CN207958032U - A kind of portable hydrotreater - Google Patents

A kind of portable hydrotreater Download PDF

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Publication number
CN207958032U
CN207958032U CN201820038701.8U CN201820038701U CN207958032U CN 207958032 U CN207958032 U CN 207958032U CN 201820038701 U CN201820038701 U CN 201820038701U CN 207958032 U CN207958032 U CN 207958032U
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water
porous
portable
layer
utility
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CN201820038701.8U
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张进
刘卫国
杨鹏飞
寇佳铭
雷嘉兴
金雨晴
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Xian Technological University
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Xian Technological University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation

Abstract

The utility model is related to solar energy hot-cast sockets to evaporate dirty water decontamination handles technical field, and in particular to a kind of portable hydrotreater.The utility model effectively increases the utilization rate of incident sunlight using solar energy condenser lens, and then improves the thermal evaporation rate of water;The filtering of bulky grain pollutant is tentatively carried out to accessing pending water using porous membrane;Using semiconductor nano material as photothermal conversion carrier, on the one hand photothermal conversion efficiency is improved, accelerate the evaporation of water, the photocatalytic effect of another aspect semi-conducting material can effectively remove the organic pollution in water, in addition, in view of the use in low-light area and night, the utility model uses electric heating assisted evaporative technology.By the processing of the present apparatus, impurity most in original water is can remove, finally obtained water quality can reach deionized water rank.The utility model by it is effective with solving pollution of waterhead and the fresh water such as island military depot lack the existence problem of water consumption in environment.

Description

A kind of portable hydrotreater
Technical field
The utility model is related to solar energy hot-cast sockets to evaporate dirty water decontamination handles technical field, and in particular to a kind of portable Formula hydrotreater.
Background technology
Population, resource and environment are three significant development problems that the world today is faced, and in resource problem, water Resource is that the mankind are most indispensable in various resources, one of irreplaceable resource, and water resources problems have become full generation today Boundary is paid close attention to the most and there is an urgent need to one of major issues for finding solution route.Really utilizable freshwater resources are rivers to the mankind A part in river and lake pool and underground water, only accounts for the 0.26% of earth total Water.Currently, there are about people more than 1,000,000,000 to be faced in the whole world The problem of shortage of water resources, estimates that, about to 2025, the world will have nearly half population lives in serious water shortage according to relevant expert Area, water resources crisis has become one of serious an important factor for restricting human kind sustainable development.Therefore, it faces increasingly tight High globalization water crisis situation, desalination technology and related industry as freshwater resources increment and substitute technology meet the tendency of and It is raw.
Currently, solar energy has received more and more attention as one of primary developing direction of regenerative resource, it will too The thermal energy that sun can generate introduces water treatment technology, and the thermal energy that on the one hand solar energy can be utilized to generate, which evaporates the water, plays removal impurity Effect;On the other hand, it can be greatly reduced using solar energy and add the cost of medicament and subsequently bring secondary pollution.Now such as The present, China are only merely that this large-scale plant of seawater desalting plant is used using desalination technology, as water in carrying(It is raw Sewage living)Or the cup of seawater cleaning function does not have substantially on the market, when people be in it is special it is severe under conditions of, such as:Water Source is impurely and the fresh water such as island military depot lack environment, and how how to purify water becomes the mankind in severe ring with sea water desalination It survives under border most crucial problem.
