CN209947452U - Conductive adhesive film and circuit board - Google Patents

Conductive adhesive film and circuit board Download PDF

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Publication number
CN209947452U
CN209947452U CN201821962245.2U CN201821962245U CN209947452U CN 209947452 U CN209947452 U CN 209947452U CN 201821962245 U CN201821962245 U CN 201821962245U CN 209947452 U CN209947452 U CN 209947452U
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China
Prior art keywords
layer
conductive
adhesive film
conductive adhesive
metal
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Withdrawn - After Issue
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CN201821962245.2U
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Chinese (zh)
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苏陟
高强
朱开辉
朱海萍
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Guangzhou Fangbang Electronics Co Ltd
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Guangzhou Fangbang Electronics Co Ltd
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Abstract

The embodiment of the utility model provides a conductive adhesive film and a circuit board, wherein the conductive adhesive film comprises a conductive adhesive layer, a first conductive layer and an adhesive film layer which are sequentially stacked, a first through hole is arranged on the first conductive layer, a metal bulge is arranged at the first through hole, and the metal bulge extends into the adhesive film layer; the metal bump is formed by cooling and solidifying the fusible metal after flowing from one side to the other side of the first through hole at a preset temperature. In practical application, when the conductors are laminated through the conductive adhesive film, the conductive adhesive film can be electrically connected with one of the conductors through the conductive adhesive layer, and meanwhile, the metal protrusion penetrates through the adhesive film layer to be electrically connected with the other conductor, so that the reliable connection between the conductors is realized. The first conductive layer and the metal protrusions are arranged in the conductive adhesive film, so that the overlapping rate of conductive particles in the conductive adhesive film is increased, the resistance of the conductive adhesive film is reduced, the conductive performance of the conductive adhesive film is improved, and the electrical connection between conductors is guaranteed.

Description

Conductive adhesive film and circuit board
Technical Field
The utility model relates to the field of electronic technology, especially, relate to conductive adhesive film and circuit board.
Background
The conductive adhesive film is a lead-free connecting material, which provides mechanical and electrical connection between the components and the circuit board, and thus is gradually and widely used in various electronic fields such as microelectronic packaging, printed circuit boards, conductive circuit bonding, and the like.
At present, the existing conductive adhesive film is generally prepared by mixing a large amount of conductive particles in the adhesive, so that the conductive adhesive film can provide mechanical connection and electrical connection simultaneously; in practical application, the conductive adhesive film is adhered between the conductors, and one surface of the conductive adhesive film is adhered to one of the conductors, and the other surface of the conductive adhesive film is adhered to the other conductor, so that the conduction between the conductors is realized. However, in the process of implementing the present invention, the utility model discloses a people finds that there is at least following problem among the prior art: under the influence of the manufacturing process, the overlapping rate of conductive particles in the traditional conductive adhesive film is generally low, so that the resistance of the conductive adhesive film is high; particularly, under the condition of high temperature, after the conductive adhesive film is heated, the colloid expands, so that the conductive particles are pulled apart, the overlapping rate of the conductive particles is further reduced, and the resistance of the conductive adhesive film is rapidly increased.
SUMMERY OF THE UTILITY MODEL
The utility model aims at providing a conductive adhesive film and circuit board to solve the technical problem that current conductive adhesive film resistance is high, with the resistance that reduces conductive adhesive film.
In order to solve the technical problem, the utility model provides a conductive adhesive film, which comprises a conductive adhesive layer, a first conductive layer and an adhesive film layer which are sequentially stacked, wherein the first conductive layer is provided with a first through hole which penetrates through the upper surface and the lower surface of the first conductive layer, the first through hole is provided with a metal bulge, and the metal bulge extends into the adhesive film layer; the metal protrusion is formed by cooling and solidifying a fusible metal after the fusible metal flows from one side to the other side of the first through hole at a preset temperature.
Preferably, the fusible metal is any one single metal or any multiple alloy of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold.
Preferably, the preset temperature is 300 ℃ to 2000 ℃.
Preferably, the first conductive layer includes a first surface in contact with the adhesive film layer, and the first surface is an undulating non-flat surface.
Preferably, the surface of the metal protrusion is provided with conductor particles; the height of the conductor particles is 1-30 μm.
Preferably, the shape of the conductive particles is cluster-like, ice-hanging-like, stalactite-like, or dendritic.
Preferably, the conductor particles are plural; a plurality of conductor particles are regularly or irregularly distributed on the surface of the metal protrusion; the plurality of conductor particles are continuously or discontinuously distributed on the surface of the metal protrusion.
Preferably, the adhesive layer comprises an adhesive layer containing conductive particles; or the adhesive film layer comprises an adhesion layer without conductive particles.
Preferably, the first conductive layer includes one or more of a metal conductive layer, a carbon nanotube conductive layer, a ferrite conductive layer, and a graphene conductive layer.
Preferably, the number of the first through holes in the first conductive layer is 10-1000 per square centimeter; and/or the cross-sectional area of the first through hole is 0.1 mu m2-1mm2
As a preferred scheme, the conductive adhesive film further comprises a first protective film layer and a second protective film layer, wherein the first protective film layer is arranged on one surface, far away from the first conductive layer, of the adhesive film layer; the second protective film layer is arranged on one surface, far away from the first conductive layer, of the conductive adhesive layer.
Preferably, the conductive adhesive film further comprises a second conductive layer, the second conductive layer is arranged between the first conductive layer and the adhesive film layer, and a protruding portion is formed at a position where the second conductive layer covers the metal protrusion.
Preferably, the surface of the protruding part is provided with conductive particles.
Compared with the prior art, the embodiment of the utility model discloses a conductive adhesive film, through setting up the conductive adhesive layer, the first conducting layer and the glued membrane layer in proper order in a cascade way, and set up the metal bulge in the first through-hole department of first conducting layer, make when pressing each other through the conductive adhesive film between the conductor, the conductive adhesive film can be connected with one of them conductor electricity through the conductive adhesive layer, impale through the metal bulge simultaneously the glued membrane layer is connected with another conductor electricity, thereby has realized the reliable connection between the conductor; meanwhile, the first conducting layer and the metal protrusions are arranged in the conducting adhesive film, so that the overlapping rate of conducting particles in the conducting adhesive film is increased, the problem that the conducting particles are pulled apart due to expansion of the colloid to increase the resistance of the conducting adhesive film at high temperature can be solved, the resistance of the conducting adhesive film is greatly reduced, the conducting performance of the conducting adhesive film is improved, and the electrical connection between conductors is guaranteed. In addition, the arrangement of the first conducting layer and the metal protrusions reduces the use of conducting particles, so that the production cost of the conducting adhesive film is reduced, and the peeling strength of the conducting adhesive film is improved.
