CN109104137A - A kind of common pole-type power generator being collected simultaneously rainwater energy and solar energy - Google Patents

A kind of common pole-type power generator being collected simultaneously rainwater energy and solar energy Download PDF

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Publication number
CN109104137A
CN109104137A CN201811057833.6A CN201811057833A CN109104137A CN 109104137 A CN109104137 A CN 109104137A CN 201811057833 A CN201811057833 A CN 201811057833A CN 109104137 A CN109104137 A CN 109104137A
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power generator
energy
gate
solar
layer
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程广贵
吴晔盛
丁建宁
刘启
张忠强
袁宁
袁宁一
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Jiangsu University
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Jiangsu University
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    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S10/00PV power plants; Combinations of PV energy systems with other systems for the generation of electric power
    • H02S10/10PV power plants; Combinations of PV energy systems with other systems for the generation of electric power including a supplementary source of electric power, e.g. hybrid diesel-PV energy systems
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02NELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N1/00Electrostatic generators or motors using a solid moving electrostatic charge carrier
    • H02N1/04Friction generators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Photovoltaic Devices (AREA)

Abstract

The present invention relates to electrostatic friction, solar battery, field of energy conversion, refer in particular to a kind of common pole-type power generator that can be collected simultaneously rainwater energy and solar energy.Present invention proposition is covered on solar cell surface with a kind of friction nanometer power generator of transparent independent layer model, instead of the protection board of conventional solar cell surface top layer, and together with solar battery surface grid line, forms a kind of common pole-type combined generating device.This common pole-type combined generating device collects solar energy as usual and carries out photovoltaic power generation in fine day, and when the rainy day, photovoltaic efficiency was greatly reduced, it is collected simultaneously rainwater energy and carries out triboelectricity.On the one hand transparent friction nanometer power generator in the invention can be used as the protective layer of solar battery, do not influence the photovoltaic efficiency of solar battery, on the other hand, and can collect the energy of rainwater in nature, be to the effective supplement of one kind of photovoltaic power generation.

Description

A kind of common pole-type power generator being collected simultaneously rainwater energy and solar energy
Technical field
The present invention relates to electrostatic friction, solar battery, field of energy conversion, refer in particular to one kind can be collected simultaneously rainwater can and The common pole-type power generator of solar energy.
Background technique
Energy problem be influence one of human progress and the significant problem of sustainable development, it is various around new energy development, The research of renewable energy recycling progress like a raging fire all over the world;Solar energy is as a kind of inexhaustible, use The inexhaustible environmentally friendly energy, be one of most promising new energy.Solar battery utilizes photoelectric effect or photochemistry Solar energy is converted into electric energy by effect, is the most effective form of Solar use;It realizes and receives for the first time from Wang Zhonglin in 2006 Since rice generator collecting mechanical energy, the mechanical energy collection technology based on piezoelectricity and triboelectric effect is deep extensive by scientific circles Concern becomes self energizing microelectronic element and system, by integrating in order to improve efficiency, it will usually while using two or two A above energy extraction element realizes collaborative work or complementary;One kind according to the present invention can be collected simultaneously rainwater energy and the sun The common pole-type power generator of energy has just accepted the above theory;Application No. is 201410380160.3 Chinese patent applications to disclose A kind of compound energy device and electricity-generating method, carry out photovoltaic power generation by solar battery, are aided with friction generator and collect rain Water energy amount carry out triboelectricity, but the friction nanometer power generator use single electrode mode, the unit time transfer total amount of electric charge compared with Few, the electric current of output is lower, and friction nanometer power generator and solar battery respectively use oneself independent electrode, and the nanometer that rubs Generator also needs additional ground terminal, increases circuit connection and energy consumption external between unit, reduces power generation effect Rate;Application No. is 201710943534.1 Chinese patent applications to disclose the energy collecting device and the energy of a kind of shared electrode System integrates solar battery and friction nanometer power generator, and friction nanometer power generator and solar battery will be silver-colored electric Pole is as a shared electrode, but friction nanometer power generator uses single electrode mode, the total amount of electric charge of unit time transfer compared with Few, the electric current of output is lower, and needs additional ground terminal.