Currently, using less efficient, the about 3-4kg/m of traditional solar energy sewage disposal or sea water desalination2/d.And it uses The efficiency of the solar energy water cleaning systems of assisted evaporative material can reach 8-10 kg/m2/d.Generally use black is organic on the market Or inorganic particulate substance(Black naphthylamines etc.)It is mixed with accessing pending water, to increase the endothermic effect of water, to accelerate water Evaporation.However, on the one hand substance of this kind is difficult to recycle, secondary pollution is on the other hand brought.In recent years, it is a kind of it is novel too The method of positive energy assisted evaporative sea water desalination causes the extensive concern of educational circles, uses black carbon material(Graphene, carbon nanometer Pipe and graphene oxide)Or nano-metal particle is suspended in liquid level, it is made fully to be infiltrated on accessing pending water, is irradiated in solar energy Under, black material absorbs most of heat in sunlight, and heat is confined to liquid level surface layer, substantially increases the evaporation of water Efficiency, evaporation rate is up to 1.5kg/m2/ h, if using its evaporation rate of solar concentrating system to may be up to 8-10 kg/ again m2/h.Auxiliary material is only laid in liquid level by this method, has both been convenient for recycling again, will not have been generated secondary pollution. But this assisted evaporative method can only filter out the metal ion in water, it can not be by the organic pollution in water also together It decomposes.
Utility model content
The utility model is in order to solve the above technical problems, provide a kind of portable hydrotreater.
In order to solve the problems existing in the prior art, the technical solution of the utility model is:A kind of portable hydrotreater, It is characterized in that:Including pure water collection device, pending water storage device and upper cover, the upper cover is set to pure water collection device At upper opening, the upper opening button of pure water collection device is equipped with conical flow guiding lid, and conical flow guiding lid is set in upper cover, upper cover Top be provided with solar energy condenser lens, setting water storage device to be handled, pending water storage in the pure water collection device The water deflector formed by water guide material is provided on the inner wall of device, the top lower end of water deflector is provided with insulation material layer, top Portion upper end is provided with porous electric heating assisted evaporative layer, and the upper surface of the porous electric heating assisted evaporative layer is provided with porous filter Film, the upper surface of porous membrane are provided with assisted evaporative Catalytic Layer, the pure water collection device, pending water storage device and on Lid is water white transparency material;
The assisted evaporative Catalytic Layer is made of black semiconductor nano material, and black semiconductor nano material selects copper Indium sulphur (CuInS2), copper indium selenide (CuInSe2), copper indium gallium selenide (CuInGaSe2), copper and tin sulphur (Cu2SnS3), copper-zinc-tin-sulfur (Cu2ZnSnS4), copper-zinc-tin-selenium (Cu2ZnSnSe4), copper zinc tin sulfur selenium (Cu2ZnSn(SSe)4) one or two kinds of above material The mixing of material;The pattern of nano material is nanosphere, nanometer sheet, nano particle or nano flower, and particle diameter distribution is 5 ~ 500nm;
The solar energy condenser lens, which are round biconvex lens, planoconvex spotlight, compound lens or Fresnel Lenses, optics, to be had Effect bore is 80 ~ 150mm, and focal length is 50 ~ 100mm, and it is colouless optical glass or colourless optical plastic to prepare material;
For the conical flow guiding lid in coniform, it is colouless optical glass or colourless optical plastic to prepare material, high by 25 ~ The working surface of 50mm, 80 ~ 150mm of bore, conical flow guiding lid carry out the hydrophobic fluorinated processing of low-surface-energy.
It is connected with power supply on the porous electric heating assisted evaporative layer.
The water system filter membrane or hybrid films in 0.22 micron or 0.45 micron of the aperture of porous membrane selection, diameter 50 ~ 100mm。
50 ~ 100mm of diameter of the porous electric heating assisted evaporative layer, including porous material substrate, resistance wire and electrode; The electrode is set to the both ends of resistance wire, and resistance wire is set in porous material substrate;
The porous material substrate selects porous ceramics or porous membrane;
For the resistance wire using alloy, simple metal or nonmetallic, alloy is nickel chromium triangle or iron nickel;Simple metal is molybdenum, tungsten Or tantalum;Nonmetallic is graphite or silicon carbide, the processing of resistance wire surface insulation;
The electrode is using gold, the metal of titanium or platinum good conductivity and acid-alkali-corrosive-resisting.
The heat-barrier material of the insulation material layer selects foamed plastics, aerogel heat-proof felt or vacuum insulation panel.