In order to solve the same technical problem, the utility model also provides a circuit board, which comprises a steel sheet and a printed circuit board;
the circuit board further comprises the conductive adhesive film in any one of the embodiments; the steel sheet is pressed with the printed circuit board through the conductive adhesive film; the conductive adhesive layer is electrically connected with the steel sheet, and the metal bulge pierces through the adhesive layer and is electrically connected with the ground layer of the printed circuit board; or the like, or, alternatively,
the steel sheet is pressed with the printed circuit board through the conductive adhesive film; the conductive adhesive layer is electrically connected with the steel sheet, and the protruding part pierces the adhesive layer and is electrically connected with the ground layer of the printed circuit board.
Compared with the prior art, the embodiment of the utility model discloses a circuit board, including steel sheet, printed wiring board and conductive adhesive film, when the steel sheet passes through the conductive adhesive film with printed wiring board is laminated mutually, the conductive adhesive film can pass through the conductive adhesive film with the steel sheet electricity is connected, pierces through the metal bulge or bellying the glued membrane layer simultaneously, and with the stratum electricity of printed wiring board is connected to reliable connection between steel sheet and the printed wiring board has been realized; meanwhile, the first conducting layer and the metal protrusions are arranged in the conducting adhesive film, so that the overlapping rate of conducting particles in the conducting adhesive film is increased, the problem that the conducting particles are pulled apart due to colloid expansion to increase the resistance of the conducting adhesive film at high temperature can be avoided, the resistance of the conducting adhesive film is greatly reduced, the conducting performance of the conducting adhesive film is improved, and the stability of grounding is guaranteed. In addition, the arrangement of the first conducting layer also reduces the use of conducting particles, thereby reducing the production cost of the conducting adhesive film and improving the peeling strength of the conducting adhesive film.
In order to solve the same technical problem, the utility model also provides another circuit board, which comprises a steel sheet, a printed circuit board and an electromagnetic shielding film, wherein the electromagnetic shielding film comprises an insulating layer and a conductor layer which are arranged in a stacking way, and the electromagnetic shielding film is electrically connected with the stratum of the printed circuit board through the conductor layer;
the circuit board further comprises the conductive adhesive film in any one of the embodiments; the steel sheet is pressed with the electromagnetic shielding film through the conductive adhesive film; the conductive adhesive layer is electrically connected with the steel sheet, and the metal bulge pierces through the adhesive film layer and the insulating layer and is electrically connected with the conductor layer;
or the steel sheet is pressed with the electromagnetic shielding film through the conductive adhesive film; the conductive adhesive layer is electrically connected with the steel sheet, and the protruding part pierces the adhesive layer and the insulating layer and is electrically connected with the conductor layer.
Compared with the prior art, the embodiment of the utility model discloses a circuit board, including steel sheet, printed wiring board, electromagnetic shielding film and conductive adhesive film when the steel sheet passes through conductive adhesive film with electromagnetic shielding film looks pressfitting, conductive adhesive film can pass through conductive adhesive film with the steel sheet electricity is connected, pierces through metal arch or bellying simultaneously the glue film layer with the insulating layer, and with the conductor layer electricity of electromagnetic shielding film is connected to reliable connection between steel sheet, electromagnetic shielding film and the printed wiring board has been realized; meanwhile, the first conducting layer and the metal protrusions are arranged in the conducting adhesive film, so that the overlapping rate of conducting particles in the conducting adhesive film is increased, the problem that the conducting particles are pulled apart due to colloid expansion to increase the resistance of the conducting adhesive film at high temperature can be avoided, the resistance of the conducting adhesive film is greatly reduced, the conducting performance of the conducting adhesive film is improved, and the stability of grounding is guaranteed. In addition, the arrangement of the first conducting layer also reduces the use of conducting particles, thereby reducing the production cost of the conducting adhesive film and improving the peeling strength of the conducting adhesive film.
Drawings
Fig. 1 is a schematic structural diagram of a conductive adhesive film according to a first embodiment of the present invention;
FIG. 2 is a schematic view of another conductive adhesive film according to the first embodiment of the present invention
Fig. 3 is a cross-sectional view of a conductive adhesive film according to a first embodiment of the present invention;
fig. 4 is a schematic structural view of a conductive adhesive film according to a second embodiment of the present invention;
fig. 5 is a schematic structural view of another conductive adhesive film according to a second embodiment of the present invention;
fig. 6 is a schematic structural view of a conductive adhesive film according to a third embodiment of the present invention;
fig. 7 is a schematic structural diagram of a circuit board in the fourth embodiment of the present invention;
fig. 8 is a schematic structural diagram of a circuit board in the fifth embodiment of the present invention;
fig. 9 is a schematic structural diagram of a circuit board in a sixth embodiment of the present invention;
fig. 10 is a schematic structural diagram of a circuit board in a seventh embodiment of the present invention;
fig. 11 is a schematic flow chart of a method for manufacturing a conductive adhesive film according to an eighth embodiment of the present invention;
fig. 12 is a schematic flow chart of a method for manufacturing a conductive adhesive film according to an embodiment of the present invention.
11, a conductive adhesive layer; 111. conductive particles; 12. a first conductive layer; 121. a first through hole; 122. a metal projection; 123. a conductive particle; 124. a first surface; 125. a second surface; 13. a glue film layer; 14. a first protective film layer; 15. a second protective film layer; 16. a second conductive layer; 161. a boss portion;
21. a steel sheet; 22. a printed wiring board; 221. a printed wiring board body; 222. an earth formation; 223. a ground hole; 23. an electromagnetic shielding film; 231. an insulating layer; 232. a conductive layer.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative efforts belong to the protection scope of the present invention.
