗΗ
Hirae Ha npHMepax BHnojiHeHHH h TatíJinnax I h 2 ποηοηηθτοηH30ÓpeTeHnee '
JIpHwep I 47,65 βθοοβηχ nacTež ^Hannnr^imnnHoro a$iipa /co^epjsaHHeSnOKCIíUHOrO .KHCJIOpOAa = 91 ΜΓ/γ / CMeUBEBaiOTCH B 3a£aH-Hoň nocoie^oBaTejiLHOCTH c 28,59 βθοοβημη nacTHMH φΘΗίυι-ΓΛΗΏΧΖξΟΒΟΓΟ 3<Ť>Kpa H C 6 ΒΘΟΟΒΗΜΗ HaCTHMH tíeH3ZJIOBOrO ΟΠΗρ-Ta Tan, Ήτο nepe;n .notíaBJíeHHeM cjie^yiomefí κομποηθητη otípa3y-βτοΗ roMorenHaa ομθοβ* Hocvie. τογο, khk 3Ta ηοχοαηθη CMecBCMeinHBaeTCH c 23,76 βθοοβημη nacTHMH H -HHKJioreKczjinponn-JieHniíaMHHa -1,3 b xanecTBe οτβθραητθλη, nojiynaeTCH γοτοβη2k yiioTpeÓJieHjro onTHHecKsfi KreiomuS: MaTepnaJi c HanaJiBHoftBH3K0CTBS HpHMepHO 100 CP ΠρΗ 20°C, KOTOpaH B ΤΟΉΘΗΗΘ5,5-qacoBofí sH3HecnocotíHocTH no^HKMaeTCH npx κομηητηοΚ TeM-nepaType ΛΟ 8000 - 10000 cP. 3631 C noMoniLK) 3Τ0Γ0 miejonjero MaTepnsuia cimeicBSJOTCH ujiockh© iuiac·ΤΚΗΚΙΪ ΛΙί3ΜΘΤρθΜ SO MM H TOJHIIZHOÍÍ 2 MM /COpT CTGKJia EK 7/ C miOCKKMiil IUiaCTHHKaMH ΑΗΒΜβΤρΟΜ SO MM H TOJimEHOň 10 MM/οορτ cTemia ΦΚ 6/ no Z3BecTHOMy MeTOfly, npineM tohhoctbodpadoTKZ noBepxHOCTH b HecKJieeHHOM coctohhku cocTaBJíaeTOT 0 ÍO I KOJILUSo ΟΤΒθρΑθΒΒΗΗβ ΠρΟΖΟΧΟ,Π,ΗΤ B ΤβΗβΗΗΘ 3 JWŘπρπ KOMHaTHofí TeMnepaTypeo Hocjie τογο, Kaz cHaaajia H3Mepa-eTca norpeiiiHocTB noBepxHocTH napu hjiockbx miacTHH β ηθοκ-jieeHHOM coctohhkh c noMOfliBio zHTep$epoMeTpa MaáKejibcoHa cTOHHOCTLKD £0 0,2 KHTepŽepeHHZOHHHX KOJILpa, tbkos ii3MepeHne.noBTopaeTcn b cicieeHHOM n oTsepneBmeM coctohhhz. KajiLHeft-mee H3MepeHiie hpoíí3boaiitch nocjre 5-pa3OBoň ομθηη TewnepaTy-pn c “40°C Ha +55°G khhphíí pas b TeaeHHe 2 aacoB z nocjie-AyiOÍUero TeMnepnpoBaHHH τθηημ odpa3OM odpadoTaHHHX cmíeen-hhx nap miacTHH a o κομηβτηο3 TewnepaTypH.
Pe3yjiBTHTH, noJiyneHHHe Z3 cpaBHSHHH τβκηχ ΖΗΤΘρφθροΜβτρη-necKKX H3MepeHH0 cJiyxaT Mepofi CTadzjiBHOCTíi Kaeromero Beme-CTBa oTHoczTeJiBHO otípaóoTKH TeMnepaTypHHM kokom. Ohii npe-ACTaBJíeHH b TadJiime I.