The power supply is hand generator, portable type solar energy battery component or all kinds of accumulators.
Compared with prior art, as follows the advantages of the utility model:
1, the utility model realizes Water warfare, black semiconductor using black semiconductor nano material assisted evaporative Catalytic Layer Nano material has the higher absorption coefficient of light and larger specific surface area, can promote the thermal energy that is converted into of solar energy highly effective Desalination function is realized in the evaporation of water;
2, the semi-conducting material for the black that the utility model uses, the principle based on conductor photocatalysis, in visible region Ability with apparent photocatalysis Decomposition organic matter can decompose the organic matter in water, realize the further purification of water;
3, the utility model is designed using solar energy condenser lens and electric heating assisted evaporative, either in the item for having solar irradiation It can be used under part or in low-light area and night, water evaporation rate can be improved, under good illumination condition, can be used too Positive energy battery component realizes electric heating auxiliary heating, realizes real environmentally protective Water warfare;
4, the utility model uses solar energy condenser lens, is greatly improved the evaporation rate of water;
5, the utility model conical flow guiding lid working surface is greatly improved pure water by the hydrophobic fluorinated processing of low-surface-energy Water conservancy diversion and collection efficiency.
6, thermal energy is limited in evaporation region by the utility model using heat-barrier material, effectively reduces the heat waste of evaporation region It loses.
7, the concrete function of utility model device is embodied in:Water is carried out by capillary water guide material and filter membrane first Preliminary filtering, then by semi-conducting material under focusing sunlight photograph, on the one hand auxiliary accelerates the evaporation of water;On the other hand, Due to the photocatalysis effect of semi-conducting material, effectively degraded to the organic pollution in water, it can effective mistake to reach Filter metal ion also can degradation of organic substances purpose,
8, the utility model will push the practicalization of inexpensive water process, and the existence in dysdipsia area can also used Water problems obtains most basic guarantee.
Description of the drawings
Fig. 1 is the structural schematic diagram of the utility model;
Fig. 2 is porous electric heating assisted evaporative schematic diagram of a layer structure;
In figure:Reference sign:1-solar energy condenser lens, 2-upper covers, 3-conical flow guiding lids, 4-assisted evaporatives are urged Change layer, 5-porous membranes, 6-porous electric heating assisted evaporative layers, 7-water guide material layers, 8-insulation material layers, 9-is pending Water storage device, 10-accessing pending waters, 11-pure water, 12-pure water collection devices, 13-external power supplys, 14-porous material bases Bottom, 15-resistance wires, 16-electrodes.
Specific implementation mode
In order to make the purpose of the utility model, technical solutions and advantages more clearly understood, below in conjunction with attached drawing and implementation Example, the present invention will be further described in detail.It should be appreciated that specific embodiment described herein is only used to explain The utility model is not used to limit the utility model.
A kind of portable hydrotreater, including pure water collection device 12, pending water storage device 9 and upper cover 2, described is upper Lid 2 is set at the upper opening of pure water collection device 12, and the upper opening button of pure water collection device 12 is equipped with conical flow guiding lid 3, conical flow guiding lid 3 is set in upper cover 2, and the top of upper cover 2 is provided with solar energy condenser lens 1, the pure water collection device Water storage device 9 to be handled is set in 12, the water guide formed by water guide material 7 is provided on the inner wall of pending water storage device 9 The top lower end of device, water deflector is provided with insulation material layer 8, and top upper end is provided with porous electric heating assisted evaporative layer 6, described The upper surface of porous electric heating assisted evaporative layer 6 is provided with porous membrane 5, and the upper surface of porous membrane 5 is provided with assisted evaporative and urges Change layer 4.
It is connected with power supply 13 on the porous electric heating assisted evaporative layer 6.
The solar energy condenser lens 1 are round biconvex lens, planoconvex spotlight, compound lens or Fresnel Lenses, optics Effective aperture is 80 ~ 150mm, and focal length is 50 ~ 100mm, and it is colouless optical glass or colourless optical plastic to prepare material.