Example one
With reference to fig. 1 to 3, a conductive adhesive film according to a preferred embodiment of the present invention includes a conductive adhesive layer 11, a first conductive layer 12 and an adhesive layer 13, which are sequentially stacked, wherein the first conductive layer 12 is provided with a first through hole 121 penetrating through upper and lower surfaces of the first conductive layer, the first through hole 121 is provided with a metal protrusion 122, and the metal protrusion 122 extends into the adhesive layer 13; the metal protrusion 122 is formed by cooling and solidifying a fusible metal after flowing from one side of the first through hole 121 to the other side thereof at a predetermined temperature.
In the embodiment of the present invention, the conductive adhesive layer 11, the first conductive layer 12 and the adhesive film layer 13 are sequentially stacked, and the metal protrusion 122 is disposed at the first through hole 121 of the first conductive layer 12, so that in practical applications, when conductors are pressed together through the conductive adhesive film, the conductive adhesive film can be electrically connected to one of the conductors through the conductive adhesive layer 11, and the adhesive film layer 13 is pierced through by the metal protrusion 122 to be electrically connected to another conductor, thereby achieving reliable connection between the conductors; meanwhile, the first conductive layer 12 and the metal protrusions 122 arranged in the conductive adhesive film increase the overlapping rate of conductive particles in the conductive adhesive film, and can avoid the problem that the resistance of the conductive adhesive film is increased due to the fact that the conductive particles are pulled apart due to expansion of the adhesive at high temperature, so that the resistance of the conductive adhesive film is greatly reduced, the conductive performance of the conductive adhesive film is improved, and the electrical connection between conductors is guaranteed. In addition, the conductive adhesive layer 11 in this embodiment includes conductive particles 111; however, compared with the conventional conductive adhesive film, in the embodiment, due to the arrangement of the first conductive layer 12 and the metal bump 122, the use of conductive particles in the conductive adhesive film is greatly reduced, so that the production cost of the conductive adhesive film is reduced, and the peel strength of the conductive adhesive film is improved.
In the embodiment of the present invention, in the process of forming the metal bump 122, the predetermined temperature is 300 ℃ to 2000 ℃. Therefore, the process of forming the metal bump 122 is embodied as: at a temperature of 300 ℃ to 2000 ℃, the fusible metal disposed in the first through hole 121 is melted and flows from one side of the first through hole 121 away from the adhesive film layer 13 to the other side, and at this time, the fusible metal is instantly cooled, so that the fusible metal is solidified, and the metal protrusion 122 is formed on one side of the first through hole 121 close to the adhesive film layer 13. Wherein, the fusible metal is any one single metal or any multiple alloy of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold.
In the embodiment of the present invention, it should be noted that the structure of the metal bump 122 shown in the drawings is only an example. Since the metal bump 122 is formed by instantly cooling the fusible metal after flowing from one side to the other side of the first through hole 121 at a predetermined temperature, in one case, the fusible metal flows out almost completely from the first through hole 121, and there is no residue in the first through hole 121, so that the metal bump 122 can be formed as shown in the drawing, that is, the metal bump 122 is formed at the boundary between the first through hole 121 and the adhesive film layer 13; in another case, a fusible metal remains in the first through hole 121, and the first through hole 121 is even filled with the fusible metal, so that one end of the metal bump 122 is formed to be located in the first through hole 121, and the other end of the metal bump 122 extends out of the first through hole 121 and into the adhesive film layer 13; in another case, a fusible metal remains on a surface of the first conductive layer 12 away from the adhesive film layer 13, and thus, the metal protrusion 122 may be formed to penetrate through the first through hole 121. In addition, the metal protrusion 122 in the present invention is not limited by the shape and the illustration, and any metal protrusion having piercing and conductive functions is within the protection scope of the present invention.
As shown in fig. 3, in order to ensure that the metal bump 122 can be formed at the first through-hole 121 while ensuring that the first conductive layer 12 is not easily broken, it is preferable that the cross-sectional area of the first through-hole 121 be 0.1 μm2-1mm2
In addition, in order to ensure that the metal bump 122 can smoothly pierce through the adhesive film layer 13 and ensure that the first conductive layer 12 is not easily broken, the number of the first through holes 121 in the first conductive layer 12 per square centimeter is 10 to 1000 in this embodiment. It should be noted that, because the metal protrusions 122 are disposed at the first through holes 121, the number of the first through holes 121 corresponds to the number of the metal protrusions 122, that is, the number of the metal protrusions 122 in each square centimeter of the first conductive layer 12 is 10 to 1000, so as to ensure that the glue film layer 13 can be smoothly pierced.
In the embodiment of the present invention, the first through holes 121 may be regularly or irregularly distributed on the first conductive layer 12; wherein, the first through holes 121 are regularly distributed on the first conductive layer 12, which means that the shapes of the first through holes 121 are the same and are uniformly distributed on the first conductive layer 12; the first through holes 121 are irregularly distributed on the first conductive layer 12, that is, the first through holes 121 have different shapes and are irregularly distributed on the first conductive layer 12. Preferably, the first through holes 121 have the same shape, and the first through holes 121 are uniformly distributed on the first conductive layer 12, as shown in fig. 3. In addition, the first through hole 121 may be a circular through hole, and may also be a through hole of any other shape, the drawings of the present invention only illustrate that the first through hole 121 is a circular through hole, but the first through hole 121 of any other shape is within the scope of the present invention.
In the embodiment of the present invention, the thickness of the first conductive layer 12 is preferably 0.1 μm to 45 μm, so as to ensure that the first conductive layer 12 is not easily broken and has good flexibility. In addition, in order to ensure that the first conductive layer 12 has good conductivity, the first conductive layer 12 includes one or more of a metal conductive layer, a carbon nanotube conductive layer, a ferrite conductive layer, and a graphene conductive layer. The metal conductive layer comprises a single metal conductive layer and/or an alloy conductive layer; the single metal conducting layer is made of any one of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold, and the alloy conducting layer is made of any two or more of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold.
In an embodiment of the present invention, the first conductive layer 12 includes a first surface 124 contacting the adhesive film layer 13. It should be noted that the first surface 124 may be a surface of any shape, for example, a flat surface as shown in fig. 1, an uneven surface as shown in fig. 2, or a rough surface; in addition, the first surface 124 may be a regular surface or an irregular surface.
