CN206986095U - Waste axial medium-high temperature catalytic cracking three-phase synthesis one-step generation reaction device - Google Patents
Waste axial medium-high temperature catalytic cracking three-phase synthesis one-step generation reaction device Download PDFInfo
- Publication number
- CN206986095U CN206986095U CN201720875382.1U CN201720875382U CN206986095U CN 206986095 U CN206986095 U CN 206986095U CN 201720875382 U CN201720875382 U CN 201720875382U CN 206986095 U CN206986095 U CN 206986095U
- Authority
- CN
- China
- Prior art keywords
- gas
- outlet
- reactor assembly
- catalytic
- liquid separation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn - After Issue
Links
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 24
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 19
- 238000003786 synthesis reaction Methods 0.000 title abstract description 6
- 239000002699 waste material Substances 0.000 title abstract description 6
- 238000004523 catalytic cracking Methods 0.000 title abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000007788 liquid Substances 0.000 claims abstract description 38
- 238000000926 separation method Methods 0.000 claims abstract description 33
- 238000000746 purification Methods 0.000 claims abstract description 31
- 239000003345 natural gas Substances 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003546 flue gas Substances 0.000 claims abstract description 11
- 238000007599 discharging Methods 0.000 claims abstract description 10
- 239000007789 gas Substances 0.000 claims description 57
- 230000003197 catalytic effect Effects 0.000 claims description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 25
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 23
- 238000005338 heat storage Methods 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000002485 combustion reaction Methods 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- 239000012071 phase Substances 0.000 claims description 15
- 238000001833 catalytic reforming Methods 0.000 claims description 14
- 238000007233 catalytic pyrolysis Methods 0.000 claims description 13
- 239000007809 chemical reaction catalyst Substances 0.000 claims description 13
- 238000005194 fractionation Methods 0.000 claims description 13
- 238000003746 solid phase reaction Methods 0.000 claims description 13
- 239000007791 liquid phase Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 230000005540 biological transmission Effects 0.000 claims description 9
- 230000008676 import Effects 0.000 claims description 6
- 244000309464 bull Species 0.000 claims description 5
- 239000000779 smoke Substances 0.000 claims description 5
- 238000003780 insertion Methods 0.000 claims description 3
- 230000037431 insertion Effects 0.000 claims description 3
- 238000009825 accumulation Methods 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 23
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 14
- 238000006555 catalytic reaction Methods 0.000 abstract description 7
- 230000009466 transformation Effects 0.000 abstract description 3
- 239000001569 carbon dioxide Substances 0.000 abstract description 2
- 238000000605 extraction Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 39
- 239000002028 Biomass Substances 0.000 description 38
- 238000000034 method Methods 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 239000002918 waste heat Substances 0.000 description 12
- 239000003245 coal Substances 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 239000002893 slag Substances 0.000 description 8
- 239000000446 fuel Substances 0.000 description 7
- 238000000197 pyrolysis Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 235000019738 Limestone Nutrition 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 5
- 210000004027 cell Anatomy 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 239000010459 dolomite Substances 0.000 description 5
- 229910000514 dolomite Inorganic materials 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 239000003077 lignite Substances 0.000 description 5
- 239000006028 limestone Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 239000011269 tar Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000003776 cleavage reaction Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 238000002309 gasification Methods 0.000 description 4
- 230000010354 integration Effects 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- 239000002154 agricultural waste Substances 0.000 description 3
- 239000012075 bio-oil Substances 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 239000011286 gas tar Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000002407 reforming Methods 0.000 description 3
- 230000001172 regenerating effect Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- RQMIWLMVTCKXAQ-UHFFFAOYSA-N [AlH3].[C] Chemical compound [AlH3].[C] RQMIWLMVTCKXAQ-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- -1 collects outlet 41 Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000013480 data collection Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005183 dynamical system Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910000015 iron(II) carbonate Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910021646 siderite Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 238000010200 validation analysis Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Processing Of Solid Wastes (AREA)
Abstract
The utility model discloses a waste axial middle-high temperature catalytic cracking three-phase synthesis one-step generation reaction device, wherein a feeding device, a steam bag and a gas-liquid separation device are arranged above a reactor device; the discharging outlet of the feeding device is connected with the material inlet of the reactor device; the feeding port of the feeding device is connected with the mixed material outlet of the mixed material conveying device; the steam bag is respectively connected with the mixed conveying device and the gas-liquid separation device; a gas-phase product collecting outlet is formed in the bottom end of the gas-liquid separation device and is installed at the top end of the reactor device; and a liquid-removing flue gas extraction outlet of the gas-liquid separation device is connected with an inlet of the purification and catalysis device. The utility model discloses replace the petrochemical industry natural gas with living beings discarded object (municipal administration, agriculture and forestry discarded object), broken away from the restriction of petrochemical industry natural gas resource, to the new kinetic energy that becomes green clean high-efficient utilization in the green energy transformation, improve the atmosphere pollution situation, reduce the carbon dioxide and discharge.
Description
Technical field
The utility model belongs to the renewable efficient technique of rainwater utilization field of bioenergy, more particularly to discarded object axial direction high temperature
Catalytic pyrolysis three-phase synthesizes a step reaction of formation device.
Background technology
Energy and environment problem, as 21 century restrict progress of human society and development key issue, exploitation cleaning,
Efficient new energy has turned into the key project of countries in the world research, and biomass energy is that unique one kind can be converted into gas, consolidate
Body and liquid fuel, realization replacement fossil energy " Mobyneb " regenerative resource, meet domestic development Major Strategic
Demand.At present, biomass on traditional miniaturization fluidized bed gasification reactor laboratory installation by having carried out hydrogen production process
Through obtaining theoretical validation and experimental verification, its transformation efficiency is also higher.But the country belongs to the large and medium-sized company of practical application
Continuous high-efficiency thermal decomposition biomass energy utilization technologies change system carries out the still perhaps insufficient of large-scale industrial production.