Ilpna/iep 2 ΟπτζΉβοκζζ KJieiomzfi MáTepnaJi npnroTaBJíHeTCH corjiacHo npHMe- py jhhhb coAepjKaHHe deH3ZJiOBoro. cnzpTa noBumaeTca ^o 10
BecoBHX HacTefte Bce ocTajiBHue ycjioBHH MeTo.ua η ηοολθαοββηηηno^odHH τθμ, KOTopne onxcaHH b npHMepe I. PesyjiBTara zHTep-φθροΜθτρζΊθοκκχ Z3MepeHzfi ouizdzz noBepxHocTH npzBe^eHH bTadJimze I. IIpzMep 3 59,33 BecoBHX aacTefi jizaH^zr^zmmHoro 3<T>zpa /cojiep&aHHe. .BnoKczuKoro xzcjiopoAa = 91,3 μγ/γ / CMeniZBaioTCH c 2,5 Be—cobhmh hhcthmz deH3HJioBoro cnzpTa Taz, Kaz onzcano b npmze-pa I. 3631 - ΙΟ - Κ θτοδ zcxouhoS cMecz npzdaBJUWTCZ 40,67 βθοοβηχ zacTeií|\|, N‘ AzdeH3HJi3TZJieH£zaMKHa b zazecTBe OTBepazTeJiz. 3τβ, roTOBaa z ynoTpedJieHzio CMecB onTzaeczoro zzenueroBemecTBa oÓJiajxaeT HaaaJiBHoň bh3Koctbío 200 cP lípu 20°C,B03pacTaiomeá b τθζθηζθ 5,5-zacoBo2 jKZ3HecnocodHOCTZ xo10000 cP. OTBepneBaHxe ocymecTBJízeTCH b TeaeHze 3 AHeítřípu KOMHaraoři TeMnepaType.
CzxeiiKa z zccjieAOBaHze omzdzz noBepxHOCTH naocxzx iuiac-thh, a Tazze zHTep$epoMeTpzzeczoe zccjienoBazze CTadzjiBHO-CTZ ΟΤΗΟΟΖΤβΛΒΗΟ OdpadOTZZ TSMUSpaTypHHM UIOZOM Πρ0Ζ3Β0ΑΖΤ-ca Tax, zaz onzcano b npzMepe I. Pe3yjiBTara npeACTaBaeHHb Tadazne I. ΠρΖΜΘΡ 4 B cocTaBe corjiacHO npxwepy 3 coaep&aHze. <5θη30οβογο cnzp-Ta noBumaeTC}! λο 5· βθοοβηχ zacTeft. «HajiBHezmze ycaosza npc-uecca boaočhh τθμ, κοτορυβ οπχοηββλζοβ b npzMepe- 3.
Cnocoó npOBPHeHZH CKJieiIBaHHH Η ΗΗΤθρφβρΟΜΘΤρΖΖβΟΖΚΧ KCCJie-Λοββηζ2 cJieAyeT 3azMCTB0BaTB Z3 npzMepa I /pe3yjiBTara cpaBH. Tadjuma· 1/. « IIpzMep 5 60 βθοοβηχ zacTefi caosHoro noazsózpa /moji. Bec 1200; 'KzcJioTHoe zzcjio = 30/, ζβγοτοβλθηηογο 03 θζβζβθλθητηογοKOJizaecTBa TeTparzzpcžTaaeBofí zzcjioth z 1,3-óyTaipizojia -CMemzBaioTCH c 26,67 Bec» zacTHMz MeTHJiMeTaKpzjiaTa, c 13,33Bec. aacTZMZ CTzpeHa z c 10 Bec. zacTHMz óeH3Z7ioBoro cnzp-Ta Taz,. zaz yza3HBajiocL b npzMepe I. K stož zcxouhoíí cMe-cz floóaBJEHJizcB 3 Bec. zacTH nacTH Z3 nepezzcz iizzaorezca-HOHa /50% b zzóyTZJiŽTajiaTe/ z 1,5 Bec. aacTz zod.ozToaTHoroyczopHKiqero pacTBopa /cTzpeHOBHZ pacTsop, I%- cozep^anzeweTajuia/ z roMoreHZ3zpoBajizci>. 3τοτ totobzíí z ynoTpedze-hzh) zaeroiyzS MaTepzaJi odaapaeT HaaaaBHoíí bh3koctlk> okojio200 cP npz 20°C, BO3pacTaxineS b τθηθηηθ 4-aac030ií .zzsHecno-codHocTZ ao 8000 cP. 3631
II OTBepneBamie ηρθΛθΛΣ-aeTca b τθηθηηθ 21 αηή ηρζ κομηητ-Hoft TeMnepaType. KccjieAOBaHHe οιπηόκη noBepxHOCTn cKJie-emmx ujiockmx πλβοτπηοκ h ycTonmiBOCTíi οτηοοκτθλβηο od-patíoTKH TewnepaTypHHM uiokom CKneeHHHX coe^HHeHnn npoii3-boahtch TaMe, KaK h b npnwepe I. Pe3yjn>TaTH Bi-wm h3TaóJitfi$[ I.