For the conical flow guiding lid 3 in coniform, it is colouless optical glass or colourless optical plastic to prepare material, high by 25 The working surface of ~ 50mm, 80 ~ 150mm of bore, conical flow guiding lid carry out the hydrophobic fluorinated processing of low-surface-energy, are conducive to pure water Water conservancy diversion and collection.
The assisted evaporative Catalytic Layer 4 is made of black semiconductor nano material, and black semiconductor nano material is selected Indium sulphur (CuInS2), copper indium selenide (CuInSe2), copper indium gallium selenide (CuInGaSe2), copper and tin sulphur (Cu2SnS3), copper-zinc-tin-sulfur (Cu2ZnSnS4), copper-zinc-tin-selenium (Cu2ZnSnSe4), copper zinc tin sulfur selenium (Cu2ZnSn(SSe)4) one or two kinds of above material The mixing of material;The pattern of nano material is nanosphere, nanometer sheet, nano particle or nano flower, and particle diameter distribution is 5 ~ 500nm.
The water system filter membrane or hybrid films in 0.22 micron or 0.45 micron of the aperture of the selection of porous membrane 5, diameter 50 ~ 100mm。
50 ~ 100mm of diameter of the porous electric heating assisted evaporative layer 6, including porous material substrate 14,15 and of resistance wire Electrode 16;The electrode 16 is set to the both ends of resistance wire 15, and resistance wire 15 is set in porous material substrate 14;
The porous material substrate 14 selects porous ceramics or porous membrane;
For the resistance wire 15 using alloy, simple metal or nonmetallic, alloy is nickel chromium triangle or iron nickel;Simple metal be molybdenum, Tungsten or tantalum;Nonmetallic is graphite or silicon carbide, the processing of resistance wire surface insulation;
The electrode 16 is using gold, the metal of titanium or platinum good conductivity and acid-alkali-corrosive-resisting.
The heat-barrier material of the insulation material layer selects foamed plastics, aerogel heat-proof felt or vacuum insulation panel.
The power supply 13 is hand generator, portable type solar energy battery component or all kinds of accumulators.
The upper cover uses cylindrical structure, and high 30 ~ 60mm, 80 ~ 150mm of bore, it can be non-colored light to prepare material Learn glass or colourless optical plastic.
Described water guide material selection cotton, long fibered paper, silk and organic polymeric fiber etc.;
Pending water storage device uses cylinder design, and 0.3 ~ 1 liter of volume, it is colouless optical glass or nothing to prepare material Color optical plastic.
Pure water collection device uses cylinder design, and 0.5 ~ 2 liter of volume, it is colouless optical glass or colourless to prepare material Optical plastic.
A kind of working method of portable hydrotreater is:Accessing pending water 10 is placed in pending water storage device 9, is utilized For water deflector made of water guide material 7 by the uniform water conservancy diversion of accessing pending water to region to be evaporated, accessing pending water 10 is auxiliary due to porous electric heating The capillary force action helped in evaporation layer 6 and porous membrane 5 is urged by uniform water conservancy diversion to black semiconductor nano material assisted evaporative Change in layer 4, realize preliminary purification, it is auxiliary that incident sunlight converged to black semiconductor nano material using solar energy condenser lens 1 It helps in evaporation Catalytic Layer 4, realizes photothermal conversion and conductor photocatalysis reaction, desalination and Organic substance in water are carried out to accessing pending water Degradation treatment, and at either pure steam, either pure steam is further condensed on pure water to conical flow guiding lid 3, due to conical flow guiding lid 3 Ramp type design, pure water 11 converges along slope in pure water collection device 12, and insulation material layer 8 is by water evaporation region and waits locating It manages 10 storage zones of water to separate, reduces the heat loss of evaporation region, assist steaming by porous electric heating at low-light area and night It sends out layer 6 and connects external power supply 13, realize electric heating assisted evaporative.