As shown in fig. 2, in order to ensure that the metal protrusion 122 can smoothly penetrate through the adhesive film layer 13 to ensure the reliability of the conductive adhesive film connection, it is preferable that the first surface 124 is an uneven non-flat surface. When the first surface 124 is an undulating non-flat surface, the first surface 124 includes a plurality of protrusions, and the first through holes 121 are preferably formed on the protrusions, so that the metal protrusions 122 can more easily pierce through the adhesive film layer 13 during the pressing process.
In addition, the first conductive layer 12 further includes a second surface 125 disposed opposite to the first surface 124, and the second surface 125 is in contact with the conductive adhesive layer 11. It should be noted that the second surface 125 may be a surface of any shape, for example, a flat surface as shown in fig. 1, an uneven surface with a wavy shape, or other rough surface; in addition, the second surface 125 may be a regular surface or an irregular surface. The present invention is illustrated in the drawings only by using the second surface 125 as a flat surface, and any other shape of the second surface 125 is within the scope of the present invention.
In the embodiment of the present invention, it should be noted that the first conductive layer 12 in the drawings of this embodiment may be a single-layer structure or a multi-layer structure. In addition, the first conductive layer 12 of the present embodiment can be provided in a grid shape, a bubble shape, etc. according to the requirements of actual production and application.
In the embodiment of the present invention, one of the structures of the adhesive film layer 13 is specifically represented as: the adhesive layer 13 includes an adhesive layer containing conductive particles. By making the glue film layer 13 include an adhesion layer containing conductive particles, the glue film layer 13 not only has an adhesion function to enable the conductive glue film and the conductor to be tightly adhered, but also the glue film layer 13 has a conductive function, and the glue film layer is matched with the first conductive layer 12 and the metal protrusion 122 to ensure the electrical connection between the conductors. The conductive particles in the adhesive film layer 13 may be mutually separated conductive particles, or large conductive particles formed by agglomeration; when the conductive particles are mutually separated, the area of electrical contact can be further increased, and the uniformity of the electrical contact is improved; and when the conductive particles are large agglomerated conductive particles, the piercing strength can be increased.
In the embodiment of the present invention, the other structure of the adhesive film layer 13 is specifically represented as: the adhesive layer 13 includes an adhesive layer containing no conductive particles. The adhesive film layer 13 has an adhesive effect by enabling the adhesive film layer 13 to include an adhesive layer without containing conductive particles, so that the conductive adhesive film can be tightly adhered to a conductor, and meanwhile, because the adhesive film layer 13 does not contain conductive particles, the insertion loss in the using process is reduced, and the bending property of the conductive adhesive film is improved.
In addition, the thickness of the adhesive film layer 13 in this embodiment is 0.1 μm to 60 μm. The glue film layer 13 is made of the following materials: modified epoxy resins, acrylic resins, modified rubbers, and modified thermoplastic polyimides. The outer surface of the adhesive film layer 13 may be a flat surface without undulation or may be an uneven surface with gentle undulation.
In the embodiment of the present invention, in order to avoid contamination from impurities such as external dust, the conductive adhesive film in this embodiment further includes a first protective film layer 14 and a second protective film layer 15, the first protective film layer 14 is disposed on a surface of the adhesive film layer 13 away from the first conductive layer 12; the second protective film layer 15 is disposed on a surface of the conductive adhesive layer 11 away from the first conductive layer 12. When the conductive adhesive film is used, the first protective film layer 14 and the second protective film layer 15 need to be peeled off.
In addition, the first protective film layer 14 and the second protective film layer 15 respectively include a PPS film layer, a PEN film layer, a polyester film layer, a polyimide film layer, a film layer formed after curing epoxy resin ink, a film layer formed after curing polyurethane ink, a film layer formed after curing modified acrylic resin, or a film layer formed after curing polyimide resin.
Example two
Referring to fig. 4 and 5, the difference between the conductive adhesive film in the present embodiment and the first embodiment is that the surface of the metal protrusion 122 is provided with conductive particles 123. By arranging the conductor particles 123 on the surface of the metal protrusion 122, the piercing strength of the metal protrusion 122 is enhanced, and it is further ensured that the metal protrusion 122 can pierce the adhesive film layer 13 smoothly in the pressing process.
Preferably, the conductive particles 123 are distributed in a concentrated manner at positions protruding outward from the surface of the metal protrusion 122, so that the piercing is easier. In addition, the conductor particles 123 may also be distributed on other positions of the first conductive layer 12 near the side of the adhesive film layer 13, not only on the surface of the metal protrusion 122, as shown in fig. 4 and 5. Of course, the conductive particles 123 may also be distributed only on the surface of the metal bump 122.
In a specific implementation, as shown in fig. 4, the first conductive layer 12 and the metal bump 122 may be formed first, and then the conductor particles 123 may be formed on the first surface 124 of the first conductive layer 12 and the outer surface of the metal bump 122 through another process. Of course, the first conductive layer 12 and the conductive particles 123 may be an integral structure formed by a one-step molding process; the metal protrusions 122 and the conductive particles 123 may also be an integral structure formed by a one-step molding process, as shown in fig. 5.
In the embodiment of the present invention, the conductor particles 123 may have a certain distance from the outer surface of the adhesive film layer 13, and may also contact or extend from the outer surface of the adhesive film layer 13.
In the embodiment of the present invention, in order to ensure the piercing strength of the metal protrusion 122 to ensure that the metal protrusion 122 can pierce the adhesive film 13, the height of the conductive particles 123 is preferably 1 μm to 30 μm.
In an embodiment of the present invention, the conductive particles 123 include one or more of metal particles, carbon nanotube particles, and ferrite particles. Further, the metal particles include single metal particles and/or alloy particles; the single metal particles are made of any one of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold, and the alloy particles are made of any two or more of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold. In addition, the conductive particles 123 may be the same as or different from the metal bumps 122.
In the embodiment of the present invention, it should be noted that the shape of the conductor particles 123 as shown in fig. 4 and 5 is only exemplary, and due to the differences in the process means and parameters, the conductor particles 123 may also be in other shapes such as cluster, ice, stalactite, and dendritic shapes. In addition, the conductive particles 123 in the present invention are not limited by the shapes shown in the drawings, and any conductive particles having piercing and conductive functions are within the scope of the present invention.
