CO4520148A1 - Procedimiento para la reduccion directa de material granular que contiene oxido de hierro y disposicion para llevar a cabo el procedimiento - Google Patents

Procedimiento para la reduccion directa de material granular que contiene oxido de hierro y disposicion para llevar a cabo el procedimiento

Info

Publication number
CO4520148A1
CO4520148A1 CO96053497A CO96053497A CO4520148A1 CO 4520148 A1 CO4520148 A1 CO 4520148A1 CO 96053497 A CO96053497 A CO 96053497A CO 96053497 A CO96053497 A CO 96053497A CO 4520148 A1 CO4520148 A1 CO 4520148A1
Authority
CO
Colombia
Prior art keywords
gas
reducing gas
fluidized bed
bed reactor
procedure
Prior art date
Application number
CO96053497A
Other languages
English (en)
Inventor
Leopoldo Werner
Felix Wallner
Leopold Schenk Johannes
Hubert Whipp Jr
Original Assignee
Voest Alpine Ind Anlagen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Voest Alpine Ind Anlagen filed Critical Voest Alpine Ind Anlagen
Publication of CO4520148A1 publication Critical patent/CO4520148A1/es

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/0033—In fluidised bed furnaces or apparatus containing a dispersion of the material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0211—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
    • C01B2203/0216—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacture Of Iron (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