Ilpmiep 6 60 BecoBtix ,nacTe& nojmsčjtopnjiacTa (moji. Bec. - 1100; kíic-ΛΟΊΉΟΘ HXCJI0 = 30) , K3r0T0BJieHHHX K3 θΚΒΚΒΒΛΘΗΤΗΟΓΟ KO—xHaecTBa TeTpar^npo$TajieBo3 kkcjioth n dyTaHAKona-1,3, cwe-uixBaioTca c 30 βθοοβημχ nacTBMH MeTiiJiMeTaKpiuiaTa, 10 Bec.HacTBMK BiiHiiJiaueTaTa a 5 Bec. HacTBMn deH3n;ioBoro cnnpTaTaK, KaK ynasaHO b npnwepe I, h roMorennsnpyioTCH. 3Taíicxo£Haa cwecB cMeinxBaeTca 3aTew c 2 βθοοβεμβ nacTHMHóeH3OMH-MeTHaoBoro 3$npa, 2 Bec. nacTHMH nepeKHcii deH3on-jia a 0,2 Bec. aac. γηλροχβηοηοβογο μοηομθτμοεογο sčnpa bKaaecTBe cncTeMn OTBepnemw. 3τοτ γοτοβηκ k ynoTpetíaeHimKJieioíUHS waTepnaJi odJia^aeT HanajiBHoň bb3koctbio 200 cP npn20°C. Peawia OTBepseBanaa KHimiuipyeTCH nyTew '3-μβηυτηογοy$-odayaemiH ropejiKoft Tnna P 180 n noejie 3-He£ejn>Horo xpa-ηθηηβ cKJieeHHHX aacTe& πρη κομηβτηο2 TeMnepaType 3aBepuiaeT-ca. HccJie^oBaHiie ouindKH ποΒβρχΗοοτη cKneeHHnx idiockxx ruiac-thhoík h odpadoTKa TewnepaTypHHM uiokom cimeeK npon3BOAHTcaTarae, KaK n b npiiMepe I (pe3yjii>TaTH cpaB. Tadjinna I). B Tadanne I ^aeTca od3op pe3yjn>TaT0B Κ3ΜθρβΗΚΗ coraacHOE3odpeTemno CTadnjiH3npoBaHHiix οπτηηβοκηχ KJieKxipix raTepna-λοβ no npnwepaM 1-6. Jpia toto, HTodu οτηβτηκΒββ ποηήτβ3Hanemie CTadrninsano corjiacHO κ3θόρβτβΗίΐιο b Tad/nme I λληcpaBHemw npnBejieHH -pe3ynBTaTU H3wepeHíiH K3BecTHHx HecTadn-jiK3iip0BaHHhix οπτηηθοκηχ κήθκχιρϊχ iwa Tepna ji ob ηήπ CKJieeK. < Upn-wepn ajih cpaBHemie οτληήήιοτοή ot npjw.epoB βειποληθηκή τθμ,ητο orní b KanecTBe cTadiwmaTopa He cojxepxaT deH3KJioBoroemipTa. 3631 12 ΠρΚΜθρΗ ΒΗΠΟΗΗΘΗΗΗ I Η 2 MOSHO ΟρΗΒΗΗΒΗΤΒ C ΠρΗΙ/epOM &7IHcpaBHeHHH A /B3HT0 H3 θκοηομηήθοκογο πητθητβ ΓΛΡ 131825/,ηκη Hcxonnan cMecL KJieionpíX semecTB coctoht H3 47,65 sec. .vacTefi sHaH£HTJiKWtHoro 3$npa /conepsaHHe οποκοκ^ηογο khc-jiopoAa 91 μγ/γ /, H3 28,59 Bec. nacTeft φβκΗΗΓΛΗΐΐΗΛΟΒΟΓΟ3$zpa, H3 5 Bec. nacTeSi opo$ena A 60 /nonHranoreHHpoBaHHHÍiΛΗφβΗΐυι φκρΜΗ η/π "OpÓHTaiuiacT BecTeperejiH"/ κ H3 23,76 Bec.nacTeií N ~ UHKJioreKCiui$eHHJieH£HaMiiHa -1,3. AHaJIOniHHHM ΠγΤβΜ CpaBHHMH ΠρΚΜβρΗ ΒΗΠΟΗΗθΗΗΗ 3 Η 4 C ΠρίΙ-wepoM cpaBHeHHH B /cornacHo βκοηομηήθοκογο naTeHTa Γ/1.