In the embodiment of the present invention, in order to further ensure the piercing strength of the metal protrusion 122, it is preferable that the number of the conductive particles 123 is plural. A plurality of the conductor particles 123 may be regularly or irregularly distributed on the surface of the metal protrusion 122; a plurality of the conductor particles 123 may also be continuously or discontinuously distributed on the surface of the metal protrusion 122. Wherein, the plurality of conductor particles 123 are regularly distributed on the surface of the metal bump 122, which means that the plurality of conductor particles 123 are the same in shape and are uniformly distributed on the surface of the metal bump 122; the plurality of conductor particles 123 irregularly distributed on the surface of the metal bump 122 means that the plurality of conductor particles 123 are irregularly shaped and irregularly distributed on the surface of the metal bump 122. In addition, the sizes of the plurality of conductor particles 123 may also be set according to actual use conditions, for example, the sizes of the plurality of conductor particles 123 are set to be the same, and certainly, the sizes of the plurality of conductor particles 123 may also be set to be different, which is not described herein further.
In addition, other structures and working principles of the conductive adhesive film of the present embodiment are the same as those of the first embodiment, and are not further described herein.
EXAMPLE III
As shown in fig. 6, the difference between the conductive adhesive film in this embodiment and the first embodiment is that the conductive adhesive film includes a conductive adhesive layer 11, a first conductive layer 12 and an adhesive layer 13, which are sequentially stacked, a first through hole 121 penetrating through upper and lower surfaces of the first conductive layer 12 is formed on the first conductive layer 12, and a metal protrusion 122 is formed at the first through hole 121;
the conductive adhesive film further includes a second conductive layer 16, the second conductive layer 16 is disposed between the first conductive layer 12 and the adhesive film layer 13, and a protrusion 161 is formed at a position where the second conductive layer 16 covers the metal protrusion 122.
In the embodiment of the present invention, the first conductive layer 12 and the glue film layer 13 are disposed between the second conductive layer 16, and the second conductive layer 16 covers the protrusion 161 is formed on the position of the metal protrusion 122, so that when the conductive adhesive film is pressed together, the conductive adhesive film can pass through the conductive adhesive layer 11 and one of the conductors are electrically connected, and the protrusion 161 pierces the glue film layer 13 and the other conductor are electrically connected, thereby realizing reliable connection between the conductors.
In the embodiment of the present invention, it should be noted that the shape of the protruding portion 161 may be the same as the shape of the metal protrusion 122, or may be different from the shape of the metal protrusion 122; the shape of the boss 161 shown in the drawings is merely exemplary.
In the embodiment of the present invention, in order to further ensure that the protruding portion 161 can smoothly pierce through the adhesive film layer 13, preferably, the surface of the protruding portion 161 is provided with the conductor particles 123. By arranging the conductor particles 123 on the surface of the protruding portion 161, the piercing strength of the protruding portion 161 is enhanced, so that the protruding portion 161 can pierce the adhesive film layer 13 more easily to ensure a reliable connection with a conductor.
Preferably, the conductive particles 123 are distributed in a concentrated manner at positions protruding outward from the surface of the protrusion 161, so that the adhesive film layer 13 can be easily pierced. Of course, the non-convex portions on the surface of the convex portion 161 may have the conductive particles 123 distributed therein. In addition, the conductor particles 123 may also be distributed on other positions of the second conductive layer 16 near the surface of the adhesive film layer 13, not only on the surface of the protruding portion 161, as shown in fig. 6. Of course, the conductive particles 123 may be distributed only on the surface of the protrusion 161.
In addition, the forming process, the structure, the shape, and the like of the conductive particles 123 may refer to the description of the conductive particles 123 in the second embodiment, and are not further described herein.
In the embodiment of the present invention, the thickness of the second conductive layer 16 is preferably 0.1 μm to 45 μm, so as to ensure that the second conductive layer 16 is not easily broken and has good flexibility. It is understood that, in order to ensure that the second conductive layer 16 has good conductivity, the second conductive layer 16 includes one or more of a metal conductive layer, a carbon nanotube conductive layer, a ferrite conductive layer, and a graphene conductive layer. The metal conductive layer comprises a single metal conductive layer and/or an alloy conductive layer; the single metal conducting layer is made of any one of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold, and the alloy conducting layer is made of any two or more of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold.
In the embodiment of the present invention, it should be noted that the second conductive layer 16 in the drawings of the present embodiment may be a single-layer structure or a multi-layer structure. In addition, the second conductive layer 16 of the present embodiment can be provided in a grid shape, a foaming shape, etc. according to the requirements of actual production and application.
In addition, other structures and working principles of the conductive adhesive film of the present embodiment are the same as those of the first embodiment, and are not further described herein.
Example four
As shown in fig. 7, an embodiment of the present invention provides a circuit board, which includes a steel sheet 21 and a printed circuit board 22; the circuit board further comprises the conductive adhesive film of the first embodiment or the second embodiment, and the steel sheet 21 is pressed with the printed circuit board 22 through the conductive adhesive film; the conductive adhesive layer 11 is electrically connected with the steel sheet 21, and the metal protrusion 122 pierces the adhesive layer 13 and is electrically connected with the ground layer 221 of the printed circuit board 22.
Specifically, the printed wiring board 22 includes a printed wiring board body 221 and a ground layer 222 which are stacked, and a ground hole 223 is formed in the printed wiring board body 221; therefore, the metal bump 122 pierces through the glue film layer 13 and is electrically connected to the ground layer 222 of the printed circuit board 22, specifically: the metal bumps 122 pierce the adhesive film layer 13 and pass through the grounding holes 223, thereby electrically connecting with the ground layer 222 of the printed wiring board 22.
In the embodiment of the present invention, it should be noted that the metal bumps 122 on the conductive adhesive film may all contact with the ground layer 222 of the printed circuit board 22, or may partially contact with the ground layer 222 of the printed circuit board 22. It can be understood that the number of the grounding holes 223 can be set according to the actual use condition, and only needs to be enough to ensure that the conductive film is effectively connected with the ground layer 222 of the printed circuit board 22.
