CN206843596U - A kind of chlorine dioxide mixed high-efficient sterilizer - Google Patents

A kind of chlorine dioxide mixed high-efficient sterilizer Download PDF

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Publication number
CN206843596U
CN206843596U CN201720286221.9U CN201720286221U CN206843596U CN 206843596 U CN206843596 U CN 206843596U CN 201720286221 U CN201720286221 U CN 201720286221U CN 206843596 U CN206843596 U CN 206843596U
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China
Prior art keywords
box
mainframe box
chlorine dioxide
cathode
water
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Expired - Fee Related
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CN201720286221.9U
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Chinese (zh)
Inventor
李建军
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Beijing Jing Ze Energy Saving And Environmental Protection Equipment Factory (general Partnership)
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Beijing Jing Ze Energy Saving And Environmental Protection Equipment Factory (general Partnership)
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Abstract

The utility model discloses a kind of chlorine dioxide mixed high-efficient sterilizer.It includes mainframe box and electrolysis power, inlet duct, Jia Yankou, copper busbar and row's hydrogen mouth are installed above the mainframe box, mainframe box surface is provided with salt box liquid level gauge and cathode section liquid level gauge, total water intaking valve, cathode section water intaking valve and salt box water intaking valve are installed in the middle part of mainframe box, the bottom side of mainframe box is provided with blow-off pipe, and the side relative with the blow-off pipe is provided with water inlet manifold and drug tube;Brine tank, water sprayer and electrolytic cell are provided with inside the mainframe box, the electrolytic cell includes anode box and cathode section, the anode box connects water sprayer by airway tube, the cathode section connects row's hydrogen mouth by airway tube, magnetic force circulating pump is additionally provided with the mainframe box, the magnetic force circulating pump connects brine tank and electrolytic cell by water pipe.It is good that the utility model extends service life of equipment, simple to operate, holding stable equipment operation, Disinfection Effect.