China has abundant agricultural crops stalk resource and the forest reserves, and it is that abatement CO2 reduces greenhouse gas to make full use of
One of maximally effective measure of bulk effect.According to statistics, annual 600000000 tons or so of agricultural crop straw annual production, about equivalent 300,000,000 tons of marks coal,
About 1.5 hundred million tons of agricultural wastes (discarded object).How high-efficiency comprehensive utilization agricultural crop straw, forestry residue (discarded object) etc. are raw
Material can turn into the important topic of various countries' research.
Agricultural wastes, water plant, city agriculture and forestry plant, stalk are a kind of neutral carbon energy.Direct returning to farmland favorably has
Disadvantage：At present, most common processing method is direct returning to farmland --- agricultural wastes, water plant, city agriculture and forestry plant, stalk
Macerate and make soil and fertilizer.But appropriate returning to the field can increase the increase soil organism and content of microorganisms, retain water and nutrients, thoroughly are improved
The ability of gas printing opacity, being advantageous to crop growth and agricultural product quality, the negative of direct returning to farmland also can gradually show with the time,
On the one hand, for stalk down on the farm without decomposed time and process, germ, worm's ovum, grass-seed in stalk are embedded to farmland in the lump, cause
Probability of plant diseases and insect pests expands, and increases difficulty of prevention and cure.
Biomass moulding catalytic pyrolysis belongs to regenerative resource into fuel technology, can be optimal as a kind of alternative fuel
Land use systems.
Lignite is a kind of inflammable fossil fuel, domestic rich reserves, explored 130,000,000,000 tons of reserves, accounts for the country
The 13% of coal reserves, environment can be polluted by being mostly used in power plant and directly participating in burning, simultaneously because its contain 20~
50% moisture, moisture consumes substantial amounts of heat energy in burning, and power plant thermal efficiency is relatively low.Biomass is blended with coal with certain proportion
Shaped catalyst, which is cracked into Fuel Process, may be used as substituting high pollution fire coal, have aboundresources, recyclability, sulfur content
Low, the features such as pollution is small, distribution is wide, reserves are big, conversion facilitates, be a kind of clean energy resource of sustainable development and the strategic energy,
It is to subtract one of principal mode of carbon in future.
Biomass/coal has complementarity in many aspects, is translated into hydrogen-rich biological flue gas clean energy resource jointly, has gas
In state product hydrogen content it is high, without raw material be dried, the advantages that will not causing secondary pollution, be domestic economic transition
Upgrading, energy structure optimizing and air quality improve, and lead energy resource structure to realize what fossil energy substituted entirely to Green Transformation
" Mobyneb " regenerative resource, it is well suited for the needs of Science in Future in China economic development, there is good market application development prospect,
Biomass castoff high temperature thermal decomposition, gas, carbon, an oily step coproduction generation technique are exactly to develop whereby under background, are biomass
The upgrading substitute products that waste effectively, cleaning recycle.
Therefore, set out with existing background technology, the utility model is intended to the synergy by discarded biomass/coal
Fast pyrogenation obtains " Mobyneb " renewable energy product-derived --- hydrogen-rich biogas, biological carbon and a small amount of bio oil, as
The reducing agent and farm, the microbial fuel cell in forest farm of the reduced iron powder of future production low cost --- gas turbine mixing
Dynamical system distributed energy supply.Original creation integrate out a kind of synthesis of biomass castoff axial direction medium and high temperature catalytic pyrolysis three-phase (gas-
Carbon-liquid) a step reaction of formation apparatus and system, turn into " new kinetic energy " that green clean and effective utilizes in energy transition, be
Improve State of Air pollution, really realize that CO2 zero-emissions are of great immediate significance ".
Utility model content
The utility model is for technical problem present in prior art, there is provided discarded object axial direction high temperature catalytic pyrolysis three
A step reaction of formation device is combined to, petrochemical industry natural gas is replaced with biomass castoff (municipal administration, agriculture and forestry discarded object), departing from
The limitation of petrochemical industry natural gas resource, turn into the new kinetic energy that green clean and effective utilizes in being made the transition to green energy resource, it is dirty to improve air
Dye situation, reduce CO2 emission.
In order to solve the above technical problems, the technical solution adopted in the utility model is：The high temperature catalysis of discarded object axial direction is split
Solve three-phase and synthesize a step reaction of formation device, including feeding device, reactor assembly, burner, gaseous products are collected and export, be solid
Phase product collects outlet, liquid-phase product collects outlet, steamdrum, main drive motor transmission device, blade pushing meanss, inner cylinder
Body, power set, gas-solid phase reaction catalyst converter, mixture conveying device, gas-liquid separation device, catalytic purification apparatus, gas separation
Device and catalytic reforming unit,
The inside center insertion of the reactor assembly is provided with burner；The inside of the reactor assembly pushes away provided with blade
Dynamic device；The top of the reactor assembly is provided with main drive motor transmission device；The bottom of the reactor assembly is provided with interior
Cylinder；The side of the inner barrel is provided with solids product and collects outlet；Collected provided with liquid-phase product the bottom of the inner barrel
Outlet；The top of the reactor assembly is provided with feeding device, steamdrum and gas-liquid separation device；The blanking of the feeding device
Outlet is connected with the material inlet of the reactor assembly；The feeding mouth of the feeding device is mixed with the mixture conveying device
Dispensing outlet connects；The steamdrum is respectively connected to mixture conveying device, power set, reactor assembly and gas-liquid separation dress
Put；The bottom of the gas-liquid separation device is provided with gaseous products and collects outlet, and the gaseous products collection outlet is installed on described
The top of reactor assembly；The de- liquid smoke gas outlet port of the gas-liquid separation device and the import phase of the catalytic purification apparatus
Even；The purification of the catalytic purification apparatus and preliminary catalytic exhanst gas outlet are connected with the entrance of the power set；The power
The purifying smoke outlet of device is connected with the import of the gas-solid phase reaction catalyst converter；Set inside the gas-solid phase reaction catalyst converter
There is catalytic reforming unit；The catalyzed gas outlet of the gas-solid phase reaction catalyst converter connects with the gas fractionation unit by the road
Connect；The separation gas export line of the gas fractionation unit utilizes end pipe road and richness with the gas of the reactor assembly respectively
The user terminal connection of hydrogen biological flue gas product；The reactor assembly collects outlet, solids product with the gaseous products respectively
Collect outlet and liquid-phase product collects outlet connection.