In addition, the circuit board further comprises an electromagnetic shielding film 23, and the electromagnetic shielding film 23 is arranged on the position, where the conductive adhesive film is not arranged, of the printed circuit board 22. Specifically, the electromagnetic shielding film 23 includes an insulating layer 231 and a conductor layer 232, which are stacked, the conductor layer 232 is disposed on the printed wiring board body 221, a conductor layer convex portion extending in a direction close to the ground hole 223 is disposed on a position of the conductor layer 232 opposite to the ground hole 223, and the conductor layer convex portion passes through the ground hole 223 and is electrically connected to the ground layer 222 of the printed wiring board 22.
In the embodiment of the present invention, in order to ensure the reinforcing effect of the steel sheet 21, the thickness of the steel sheet is preferably 0.05mm to 0.2 mm; in addition, the material of the steel sheet 21 may be set according to actual use conditions, and in the embodiment, the steel sheet 21 is preferably a nickel-plated steel sheet.
In the embodiment of the utility model, due to the arrangement of the steel sheet 21, the stiffness of the circuit board is enhanced, and the phenomenon that the installation part of the circuit board is deformed due to bending and other reasons can be effectively prevented, thereby being beneficial to the operations of installing and carrying printed circuit board parts and the like; meanwhile, under the matching of the conductive adhesive film and the steel sheet 21, the circuit board has good grounding stability, interference charges in the circuit board can be effectively led out, and the effect of effectively shielding external electromagnetic wave interference can be realized.
In a specific implementation, when the circuit board is applied to an electronic device, the steel sheet 21 may be connected to a housing of the electronic device, so that the interference charges accumulated in the circuit board are conducted out by the cooperation of the steel sheet 21 and the conductive adhesive film.
In addition, in this embodiment, reference may be made to the description of the first embodiment and the second embodiment for the implementation of the conductive adhesive film, and details are not repeated herein.
In the embodiment of the present invention, the printed circuit board 22 is preferably one of a flexible single-sided board, a flexible double-sided board, a flexible multi-layer board, and a rigid-flex board.
In the embodiment of the utility model, the reliable connection between the steel sheet and the printed circuit board is realized through the structure; meanwhile, the first conducting layer and the metal protrusions are arranged in the conducting adhesive film, so that the overlapping rate of conducting particles in the conducting adhesive film is increased, the problem that the conducting particles are pulled apart due to colloid expansion to increase the resistance of the conducting adhesive film at high temperature can be solved, the resistance of the conducting adhesive film is greatly reduced, the conducting performance of the conducting adhesive film is improved, and the stability of grounding is guaranteed. In addition, the arrangement of the first conducting layer and the metal protrusions reduces the use of conducting particles, so that the production cost of the conducting adhesive film is reduced, and the peeling strength of the conducting adhesive film is improved.
EXAMPLE five
As shown in fig. 8, the circuit board according to the embodiment of the present invention is different from the fourth embodiment in that the circuit board includes a steel sheet 21, a printed circuit board 22, and the conductive film according to the third embodiment, and the steel sheet 21 is pressed to the printed circuit board 22 through the conductive film; the conductive adhesive layer 11 is electrically connected with the steel sheet 21, and the protruding portion 161 pierces the adhesive layer 13 and is electrically connected with the ground layer 221 of the printed circuit board 22.
Specifically, the printed wiring board 22 includes a printed wiring board body 221 and a ground layer 222 which are stacked, and a ground hole 223 is formed in the printed wiring board body 221; therefore, the protruding portion 161 pierces through the adhesive film layer 13 and is electrically connected to the ground layer 222 of the printed circuit board 22, specifically: the boss 161 penetrates the adhesive film layer 13 and passes through the ground hole 223, thereby electrically connecting with the ground layer 222 of the printed wiring board 22.
The protrusions 161 on the conductive film may be all in contact with the ground layer 223 of the printed circuit board, or may be partially in contact with the ground layer 222 of the printed circuit board 22.
In this embodiment, reference may be made to the description of the third embodiment for the implementation of the conductive adhesive film, and details are not repeated herein. In addition, other structures and working principles of the circuit board in this embodiment are the same as those in the fourth embodiment, and further description is omitted here.
EXAMPLE six
As shown in fig. 9, the embodiment of the present invention further provides another circuit board, which includes a steel sheet 21, a printed circuit board 22, and an electromagnetic shielding film 23, where the electromagnetic shielding film 23 includes an insulating layer 231 and a conductor layer 232 that are stacked, and the electromagnetic shielding film 23 is electrically connected to the ground layer 222 of the printed circuit board 22 through the conductor layer 232;
the circuit board further comprises the conductive adhesive film of the first embodiment or the second embodiment, and the steel sheet 21 is pressed with the electromagnetic shielding film 23 through the conductive adhesive film; the conductive adhesive layer 11 is electrically connected to the steel sheet 21, and the metal protrusion 122 pierces through the adhesive layer 13 and the insulating layer 231 and is electrically connected to the conductor layer 232.
The electromagnetic shielding film 23 is electrically connected to the ground layer 222 of the printed circuit board 22 through the conductor layer 232, which is specifically represented as: the printed circuit board 22 comprises a printed circuit board body 221 and a ground layer 222 which are arranged in a stacked mode, and a grounding hole 223 is formed in the printed circuit board body 221; the conductor layer 232 is disposed on the printed wiring board body 221, and a conductor layer convex portion extending in a direction close to the ground hole 223 is disposed on a position of the conductor layer 232 opposite to the ground hole 223, and the conductor layer convex portion passes through the ground hole 223, thereby being electrically connected to the ground layer 222 of the printed wiring board 22.
In the embodiment of the present invention, through making the conductive adhesive layer 11 with the steel sheet 21 is electrically connected, and makes the metal protrusion 122 pierces through the adhesive film layer 13 with the insulating layer 231, thereby with the conductor layer 232 is electrically connected, so that the steel sheet 21 can pass through the conductive adhesive film with the electromagnetic shielding film 23 the conductor layer 232 is electrically connected, and then the realization and the stratum 222 of the printed circuit board 22 is electrically connected.
In addition, in this embodiment, reference may be made to the description of the first and second embodiments for implementation of the conductive adhesive film; regarding the thickness, the purpose, etc. of the steel sheet 21, reference is made to the description of the fourth embodiment, which is not repeated herein.
In the embodiment of the present invention, the printed circuit board 7 is preferably one of a flexible single-sided board, a flexible double-sided board, a flexible multilayer board, and a rigid-flex board.
