CN87101850A - Method for extracting sweetening agent from fructus Siraitiae Grosvenorii - Google Patents
Method for extracting sweetening agent from fructus Siraitiae Grosvenorii Download PDFInfo
- Publication number
- CN87101850A CN87101850A CN87101850.0A CN87101850A CN87101850A CN 87101850 A CN87101850 A CN 87101850A CN 87101850 A CN87101850 A CN 87101850A CN 87101850 A CN87101850 A CN 87101850A
- Authority
- CN
- China
- Prior art keywords
- sweetener
- siraitiae grosvenorii
- extracting
- fructus siraitiae
- fructus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000003599 food sweetener Nutrition 0.000 title claims abstract description 20
- 239000003765 sweetening agent Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 14
- 235000017048 Garcinia mangostana Nutrition 0.000 claims description 13
- 240000006053 Garcinia mangostana Species 0.000 claims description 13
- 235000013399 edible fruits Nutrition 0.000 claims description 8
- 238000000605 extraction Methods 0.000 claims description 7
- 235000009815 Momordica Nutrition 0.000 claims description 5
- 241000218984 Momordica Species 0.000 claims description 5
- 238000010612 desalination reaction Methods 0.000 claims description 5
- 239000000284 extract Substances 0.000 claims description 5
- 238000010009 beating Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 230000032696 parturition Effects 0.000 claims description 2
- 229920003002 synthetic resin Polymers 0.000 claims 2
- 239000000057 synthetic resin Substances 0.000 claims 2
- 239000012141 concentrate Substances 0.000 claims 1
- 238000005194 fractionation Methods 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011347 resin Substances 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 abstract description 4
- 239000013078 crystal Substances 0.000 abstract description 3
- 238000001914 filtration Methods 0.000 abstract description 2
- 238000004108 freeze drying Methods 0.000 abstract description 2
- 239000012535 impurity Substances 0.000 abstract description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- 239000003463 adsorbent Substances 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 238000011033 desalting Methods 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 238000004537 pulping Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000002594 sorbent Substances 0.000 description 5
- 238000011010 flushing procedure Methods 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Natural products CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 235000011171 Thladiantha grosvenorii Nutrition 0.000 description 1
- 244000185386 Thladiantha grosvenorii Species 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 235000019605 sweet taste sensations Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Seasonings (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
A method for extracting fructus Siraitiae Grosvenorii sweetener. Grinding fructus Siraitiae Grosvenorii, pulping, extracting with warm water at 50-60 deg.C, and filtering. Separating with DA-201 acrylic acid type adsorbent, dissolving with 50% (V/V) ethanol, decolorizing with D-211 acrylic acid type anion resin, desalting, and removing impurities. Recovering ethanol by distillation, vacuum concentrating, and freeze drying to obtain white crystal fructus Siraitiae Grosvenorii sweetener. The adopted fructus momordicae does not need to go through the post-ripening period and does not need to be roasted, the construction period is shortened, the cost is saved, and the method is suitable for industrial production.
Description
The present invention relates to a kind of extracting method of mangosteen sweetener.
Grosvenor Momordica (Momordica Grosvenori Swingie) is the fruit of perennial herb cucurbitaceous plant, and fruit contains a kind of glycoside-mangosteen sweetener of strong sweetness, has very high economic worth and pharmaceutical use.Caused the attention of Chinese scholars.Japan once disclosed several different methods to extracting mangosteen sweetener, as Japanese Patent JP83986(1977) and JP117781(1981), the extracting method of bamboo Ben Changsong, the first-class people's invention in Pinggu, make raw material with the dry fruit that toasted, make organic solvent with methyl alcohol, ether, vinyl acetic monomer etc., make sorbent material with magnesium aluminum silicate, magnesium oxide system, not only the complex process cost is also quite high for this, more is unsuitable for suitability for industrialized production.
The invention provides a kind of simple to operately, cost is low, is convenient to suitability for industrialized production, from a kind of method of extracting mangosteen sweetener the fruit of giving birth to of Grosvenor Momordica.
The present invention realizes by following step:
1. get living Grosvenor Momordica and grind, pull an oar, extract in 50-60 ℃ warm water, get extraction liquid with four layers of filtered through gauze, residue divides four extractions with warm water, and combining extraction liquid is used double-deck filter paper filtering, gets yellowish filtrate.
2. with the glass column of filtrate by acrylic type sorbent material (DA-201), mangosteen sweetener contained in the solution is adsorbed, and other carbohydrate and impurity are released, the glass column that sorbent material is equipped with in the flushing of Yong Zheng Evaporated water repeatedly, with effluent liquid clarification degree of being.