PROCEDIMIENTO PARA LA REDUCCION DIRECTA DE MATE- RIAL GRANULAR QUE CONTIENE OXIDO DE HIERRO MEDIAN- TE UN PROCESO DE LECHO FLUIDIZADO, EN EL CUAL EL MATERIAL QUE CONTIENE OXIDO DE HIERRO ES REDUCIDO PREVIAMENTE POR MEDIO DE UN GAS REDUCTOR EN AL ME- NOS UNA ETAPA DE PREREDUCCION (7) Y A CONTINUACION REDUCIDO A HIERRO ESPONJOSO EN UNA ETAPA DE REDUC- CION FINAL (8), EN EL CUAL SE PRODUCE GAS REDUCTOR PARCIALMENTE A PARTIR DE GAS REDUCTOR SUMINISTRADO FRESCO Y GAS DE CERVEZA QUE TIENE LUGAR DURANTE LA REDUCCION DIRECTA DEL MATERIAL QUE CONTIENE HIE- RRO, SIENDO EL MISMO ALIMENTADO A LA ETAPA DE RE- DUCCION FINAL (8), REACCIONANDO EN ESTE Y EXTRAIDO DE ESTE, SIENDO UNA PORCION SUBSIGUIENTEMENTE ALI- MENTADA A AL MENOS UNA ETAPA DE PREREDUCCION EN LA CUAL REACCIONA, SIENDO EXTRAIDA DE ESTA, SOMETIDO A LACADO Y DESPUES DESCARGADO COMO GAS DE CABEZA Y SIENDO LA OTRA PORCION DERIVADA, LAVADA, PURIFICA- DA DE CO2, CALENTADA Y UTILIZADA A CONTINUACION EN FORMA SIMILAR COMO GAS REDUCTOR, CARACTERIZADO PORQUE EL GAS REDUCTOR FRESCO ES FORMADO POR GAS DE SINTESIS, TAL COMO GAS NATURAL REFORMADO, Y EL TOTAL DE GAS REDUCTOR SUMINISTRADO A LA ETAPA DE REDUCCION FINAL (8) ES PURIFICADO DE CO2 Y ACONDI- CIONADO CON RESPECTO A SU COMPOSICION QUIMICA EN UNA SOLA ETAPA DE PREPARACION DE GAS (19, 15); Y FINALMENTE CALENTADO. DISPOSICION PARA LLEVAR A CABO EL PROCEDIMIENTO DE ACUERDO CON ALGUNA DE LAS REIVINDICACIONES 1 A 10, LA CUAL COMPRENDE: AL MENOS DOS REACTORES DE LE- CHO FLUIDIZADO (1, 2, 3) CONECTADOS MUTUAMENTE EN SERIE, EN LA CUAL EL MATERIAL QUE CONTIENE OXIDO DE HIERRO ES CONDUCIDO A TRAVES DE CONDUCTOS TRANSPORTADORES (6) DE UN REACTOR DE LECHO FLUIDI- ZADO (1) A OTRO REACTOR DE LECHO FLUIDIZADO (2, 3), EN UNA DIRECCION Y EL GAS REDUCTOR ES CON- DUCIDO A TRAVES DE CONDUCTOS DE CONEXION (11) PARA GAS REDUCTOR EN SENTIDO OPUESTO DE REACTOR DE LE- CHO FLUIDIZADO (3) A REACTOR DE LECHO FLUIDIZADO (2, 1); UN CONDUCTO DE DESCARGA DE GAS DE CABEZA (12) QEU DESCARGA EL GAS REDUCTOR QUE HA REACCIO- NADO DEL PRIMER REACTOR DE LECHO FLUIDIZADO; UN CONDUCTO-RAMAL (22) QUE SE DERIVA DEL CONDUCTO DE CONEXION (11) PARA GAS REDUCTOR QUE CONECTA AL RE- ACTOR DE LECHO FLUIDIZADO (3) DISPUESTO EN ULTIMO TERMINO VISTO EN LA DIRECCION DEL FLUJO DEL MATE- RIAL QUE CONTIENE OXIDO DE HIERRO CON EL REACTOR DE LECHO FLUIDIZADO (2) DISPUESTO DE MANERA QUE LO PRECEDA; Y UN MEDIO DE PREPARACION DE GAS PARA PREPARAR EL GAS DE CABEZA Y EL GAS REDUCTOR DERI- VADO A TRAVES DEL CONDUCTO-RAMAL (22), COMO TAM- BIEN UN MEDIO DE PREPARACION DE GAS PARA GAS RE- DUCTOR FRESCO SUMINISTRADO Y CON UN CALENTADOR DE GAS (20) DEL CUAL SALE UN CONDUCTO DE GAS REDUCTOR DE ALIMENTACION QUE CONDUCE EL GAS REDUCTOR CALEN- TADO HACIA EL REACTOR DE LECHO FLUIDIZADO (3) DIS- PUESTO EN ULTIMO TERMINO, CARACTERIZADO PORQUE EL REACTOR DE LECHO FLUIDIZADO DISPUESTO EN ULTIMO TERMINO VISTO EN LA DIRECCION DE LA CORRIENTE DEL MATERIAL QUE CONTIENE OXIDO DE HIERRO ESTA PRECE- DIDO POR UN SOLO MEDIO DE PREPARACION DE GAS (15, 19) PARA ACONDICIONAR QUIMICAMENTE GAS REDUCTOR FRESCO, GAS DE CABEZA Y EL GAS REDUCTOR DERIVADO, COMO TAMBIEN POR UN CALENTADOR DE GAS (20). PROCEDIMIENTO PARA LA PRODUCCION DE UN PRODUCTO COMERCIABLE, TAL COMO LAMINADOS PRODUCIDOS DE A- RRABIO O ACEROS SEMIELABORADOS FABRICADOS SEGUN UN PROCEDIMIENTO SEGUN UNA DE LAS REIVINDICACIONES 1 A 10. FIGURA 1
CO96053497A 1995-10-10 1996-10-08 Procedimiento para la reduccion directa de material granular que contiene oxido de hierro y disposicion para llevar a cabo el procedimiento CO4520148A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT0168295A AT406379B (de) 1995-10-10 1995-10-10 Verfahren zur direktreduktion von teilchenförmigem eisenoxidhältigem material und anlage zur durchführung des verfahrens

Publications (1)

Publication Number Publication Date
CO4520148A1 true CO4520148A1 (es) 1997-10-15

Family

ID=3518717

Family Applications (1)

Application Number Title Priority Date Filing Date
CO96053497A CO4520148A1 (es) 1995-10-10 1996-10-08 Procedimiento para la reduccion directa de material granular que contiene oxido de hierro y disposicion para llevar a cabo el procedimiento

Country Status (14)