Preferably, the burner include natural gas pipeline, main blower, air exhauster, outer heat storage, igniter,
From heat storage, radiant tube, protection pull bar, support insert, natural gas combustion nozzle, gasifying agent input and gasifying agent output end；It is described
One end is fixed with from heat storage inside radiant tube；The inside center of the radiant tube is provided with support insert；The radiant tube
Outside is provided with multiple protection pull bars；The appearance both ends of the radiant tube are fixed with natural gas combustion nozzle respectively；The radiant tube leans on
The nearly access from one end of heat storage is provided with gasifying agent output end；The radiant tube accesses away from described from one end of heat storage
Provided with gasifying agent input；The natural gas combustion nozzle is all connected with being provided with igniter；Below the both ends of the radiant tube respectively
Provided with outer heat storage；The outer heat storage is respectively connected to the natural gas combustion nozzle, main blower and air exhauster；Two described natural
Gas burner is respectively connected to natural gas pipeline.
Preferably, the center of the blade pushing meanss is provided with burner；The bottom of the blade pushing meanss is provided with
Movable scraper；The both ends of the blade pushing meanss are respectively equipped with termination bull gear.
Preferably, the catalytic purification apparatus include purifying and catalyzing casing, blanking bin, batcher, water conservancy diversion shutter board and
Discharging machine；The inner homogeneous of the purifying and catalyzing casing is provided with multiple water conservancy diversion shutter boards；The bottom of the purifying and catalyzing casing is set
There is discharging machine；The top of the purifying and catalyzing casing is provided with batcher；The top of the batcher is provided with blanking bin.
Compared with prior art, beneficial effect possessed by the utility model is：
1st, compared with existing biomass gasification technology, rapid cleavage reaction unit of the present utility model is in tiny structure shape
Worked under state, operating temperature is regulated and controled to 500~900C °, and adjust the saturated vapor of appropriate concentration, it is possible to quick hot tearing
Solve a step and complete (gas-carbon-liquid) product, the hydrogen-rich gas adjustable extent of reaction unit greatly, high conversion rate be other flows without
Method analogy, in addition using high-effect " EIC integration " run automatic control system production line automatically control it is flat
Platform, it is manipulated, and simple, stability is good, small investment, system maintenance cost are low, environment-friendly, and with producing higher thermal value combustion gas
With in combustion gas the advantages that low tar content, it can be promoted for its process unit engineering innovation and industrialization provide technical support.With it
Traditional technology, which compares, overcomes that production scale is small, production capacity is low, supplies consumption is larger and temperature is difficult to control, secondary
Product recycling utilization is difficult, environmental pollution, many deficiencies such as energy conversion is low with utilization rate.
2nd, the utility model is to can be according to raw material and the amount of progress of product qualities amount in biomass/coal used during fast thermal cracking
Change the system operational parameters such as regulation cracking, the temperature of charing, time, so as to control and adjust the equal of three-phase (gas-carbon-liquid) product
Even quality has met the needs of market, and its byproduct is all used, and reduces the discharge of pollutant, saves energy money
Source, it will be equipped as a kind of waste biomass high efficiency of energy using breakthrough novel technique, its action effect is departing from petrochemical industry
The limitation of natural gas resource, there is great attraction for the area for lacking cheap natural gas resource.
3rd, the utility model " is carried using the discarded metallurgy steel prepared from steel slag of original creation for overall composite slag calcium and magnesium base " 2+1 "
Body+active component+group agent " catalytic pyrolyzing agent, there are substantial amounts of calcium and iron in discarded slag, be that preferable biological carbon gas gasification is high
Catalysts, it is smelting that biological tar, which can be greatly lowered, and produce it the advantages of not only catalyst cost is cheap, catalytic activity is high
The cycling and reutilization of golden slag provides a kind of new approaches, and " treatment of wastes with processes of wastes against one another " is also town and country abandoned biomass/brown coal hydrogasification simultaneously
The industrial applications of technical finesse are breakthrough to provide a novelty, economy and feasible approach.
4th, the utility model can utilize what caused fuel gas, biological carbon, biological tar and UTILIZATION OF VESIDUAL HEAT IN obtained
Saturated vapor carries out circulation energy supply to itself process system, greatly reduces production cost, is that a kind of original creation efficiently utilizes very much
Feasible biomass castoff axial direction medium and high temperature catalytic pyrolysis three-phase synthesizes (gas-carbon-liquid) step reaction of formation device and is
System, particularly its byproduct biological carbon be applied to ecology and environmental area, can carbon fixation and emission reduction, can applied to agricultural application farmland
Improve the physicochemical property of soil, adsorb the heavy metal of pollution and purify water, be to use innovative technology System conformity the resource structure
The negative influence in terms of a series of industry environment to caused by environment and energy expenditure is reduced, is turned into being made the transition to green energy resource
" the new kinetic energy " that green clean and effective utilizes, to improve State of Air pollution, it is great really to realize that CO2 zero-emissions have
Realistic meaning.
Brief description of the drawings
Fig. 1 is structural representation of the present utility model；
Fig. 2 is the structural representation of burner of the present utility model；
Fig. 3 is the structural representation of blade pushing meanss of the present utility model；
Fig. 4 is the structural representation of blade pushing meanss of the present utility model and burner；
Fig. 5 is the structural representation of catalytic purification apparatus of the present utility model.