Embodiment 1, the Fresnel Lenses that solar energy condenser lens are prepared using the colourless plastics of optics, optics effective aperture 80mm, focal length 50mm;Upper cover is prepared using the colourless plastics of optics, high 30mm, bore 80mm;Conical flow guiding lid is colourless using optics Prepared by plastics, high 25mm, bore 80mm, and working surface carries out the hydrophobic fluorinated processing of low-surface-energy;Black semiconductor nano material Assisted evaporative Catalytic Layer uses the copper-zinc-tin-selenium (Cu of grain size 200nm2ZnSnSe4) nanosphere;Porous membrane uses diameter 50mm, 0.22 micron of water system filter membrane;Porous electric heating assisted evaporative layer is using porous ceramics as substrate, diameter 50mm, resistance wire use Nichrome wire brushed with insulated paint, electrode use titanium;Water guide material uses cotton;Heat-barrier material uses foamed plastics, Pending water storage device is prepared using colourless optical plastic, 0.3 liter of volume;Pure water collection device uses colourless optical plastic system It is standby, 0.5 liter of volume;External power supply selects hand generator.
Embodiment 2, the biconvex lens that solar energy condenser lens are prepared using optics flint glass, optics effective aperture 150mm, Focal length 100mm;Upper cover is prepared using optics flint glass, high 60mm, bore 150mm;Conical flow guiding lid uses the colourless glass of optics Prepared by glass, 50mm, bore 150mm, and working surface carries out the hydrophobic fluorinated processing of low-surface-energy;Black semiconductor nano material assists Evaporate the indium sulphur (CuInS that Catalytic Layer uses grain size 5nm2) nano particle;Porous membrane is using diameter 100mm, 0.45 micron Water system filter membrane;Porous electric heating assisted evaporative layer is using porous ceramics as substrate, and diameter 100mm, resistance wire, which uses, to be brushed with absolutely The tungsten filament of edge paint, electrode is using gold;Water guide material uses long fibered paper;Heat-barrier material uses vacuum insulation panel, pending water storage Device is prepared using colouless optical glass, 1 liter of volume;Pure water collection device is prepared using colouless optical glass, 2 liters of volume;Outside It connects power supply and selects accumulator.
Embodiment 3, the planoconvex spotlight that solar energy condenser lens are prepared using optics flint glass, optics effective aperture 100mm, Focal length 100mm;Upper cover is prepared using the colourless plastics of optics, high 50mm, bore 100mm;Conical flow guiding lid uses the colourless modeling of optics Prepared by material, 40mm, bore 100mm, and working surface carries out the hydrophobic fluorinated processing of low-surface-energy;Black semiconductor nano material assists Evaporate the copper-zinc-tin-sulfur (Cu that Catalytic Layer uses grain size 500nm2ZnSnS4) nano flower;Porous membrane uses diameter 60mm, and 0.45 is micro- The mixing filter membrane of rice;Porous electric heating assisted evaporative layer is using porous membrane as substrate, and diameter 60mm, resistance wire, which uses, to be brushed with absolutely The graphite silk of edge paint, electrode use platinum;Water guide material uses organic polymeric fiber;Heat-barrier material uses aerogel heat-proof felt, Pending water storage device is prepared using colourless optical plastic, 0.75 liter of volume;Pure water collection device uses colourless optical plastic system It is standby, 1.5 liters of volume;External power supply selects solar cell module.
In conclusion the utility model not only can carry out bulky grain pollutant filtering by filter membrane to accessing pending water, The removal of desalination and organic pollution can be carried out to water by thermal evaporation and light-catalyzed reaction, final obtain has deionized water grade Other purified water.The utility model by it is effective with solving pollution of waterhead and the fresh water such as island military depot lack the existence in environment and use Water problems.
The above, the only preferred embodiment of the utility model, are not intended to limit the protection of the utility model Range.