3. with 50%(V/V) ethanol be lysate, mangosteen sweetener is dissolved out from sorbent material.
4. the ethanolic soln that will be dissolved with mangosteen sweetener by acrylic type anionite-exchange resin (D-211) decolour, desalination, decon, use the alcohol flushing of above-mentioned concentration again, make effluent liquid not have sweet taste.Reclaim ethanol with steaming the Evaporated method, the vacuum pump concentrating under reduced pressure uses freeze-drying drying (liquid that earlier ripple contracted is refrigerated to-40 ℃, is warming up to 40 ℃ more gradually) to get white crystals shape sweetener then, and its structural formula is:
R in the formula
1And
Representative is with 1,2; 1,4 or 1,6 bonded molecules hang down rapid-d-glucose pyrans molecule:
Embodiment:
Give birth to fruit 100 grams, grind, making beating, four layers of filtered through gauze of extraction in 250ml 50-60 ℃ warm water, residue divides four extractions with 100ml warm water, combining extraction liquid, and the glass column (interior dress 100mlDA-201 acrylic type sorbent material) by 200ml separates, the flushing of glass column Yong Zheng Evaporated water makes the effluent liquid clarification be degree.Use 250m50%(V/V subsequently) ethanol elution, must contain the elutriant of mangosteen sweetener.With this contain that the glass column (interior dress 200mlD-211 acrylic type negative resin) of the elutriant of mangosteen sweetener by 300ml decolours, desalination, decon, alcohol flushing Zheng Evaporated method with the above-mentioned concentration of 100ml reclaims ethanol again, the vacuum pump concentrating under reduced pressure, lyophilize gets 1.2 gram white crystals shape mangosteen sweeteners approximately.
Advantage of the present invention:
Directly with the fruit that gives birth to after gathering, need not pass through latter stage of ripening, need can not extract sweetener through roasting fruit operation, shorten the process time of raw material, simplify procedure, reduce the cost of raw material; Adopt domestic resin to separate, decolour, desalination, decontamination has replaced magnesia system, Magnesiumaluminumsilicate, has replaced ether, methyl alcohol, ethyl acetate to make organic solvent with ethanol, has reduced cost, has simplified technology, is suitable for suitability for industrialized production; The sweetener that extracts has free from extraneous odour, strong sweetness, the characteristic such as heat-resisting.
Claims (1)
1, mangosteen sweetener, molecular formula are C
60H
109O
292H
2O, structural formula:
The Grosvenor Momordica extraction method is that Grosvenor Momordica is carried out grain is broken, and making beating is filtered, separate, and decolouring, desalination, decon, concentrate drying therefrom extracts a kind of method of mangosteen sweetener, it is characterized in that:
A. directly extract mangosteen sweetener from giving birth to fruit,
B. use synthetic resins (D-211) to decolour, desalination, decon,
C. use synthetic resins (DA-201) to carry out fractionation by adsorption.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN87101850A CN1019935C (en) | 1987-03-09 | 1987-03-09 | Method for extracting sweetening agent from momordica grosvenori |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN87101850A CN1019935C (en) | 1987-03-09 | 1987-03-09 | Method for extracting sweetening agent from momordica grosvenori |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN87101850A true CN87101850A (en) | 1987-12-16 |
| CN1019935C CN1019935C (en) | 1993-02-24 |
Family
ID=4813659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN87101850A Expired - Fee Related CN1019935C (en) | 1987-03-09 | 1987-03-09 | Method for extracting sweetening agent from momordica grosvenori |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1019935C (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1293089C (en) * | 2004-06-04 | 2007-01-03 | 何伟平 | Low calorie candy made from luohanguo and its production |
| WO2008030121A1 (en) * | 2006-09-07 | 2008-03-13 | Biovittoria Limited | Sweetening compositions and processes for preparing them |
| CN100382723C (en) * | 2003-09-22 | 2008-04-23 | 桂林思特新技术公司 | Fruit drink prepared from fruit of Grosvenor momordica |