Summary of the invention
Technical problem solved by the present invention is decline for rainy season or night rainy day solar cell power generation efficiency, and Surface is easy contaminated, accumulation dust in solar battery use process, seriously affects generating efficiency and needs often cleaning etc. Problem.
The invention proposes the common pole-type power generator that one kind can be collected simultaneously rainwater energy and solar energy, to make up the rainy day too The low deficiency of positive cell conversion efficiency;In fine day, after sunlight penetrates transparent friction nanometer power generator, solar battery does as usual It collects solar energy and carries out photovoltaic power generation, in the rainy day, photovoltaic efficiency is greatly reduced, and friction nanometer power generator collects rainwater Energy carries out triboelectricity;On the one hand transparent friction nanometer power generator is protected as the solar battery for not influencing photoelectric conversion efficiency On the other hand backplate, and can collect the energy of rainwater in nature, which uses independent layer model, The quantity of electric charge shifted in unit time is more, and output electric current is larger, ground terminal that should not be additional;And friction nanometer power generator and too Positive energy battery shares solar cell surface gate electrode, reduces circuit connection and energy consumption external between unit, improves Generating efficiency.The present invention by share solar battery surface gate electrode, by the solar panel of photovoltaic power generation and friction Nano generator is organically combined, and a kind of common pole-type combined generating device is formed, and is had widely in field of renewable energy Application prospect.
To achieve the above object, the present invention proposes to be covered on a kind of friction nanometer power generator of transparent independent layer model Solar cell surface, instead of the protection board of conventional solar cell surface top layer, and together with solar battery surface grid line, Form a kind of common pole-type combined generating device.This common pole-type combined generating device collects solar energy in fine day as usual Photovoltaic power generation is carried out, and when the rainy day, photovoltaic efficiency was greatly reduced, it is collected simultaneously rainwater energy and carries out triboelectricity.The hair On the one hand transparent friction nanometer power generator in bright can be used as the protective layer of solar battery, do not influence the light of solar battery Efficiency is lied prostrate, on the other hand, and the energy of rainwater in nature can be collected, is to the effective supplement of one kind of photovoltaic power generation.
Common pole-type combined generating device proposed by the present invention, comprising: solar battery is covered on solar cell surface The rectification circuit of transparent friction nanometer power generator and friction generator.Wherein: the friction nanometer power generator is independent stratum mould The friction nanometer power generator of formula is made of gate-shaped electrode layer and transparent frictional layer from bottom to top, wherein gate-shaped electrode layer is by first Group gate-shaped electrode layer and second group of gate-shaped electrode layer are constituted, and the lower surface of the transparent frictional layer is printed on first group of gate-shaped electrode Layer, solar battery plate surface gate line electrode are used as second group of gate-shaped electrode layer, first group of gate-shaped electrode and solar-electricity simultaneously Pond plate surface gate line electrode is alternatively arranged along solar cell surface gate line electrode orientation.The rectification circuit is by rectifier bridge It constitutes, rectifier bridge any end is connected by conducting wire and first group of gate-shaped electrode layer of friction nanometer power generator, and the other end passes through Conducting wire is connected with one end of energy storage device, and one end of energy storage device passes through second group of grid of conducting wire and friction nanometer power generator again The connection of shape electrode layer.The solar battery preparation is square on flexible substrates, from bottom to top by flexible substrate, solar battery Hearth electrode, solar battery PN junction, solar battery plate surface gate line electrode composition.
Preferably, the material of the transparent frictional layer is transparent insulation material, can for one of llowing group of materials or It is several: polytetrafluoroethylene (PTFE), dimethyl silicone polymer, polyethylene, polypropylene, polystyrene and polyethylene terephthalate, and It is flexible material.
Preferably, the surface of the transparent frictional layer is hydrophobic structure, and the surface of frictional layer has super-hydrophobicity.