Ρ135623/, a npHMep βηποηηθηηη 5 cpaBHHM c npHMepoM cpaBHeHHHC /corJiacno aKOHOMKaecKoro naTeHTa ΓΑΡ CO 9J/2IS339 /.ΠρΗΜερ cpaBHeHHH JI HMeeT 3a ηοκηηηθηκθμ conépsaHHH óeH3HJio-βογο cimpTa Taxofí se cocTaB, KaK h, cornacno H30ÓpeTeHiro,
I npHMep ΒΗΗΟΗΗβΗΗΗ 6. B TaÓJIHIie B ΚΒΗΘΟΤΒβ OCHOBH ΛΗΗ H3Me—peHHH H cpaBHeHHH CJiysaT Η3ΜβΗΘΗΗΗ O1UHÓKH nOBepXHOCTH, BO3-HHKffiHe H3-3a GKJieHBHHHH H OÓpaÓOTKH TeMnepaTypHHM IIIOKOM, KO-Topae H3MepHioTCH c πομοιιιβιο ΗΗΤθρφθροΜβτρα MaíucenBcoHa Ha no-BepXHOCTH IUIOCKHX IUiaCTKH H3 BK-7 /cpaBH. npHMep 1/ c TOJI—uihhoS = 2 mm KaK hhcjio ηητθρΦθρθηιιηοηηηχ KOJieií nepen CKJien-BaHHeM, nocne οκηθηββηηη h oTBepueBaHHH h nocne oópaóoTKHTeMIiepaTypHHM hjokom. B HHTepecax nonyneHHH χοροηκχ cpenHnx 3HaneHHS H3MepeHHH,npoBOUHMue KaxnHŽ pa3 Ha 5 οπητηηχ napax nnacTHH τβκηχ, KaKyKa3aHo b npiiMepe I b HecKneeHHOM /1/, b CKnesHHOM h OTBep—jieBiiieM coctohhhh /2/ h nocne oópaóoTKH TeMIiepaTypHHM iuokom/3/ cyMMHpyioTCH. Me?xny /1/,/2/ h /3/ BunHcnneTCH pa3HOCTB.nonyneHHHe τβκημ oópa3OM 3HaneHHH ΗΗΤβρφβρβκίζΗΟΗΗΗΧ κοηβπHBJLHK3TCH MepOH CTaÓHHBHOCTH ΟΠΤΗΗΘΟΚΗΧ KJieiOIUHX BeqeCTB ÍMHCKJieeK οτΗοοπτβηΒΗΟ oópaóoTKH TeMnepaTypHHM iiiokom /cpaBH.noHCHeHHH b Taón. 1/. yMeHLineHHe hhchobhx 3HaneHHS b npHMepax-ΒΗποηΗβΗΗΗ οτ I no6, CTaÓHJiH3Hp0BaHHHX cornacno H30ÓpeTeHHH, no cpaBHeHHK) cnpHwepaMH cpaHeHHH A,B, C, Λ οτηθτπηβο neMOHCTpnpyeT hoctht-HyTHH 3φφβΚΤ CTaÓHJIH3aUHH. 3631 13 ΛΛΗ ΤΟΓΟ, HTOÓH HCCJieAOBaTL ΒΛΗΗΗΗ&· ΑΟόΒΒΑΘΚΗΗ ÓeH3IUIOBOrOcnnpTa Ha cneKTpajiBHyio nponycKaewocTL· οπτεήθοκηχ KJiewKsemecTB ao h nocjie B03£eíícTBHH raMMa-on peHireKOBCKorooóJiyaeKKH, BHAO^eHHHe τθΦαοηομ οτθκληηηηθ KOJima /AKaweTp35 mm/ 3ajuiBaK)TCH οπτκήθοκημη wieraim MaTepnajiaMH, γοτο-bhmh κ ynoTpetíJieKiao, xaK onKCHBajiocL b npwepax βηιίοληθηηηI H 2. ΟΤΒβρΑθΒΗΗΗΘ npOHCXOAHT ΠρΗ KOMHHTHOfí TeMHepaTypeHa pTyTHOM 3epKane aah