1- feeding devices in figure, 2- reactor assemblies, 3- burners, 41- gaseous products collect outlet, 42- solids products
Outlet is collected, 43- liquid-phase products collect outlet, 5- steamdrums, 6- main drive motor transmission devices, 7- blade pushing meanss, 8-
Inner barrel, 9- power set, 10- gas-solid phase reaction catalyst converters, 11- mixture conveying devices, 12- gas-liquid separation devices, 13- purifications
Catalytic unit, 14- gas fractionation units, 15- catalytic reforming units；
301- natural gas pipelines, 302- main blowers, 303- air exhausters, the outer heat storages of 304-, 305- igniters, 306-
From heat storage, 307- radiant tubes, 308- protection pull bars, 309- support inserts, 310- natural gas combustion nozzles, the input of 311- gasifying agents
End, 312- gasifying agent output ends；
701- terminations bull gear, 702- movable scrapers；
1301- purifying and catalyzing casings, 1302- blanking bins, 1303- batchers, 1304- water conservancy diversion shutter boards, 1305- dischargings
Machine.
Embodiment
It is below in conjunction with the accompanying drawings and specific real to make those skilled in the art be better understood from the technical solution of the utility model
Example is applied to elaborate to the utility model.
Embodiment of the present utility model discloses discarded object axial direction high temperature catalytic pyrolysis three-phase and synthesizes a step reaction of formation
Device, as illustrated, it, which includes feeding device 1, reactor assembly 2, burner 3, gaseous products, collects outlet 41, solids product
Collect outlet 42, liquid-phase product collects outlet 43, steamdrum 5, main drive motor transmission device 6, blade pushing meanss 7, inner cylinder
Body 8, power set 9, gas-solid phase reaction catalyst converter 10, mixture conveying device 11, gas-liquid separation device 12, catalytic purification apparatus
13rd, gas fractionation unit 14 and catalytic reforming unit 15,
The inside center insertion of reactor assembly 2 is provided with burner 3；The inside of reactor assembly 2 is provided with blade and promotes dress
Put 7；The top of reactor assembly 2 is provided with main drive motor transmission device 6；The bottom of reactor assembly 2 is provided with inner barrel 8；It is interior
The side of cylinder 8 is provided with solids product and collects outlet 42；The bottom of inner barrel 8 is provided with liquid-phase product and collects outlet 43；Reaction
The top of device device 2 is provided with feeding device 1, steamdrum 5 and gas-liquid separation device 12；The blanking outlet and reaction of feeding device 1
The material inlet connection of device device 2；The feeding mouth of feeding device 1 and the mixed ingredients outlet of mixture conveying device 11 connect；Steam
Bag 5 is respectively connected to mixture conveying device 11, power set 9, reactor assembly 2 and gas-liquid separation device 12；Gas-liquid separation device
12 bottom is provided with gaseous products and collects outlet 41, and gaseous products collect the top that outlet 41 is installed on reactor assembly 2；Gas-liquid
The de- liquid smoke gas outlet port of separator 12 is connected with the import of catalytic purification apparatus 13；The purification of catalytic purification apparatus 13 and just
Level catalysis exhanst gas outlet is connected with the entrance of power set 9；Purifying smoke outlet and the gas-solid phase reaction catalyst converter of power set 9
10 import connection；The inside of gas-solid phase reaction catalyst converter 10 is provided with catalytic reforming unit 15；Gas-solid phase reaction catalyst converter 10 is urged
Change gas vent to be connected with gas fractionation unit 14 by the road；The separation gas export line of gas fractionation unit 14 respectively with instead
The gas of device device 2 is answered to be connected using end pipe road with the user terminal of hydrogen-rich biological flue gas product；Reactor assembly 2 respectively with gas phase
Product collects outlet 41, solids product collects outlet 42 and liquid-phase product collects the connection of outlet 43.
In the present embodiment, burner 3 includes natural gas pipeline 301, main blower 302, air exhauster 303, outer heat storage
304th, igniter 305, from heat storage 306, radiant tube 307, protection pull bar 308, support insert 309, natural gas combustion nozzle 310,
Gasifying agent input 311 and gasifying agent output end 312；The inside one end of radiant tube 307 is fixed with from heat storage 306；Radiant tube
307 inside center is provided with support insert 309；The outside of radiant tube 307 is provided with multiple protection pull bars 308；Outside radiant tube 307
Table both ends are fixed with natural gas combustion nozzle 310 respectively；Radiant tube 307 is provided with gasifying agent close to the access from one end of heat storage 306
Output end 312；Radiant tube 307 is provided with gasifying agent input 311 away from the access from one end of heat storage 306；Natural gas combustion nozzle 310
It is all connected with being provided with igniter 305；Outer heat storage 304 is respectively provided with below the both ends of radiant tube 307；Outer heat storage 304 divides
Jie Ru not natural gas combustion nozzle 310, main blower 302 and air exhauster 30；Two natural gas combustion nozzles 310 are respectively connected to natural gas pipeline
301。
In the present embodiment, the center of blade pushing meanss 7 is provided with burner 3；The bottom of blade pushing meanss 7 is provided with activity
Scraper 702；The both ends of blade pushing meanss 7 are respectively equipped with termination bull gear 701.
In the present embodiment, catalytic purification apparatus 13 include purifying and catalyzing casing 1301, blanking bin 1302, batcher 1303,
Water conservancy diversion shutter board 1304 and discharging machine 1305；The inner homogeneous of purifying and catalyzing casing 1301 is provided with multiple water conservancy diversion shutter boards 1304；
The bottom of purifying and catalyzing casing 1301 is provided with discharging machine 1305；The top of purifying and catalyzing casing 1301 is provided with batcher 1303；Give
The top of material machine 1303 is provided with blanking bin 1302.