Preferably, the transparent friction layer surface has hydrophobic structure, and the hydrophobic structure is one-dimensional or two-dimentional micro-nano knot Structure is nano-pillar, nanocone, micron cone, nano particle, nano flower, nanometer channel, micron trenches, and nanosphere and micron are spherical One of which in structure, and the array formed by aforementioned structure.
Preferably, the hydrophobic structure is prepared by template or lithographic methods in the upper surface of the transparent frictional layer It forms.
Preferably, the transparent frictional layer with a thickness of 100nm-0.5mm.
Preferably, the material of first group of gate-shaped electrode layer is transparent conductive film TCO, Indium-tin Oxide Transparent Conductive Film ITO, fluorine-doped tin oxide transparent conductive film FTO, aluminum-doped zinc oxide transparent conductive film AZO, conductive hydrogel use silver nanoparticle The dispersion liquid of line is printed in frictional layer lower surface by industrial silk-screen printing technique, and is flexible material;First group The grid line width of gate-shaped electrode layer is 0.1mm-0.5mm.
Preferably, the friction nanometer power generator fits closely encapsulation using the packaging technology in manufacture of solar cells And it is fixed on solar battery upper surface.
Preferably, the angular range on the surface and ground of the transparent frictional layer of the friction nanometer power generator be 20 ° extremely 70°。
Preferably, the solar battery is flexible thin-film solar cell.
Preferably, the friction nanometer power generator is flexible friction nano generator, is packaged in solar cell surface.
Preferably, the present invention provides a kind of energy collecting devices of shared electrode, including solar battery, friction nanometer Generator and full bridge rectifier, the solar battery and the friction nanometer power generator share second group of gate-shaped electrode (i.e. Solar cell surface gate line electrode).
Preferably, the present invention also provides a kind of electricity-generating methods, and sunlight is through the transparent friction nanometer power generator irradiation Photoelectric conversion is carried out to the solar battery;And/or the rainwater of electrically charged raindrop or flowing is in the friction nanometer generating The transparent friction layer surface of machine is slided, and sense is generated between first group of gate-shaped electrode layer and second group of gate-shaped electrode layer It answers charge and forms electric current.
Compared with prior art, the invention has the advantages that;
1, the invention proposes one kind can be collected simultaneously the common pole-type power generator of rainwater energy and solar energy, for simultaneously or The solar energy and rainwater energy in nature under different weather situation are collected respectively.The compound power-generating battery system is independent by two sets Electrification component constitute, lower layer is solar battery, by photovoltaic effect collect sunshine in through friction nanometer power generator too Sunlight energy;Upper layer is transparent friction nanometer power generator, collects rainy day rain by " frictional electricity " and " electrostatic induction " effect The electrostatic energy of water, while friction nanometer power generator is also used as solar cell surface protection board.
2, one kind proposed by the present invention can be collected simultaneously the common pole-type power generator of rainwater energy and solar energy, and when fine day can The effective photoelectric conversion for guaranteeing solar energy, when rainy day photovoltaic efficiency is greatly reduced, friction nanometer power generator collects rainwater energy Amount carries out power generation output, is to a kind of insufficient useful supplement of rainy day solar battery transformation efficiency.The present invention has expanded single A kind of completely new compound green power generation device using the power generator of the solar panel of photovoltaic power generation, rainwater compared with More areas and rainwater more season have extensive practical application value.
3, the friction nanometer power generator uses independent layer model, and the quantity of electric charge shifted within the unit time is more, output Electric current is larger, and does not need additional ground terminal.
4, the solar battery and the friction nanometer power generator include second group of gate-shaped electrode layer being used in conjunction with (i.e. solar cell surface gate line electrode layer) reduces circuit connection and energy consumption external between unit, improves hair Electrical efficiency.
5, the present invention in friction nanometer power generator layers of material, be in sunlight wave band it is transparent, almost without absorption, class Like the protection board of existing commercial solar cell plate, absorption of the solar battery to daylight is not influenced, i.e., does not influence solar-electricity The photoelectric conversion efficiency of pond plate.
6, the frictional layer surface hydrophobicity structure of friction nanometer power generator has self-cleaning function, it will help maintains friction The friction layer surface of nano generator is clean, ensure that and uses in environment outdoors, effective output of solar cell, while effectively Reduce the cost of manual maintenance.