Description

A kind of chlorine dioxide mixed high-efficient sterilizer
Technical field
It the utility model is related to Water Disinfection apparatus field, more particularly to a kind of chlorine dioxide mixed high-efficient sterilizer.
Background technology
Chlorine dioxide (ClO2) be found in 1911, but due to technical reason, until nineteen forties Just applied.After the seventies, because it is found that liquid chlorine (Cl2) easily there is " three cause " (teratogenesis, cause after sterilization drinking water Cancer, mutagenesis) effect the chlorinatedorganic such as chloroform, nineteen eighty-three American National Environmental Protection Agency formal provision:Three in drinking water Chloromethanes content must assure that in below 0.1mg/l, and recommend chlorine dioxide (ClO2) sterilize and quote trichlorine in water as control One of effective ways of methane content.From this, chlorine dioxide (ClO2) the sterilization advantage in drinking water just gradually causes people Attention, its America and Europe by the optimal selection as disinfection of tap water.Thus start, chlorine dioxide (ClO2) developmental research Faster development has been obtained with application.Chlorine dioxide be a kind of yellow green to orange gas, there is the stimulation similar to chlorine Property gas, and soluble in water, solubility is 5 times of chlorine, unlike chlorine chlorine dioxide in water with pure dissolving The form of gas is present, and hydrolysis does not occur, has efficient oxidation ability and sterilizing ability, and chlorine dioxide extensively should at present Sterilization for running water, secondary water-supply, swimming-pool water, municipal wastewater, recirculated cooling water, hospital sewage and Treated sewage reusing etc. Processing, and the deodorizing and fresh-keeping of food processing storage, aquaculture etc. and sterilizing etc..
At present, domestic existing some manufacturer production chlorine dioxide (ClO2) mixed high-efficient sterilizer equipment, but most of be Chemical law generator.These device structures are simple and crude, cumbersome, and labor intensity and danger are big, and equipment performance is unstable, reaction It can not control, raw material availability is low.With acid and NaClO2(or NaClO3) solution makees raw material, addition and using trouble, storage, purchase Difficulty is bought, price is high, while NaClO2(or NaClO3) quality does not ensure may cause secondary pollution.The chemical method having Device raw material availability is low, and caused sewage quantity is big, and sewage caused by equipment is added to by manufacturer together with sterilization gas In accessing pending water, handled water quality is directly affected, while service life of equipment is short, poor practicability.
Electrolyze table salt (NaCl) method chlorine dioxide (ClO2) mixed high-efficient sterilizer, it is raw material using salt (NaCl), electricity Solution produces disinfectant, and the mono- ﹑ of raw material Jian are easy to get, price is low and quality is secure, but technology has problems with:
1. aerogenesis is unstable, gas production is difficult to control in use.
2. power consumption, salt consumption are big, factor of created gase is low.
3. critical component (electrolyte membrane) uses asbestos cloth or Polypropylene, service life short (being no more than three months) and need Periodic cleaning, and cleaning operation is complicated, it is difficult to it is easily accepted by a user.
4. equipment general structure is unreasonable, fault rate is high, short life, seriously damages user benefit.
5. electrolyte component is unstable:As equipment is electrolysed, anode chamber's salt (NaCl) concentration is gradually reduced, it is impossible to is kept Saturation state, to directly result in equipment gas production unstable for electrolyte component unstable.
6. equipment heat transfer problem without solving well (without the heat-exchange system of science), causes in equipment temperature more than 80 DEG C, cause electrolytic film to be denatured, UPVC plates intensity declines and deformed used in equipment, causes equipment scrapping.
Utility model content
In view of this, the purpose of this utility model is to provide a kind of chlorine dioxide mixed high-efficient sterilizer, for overcoming One or more problems existing for above-mentioned electrolysis chlorine dioxide sterilizer.
The purpose of this utility model is achieved through the following technical solutions:
A kind of chlorine dioxide mixed high-efficient sterilizer, including mainframe box and electrolysis power, the mainframe box top are provided with Inlet duct, Jia Yankou, copper busbar and row's hydrogen mouth, mainframe box surface is provided with salt box liquid level gauge and cathode section liquid level gauge, main frame Total water intaking valve, cathode section water intaking valve and salt box water intaking valve are installed in the middle part of case, the bottom side of mainframe box is provided with blow-off pipe, with institute State the relative side of blow-off pipe and be provided with water inlet manifold and drug tube;Brine tank, water sprayer and electrolysis are provided with inside the mainframe box Groove, the electrolytic cell include anode box and cathode section, and the anode box connects water sprayer by airway tube, and the cathode section passes through Airway tube connection row's hydrogen mouth, the brine tank are connected by salt box filler pipe with electrolytic cell, and cathode section adds water provided with cathode section Pipe;Magnetic force circulating pump is additionally provided with the mainframe box, the magnetic force circulating pump connects brine tank and electrolytic cell, magnetic force by water pipe Circulating pump, brine tank and electrolytic cell group are into electrolyte circulation system.