In the present embodiment, discarded town and country biomass product grain material, lignite, Iron concentrate (dolomite/lime stone/discarded
Slag) etc. raw material add respectively at the top of the mixture conveying device and respectively it is individual from feed opening through automatic blending check the weight equipment enter it is light
Type rod milling roller and closed intensive mixer and continuous feeding hollow screw conveyor send equipment, through mixture, granulation and adjust
The moisture of compound and preheating (incorporation time is 7~10min, and water temperature is more than 80 DEG C), as rapid cleavage biomass compound
Series connection vertical type biomass spiral sealed feeding system and device before into machine；Series connection vertical type biomass spiral sealed feeding system before machine
Device is using one-level, two-stage tandem built-in screw type closed conveying blanking, and biomass compound mutually compresses close in blanking process
It is real, enter reactor assembly through discharging opening；Hollow variable-pitch auger (ceramic coated material) blade in reactor assembly promotes
Device, through main drive motor transmission device, driving hollow variable-pitch auger (ceramic coated material) blade promotes biomass mixing
Material continuously moves in inner barrel；When cracking temperature progressively reaches 950 DEG C of left sides under reactor assembly inner burner heat effect
The right side, the continuous rapid cleavage reaction of high temperature is completed in course of conveying；Most of high-end product multiporous biological carbon in reaction product
Grain/amorphous biological carbon falls directly into closed biological carbon storehouse (case), and (hydrogen-rich biology is natural with volatilization fuel gas for a small amount of particle
Gas) it is extracted rising and enters through louvered dividing plate in gas-liquid separation device, (flat is cold by condenser for volatilization combustibles gas
The waste heat recovery of solidifying pipeline, 850~650 DEG C of temperature) and eddy flow diffusive separation after, temperature is down to less than 500 DEG C, biology therein
Tar, which is taken down into product, collects EXPORT CARTON, and uncondensable volatilization fuel gas is exported by type gas-liquid separation device to be extracted
Discharge, biological carbon purification, absorption and loose structure are realized using the waste heat (550~650 DEG C) of gas into catalytic purification apparatus
(limonite) iron ore particle type catalyst (or dolomite/lime stone) preliminary catalytic reformation hydrogen production, filtering, reach higher
The H2 of concentration output capacity, the hydrogen-rich gas of generation are then drawn into power set through output pipe, surpass powerful caused by it
The lower air-liquid body of gravity (or centrifugal force) effect is discrete again, after purification de-oiling, is sent into (raw material particle size 1mm or so, particle again
Shape porous honeycomb type dolomite mineral or limestone mine, process conditions should be set to less than 750 DEG C, can be passed through vapor (more than 750
More than DEG C, water vapour is not passed through), wherein the flow of control vapor can control the ratio of H2 and CO contents, steam vapour amount accounts for
With biomass/coal compound, the ratio of total amount is 0.2~0.5Kg/Kg, and gas production can be increased considerably by being passed through vapor, and
And increase the content of hydrogen in reformed gas, but the content of carbon dioxide is also increased simultaneously, but reduce carbon monoxide
Content) from waste heat (550~450 DEG C) catalytic reforming unit two-stage catalytic reaction, gas are carried out to the hydrogen-rich gas of generation again
In CH2, CO2, C3 etc. be selectively converted to CO2 and H2；The hydrogen-rich of the high concentration content of generation through two-stage catalytic reaction
Gas is sent into tandem twin-stage CO2 gas fractionation units (or pressure-variable adsorption PSA techniques) by the road, again effectively by CO2 with
Separated containing H2, promote the emergence work of biomass volatile matter small molecule to improve H2 yields, reach the high-quality for meeting national standard
Bio-natural gas, be available for all types of user to use.
Abandoned biomass mixture raw material is the particulate material less than 2mm in this implementation, and it is mixed less than both 2mm that coal is crushed to granularity
Be passed through air and vapor, (combustible gas component is fast pyrogenation energy conversion rate up to 75%：35%CO, 32%H2,6~
8%CH2,22CO2).Mix to match somebody with somebody in proportion in biomass mixture raw material and be distributed the more cheap catalyst of wide material sources, cost
(slag is discarded in natural dolomite, lime stone or limonite, siderite (FeCO3) particle, magnetic separation), is adapted in biomass castoff
Followed again in axial medium and high temperature catalytic pyrolysis three-phase synthesis (gas-carbon-liquid) step coproduction reaction of formation apparatus and system technical process
Ring uses, and catalytic effect is probably 75% or so.The medium and high temperature catalytic pyrolysis three-phase synthesis of biomass castoff axial direction (gas-carbon-
Liquid) for a step coproduction reaction of formation device pyrolysis temperature in 650~950C ° of scope, system working pressure remains tiny structure environment,
Have the advantages that response intensity is high, treating capacity is big, control pollutant emission is excessive, improve production environment.
Feeding device is preceding series connection vertical type biomass spiral sealed feeding device, provided with two vertical storehouse centres of series connection
The main motor and tandem drive form worm gear pole of the one-level screw feeding batcher of material outlet rotate bottom vertical conical storage bin
And the two level umbellate form feeding screw inside the vertical conical feed hopper of bottom is arranged on, continuity, the uniformity with charging
And sealing, pressure maintaining effect.Feeding device is provided with upper side charging and lower vertical CD outlet in series connection warehouse.
Feeding device is connected through lower vertical discharging Hatch Opening with reactor assembly, the two level in through feeding device middle warehouse
Biomass compound is delivered in reactor assembly in the presence of umbellate form feeding screw and carries out middle and high rapid cleavage.
The synergy fast pyrogenation acquisition that the utility model is mainly to provide a kind of discarded biomass/coal is " multi-functional
Type " renewable energy product-derived --- hydrogen-rich biogas, biological carbon and a small amount of bio oil, for the reduced iron of following production low cost
The reducing agent of powder and farm, the microbial fuel cell in forest farm --- gas turbine hybrid power system distributed energy supply.