Detailed description of the invention
By attached drawing, summary of the invention of the invention and its purpose, feature and advantage will be more clear.Phase in all the attached drawings Same appended drawing reference indicates identical part.Attached drawing deliberately is not drawn by actual size equal proportion scaling, it is preferred that emphasis is is shown Purport of the invention.
Fig. 1 is the structural schematic diagram of common pole-type power generator of the present invention.
Fig. 2 is friction nanometer power generator gate-shaped electrode schematic diagram in common pole-type power generator of the present invention.
Fig. 3 is rectification circuit schematic diagram of the present invention.
Fig. 4 is working principle diagram of the friction nanometer power generator when raining in common pole-type power generator of the present invention;(a) raindrop The working principle diagram to fall when touching friction nanometer power generator;(b) working principle diagram of raindrop sliding process.
It is below the explanation and illustration of each code name in figure: 10, common pole-type power generator 11, friction nanometer power generator 12, too Positive energy battery;111, transparent frictional layer, 112, first groups of gate-shaped electrode layers, 113, second groups of gate-shaped electrode layer (i.e. solar-electricities Pond plate surface gate line electrode), 121, solar cell PN junction, 122, solar battery bottom electrode layer, 123, flexible substrate
Specific embodiment
The present invention provides a kind of solar battery by single photovoltaic power generation and the friction nanometer of transparent independent layer model is sent out The common pole-type power generator that motor combines.In fine day, after sunlight penetrates friction nanometer power generator, solar battery does as usual It collects solar energy and carries out photovoltaic power generation, when the rainy day, photovoltaic efficiency was greatly reduced, be aided with friction nanometer power generator receipts Collect rainwater energy and carries out triboelectricity;Transparent friction nanometer power generator is on the one hand as the solar energy for not influencing photoelectric conversion efficiency On the other hand battery protecting plate, and can collect the energy of rainwater in nature.
Specific embodiment party of the invention is discussed in detail in technical solution to facilitate the understanding of the present invention with reference to the accompanying drawing Method.
It is a kind of schematic diagram of typical structure of common pole-type power generator 10 provided by the invention, comprising: too referring to Fig. 1 Positive energy battery 11, covers friction nanometer power generator 12 and friction nanometer power generator rectification circuit group on the solar cell At, in which: the friction generator is made of gate-shaped electrode layer and the stacking of transparent frictional layer 111 from bottom to top, wherein palisade electricity Pole layer is made of first group of gate-shaped electrode layer 112 and second group of gate-shaped electrode layer 113 (solar battery plate surface gate line electrode), The lower surface of transparent frictional layer 111 is printed on first group of gate-shaped electrode layer 112, and second group of gate-shaped electrode layer 113 is located at solar-electricity 121 surface of pond PN junction;As shown in Fig. 2, first group of gate-shaped electrode layer 112 and second group of gate-shaped electrode layer 113 are along solar battery Surface gate line electrode orientation is alternatively arranged and connects with energy storage devices such as rectification circuit and batteries, rectification circuit such as Fig. 3 It is shown.The solar battery is by taking flexible thin-film solar cell as an example, from bottom to top by flexible substrate 123, solar battery Hearth electrode 122, solar cell PN junction 121, solar battery plate surface gate line electrode form, wherein solar battery plate surface grid Line electrode is the shared electrode with friction nanometer power generator.Friction nanometer power generator is packaged and fixes table on the solar cell Face.For solar battery by solar battery plate surface gate line electrode as positive electrode, solar energy hearth electrode 122 is used as negative electrode, The electric current that photovoltaic effect generates inputs energy storage system by solar battery hearth electrode 122 and solar battery plate surface gate line electrode In system, the energy storage device of the energy-storage system and friction nanometer power generator is not shared, and is two independent energy storage devices.Rub nanometer Generator is independent layer model, and rainwater is exchange in the electric current that the friction layer surface sliding process of friction nanometer power generator generates Electricity, can first pass through rectification circuit becomes direct current, then accesses external circuit again or energy storage device stores.The compound power-generating Friction nanometer power generator and this two sets of electrification components of solar battery are mutually indepedent in device, can be under different weather conditions Output electric energy outward.