Further, the copper busbar includes anode connection copper bar and cathode connection copper bar.
Preferably, the electrolysis power is independently mounted at outside mainframe box, and the positive pole of electrolysis power and anode connection copper Row's bolt is fastenedly connected, and negative pole and the cathode connection copper bar bolt of electrolysis power are fastenedly connected.
Further, the electrolytic cell includes anode box and cathode section, and anode bodies and neutral body are provided with the anode box, Cathode is provided with the cathode section, electrolyte membrane is set between the neutral body and cathode.
Preferably, cathode section exhaust-valve and salt box exhaust-valve, the cathode section exhaust-valve are additionally provided with inside the mainframe box It is connected to salt box exhaust-valve on blow-off pipe.
Further, in the jack of the attaching plug insertion electrolysis power of the magnetic force circulating pump, the water of magnetic force circulating pump Magnetic force pump inlet valve is installed on pipe.
Further, cooled cathode water pipe and anode cooling water pipe are additionally provided with inside the mainframe box.
Preferably, the electrolysis power uses silicon controlled rectifier electrolysis power.
Preferably, the electrolyte membrane and the anode bodies, neutral body and cathode are arranged in parallel.
Compared with prior art, the utility model at least has advantages below:
1. the utility model uses corrosion-resistant asymmetric electrolyte membrane, the film in use, can autobalance yin, yang Pole case acid-base value, makes gas producing efficiency reach optimal, stable performance, reduces operating cost.
2. setting magnetic force circulating pump system, keep electrolytic solution component to be in dynamic balance state all the time, ensure equipment fortune Row is stable, it is ensured that the using effect of equipment.
3. the heat-exchange system of cooled cathode water pipe and anode cooling water pipe composition uniqueness, avoids equipment in electrolytic process In, make temperature in equipment more than 80 DEG C, cause electrolytic film to be denatured because of heat production, aperture becomes big permeability increase, meanwhile, avoid The problem of causing the UPVC strengths of materials used in equipment to decline deforms equipment.
4. use silicon controlled rectifier electrolysis power so that more stable, the Er Qieshi of chlorine dioxide mixed high-efficient sterilizer work The full-automatic operation of the equipment is showed;And remote computer operation or it can realize that automatic close is followed with online flowmeter and chlorine residue instrument Ring controls.
Brief description of the drawings
Fig. 1 is the structural representation of chlorine dioxide mixed high-efficient sterilizer provided by the utility model;
Fig. 2 is the structural representation of chlorine dioxide mixed high-efficient sterilizer provided by the utility model.
Embodiment
Below in conjunction with the accompanying drawing in the utility model, the technical scheme in the utility model is carried out clearly and completely Description, it is clear that described embodiment is only part of the embodiment of the present utility model, rather than whole embodiments.Base Embodiment in the utility model, the institute that those of ordinary skill in the art are obtained under the premise of creative work is not made There is other embodiment, belong to the scope of the utility model protection.
As shown in figure 1, a kind of chlorine dioxide mixed high-efficient sterilizer proposed for the utility model embodiment, including main frame Case 1 and electrolysis power, the top of mainframe box 1 are provided with inlet duct 2 plus salt mouth 3, copper busbar 4 and row's hydrogen mouth 5, the table of mainframe box 1 Face is provided with salt box liquid level gauge 6 and cathode section liquid level gauge 7, and the middle part of mainframe box 1 is provided with total water intaking valve 8, cathode section water intaking valve 9 and salt Case water intaking valve 10, the bottom side of mainframe box 1 are provided with blow-off pipe 11, the side relative with blow-off pipe 11 be provided with water inlet manifold 12 and Drug tube 13.
Further, copper busbar 4 includes anode connection copper bar and cathode connection copper bar.
Preferably, electrolysis power is independently mounted at outside mainframe box 1, and the positive pole of electrolysis power and anode connection copper bar spiral shell Bolt is fastenedly connected, and negative pole and the cathode connection copper bar bolt of electrolysis power are fastenedly connected.
As shown in Fig. 2 the inside of mainframe box 1 is provided with brine tank, water sprayer 14 and electrolytic cell, electrolytic cell includes anode box and the moon Pole case, anode box connect water sprayer 14 by airway tube, and cathode section connects row's hydrogen mouth 5 by airway tube, and brine tank passes through salt box Filler pipe is connected with electrolytic cell, and cathode section is provided with cathode section filler pipe 15.Magnetic force circulating pump 16, magnetic are additionally provided with mainframe box 1 Power circulating pump 16 connects brine tank by water pipe and electrolytic cell, magnetic force circulating pump 16, brine tank and electrolytic cell group are followed into electrolyte Loop system, electrolyte circulation system ensure that the electrolyte in electrolytic cell is in dynamic balance state all the time.