In the embodiment of the utility model, the reliable connection between the steel sheet and the printed circuit board is realized through the structure; meanwhile, the first conducting layer and the metal protrusions are arranged in the conducting adhesive film, so that the overlapping rate of conducting particles in the conducting adhesive film is increased, the problem that the conducting particles are pulled apart due to colloid expansion to increase the resistance of the conducting adhesive film at high temperature can be solved, the resistance of the conducting adhesive film is greatly reduced, the conducting performance of the conducting adhesive film is improved, and the stability of grounding is guaranteed. In addition, the arrangement of the first conducting layer and the metal protrusions reduces the use of conducting particles, so that the production cost of the conducting adhesive film is reduced, and the peeling strength of the conducting adhesive film is improved.
EXAMPLE seven
As shown in fig. 10, the circuit board according to the embodiment of the present invention is different from the sixth embodiment in that the circuit board includes the conductive adhesive film according to the third embodiment, and the steel sheet 21 is pressed with the electromagnetic shielding film 23 through the conductive adhesive film; the conductive adhesive layer 11 is electrically connected to the steel sheet 21, and the protruding portion 161 pierces through the adhesive layer 13 and the insulating layer 231 and is electrically connected to the conductor layer 232.
The protrusions 161 on the conductive adhesive film may be all in contact with the conductive layer 232, or may be partially in contact with the conductive layer 232.
In this embodiment, reference may be made to the description of the third embodiment for the implementation of the conductive adhesive film, and details are not repeated herein. In addition, other structures and working principles of the circuit board in this embodiment are the same as those in the sixth embodiment, and further details are not described herein.
Example eight
As shown in fig. 11, an embodiment of the present invention provides a method for preparing a conductive adhesive film, which is suitable for preparing the conductive adhesive film of the first embodiment, including steps S11 to S13:
s11, forming a first conductive layer; wherein, a first through hole penetrating through the upper surface and the lower surface of the first conducting layer is formed on the first conducting layer;
in the embodiment of the present invention, preferably, the cross-sectional area of the first through hole is 0.01 μm2-1mm2(ii) a The number of the first through holes in the first conductive layer per square centimeter is 5-106And (4) respectively.
S12, forming a metal bulge at the first through hole; one end of the metal bulge extends out of the first through hole;
specifically, a fusible metal is provided at the first through hole, and is instantly cooled after flowing from one side to the other side of the first through hole at a predetermined temperature, thereby forming the metal bump at the first through hole. Wherein, the fusible metal is any one single metal or any multiple alloy of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold; the preset temperature is 300 ℃ to 2000 ℃.
And S13, forming an adhesive film layer on one side of the first conductive layer close to the metal bump, and forming a conductive adhesive layer on the other side of the first conductive layer.
Specifically, in a preferred mode, a glue film layer may be coated on one side of the first conductive layer close to the metal bump, and a conductive glue layer may be coated on the other side of the first conductive layer;
in another preferred mode, a glue film layer can be coated on a release film, and the glue film layer is transferred to one side of the first conductive layer close to the metal protrusion in a pressing mode;
and coating a conductive adhesive layer on the release film, and transferring the conductive adhesive layer to the other side of the first conductive layer in a pressing manner. The other side of the first conducting layer is the side, far away from the adhesive film layer, of the first conducting layer.
In another preferred embodiment suitable for preparing the adhesive conductive film of the second embodiment, after step S12 and before step S13, the method further comprises the steps of:
forming conductor particles on the outer surface of the metal protrusion by one or more processes of physical roughening, chemical plating, physical vapor deposition, chemical vapor deposition, evaporation plating, sputtering plating, electroplating and hybrid plating.
The embodiment of the utility model provides an in, in the conductive adhesive film first conducting layer and the metal is protruding, has increased conductive particle's overlap ratio in the conductive adhesive film to can avoid when high temperature, make its conductive particle pull open and lead to the problem of conductive adhesive film's resistance increase because the colloid inflation, thereby greatly reduced conductive adhesive film's resistance, and then improved conductive adhesive film's electric conductive property, consequently guaranteed the electric connection between the conductor. In addition, the arrangement of the first conducting layer also reduces the use of conducting particles, thereby reducing the production cost of the conducting adhesive film and improving the peeling strength of the conducting adhesive film.
Example nine
As shown in fig. 12, an embodiment of the present invention provides another method for preparing a conductive adhesive film, which is suitable for preparing the conductive adhesive film described in the third embodiment, including steps S21 to S24:
s21, forming a first conductive layer; wherein, a first through hole penetrating through the upper surface and the lower surface of the first conducting layer is formed on the first conducting layer;
in the embodiment of the present invention, preferably, the cross-sectional area of the first through hole is 0.01 μm2-1mm2(ii) a The number of the first through holes in the first conductive layer per square centimeter is 5-106And (4) respectively.
S22, forming a metal bulge at the first through hole; one end of the metal bulge extends out of the first through hole;
specifically, a fusible metal is provided at the first through hole, and is instantly cooled after flowing from one side to the other side of the first through hole at a predetermined temperature, thereby forming the metal bump at the first through hole. Wherein, the fusible metal is any one single metal or any multiple alloy of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver and gold; the preset temperature is 300 ℃ to 2000 ℃.
S23, forming a second conductive layer on one side, close to the metal bump, of the first conductive layer, and forming a bump at a position where the second conductive layer covers the metal bump;
preferably, after step S23 is performed, the conductor particles may be formed on the outer surface of the protrusion part by one or more processes of physical roughening, electroless plating, physical vapor deposition, chemical vapor deposition, evaporation plating, sputter plating, electroplating, and hybrid plating.
And S24, forming an adhesive film layer on one side of the second conductive layer far away from the first conductive layer, and forming a conductive adhesive layer on one side of the first conductive layer far away from the second conductive layer.
Specifically, in a preferred mode, a glue film layer may be coated on a side of the second conductive layer away from the first conductive layer, and a conductive glue layer may be coated on a side of the first conductive layer away from the second conductive layer;
in another preferred mode, a glue film layer can be coated on a release film, and the glue film layer is transferred to one side of the second conductive layer far away from the first conductive layer in a pressing mode;
and coating a conductive adhesive layer on the release film, and transferring the conductive adhesive layer to one side of the first conductive layer, which is far away from the second conductive layer in a pressing manner.