Fig. 4 is the electricity generating principle schematic diagram of friction generator.The rainfall generated in cloud layer is in the sky in dropping process, with sky Gas and aerial molecule rub, and generate and carry triboelectric charge.The polarity of triboelectric charge entrained by raindrop is by working as When cloud layer charging property and dropping process in fine particle in the air and air that are rubbed determine, can be positive charge, But negative electrical charge.For the sake of simplicity, in Fig. 4 (a), it is assumed that entrained triboelectric charge is positive charge in raindrop.When carrying positive electricity When the raindrop of lotus are dropped on the surface of frictional layer polytetrafluoroethylene film, due to electrostatic induction, in first group of gate-shaped electrode layer Between 112 and second group of gate-shaped electrode layer 113, a positive potential difference values are formed, this potential difference is by first group of gate-shaped electrode layer Free electron in 112 flows to second group of gate-shaped electrode layer 113, to generate the forward current of a period until first group Potential difference between gate-shaped electrode layer 112 and second group of gate-shaped electrode layer 113 is reduced to zero.As shown in Fig. 4 (b), when raindrop are rubbing It wipes after being slid on layer polytetrafluoroethylene film, due to electrostatic induction, in first group of gate-shaped electrode layer 112 and second group of gate-shaped electrode A negative potential difference values are generated between layer 113 again, this potential difference drives electronics to flow back into the from second group of gate-shaped electrode layer 113 One group of gate-shaped electrode layer 112, to generate the negative current of a short time until first group of gate-shaped electrode layer 112 and second group Potential difference between gate-shaped electrode layer 113 is reduced to zero.As a result, raindrop frictional layer polytetrafluoroethylene film slide during, It is generated between first group of gate-shaped electrode layer 112 and second group of gate-shaped electrode layer 113 and continuously exports positive and negative alternate periodically electricity Stream.It should be noted that raindrop carry the sliding speed between the size and a large amount of raindrop and polytetrafluoroethylene film of the quantity of electric charge Degree, directly affects the size of power output.
One kind of the invention, which can be collected simultaneously rainwater, to be mainly used in outdoor ring with the common pole-type power generator of solar energy In border, friction nanometer power generator is placed directly within solar battery upper surface, another on the one hand as the protective layer of solar battery Aspect collects rainwater energy and carries out triboelectricity, and shares solar cell surface gate electrode, reduces outside between unit Circuit connection and energy consumption, improve generating efficiency, are a kind of very useful green energy resource systems.
The present invention also provides a kind of using the common pole-type composite power generation method, and sunlight is sent out through the friction nanometer Motor is irradiated to the solar battery and carries out photoelectric conversion;And/or the rainwater of electrically charged raindrop or flowing is in the friction The transparent friction layer surface of nano generator is slided, and charge inducing is generated between gate-shaped electrode layer and forms electric current.Described Electricity-generating method, in fine day sunshine abundance, solar battery capture sunlight carries out photovoltaic power generation and exports electric signal outward;And The night of rainy day or rainy day are aided with friction nanometer power generator and collect rainwater in the case where solar energy photoelectric conversion efficiency reduces Energy generates electricity, and has extensive practical value.
Embodiment above describes basic principles and main features of the invention and advantage, the technical staff of the industry should Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe originals of the invention Reason, under the range for not departing from the principle of the invention, various changes and improvements may be made to the invention, these changes and improvements are each fallen within In the scope of protection of the invention.