Saturated common salt (NaCl) water is electrolysed in a cell, and ClO is produced in anode box2、Cl2、O3、H2O2Gas is sterilized Deng mixing Body, mixed by water sprayer with staying water, while hydrogen is produced in cathode section, discharged by airway tube to air.
Further, electrolytic cell includes anode box and cathode section, is provided with anode bodies and neutral body in anode box, in cathode section Provided with cathode, electrolyte membrane is set between neutral body and cathode.
Preferably, cathode section exhaust-valve 17 and salt box exhaust-valve 18, the He of cathode section exhaust-valve 17 are additionally provided with inside mainframe box 1 Salt box exhaust-valve 18 is connected on blow-off pipe 11.
Further, in the jack of the attaching plug insertion electrolysis power of magnetic force circulating pump 16, the water of magnetic force circulating pump 16 Magnetic force pump inlet valve 19 is installed on pipe.
In specific implementation process, cooled cathode water pipe 20 and anode cooling water pipe 21, negative electrode are additionally provided with inside mainframe box 1 Cooling water pipe 20 and anode cooling water pipe 21 can form the heat-exchange system of uniqueness,
A kind of optional or be preferably carried out mode as the utility model, electrolysis power is using silicon controlled rectifier electrolysis electricity Source.
Electrolyte membrane and anode bodies, neutral body and cathode are arranged in parallel.
First, operation principle of the present utility model is described as follows below in conjunction with the accompanying drawings:
Saturated common salt (NaCl) water is electrolysed in the electrolytic cell with special electrolyte membrane, caused to contain ClO2、Cl2、 O3、H2O2Etc. strong oxidizing property sterilizing gas, by water sprayer negative pressure extraction, mix safely, reach at sterilization with pending water body The purpose of reason.
2nd, through actual use and it is demonstrated experimentally that electrolysis chlorine dioxide generator and chemical process CO 2 generator phase Than having following good characteristic:
It is electrolysed using salt (NaCl) and produces chlorine dioxide (ClO2) mixed high-efficient disinfectant, raw material, which is easy to get, is supplied with guarantor Barrier.Chlorine dioxide (ClO2) mixed high-efficient disinfectant is is prepared in situ, onsite application, it is perfectly safe reliable, meanwhile, operating cost It is low.On the other hand, (NaCl) method that electrolyzes table salt production chlorine dioxide (ClO2) mixed high-efficient disinfectant and chemical method production dioxy Change chlorine (ClO2) mixed high-efficient disinfectant compares, electrolyze table salt (NaCl) method, avoids using acid solution, sodium chlorate or sodium chlorite Solution, easy to operation and management and the buying of raw material storage, while liquid waste processing is it also avoid, and also operating cost is low, therefore, Chlorine dioxide mixed high-efficient sterilizer has good practicality.
3rd, the Essential Environment condition that the utility model device uses is as follows:
1st, environment temperature:0 DEG C~50 DEG C;
2nd, water temperature:0 DEG C~35 DEG C;
3rd, hydraulic pressure:0.15MPa~0.45MPa;
4th, dispensing mouth pressure is less than:0.05MPa;
5th, the mainframe box of equipment and electrolysis power locellus are placed;
6th, there is pumping equipment and well-ventilated in equipment room.
Compared with prior art, the utility model at least has advantages below:
1. the utility model uses corrosion-resistant asymmetric electrolyte membrane, the film in use, can autobalance yin, yang Pole case acid-base value, makes gas producing efficiency reach optimal, stable performance, reduces operating cost.
2. setting magnetic force circulating pump system, keep electrolytic solution component to be in dynamic balance state all the time, ensure equipment fortune Row is stable, it is ensured that the using effect of equipment.
3. the heat-exchange system of cooled cathode water pipe and anode cooling water pipe composition uniqueness, avoids equipment in electrolytic process In, make temperature in equipment more than 80 DEG C, cause electrolytic film to be denatured because of heat production, aperture becomes big permeability increase, meanwhile, avoid The problem of causing the UPVC strengths of materials used in equipment to decline deforms equipment.
4. use silicon controlled rectifier electrolysis power so that more stable, the Er Qieshi of chlorine dioxide mixed high-efficient sterilizer work The full-automatic operation of the equipment is showed;And remote computer operation or it can realize that automatic close is followed with online flowmeter and chlorine residue instrument Ring controls.
It is described above, the only preferable embodiment of the utility model, but the scope of protection of the utility model is not This is confined to, any one skilled in the art can readily occur in the technical scope that the utility model discloses Change or replacement, should all cover within the scope of protection of the utility model.Therefore, the scope of protection of the utility model should It is defined by the protection domain of claims.