| JP2011234652A (en) * | 2010-05-07 | 2011-11-24 | Choko Co Ltd | Method of producing powder sweetener containing momordica grosvenori extract powder and reduced hard digestive dextrin, and momordica grosvenori extract powder |
| CN102283338A (en) * | 2011-06-15 | 2011-12-21 | 中国农业大学 | Method for deodorizing fructus momordicae |
| CN103461767A (en) * | 2012-11-07 | 2013-12-25 | 张雨生 | Sucrose-free health-care type sweet mouth lozenge |
| CN103462139A (en) * | 2012-11-07 | 2013-12-25 | 张雨生 | Sugar-free health-care type sweet fruit juice beverage |
| CN103461812A (en) * | 2012-11-07 | 2013-12-25 | 张雨生 | Sugarless sweet glutinous rice soft cake with health-care function |
| CN104098641A (en) * | 2014-07-29 | 2014-10-15 | 桂林实力科技有限公司 | Method used for extracting mogroside V from siraitia grosvenorii |
| CN105218612A (en) * | 2015-09-30 | 2016-01-06 | 大闽食品（漳州）有限公司 | A kind of method improving Momordica grosvenori mogroside V purity in mogroside |
| CN109924535A (en) * | 2019-03-04 | 2019-06-25 | 海口日岛香料有限公司 | Flower of Fructus Momordicae burns and sucks the preparation method and application spilt in category shredded tobacco for water pipes in flowers and fruits |
| CN110523440A (en) * | 2019-08-28 | 2019-12-03 | 华南理工大学 | A kind of desalination method of purification of water-solubility chitosan derivative |
| US11576412B2 (en) | 2016-10-24 | 2023-02-14 | Guilin Gfs Monk Fruit Corporation | Extracts from fruits of the Cucurbitaceae family, and methods of preparing thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1064048C (en) * | 1996-08-29 | 2001-04-04 | 中国科学院昆明植物研究所 | Five compounds of Qingyang ginseng glucoside and its preparation method and application |
-
1987
- 1987-03-09 CN CN87101850A patent/CN1019935C/en not_active Expired - Fee Related
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100382723C (en) * | 2003-09-22 | 2008-04-23 | 桂林思特新技术公司 | Fruit drink prepared from fruit of Grosvenor momordica |
| CN1293089C (en) * | 2004-06-04 | 2007-01-03 | 何伟平 | Low calorie candy made from luohanguo and its production |
| US11464247B2 (en) | 2006-09-07 | 2022-10-11 | Guilin Gfs Monk Fruit Corp. | Sweetening compositions and processes for preparing them |
| WO2008030121A1 (en) * | 2006-09-07 | 2008-03-13 | Biovittoria Limited | Sweetening compositions and processes for preparing them |
| CN103652776B (en) * | 2006-09-07 | 2015-08-19 | 维多利亚生物有限公司 | Sweetening compositions and their method of preparation |
| JP2011234652A (en) * | 2010-05-07 | 2011-11-24 | Choko Co Ltd | Method of producing powder sweetener containing momordica grosvenori extract powder and reduced hard digestive dextrin, and momordica grosvenori extract powder |
| CN102283338A (en) * | 2011-06-15 | 2011-12-21 | 中国农业大学 | Method for deodorizing fructus momordicae |
| CN103461767A (en) * | 2012-11-07 | 2013-12-25 | 张雨生 | Sucrose-free health-care type sweet mouth lozenge |
| CN103462139A (en) * | 2012-11-07 | 2013-12-25 | 张雨生 | Sugar-free health-care type sweet fruit juice beverage |
| CN103461812A (en) * | 2012-11-07 | 2013-12-25 | 张雨生 | Sugarless sweet glutinous rice soft cake with health-care function |
| CN104098641A (en) * | 2014-07-29 | 2014-10-15 | 桂林实力科技有限公司 | Method used for extracting mogroside V from siraitia grosvenorii |
| CN105218612A (en) * | 2015-09-30 | 2016-01-06 | 大闽食品（漳州）有限公司 | A kind of method improving Momordica grosvenori mogroside V purity in mogroside |
| US11576412B2 (en) | 2016-10-24 | 2023-02-14 | Guilin Gfs Monk Fruit Corporation | Extracts from fruits of the Cucurbitaceae family, and methods of preparing thereof |
| CN109924535A (en) * | 2019-03-04 | 2019-06-25 | 海口日岛香料有限公司 | Flower of Fructus Momordicae burns and sucks the preparation method and application spilt in category shredded tobacco for water pipes in flowers and fruits |
| CN109924535B (en) * | 2019-03-04 | 2022-02-01 | 海口日岛香料有限公司 | Preparation method and application of momordica grosvenori flowers in fruit burning and spraying type hookah |
| CN110523440A (en) * | 2019-08-28 | 2019-12-03 | 华南理工大学 | A kind of desalination method of purification of water-solubility chitosan derivative |
| CN110523440B (en) * | 2019-08-28 | 2022-04-22 | 华南理工大学 | Desalination purification method of water-soluble chitosan derivative |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1019935C (en) | 1993-02-24 |
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| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| C19 | Lapse of patent right due to non-payment of the annual fee |