Claims (6)

1. a kind of portable hydrotreater, it is characterised in that:Including pure water collection device(12), pending water storage device(9)With Upper cover(2), the upper cover(2)It is set to pure water collection device(12)Upper opening at, pure water collection device(12)It is upper Opening button is equipped with conical flow guiding lid(3), conical flow guiding lid(3)It is set to upper cover(2)It is interior, upper cover(2)Top be provided with too Positive energy condenser(1), the pure water collection device(12)Interior setting water storage device to be handled(9), pending water storage device (9)Inner wall on be provided with by water guide material(7)The top lower end of the water deflector of formation, water deflector is provided with insulation material layer (8), top upper end is provided with porous electric heating assisted evaporative layer(6), the porous electric heating assisted evaporative layer(6)Upper surface set It is equipped with porous membrane(5), porous membrane(5)Upper surface be provided with assisted evaporative Catalytic Layer(4), the pure water collection device (12), pending water storage device(9)And upper cover(2)It is water white transparency material;
The solar energy condenser lens(1)For round biconvex lens, planoconvex spotlight, compound lens or Fresnel Lenses, optics has Effect bore is 80 ~ 150mm, and focal length is 50 ~ 100mm, and it is colouless optical glass or colourless optical plastic to prepare material;
The conical flow guiding lid(3)In coniform, it is colouless optical glass or colourless optical plastic to prepare material, high by 25 ~ The working surface of 50mm, 80 ~ 150mm of bore, conical flow guiding lid carry out the hydrophobic fluorinated processing of low-surface-energy.
2. a kind of portable hydrotreater according to claim 1, it is characterised in that:The porous electric heating assisted evaporative Layer(6)On be connected with power supply(13).
3. a kind of portable hydrotreater according to claim 1 or 2, it is characterised in that:The porous membrane(5)Choosing With 0.22 micron or 0.45 micron of the water system filter membrane or hybrid films in aperture, 50 ~ 100mm of diameter.
4. a kind of portable hydrotreater according to claim 3, it is characterised in that:The porous electric heating assisted evaporative Layer(6)50 ~ 100mm of diameter, including porous material substrate(14), resistance wire(15)And electrode(16);The electrode(16) It is set to resistance wire(15)Both ends, resistance wire(15)It is set to porous material substrate(14)On;
The porous material substrate(14)Select porous ceramics or porous membrane;
The resistance wire(15)Using alloy, simple metal or nonmetallic, alloy is nickel chromium triangle or iron nickel;Simple metal is molybdenum, tungsten Or tantalum;Nonmetallic is graphite or silicon carbide, the processing of resistance wire surface insulation;
The electrode(16)Using gold, the metal of titanium or platinum good conductivity and acid-alkali-corrosive-resisting.
5. a kind of portable hydrotreater according to claim 4, it is characterised in that:The insulation material layer it is heat-insulated Material selection foamed plastics, aerogel heat-proof felt or vacuum insulation panel.
6. a kind of portable hydrotreater according to claim 2, it is characterised in that:The power supply(13)For hand Generator, portable type solar energy battery component or all kinds of accumulators.
CN201820038701.8U 2018-01-10 2018-01-10 A kind of portable hydrotreater Active CN207958032U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108558100A (en) * 2018-01-10 2018-09-21 西安工业大学 A kind of portable type solar energy photothermal conversion purifier for treating water
CN111819944A (en) * 2020-07-21 2020-10-27 鲁东大学 Desalination method for repairing saline soil by combining plant bionics and salinity crystallization inhibitor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108558100A (en) * 2018-01-10 2018-09-21 西安工业大学 A kind of portable type solar energy photothermal conversion purifier for treating water
CN108558100B (en) * 2018-01-10 2024-01-26 西安工业大学 Portable solar photo-thermal conversion water treatment purification device
CN111819944A (en) * 2020-07-21 2020-10-27 鲁东大学 Desalination method for repairing saline soil by combining plant bionics and salinity crystallization inhibitor

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