Claims (9)

1. a kind of chlorine dioxide mixed high-efficient sterilizer, including mainframe box and electrolysis power, it is characterised in that:On the mainframe box Side is provided with inlet duct, Jia Yankou, copper busbar and row's hydrogen mouth, and mainframe box surface is provided with salt box liquid level gauge and cathode section liquid level Meter, mainframe box middle part are provided with total water intaking valve, cathode section water intaking valve and salt box water intaking valve, and the bottom side of mainframe box is provided with blowdown Pipe, the side relative with the blow-off pipe is provided with water inlet manifold and drug tube;Brine tank, water sprayer are provided with inside the mainframe box And electrolytic cell, the electrolytic cell include anode box and cathode section, the anode box connects water sprayer, the negative electrode by airway tube Case connects row's hydrogen mouth by airway tube, and the brine tank is connected by salt box filler pipe with electrolytic cell, and cathode section is provided with negative electrode Case filler pipe;Magnetic force circulating pump is additionally provided with the mainframe box, the magnetic force circulating pump connects brine tank and electrolysis by water pipe Groove, magnetic force circulating pump, brine tank and electrolytic cell group are into electrolyte circulation system.
2. chlorine dioxide mixed high-efficient sterilizer according to claim 1, it is characterised in that:The copper busbar includes sun Pole copper busbar and cathode connection copper bar.
3. chlorine dioxide mixed high-efficient sterilizer according to claim 1, it is characterised in that:The electrolysis power is independently pacified Outside mainframe box, and the positive pole of electrolysis power is fastenedly connected with anode connection copper bar bolt, negative pole and the moon of electrolysis power Pole copper busbar bolt is fastenedly connected.
4. chlorine dioxide mixed high-efficient sterilizer according to claim 1, it is characterised in that:The electrolytic cell includes anode Case and cathode section, anode bodies and neutral body are provided with the anode box, are provided with cathode in the cathode section, the neutral body and Electrolyte membrane is set between cathode.
5. chlorine dioxide mixed high-efficient sterilizer according to claim 1, it is characterised in that:Also set inside the mainframe box There are cathode section exhaust-valve and salt box exhaust-valve, the cathode section exhaust-valve and salt box exhaust-valve are connected on blow-off pipe.
6. chlorine dioxide mixed high-efficient sterilizer according to claim 1, it is characterised in that:The electricity of the magnetic force circulating pump In the jack of source plug insertion electrolysis power, magnetic force pump inlet valve is installed on the water pipe of magnetic force circulating pump.
7. chlorine dioxide mixed high-efficient sterilizer according to claim 1, it is characterised in that:Also set inside the mainframe box There are cooled cathode water pipe and anode cooling water pipe.
8. the chlorine dioxide mixed high-efficient sterilizer according to claim 1 or 3, it is characterised in that:The electrolysis power is adopted With silicon controlled rectifier electrolysis power.
9. chlorine dioxide mixed high-efficient sterilizer according to claim 4, it is characterised in that:The electrolyte membrane with it is described Anode bodies, neutral body and cathode are arranged in parallel.
CN201720286221.9U 2017-03-22 2017-03-22 A kind of chlorine dioxide mixed high-efficient sterilizer Expired - Fee Related CN206843596U (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113148957A (en) * 2021-04-24 2021-07-23 浙江南方梦科技有限公司 Negative pressure integral type chlorine dioxide generator that water purification was used

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113148957A (en) * 2021-04-24 2021-07-23 浙江南方梦科技有限公司 Negative pressure integral type chlorine dioxide generator that water purification was used

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Granted publication date: 20180105

Termination date: 20200322