toto, htoóh coxpaHETB ^opwoEaHHoeH3AeJiiie H3 KJieiOLqero MaTepnana c iuiockhmh noBepxHOCTHrzií.To-WíHa cjioh TaKoro čopwoBaHHoro H3Ae^nH cocTasJíneT 4,3 mm.K3MepeHne nponycKaHKLH προκ3ΒθΑκτοη 4 Hejxejin nocjie OTsepAe-BaHHH lípu npHMeHeHHZ CBeTa C jyUíHQŽ B O JIHLI Jí = 589 HM, HC-nojiB3yff npa 3tom cepeAHHy čopMOBaHHoro hspeJiiia, htoóh hc-KJDOHHTL cnan Ha KpaX) BCJieACTBHe 0Ópa30BaHHH MeHHCKa. 9toE3MepeHHe ποΒΤορηβτοη nepe3 48 nacoB nocue oÓAyqeHHH c ao~sofí ao 5 · I04£-y.
KpOMe yxe onzcaHHHX npuMepoB I h 2 ohh nccjieAyioTCH TaxHMjse nyrew b oiuíchhhhx ηεκθ npHMepax βηποαηθηκη 7 η 8. IIpHMep 7
61,37 Bec. -qacTH α^ηηαηγαηιχιϊαοβογο 3<Sapa /coAsp^anae 3ποκ-ckahobo KHCJiopoAa = 91 μγ/γ / CMemzBaEjTCH thk, Kan sto onn~caHO b npnMepe I,e 1.5^35’.ΒθσκΤ.:.· Φθηκαγακιχκαοβογο spxpa h ca/ 2 Bec. qaeTHMH óeH3KJI0B0r0 CHEpTa HAH
tí/ 5 ΒΘΟφ HaCTHMH ÓeH3EJI0B0r0 CnHpTa EJIH b/ 10 Bec. HaCTHMH 0ΘΗ3ΗΑ0Ε0Γ0 CIIIípTa.
HocJie Toro, Kan cooTBeTCTBywrfí BapEaHT cMemHBaeTCH c 23, 28Bec. HacTHMH N ~mnuioreKCHJinpomuieHAJiawíHa-I,3 b nanecTBeoTBepAHTejia, E3 Tanoro γοτοβογο k ynoTpedJieHiro οπτηηθοκογοMaTepnaJia E3rOTOBJLSJOTCH φορΜΟΒΗΗΗΗβ Η3ΑΘΙΙΗΗ a-eh HSMepeHKHnponycKaH&H no yise onucaHHOMy cnocoóy. 3631 14 ΙΙρπΜβρ 8 ΟπτίίΉεοκΗίί KJiewrií MaTepnaji npETOTOBJíneTca coraacHO npHMe-pa 5. O^HaKO, coaepxaHHe tíeH3HJioBoro cmípTa CHincaeTca na5 Bec. aacTefi. M3 πρϋτοτοκτιβΗΗΟΗ hcxo^hoS cMecn Κ3Γοτοβχη-BTCH φορΜΟΒΗΗΗΗβ Η3ΑβΛΗΗ £ΛΗ Η3ΜθρθΗΕΗ ΠρΟΠγΟΚΗΗΗΗ ΠΟ ΟΠΗ-caHHOMy cnocotíy. Β TaóJiime 2 πρθαοτββλθη oÓ3op pe3yjiLTaT0B H3MepeHHH nponyc-KaHHa na á>opMOBaHHHX H3sejiHHX H3 coraacHO H3oópeTeHiro cTa-ÓJUIH3OBaHHHX ΟΠΤΗΉΘΟΚΚΧ KJieWK ΜΒΤβρΗΘΛΟΒ ΠΟ ΠρίΙΜβρβΜ I, 2,7 h 8, JUa τογο, htoóh HCHee: upejicTaBHTL οφφεκτ cTatíminsamra οτ-HocHTejiLHO βο3Λθ3θτβκη oÓJiyqeHHH, b TaÓJiime 2 jyia cpasneKnanpKBe^eHn p63yJ!BTaTH HCCJieAOBaHHH npHMepOB CpaBHeHHH A H'C,a Taiose eme οαηογο, otíosHaaeHHoro E c H3BecTHKMH, HecTatímin-3HpOBaHKHMH ΟΠΤΗΉΘΟΚΗΜΙΪ KJieroiUHMH MaTepKaJiaMH KJIH