CS196549B1 - Process for selective catalytic reduction of nitrogen oxides from waste gases - Google Patents
Process for selective catalytic reduction of nitrogen oxides from waste gases Download PDFInfo
- Publication number
- CS196549B1 CS196549B1 CS753204A CS320475A CS196549B1 CS 196549 B1 CS196549 B1 CS 196549B1 CS 753204 A CS753204 A CS 753204A CS 320475 A CS320475 A CS 320475A CS 196549 B1 CS196549 B1 CS 196549B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- oxides
- ammonia
- nitrogen oxides
- catalyst
- waste gases
- Prior art date
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims description 72
- 238000000034 method Methods 0.000 title claims description 13
- 239000002912 waste gas Substances 0.000 title claims description 10
- 238000010531 catalytic reduction reaction Methods 0.000 title claims description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 239000010953 base metal Substances 0.000 claims abstract description 4
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 4
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 4
- 229910052802 copper Inorganic materials 0.000 claims abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 52
- 229910021529 ammonia Inorganic materials 0.000 claims description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- -1 platinum metals Chemical class 0.000 claims description 4
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- XTUHPOUJWWTMNC-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)chromium Chemical class [Co+2].[O-][Cr]([O-])(=O)=O XTUHPOUJWWTMNC-UHFFFAOYSA-N 0.000 claims 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical class [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 20
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract description 5
- 229910017604 nitric acid Inorganic materials 0.000 abstract description 5
- 229910052748 manganese Inorganic materials 0.000 abstract description 3
- 229930195733 hydrocarbon Natural products 0.000 abstract description 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 2
- 150000002739 metals Chemical class 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 239000003345 natural gas Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000009467 reduction Effects 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 238000011946 reduction process Methods 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 206010010071 Coma Diseases 0.000 description 1
- 241001521291 Morus bassanus Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229940117975 chromium trioxide Drugs 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS753204A CS196549B1 (en) | 1975-05-07 | 1975-05-07 | Process for selective catalytic reduction of nitrogen oxides from waste gases |
| NO761370A NO761370L (enrdf_load_stackoverflow) | 1975-05-07 | 1976-04-22 | |
| DE19762618510 DE2618510A1 (de) | 1975-05-07 | 1976-04-27 | Verfahren zur entfernung von stickstoffoxiden aus sauerstoffhaltigen gasen |
| IT22929/76A IT1059763B (it) | 1975-05-07 | 1976-05-03 | Procedimento per allontanare ossidi di azoto da gas contenenti ossigeno |
| NL7604741A NL7604741A (nl) | 1975-05-07 | 1976-05-04 | Werkwijze voor het verwijderen van stikstof- oxyden uit zuurstof bevattende gassen. |
| DD192685A DD123928A1 (enrdf_load_stackoverflow) | 1975-05-07 | 1976-05-05 | |
| FR7613508A FR2310153A1 (fr) | 1975-05-07 | 1976-05-06 | Elimination des oxydes d'azote contenus dans des gaz oxygenes, par melange de ceux-ci a de l'ammoniac, et leur passage sur un catalyseur, suivi d'une phase d'elimination de l'ammoniac residuel |
| BE166868A BE841612A (fr) | 1975-05-07 | 1976-05-07 | Procede en vue d'eliminer des oxydes d'azote de gaz oxygenes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS753204A CS196549B1 (en) | 1975-05-07 | 1975-05-07 | Process for selective catalytic reduction of nitrogen oxides from waste gases |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS196549B1 true CS196549B1 (en) | 1980-03-31 |
Family
ID=5371448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS753204A CS196549B1 (en) | 1975-05-07 | 1975-05-07 | Process for selective catalytic reduction of nitrogen oxides from waste gases |
Country Status (8)
| Country | Link |
|---|---|
| BE (1) | BE841612A (enrdf_load_stackoverflow) |
| CS (1) | CS196549B1 (enrdf_load_stackoverflow) |
| DD (1) | DD123928A1 (enrdf_load_stackoverflow) |
| DE (1) | DE2618510A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2310153A1 (enrdf_load_stackoverflow) |
| IT (1) | IT1059763B (enrdf_load_stackoverflow) |
| NL (1) | NL7604741A (enrdf_load_stackoverflow) |
| NO (1) | NO761370L (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1586530A (en) * | 1977-05-31 | 1981-03-18 | Caterpillar Tractor Co | Two-stage catalysts of engine exhaust |
| US4438082A (en) * | 1982-09-30 | 1984-03-20 | Engelhard Corporation | Platinum gold catalyst for removing NOx and NH3 from gas streams |
| DE3335917C3 (de) * | 1983-10-03 | 1997-03-13 | Wahlco Power Products Inc | Vorrichtung zum regenerativen Vorwärmen eines Verbrennungsluftstromes mit einem heißen NO¶x¶-haltigen Rauchgasstrom und zum Vermindern des in den Rauchgasen enthaltenen NO¶x¶ |
-
1975
- 1975-05-07 CS CS753204A patent/CS196549B1/cs unknown
-
1976
- 1976-04-22 NO NO761370A patent/NO761370L/no unknown
- 1976-04-27 DE DE19762618510 patent/DE2618510A1/de active Pending
- 1976-05-03 IT IT22929/76A patent/IT1059763B/it active
- 1976-05-04 NL NL7604741A patent/NL7604741A/xx unknown
- 1976-05-05 DD DD192685A patent/DD123928A1/xx not_active IP Right Cessation
- 1976-05-06 FR FR7613508A patent/FR2310153A1/fr active Granted
- 1976-05-07 BE BE166868A patent/BE841612A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE841612A (fr) | 1976-09-01 |
| DE2618510A1 (de) | 1976-11-25 |
| IT1059763B (it) | 1982-06-21 |
| NO761370L (enrdf_load_stackoverflow) | 1976-11-09 |
| FR2310153B3 (enrdf_load_stackoverflow) | 1979-03-16 |
| FR2310153A1 (fr) | 1976-12-03 |
| NL7604741A (nl) | 1976-11-09 |
| DD123928A1 (enrdf_load_stackoverflow) | 1977-01-26 |
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