Claims (8)

1. one kind can be collected simultaneously rainwater can be with the common pole-type power generator of solar energy, which is characterized in that the common pole-type power generation Device including solar battery, is covered on the transparent friction nanometer power generator and friction generator of solar cell surface Rectification circuit;
The friction nanometer power generator is the friction nanometer power generator of independent layer model, from bottom to top by gate-shaped electrode layer and transparent Frictional layer composition, wherein gate-shaped electrode layer is made of first group of gate-shaped electrode layer and second group of gate-shaped electrode layer, described transparent to rub The lower surface for wiping layer is printed on first group of gate-shaped electrode layer, and solar battery plate surface gate line electrode is used as second group of palisade electricity simultaneously Pole layer, first group of gate-shaped electrode and solar battery plate surface gate line electrode are along solar cell surface gate line electrode orientation It is alternatively arranged;
The rectification circuit is made of rectifier bridge, and rectifier bridge any end passes through first group of grid of conducting wire and friction nanometer power generator The connection of shape electrode layer, the other end is connected by conducting wire with one end of energy storage device, one end of energy storage device pass through again conducting wire and Second group of gate-shaped electrode layer of friction nanometer power generator connects;
Described solar battery preparation side on flexible substrates, from bottom to top by flexible substrate, solar battery hearth electrode, too Positive energy battery PN junction, solar battery plate surface gate line electrode composition.
2. one kind as described in claim 1, which can be collected simultaneously rainwater, to exist with the common pole-type power generator of solar energy, feature In it is one of llowing group of materials or several that the material of the transparent frictional layer, which is transparent insulation material: polytetrafluoroethylene (PTFE), Dimethyl silicone polymer, polyethylene, polypropylene, polystyrene and polyethylene terephthalate, and be flexible material;It is described Transparent frictional layer with a thickness of 100nm-0.5mm.
3. one kind as described in claim 1, which can be collected simultaneously rainwater, to exist with the common pole-type power generator of solar energy, feature In the surface of the transparent frictional layer is hydrophobic structure, and the surface of frictional layer has super-hydrophobicity;The hydrophobic structure is one-dimensional Or two-dimentional micro-nano structure, it is nano-pillar, nanocone, micron cone, nano particle, nano flower, nanometer channel, micron trenches, nanometer One of which in ball and micron chondritic, and the array formed by aforementioned structure;The hydrophobic structure passes through template Or lithographic methods are prepared in the upper surface of the transparent frictional layer.
4. one kind as described in claim 1, which can be collected simultaneously rainwater, to exist with the common pole-type power generator of solar energy, feature In the material of first group of gate-shaped electrode layer is transparent conductive film TCO, Indium-tin Oxide Transparent Conductive Film ITO, fluorine-doped tin oxide Transparent conductive film FTO, aluminum-doped zinc oxide transparent conductive film AZO, conductive hydrogel or the dispersion liquid using silver nanowires, pass through Industrial silk-screen printing technique is printed in frictional layer lower surface, and is flexible material;The grid of first group of gate-shaped electrode layer Line width is 0.1mm-0.5mm.
5. one kind as described in claim 1, which can be collected simultaneously rainwater, to exist with the common pole-type power generator of solar energy, feature In the friction nanometer power generator is fitted closely using the packaging technology in manufacture of solar cells in table on solar battery Face.
6. one kind as described in claim 1, which can be collected simultaneously rainwater, to exist with the common pole-type power generator of solar energy, feature In the surface of the transparent frictional layer of the friction nanometer power generator and the angular range on ground are 20 ° to 70 °.
7. one kind as described in claim 1, which can be collected simultaneously rainwater, to exist with the common pole-type power generator of solar energy, feature In the solar battery is flexible thin-film solar cell;The friction nanometer power generator is flexible friction nano generator, It is packaged in solar cell surface.
8. one kind as described in claim 1, which can be collected simultaneously rainwater, to exist with the common pole-type power generator of solar energy, feature In sunlight is irradiated to the solar battery through the transparent friction nanometer power generator and carries out photoelectric conversion;And/or band The raindrop of charge or the rainwater of flowing are slided in the transparent friction layer surface of the friction nanometer power generator, described first Charge inducing is generated between group gate-shaped electrode layer and second group of gate-shaped electrode layer and forms electric current.
CN201811057833.6A 2018-09-11 2018-09-11 A kind of common pole-type power generator being collected simultaneously rainwater energy and solar energy Pending CN109104137A (en)

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Application publication date: 20181228