CKJiefiKaMK.IIpircěM, ποΑοόξΐο Tatíjnme I, npHMepti ΒΗΠΟΛΗβΗΗΗ Ih2 cpaBHZ-MH C npKMepOM ftTIH CpaBHBHHH A /b3HTO H3 3Κ0Η0ΓΛΖπθ0Κ0Γ0 ΠΗΤθΚTa ΓΛΡ 131825/, a npwep βηποληθηηη 8 c npnwepoM cpaBHeiuw C/corJiacHO θκοηομηήθοκογο naTeHTa ΓΑΡ CO 9^/213339/.: ΠρΚΜθρΗ ΒΗΠΟΛΗΘΗΗΗ 7a, 7tí H 7b CpaBHEMH C ΠρΧΜβρΟΜ CpaBHeHKHE /β3ητο H3 3KOHOMzaecKoro naTeHTa 131825/, β κοτοροΜ hcxoa-Haa cř/iecL juiennero BemecTBa^cocTOKT H3 61,37 βθοοβηχ aacTeňAiíaHAHraiwWHoro 3$Jipa /coAepxaHHe snoKCZjíHoro KHCJiopona= 91 μγ/γ /, H3 15,35 Bec. aacTeft φεΗΐυίΓΛΗΐΗίΑΗΟΓΟ síTwpa, 5 Bec. aacTefi opcx^eHa A60 /nojmrajioreHHpoBaHHUH ΛχφθΗίυι φκρ-mh η/π "OptíHTanaacT BecTepereaH"/ h k3 23,28 Bec. aacTeftf\l -iptiKJioreKCHJinponHJieHSiiaMKHa--1,3.
CpaBHeHire πρπΒβΑθΗΗΗΧ b TatíJixne 2 pe3yjii>TaT0B H3MepeHirií npo-nycKaaiia λο h nocae BO3neficTBaa otíayaeHHa οτηθτλήβο noKa-3HBaeT, hto coxpaHeHHe hjih noBumeHne nponycKaHna tíe3 Β03Λβίί~ctbhh otíJiyneHKH h 3HaanTejiBHoe yMeHEmeHne noTepeft nponycKa-HKH nOCJie B03£eÉCTBJIH OtíJiyqeHKB HBJLHK3TCH CJieACTBÍieM npiaie-HeniiH coraacHo H3otípeTeHM tíeH3mioBoro cnnpTa b KaaecTBeCTatíiuiH3aTopa. i 3631 15
TaÓJizqa I
Od30p ΑΛΗ CpaBHeHiíH HeCTaÓHJLK3íipOBaHHHX H CTaÓEJIÍÍSHpOEaH-hhx προτΗΒ oópaóOTKK TewnepaTypHHM idokom cbožctb οπτηήθο-khx KJieiwix BemecTB Λ Δ Δ Jfc npiozepa .HoóaBKa .1 - 2 2 τ3 1-3 3aveHaHKH ΒΗΠΟΛΗθΗΗΗ óeH3IUI· /KOJima/ , /xojima/ cnspTa ·. -/βθο. π./ - I 6 2,3 2,6 4,9 2 10 1,0 0,5 0,5 A 2,2 20,7 22,9 ΠρΚΜβρ JW cpaBneHKa 3 2,5 0,3 0,9 1,2 4 5 3,6’ Ι,ι 3,5 B 2,8 34,2 36,2 ΠρΚΜβρ JULfí CpaBHeHHH 5 10 0,4 0,4 0,5 C • - , 4,6 2,2 4,3 . ΠρΚΜθρ - βΠΧ CpaBHeHIÍH. 6 5 0,8 0,9 1,3 Λ *· 8,0ur 3,0 ur 4,9 ur 3631 - 16’ -
HoHCHeHHH κ TadJimte I: 1- 2: Pa3HOCTL cyMM HHTep$epeHnnoHHnx KOJien, H3MepeH— hhx KajRHuíí pa3 Ha 5~th napax οπητηηχ imacTíiH/cpaB. npuMep 1/ b HecmieenHOM coctohhhh h noc- jie' cKJienBaHHH η οτεβρΑβΗΚΗ, KaK Mepa HanpH^eHKHποΒβρχΗοοτθδ den odpadoTKH TeMnepaTypHHM iuokom 2- 3: Pa3H0CTL cyMM nHTep$epeHnnoHHnx KOJien, H3MepeH— HHX