The embodiment of the utility model provides an in, in the conductive adhesive film first conducting layer with the metal is protruding, has increased conductive particle's overlap ratio in the conductive adhesive film to can avoid when high temperature, make its conductive particle pull open and lead to the problem of conductive adhesive film's resistance increase because the colloid inflation, thereby greatly reduced conductive adhesive film's resistance, and then improved conductive adhesive film's electric conductive property, in order to guarantee the electric connection between the conductor. In addition, the arrangement of the first conducting layer and the metal protrusions reduces the use of conducting particles, reduces the production cost of the conducting adhesive film and improves the peeling strength of the conducting adhesive film.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, a plurality of modifications and replacements can be made without departing from the technical principle of the present invention, and these modifications and replacements should also be regarded as the protection scope of the present invention.

Claims (15)

1. A conductive adhesive film is characterized by comprising a conductive adhesive layer, a first conductive layer and an adhesive film layer which are sequentially stacked, wherein the first conductive layer is provided with a first through hole penetrating through the upper surface and the lower surface of the first conductive layer, a metal bulge is arranged at the first through hole, and the metal bulge extends into the adhesive film layer; the metal protrusion is formed by cooling and solidifying a fusible metal after the fusible metal flows from one side to the other side of the first through hole at a preset temperature.
2. The conductive adhesive film according to claim 1, wherein the fusible metal is any one of aluminum, titanium, zinc, iron, nickel, chromium, cobalt, copper, silver, and gold.
3. The conductive adhesive film of claim 1, wherein the predetermined temperature is 300 ℃ to 2000 ℃.
4. The conductive adhesive film of claim 1, wherein the first conductive layer comprises a first surface in contact with the adhesive film layer, the first surface being a non-planar surface that undulates.
5. The conductive adhesive film according to claim 1, wherein the surface of the metal protrusion is provided with conductive particles; the height of the conductor particles is 1-30 μm.
6. The conductive adhesive film according to claim 5, wherein the conductive particles have a cluster shape, an ice-hanging shape, a stalactite shape, or a dendritic shape.
7. The conductive adhesive film according to claim 5, wherein the conductive particles are plural; a plurality of conductor particles are regularly or irregularly distributed on the surface of the metal protrusion; the plurality of conductor particles are continuously or discontinuously distributed on the surface of the metal protrusion.
8. The conductive adhesive film of claim 1, wherein the adhesive layer comprises an adhesive layer containing conductive particles; or the adhesive film layer comprises an adhesion layer without conductive particles.
9. The conductive adhesive film of any one of claims 1-8, wherein the first conductive layer comprises one or more of a metal conductive layer, a carbon nanotube conductive layer, a ferrite conductive layer, and a graphene conductive layer.
10. The conductive adhesive film according to any one of claims 1 to 8, wherein the number of the first through holes in the first conductive layer per square centimeter is 10 to 1000; and/or the cross-sectional area of the first through hole is 0.1 mu m2-1mm2
11. The adhesive conductive film of any one of claims 1-8, further comprising a first protective film layer and a second protective film layer, wherein the first protective film layer is disposed on a side of the adhesive film layer away from the first conductive layer; the second protective film layer is arranged on one surface, far away from the first conductive layer, of the conductive adhesive layer.
12. The adhesive conductive film according to any one of claims 1 to 8, further comprising a second conductive layer disposed between the first conductive layer and the adhesive film layer, wherein a protrusion is formed at a position where the second conductive layer covers the metal protrusion.
13. The conductive adhesive film according to claim 12, wherein the surface of the protrusion is provided with conductive particles.
14. A circuit board comprising a steel sheet and a printed wiring board, wherein the circuit board further comprises the conductive adhesive film according to any one of claims 1 to 11, and the steel sheet is laminated with the printed wiring board through the conductive adhesive film; the conductive adhesive layer is electrically connected with the steel sheet, and the metal bulge pierces through the adhesive layer and is electrically connected with the ground layer of the printed circuit board;
or, the circuit board further comprises the conductive adhesive film of claim 12 or 13, the steel sheet is laminated with the printed circuit board through the conductive adhesive film; the conductive adhesive layer is electrically connected with the steel sheet, and the protruding part pierces the adhesive layer and is electrically connected with the ground layer of the printed circuit board.
15. A circuit board comprises a steel sheet, a printed circuit board and an electromagnetic shielding film, and is characterized in that the electromagnetic shielding film comprises an insulating layer and a conductor layer which are arranged in a laminated manner, and the electromagnetic shielding film is electrically connected with the ground layer of the printed circuit board through the conductor layer;
the circuit board further comprises the conductive adhesive film as set forth in any one of claims 1 to 11, wherein the steel sheet is pressed with the electromagnetic shielding film through the conductive adhesive film; the conductive adhesive layer is electrically connected with the steel sheet, and the metal bulge pierces through the adhesive film layer and the insulating layer and is electrically connected with the conductor layer;
or, the circuit board further comprises the conductive adhesive film of claim 12 or 13, the steel sheet is pressed with the electromagnetic shielding film through the conductive adhesive film; the conductive adhesive layer is electrically connected with the steel sheet, and the protruding part pierces the adhesive layer and the insulating layer and is electrically connected with the conductor layer.
CN201821962245.2U 2018-11-26 2018-11-26 Conductive adhesive film and circuit board Withdrawn - After Issue CN209947452U (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110783022A (en) * 2018-11-26 2020-02-11 广州方邦电子股份有限公司 Conductive adhesive film, circuit board and preparation method of conductive adhesive film
WO2023092509A1 (en) * 2021-11-26 2023-06-01 京东方科技集团股份有限公司 Conductive adhesive film and preparation method therefor, and electronic device and manufacturing method therefor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110783022A (en) * 2018-11-26 2020-02-11 广州方邦电子股份有限公司 Conductive adhesive film, circuit board and preparation method of conductive adhesive film
CN110783022B (en) * 2018-11-26 2024-03-19 广州方邦电子股份有限公司 Conductive adhesive film, circuit board and preparation method of conductive adhesive film
WO2023092509A1 (en) * 2021-11-26 2023-06-01 京东方科技集团股份有限公司 Conductive adhesive film and preparation method therefor, and electronic device and manufacturing method therefor

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