Country Link
EP (1) EP0799322B1 (es)
JP (1) JPH10510589A (es)
KR (1) KR100246630B1 (es)
AR (1) AR003824A1 (es)
AT (1) AT406379B (es)
AU (1) AU705043B2 (es)
BR (1) BR9607995A (es)
CA (1) CA2207416A1 (es)
CO (1) CO4520148A1 (es)
DE (1) DE59606512D1 (es)
PE (1) PE18597A1 (es)
RU (1) RU2148652C1 (es)
WO (1) WO1997013878A1 (es)
ZA (2) ZA968499B (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT409387B (de) 2000-06-28 2002-07-25 Voest Alpine Ind Anlagen Verfahren und anlage zur gasreduktion von teilchenförmigen oxidhältigen erzen
AT408992B (de) * 2000-06-28 2002-04-25 Voest Alpine Ind Anlagen Verfahren zur direktreduktion von feinerz sowie anlage zur durchführung des verfahrens
AT409386B (de) * 2000-06-28 2002-07-25 Voest Alpine Ind Anlagen Verfahren und anlage zur direktreduktion von teilchenförmigen oxidhältigen erzen
AT507632A1 (de) * 2008-11-21 2010-06-15 Siemens Vai Metals Tech Gmbh Verfahren und vorrichtung zur erzeugung eines syntheserohgases
WO2013110969A2 (en) * 2011-12-27 2013-08-01 Hyl Technologies, S.A. De C.V. Blast furnace with top-gas recycle
EP3453773A1 (de) * 2017-09-06 2019-03-13 Primetals Technologies Austria GmbH Reduktionsgasgewinnung aus gesättigtem topgas
EP4273271A1 (de) * 2022-05-05 2023-11-08 Primetals Technologies Austria GmbH Verfahren und vorrichtung zur reduktion von metalloxidhaltigem material

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2547685A (en) * 1947-11-25 1951-04-03 Brassert & Co Reduction of metallic oxides
DE1163353B (de) * 1957-11-21 1964-02-20 United States Steel Corp Kontinuierliches zweistufiges Verfahren zum direkten Reduzieren von pulverisiertem Eisenoxyd und Vorrichtung zur Durchfuehrung dieses Verfahrens
US2921848A (en) * 1957-11-21 1960-01-19 United States Steel Corp Fluidized-bed reduction of ore
US3021208A (en) * 1961-03-23 1962-02-13 United States Steel Corp Method of reducing ore in a fluidized bed
US3475160A (en) * 1967-02-15 1969-10-28 Exxon Research Engineering Co Method of producing reducing gases for the fluidized bed reduction of ores
US4032120A (en) * 1975-11-10 1977-06-28 Midrex Corporation Apparatus for direct reduction of sulfur-containing iron ore
SE429898B (sv) * 1980-01-16 1983-10-03 Stora Kopparbergs Bergslags Ab Sett att forhindra pakladdning vid reduktion i flytbedd av finfordelat metalloxidhaltigt material
US5082251A (en) * 1990-03-30 1992-01-21 Fior De Venezuela Plant and process for fluidized bed reduction of ore
AT402937B (de) * 1992-05-22 1997-09-25 Voest Alpine Ind Anlagen Verfahren und anlage zur direktreduktion von teilchenförmigem eisenoxidhältigem material
DE4307484A1 (de) * 1993-03-10 1994-09-15 Metallgesellschaft Ag Verfahren zur Direktreduktion von eisenoxidhaltigen Materialien mit festen kohlenstoffhaltigen Reduktionsmitteln
US5370727A (en) * 1993-04-19 1994-12-06 Fior De Venezuela Fluidized process for direct reduction

Also Published As

Publication number Publication date
DE59606512D1 (de) 2001-04-05
ATA168295A (de) 1999-09-15
BR9607995A (pt) 1998-06-09
EP0799322B1 (de) 2001-02-28
RU2148652C1 (ru) 2000-05-10
AU7205896A (en) 1997-04-30
EP0799322A1 (de) 1997-10-08
KR100246630B1 (ko) 2000-04-01
JPH10510589A (ja) 1998-10-13
PE18597A1 (es) 1997-06-04
AU705043B2 (en) 1999-05-13
CA2207416A1 (en) 1997-04-17
AT406379B (de) 2000-04-25
MX9704230A (es) 1997-09-30
ZA968499B (en) 1997-05-20
AR003824A1 (es) 1998-09-09
WO1997013878A1 (de) 1997-04-17
ZA968498B (en) 1997-05-20

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