KaKAHS pa3 Ha 5~TH CKJieeHHHX Η ΟΤΒβρΛθΒΠΙΗΧnapax οπητηηχ rmacTUH so h nocjie 5-Tnpa3OBoft,προΒΟΑ^Μοίί Kasané #Ba naca ομθηη TeMnepaTypn c-40°C Ha +55°C, KaK Mepa HanpaseHHH noBepxHocTeítb pe3yjiLTaTe TeMnepaTypHoro niona 1-3: Pa3HočTL cyMM ΚΗτβρφβρβΗίξΗΟΗΗΗΧ KOJien, H3MepeH-hhx KaKSHg pa3 Ha 5-th napax οπητηηχ imacTHH bHecKJieeHHOM coctohhhh h nocjie CKJieHBaHiw, οτΒβρ-ΛθΗΐΐΗ η odpaóoTKH TeMnepaTypHHM πιοκομ, KaK MepaOdmeJÍ CTadlUILHOCTH COOTBeTCTByiOmHX.. H30dpeTeHHIOonTHHecKHX KJiewix BemecTB no οτηοπιθηηιο k odpa-ΰοτκβ TeMnepaTypHHM πιοκομ
uťl HeperyjrapHoe HanpaxeHHe; dea odO3HaneHHH:peryjiflpHaH norpeniHocTB noBepxHOCTH 3631 17
TaÓJiKi^a 2
Od 3 op cBoficTB nponycKaHza CTadmmsHpoBaHHHX z HecTadao-3zpoBaHifflx onTHHecKHX KJiewoí BemecTB 30 h nocjie B033eft-CTBHfl OÓJiy^eHHH J6 npHMepa JlodaBKaΒΗΠΟΛΗΘΗΗΗ ' deH3HJI. cmapTa/pec. π./ IIponycKaHHe, TowiHa = 4,3 mm_A = 589 hm_ nepeA oÓJiyaeH. nocjie odJiyneH. 69/%/ /1,1-5-104Gy/ I 6 89,5· 75,5 2 10 86,5 84,3 - A...... _____ 85,2 . 5,8 ř 7a 2 89,0 56,0 7d -5 88,0 67,5 7b 10 84,5 70,0 . B - -. ------73,0....... ......12,5 8 5 80,0 80,0 C - 80,0 77,5 3631 18 ffopMyJia HsoópeTeHHg- Μβτοπ hjih cTaóíuiH3annH onriraecKHX kjicwíx semecTB h cmíe-ΘΚ Ha OCHOBe ΘΠΟΚΟΗβΗΝΧ CMOJI, CJIOJKHHX θφίφΟΒ ΜβΤΗΠΟΚρίυΐΟ—BOÉ KJ3CJIOTN OH ΠΟΛΗΒφκρΗΗΧ CMOJI H HX CMeceft C BHHOMOHO-MepaMH IipOTHB B03Ae^CTBHH KOpOTKOBOJIHOBOIO H3JiyHeHíLH H 0Ó-paóoTKH TeMnepaTypHHM hiokom nyrěM npHÓaBJísHPLH CTaómiH3aT0-pa, oTJuraaioqnScH τθμ, hto k hcxohhoS cmoch KJierouiero Benie-CTBa nocjie roMoreHH3annH μοηομθρηηχ κομποηθητοβ KJieromero .BemecTBa h ho noóaBJíeHíra oTBepHHTejiH hjih panHKaJiLHoro cbh-33Ή111βΓθ/θΗΟΤθΜΗ yCKOpHTeJIH npiídaBJIHeTCH óeH3O0BHÍÍ crmpTb KOJioecTBe οτ I ho 10 βθοοβηχ npopeHTOB b nepecněTe Haoómnfi Bec hcxohhoS CM6CH KJieromero BemecTBa. 3631 19
Ashotwíh ,« ‘i ΜθτοΛ jyiH cTatíiuuisanzH οπτεηθοκεχ kjiskíhhx BemecTB h cmíeθκ προτΗΒ B03ňeScTBHH KopoTKOBOJiHQBoro H3JiyneHHH η oópa-Óotkh TeMnepaTypHHM πιοκομ.