The utility model is using discarded biomass castoff (municipal administration, agriculture and forestry discarded object) and cheap, a small amount of lignite
As the resource for providing production, hydrogen-rich biogas (gas-carbon-liquid) product is produced.
Reactor assembly is production center link, and preceding working procedure is automatic blending system and feeding device, and subsequent handling is removed
Dirt purification, Reforming catalyst, discarded biomass castoff (municipal administration, agriculture and forestry discarded object) lignite and natural Iron concentrate or white clouds
Stone flour (agstone) is entered inside reactor assembly by blending proportioning by mixing system, in medium and high temperature caused by burner
Cracking, catalysis and gasifying agent (air, vapor) gasification reaction and under heat-resisting hollow variable-pitch auger blade impetus,
Generate the products such as hydrogen-rich biogas (gas-carbon-liquid).
In gas-liquid separation device, catalytic purification apparatus, power set, catalytic reforming unit, gas fractionation unit, pass through
Appropriate cooling, dedusting, desulfurization, Reforming catalyst and de- CO2, obtain end product generation hydrogen-rich biogas (methane
H262.12%th, CO13.0, CO224.88%).
Caused iron ore in the byproduct biological carbon, bio oil and the dust separation that generate in production, catalytic process steps,
Dolomite particles (lime stone) etc. can still be used as feedstock circulation to recycle；The thick combustion of biology of every set system biological matter/coal generation
Gas need to use by oneself 45~55%, and all the Reforming catalyst by synthesis system and de- CO2 are used for terminal user, practical application for remaining
It is middle to be produced using multimachine coproduction collaboration and high-effect " EIC integration " operation automatic control system control safe operation.
The mechanical energy that the biomass rough gas of generation is rotated by power set using frequency control is converted to centrifugal force and born
Pressure effect, which is strengthened to absorb, discharges gas, and has S, CO2 and double purification function in removing biomass rough gas, described super
Gravity techniques power set are connected by pipeline with catalytic reforming unit, gas fractionation unit.
Also include automatically controlling production line using high-effect " EIC integration " operation automatic control system,
High-effect " EIC integration " operation automatic control system includes the Quantum series of PLC from Schneider company, completes
Automatic start-stop and the electric interlock protection of production process equipment, the Data Data collection of production process, data processing, pid loops
With automatically adjust, technique picture is shown, fault alarm, is formed in real time with the function such as historical trend and combined network communication.
One is set in reactor assembly and runs through the main fast pyrolysis core reaction room of center circle cartridge type fixed bed, including is set
Put inside outer barrel support member, the built-in main fast pyrolysis reative cell of cylinder type fixed bed that center line is provided with a set of open type is straight
Heating radiation pipe (aluminium carbonaceous corrosion-inhibiting coating) and a two ends band gear ring blade pushing meanss, two ends in cylinder continuous heat accumulation type
Blade tip with gear ring blade pushing meanss coordinates with wall gap in built-in fixes sleeve body, hollow variable-pitch auger blade
Surface handled through grid, direct spraying is smeared to form one layer of hard anti-corrosion of 5mm, thermal insulation ceramicses glaze paint duricrust aspect, two ends
Bull gear and be connected with housing peripheral hardware variable-frequency motor, drive the transmission wrom tooth wheel drive mechanism of rotation, and by being driven snail
Gear band moves hollow propeller blade pushing meanss of the ring gear against rotation relative to barrel body rotation, two ends band gear ring blade pushing meanss
Also include the support roller station part of both ends bottom.
Put the main fast pyrolysis reative cell of cylinder type fixed bed, it is characterised in that：Nucleus equipment is that built-in inner barrel (divides 6
Individual sleeve pipe is connected, each internal diameter 1500mm, length 900mm, and sleeve lining arranges the oil guiding hole of cross staggered-mesh arrangement)
And including exclusive high-temp. far infrared radiation paint (be painted on inner wall surface, through high-temperature process, 1~3mm can be penetrated into,
One layer of hard Ceramic glaze duricrust is formed, isolation inner barrel inner wall surface directly contacts with high temperature gas flow, avoids air-flow
Wash away and corrode, so as to play a part of protecting and extend the life-span) and including both ends, the support of middle sealing iris type).
Put the main fast pyrolysis reative cell of cylinder type fixed bed, it is characterised in that：A set of open type straight tube is provided with continuously to store
Heating radiation pipe (aluminium carbonaceous corrosion-inhibiting coating) nucleus equipment in hot type, including both ends burner, system include radiant tube body, spoke
Penetrate in pipe body and be provided with aluminium carbon materials matter honeycomb jacket internal lining pipe and built-in S types insert and can be reduced to flue gas NOx
0.06% or so, in addition to radiant tube body is that section is four sides circle (or six face circles), pipe is outer to be installed with 4~6 reinforcement guarantors
Shield pull bar is passed through gasifying agent (air or vapor) any enhanced protection, and system also includes outside heat storage, fuel burner nozzle, burner connection
Pipe, rotation connection pipe and valve regulator control system, biological flue gas container bag and air blower.
Steel thermal insulation hermetic enclosure cylinder (being made up of steel plate, reinforced steel, aluminium carbon heat-insulating material), it divide upper board half
Elliptical shell point sets biomass feed pipe (mouth) and high temperature pyrolysis flue gas (hydrogen-rich) export pipeline, and bottom sets up reverse V-shaped housing separately
(high-temperature steam occurs and recover and anti-corrosion for structure and the staggeredly ceramic heat insulating coating of layout, piece, built-in waste heat condensation device
Coating) pipeline biological tar recovery bin (tank) and pyrolysis (biological carbon) product discharge pipe, including (hydrogen-rich) fume emission outlet
It is connected provided with special stainless steel expansion joint with the thick gas pipeline of (hydrogen-rich) flue gas biology.
System also includes being provided with gasifying agent filling (water vapour) composition regulation device and pipeline, and (water steams for gasifying agent filling
Vapour) form regulation device directly with drum by water-in and water-out steam pipework and with valve, electric instrument auto-control equipment and drum
It is connected.
Reactor assembly, in addition to exported with (hydrogen-rich) fume emission and be connected outer row pipeline provided with special stainless steel expansion joint
Biology (hydrogen-rich) gas tar oil purification separation (the 1+1 straight tube circle cyclone types gas solid separation) device (band cooling tube) being connected
(own patented technology), biological (hydrogen-rich) gas tar oil purification separation (1+1 straight tube circles cyclone type) device are included provided with built-in
Flat tube waste heat recovery steam generator, the biomass raw flue gas of gas-liquid separation device suction are net into biological (hydrogen-rich) gas tar oil
Change in separator housing, biomass raw flue gas, which rises, flows through shaftless hollow water conservancy diversion internals effect generation eddy flow, by expansion chamber
The effect such as the Diffusion of gas stream of chamber, condensation is discharged through Oil Guide pipeline, completes to carry out purifying and dedusting to flying dust, biological oil droplet.
System also includes catalytic purification apparatus, and catalytic purification apparatus is connected with type gas-liquid separation device through pipeline, and purification is urged
Makeup, which installs, is equipped with middle difunctional purification/catalysis bin and screw feeder/discharger.
It is 2 × adverse current type hypergravity power set that system, which includes main negative pressure air exhauster (generation negative pressure running status), 2 × inverse
Flow pattern hypergravity power set pipeline is directly connected with catalytic purification apparatus.
Also include being filled with slag based composite catalyst pellet, fixed-bed catalytic weight built in fixed-bed catalytic reforming reactor
Whole reactor and 2 × adverse current type hypergravity power set are direct through pipeline, and fixed-bed catalytic reforming reactor is vertical structure, also
Including the slag based composite catalyst used built in fixed-bed catalytic reforming reactor.
Also include gas fractionation unit (1+1), gas fractionation unit (1+1) connects with fixed-bed catalytic reforming reactor pipeline
Connect.
System also includes multistage gradient and is provided with from waste heat recovery waste heat apparatus full from waste heat recovery waste heat apparatus, multistage gradient
With recovered steam bag, multistage gradient waste-heat recoverer and electric instrument auto-control equipment, system is through entering and (going out) water vapour pipe valve
It is connected with multistage gradient from waste heat recovery waste heat apparatus.
The utility model is described in detail above by embodiment, but the content is only of the present utility model shows
Example property embodiment, it is impossible to be considered as being used to limit practical range of the present utility model.The scope of protection of the utility model is by right
Claim limits.It is all to utilize technical scheme described in the utility model, or those skilled in the art is in the utility model technology
Under the inspiration of scheme, in essence of the present utility model and protection domain, design similar technical scheme and reach above-mentioned skill
Art effect, or the equivalent change made to application range and improvement etc., it all should still belong to patent of the present utility model and contain
Within lid protection domain.
Claims (4)
1. discarded object axial direction high temperature catalytic pyrolysis three-phase synthesizes a step reaction of formation device, it is characterised in that is filled including charging
Put, reactor assembly, burner, gaseous products collect outlet, solids product collects outlet, liquid-phase product collects outlet, steam
Bag, the conveying of main drive motor transmission device, blade pushing meanss, inner barrel, power set, gas-solid phase reaction catalyst converter, mixture
Device, gas-liquid separation device, catalytic purification apparatus, gas fractionation unit and catalytic reforming unit,
The inside center insertion of the reactor assembly is provided with burner；The inside of the reactor assembly is provided with blade and promotes dress
Put；The top of the reactor assembly is provided with main drive motor transmission device；The bottom of the reactor assembly is provided with inner barrel；
The side of the inner barrel is provided with solids product and collects outlet；The bottom of the inner barrel is provided with liquid-phase product and collects outlet；Institute
The top for stating reactor assembly is provided with feeding device, steamdrum and gas-liquid separation device；The feeding device blanking outlet with
The material inlet connection of the reactor assembly；The feeding mouth of the feeding device and the mixed ingredients of the mixture conveying device go out
Mouth connection；The steamdrum is respectively connected to mixture conveying device, power set, reactor assembly and gas-liquid separation device；It is described
The bottom of gas-liquid separation device is provided with gaseous products and collects outlet, and the gaseous products collect outlet and are installed on the reactor dress
The top put；The de- liquid smoke gas outlet port of the gas-liquid separation device is connected with the import of the catalytic purification apparatus；It is described net
The purification and preliminary catalytic exhanst gas outlet for changing catalytic unit are connected with the entrance of the power set；The purification of the power set
Exhanst gas outlet is connected with the import of the gas-solid phase reaction catalyst converter；Catalytic reforming is provided with inside the gas-solid phase reaction catalyst converter
Device；The catalyzed gas outlet of the gas-solid phase reaction catalyst converter is connected with the gas fractionation unit by the road；The gas
The separation gas export line of separator utilizes end pipe road and hydrogen-rich biological flue gas with the gas of the reactor assembly respectively
The user terminal connection of product；The reactor assembly respectively with the gaseous products collect outlet, solids product collect outlet and
Liquid-phase product collects outlet connection.
2. high temperature catalytic pyrolysis three-phase in discarded object axial direction according to claim 1 synthesizes a step reaction of formation device, its
Be characterised by, the burner include natural gas pipeline, main blower, air exhauster, outer heat storage, igniter, from heat storage,
Radiant tube, protection pull bar, support insert, natural gas combustion nozzle, gasifying agent input and gasifying agent output end；Inside the radiant tube
One end is fixed with from heat storage；The inside center of the radiant tube is provided with support insert；The outside of the radiant tube is provided with more
Individual protection pull bar；The appearance both ends of the radiant tube are fixed with natural gas combustion nozzle respectively；The radiant tube is close to described from storage
One end access of hot body is provided with gasifying agent output end；The radiant tube is provided with gasifying agent away from the access from one end of heat storage
Input；The natural gas combustion nozzle is all connected with being provided with igniter；Outer accumulation of heat is respectively provided with below the both ends of the radiant tube
Body；The outer heat storage is respectively connected to the natural gas combustion nozzle, main blower and air exhauster；Two natural gas combustion nozzle difference
Access natural gas pipeline.