UeJiB h Ha3HaaeHne οπτεπθοκεχ KJiewcc BemecTB h ciuieeK 3aKmoaaioTCH* b cTaómin3amín προτΗΒ raMMa- h peHTreHOBCKoroH3JiyaeHKH z oÓpaóOTKK TeMnepaTypHHM πιοκομ Óe3 HapymeHEHApyrnx XEMHaecKEX, $E3HHecKHX, οπτείθοκεχ h TexHOJiorirae-CKHX CBOfiCTB. CyUlHOCTL H30Óp6T6HHH COCTOHT B TOM, HTO KhcxoahoS cMecH onTiraecKHX ivieninzx BemecTB modasJíneTCn 3KaaecTBe cTadmiE3aTopa óeH3imoBirii οπκρτ b KOJisaecTBe otΓ ΑΟ 10 BeCOBHX ΠρΟΙΪΘΗΤΟΒ. ΠοΛοόΗΗθ KJieioiHHe BenjecTBa cJiy^aT £jih CKJieHBaHEH Óe3 na-ΠριΗΧβΗΣώ HJIH AJLH flepmaHEH H OUpaBH, HyBCTBHTOJILHHX ΟΠΤΕ—ΗβΟΚΗΧ ΘΛΘΜΘΗΤΟΒ BHCOKOS TOEHOCTE. 3631
Claims (1)
- -ti) Předmět vynálezu. Způsob stabilizace pojiv a lepidel optických soustav nazákladě epoxidových pryskyřic, esterů kyseliny metakrylovénebo polyesterových pryskyřic a jejich směsi s vinylovými mono- * méry proti účinkům krátkovlnného zářeni a zpracováni tepelným nárazem po přidání stabilizátoru, vyznačující se tím, že k vý-chozí směsi pojivá po homogenizaci monomerních složek pojiváa před přidáním tužidla nebo silného urychlsvače tuhnutí pojiváse přidává benzylalkohol v množství 1 až 10 % v přepočtu nacelkovou hmotnost výchozí směsi pojivá. Uznáno vynálezem na základě výsledků expertizy, provedenéÚřadem pro vynálezectví a patentnictví, BSrlín, DD Opraw ve vytOtW«h. pepiatch f peplss vynáleau k mtorekéau osviáleií β*2» ( W |« ehybnl vyttátSuo J®fe© čtvrtého «stera# spHvnés.#. ««na «mamas m®a#isg»e »αο@α»,
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD80222610A DD154867A3 (de) | 1980-07-15 | 1980-07-15 | Verfahren zur stabilisierung von optikklebstoffen und-verklebungen gegen die einwirkung kurzwelliger strahlung und gegen temperaturschockbehandlung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS337381A1 CS337381A1 (en) | 1984-06-18 |
| CS233336B1 true CS233336B1 (en) | 1985-02-14 |
Family
ID=5525311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS813373A CS233336B1 (en) | 1980-07-15 | 1981-05-06 | Stabilizing method of optical systems' binders and adhesives on base of epoxy resins of esters of metacrylic or of polyester resins ans their mixtures with vinyl monomers against efects of short-term radiation and heat shocking treatment |
Country Status (3)
| Country | Link |
|---|---|
| CS (1) | CS233336B1 (cs) |
| DD (1) | DD154867A3 (cs) |
| DE (1) | DE3112087A1 (cs) |
-
1980
- 1980-07-15 DD DD80222610A patent/DD154867A3/de not_active IP Right Cessation
-
1981
- 1981-03-27 DE DE19813112087 patent/DE3112087A1/de not_active Withdrawn
- 1981-05-06 CS CS813373A patent/CS233336B1/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DD154867A3 (de) | 1982-04-28 |
| CS337381A1 (en) | 1984-06-18 |
| DE3112087A1 (de) | 1982-04-08 |
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