3. high temperature catalytic pyrolysis three-phase in discarded object axial direction according to claim 1 synthesizes a step reaction of formation device, its
It is characterised by, the center of the blade pushing meanss is provided with burner；The bottom of the blade pushing meanss is provided with movable scraper；
The both ends of the blade pushing meanss are respectively equipped with termination bull gear.
4. high temperature catalytic pyrolysis three-phase in discarded object axial direction according to claim 1 synthesizes a step reaction of formation device, its
It is characterised by, the catalytic purification apparatus includes purifying and catalyzing casing, blanking bin, batcher, water conservancy diversion shutter board and discharging machine；Institute
The inner homogeneous for stating purifying and catalyzing casing is provided with multiple water conservancy diversion shutter boards；The bottom of the purifying and catalyzing casing is provided with discharging machine；
The top of the purifying and catalyzing casing is provided with batcher；The top of the batcher is provided with blanking bin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201720875382.1U CN206986095U (en) | 2017-07-19 | 2017-07-19 | Waste axial medium-high temperature catalytic cracking three-phase synthesis one-step generation reaction device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201720875382.1U CN206986095U (en) | 2017-07-19 | 2017-07-19 | Waste axial medium-high temperature catalytic cracking three-phase synthesis one-step generation reaction device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206986095U true CN206986095U (en) | 2018-02-09 |
Family
ID=61404845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201720875382.1U Withdrawn - After Issue CN206986095U (en) | 2017-07-19 | 2017-07-19 | Waste axial medium-high temperature catalytic cracking three-phase synthesis one-step generation reaction device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206986095U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109280559A (en) * | 2017-07-19 | 2019-01-29 | 天津汇金敏峰新材料科技有限公司 | Waste axial medium-high temperature catalytic cracking three-phase synthesis one-step generation reaction device |
| CN110846058A (en) * | 2019-11-08 | 2020-02-28 | 江苏科技大学 | Biomass carbonization device based on fuel cell waste heat and working method |
-
2017
- 2017-07-19 CN CN201720875382.1U patent/CN206986095U/en not_active Withdrawn - After Issue
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109280559A (en) * | 2017-07-19 | 2019-01-29 | 天津汇金敏峰新材料科技有限公司 | Waste axial medium-high temperature catalytic cracking three-phase synthesis one-step generation reaction device |
| CN109280559B (en) * | 2017-07-19 | 2024-03-12 | 天津汇金敏峰新材料科技有限公司 | Three-phase synthesis one-step generation reaction device for waste axial middle-high temperature catalytic pyrolysis |
| CN110846058A (en) * | 2019-11-08 | 2020-02-28 | 江苏科技大学 | Biomass carbonization device based on fuel cell waste heat and working method |
| CN110846058B (en) * | 2019-11-08 | 2021-04-06 | 江苏科技大学 | Biomass carbonization device based on fuel cell waste heat and working method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101469865B (en) | Plasma and calcium oxide cooperation-gasified rubbish biomass gasification method and equipment | |
| CN101823073B (en) | Gasification-liquefaction disposal method, system and equipment for household garbage | |
| CN100381352C (en) | Method and device for plasma producing hydrogen by using garbage biomass and water as raw material | |
| CN102530859B (en) | External-heating-type microwave plasma gasification furnace and synthesis gas production method | |
| CN101468788B (en) | System and apparatus for producing synthesis gas from garbage and biomass raw material | |
| CN109609190B (en) | Garbage gasification and tar catalytic gasification device | |
| CN104229797B (en) | Pyrolysis activation combustion gasification all-in-one oven, refuse landfill Coordination Treatment system, activated carbon manufacture method | |
| CN1831094A (en) | Process and equipment for co-gasification of biomass and coal | |
| CN103045273A (en) | Method and equipment for preparing fuel from household garbage for suppressing dioxin | |
| CN201218507Y (en) | Plasma and calcium oxide cooperation-gasified rubbish biomass gasification equipment | |
| CN103666505A (en) | Equipment for reducing and transforming household garbage or organic waste into energy resources | |
| CN201321439Y (en) | Garbage biomass gasification furnace | |
| CN206986095U (en) | Waste axial medium-high temperature catalytic cracking three-phase synthesis one-step generation reaction device | |
| CN101962558B (en) | Biomass combustible gas high-temperature oxygen-free reinforced dry-distillation pyrolysis plant | |
| CN201109766Y (en) | Equipment system for producing dimethyl ether by garbage and biomass raw material | |
| CN104531183B (en) | System for transforming waste combustible material recovered from building rubbish into clean gas | |
| CN201254454Y (en) | System and equipment for producing synthesis gas by rubbish and biomass raw material | |
| CN107202325A (en) | The controllable pyrolysis carbonizing kiln of swinging | |
| CN202186990U (en) | Device for pyrogenation and gasification of organic solid waste | |
| CN101974351B (en) | Scale fixed bed biomass gasification power generation production technology and suite of equipment | |
| CN104226666A (en) | Coordinative processing method for refuse landfill | |
| CN104817056A (en) | Method for preparing biological hydrogen by using traditional Chinese medicine residue | |
| CN204369820U (en) | Biomass gasifying furnace waste heat comprehensive utilization system | |
| CN104479742B (en) | Biomass gas preparation system | |
| CN109280559A (en) | Waste axial medium-high temperature catalytic cracking three-phase synthesis one-step generation reaction device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned | ||
| AV01 | Patent right actively abandoned | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20180209 Effective date of abandoning: 20240312 |
|
| AV01 | Patent right actively abandoned |
Granted publication date: 20180209 Effective date of abandoning: 20240312 |