CN206843595U - A kind of electrolysis chlorine dioxide generator - Google Patents

A kind of electrolysis chlorine dioxide generator Download PDF

Info

Publication number
CN206843595U
CN206843595U CN201720284500.1U CN201720284500U CN206843595U CN 206843595 U CN206843595 U CN 206843595U CN 201720284500 U CN201720284500 U CN 201720284500U CN 206843595 U CN206843595 U CN 206843595U
Authority
CN
China
Prior art keywords
electrolytic cell
electrolysis
chlorine dioxide
dioxide generator
cathode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201720284500.1U
Other languages
Chinese (zh)
Inventor
李建军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Jing Ze Energy Saving And Environmental Protection Equipment Factory (general Partnership)
Original Assignee
Beijing Jing Ze Energy Saving And Environmental Protection Equipment Factory (general Partnership)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Jing Ze Energy Saving And Environmental Protection Equipment Factory (general Partnership) filed Critical Beijing Jing Ze Energy Saving And Environmental Protection Equipment Factory (general Partnership)
Priority to CN201720284500.1U priority Critical patent/CN206843595U/en
Application granted granted Critical
Publication of CN206843595U publication Critical patent/CN206843595U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The utility model discloses a kind of electrolysis chlorine dioxide generator.It includes brine tank, electrolytic cell and electrolysis power, it is provided with above the brine tank and adds salt mouth, the brine tank connects electrolytic cell by circulation line, is provided with magnetic force circulating pump on the circulation line, and the brine tank, magnetic force circulating pump and electrolytic cell group are into electrolyte circulation system;Anode chamber and cathode chamber are provided with the electrolytic cell, electrolytic cell is connected to water sprayer by the airway tube above it, and the bottom side of electrolytic cell is provided with blow-off pipe, the both positive and negative polarity connection of electrolytic cell and electrolysis power.The utility model extends service life of equipment, simple to operate, stable equipment operation, and mixing sterilizing gas is thoroughly mixed with accessing pending water, has reached good Disinfection Effect.

Description

A kind of electrolysis chlorine dioxide generator
Technical field
It the utility model is related to Water Disinfection apparatus field, more particularly to a kind of electrolysis chlorine dioxide generator.
Background technology
Chlorine dioxide (ClO2) be found in 1911, but due to technical reason, until nineteen forties Just applied.After the seventies, because it is found that liquid chlorine (Cl2) easily there is " three cause " (teratogenesis, cause after sterilization drinking water Cancer, mutagenesis) effect the chlorinatedorganic such as chloroform, nineteen eighty-three American National Environmental Protection Agency formal provision:Three in drinking water Chloromethanes content must assure that in below 0.1mg/l, and recommend chlorine dioxide (ClO2) sterilize and quote trichlorine in water as control One of effective ways of methane content.From this, chlorine dioxide (ClO2) the sterilization advantage in drinking water just gradually causes people Attention, its America and Europe by the optimal selection as disinfection of tap water.Thus start, chlorine dioxide (ClO2) developmental research Faster development has been obtained with application.Chlorine dioxide be a kind of yellow green to orange gas, there is the stimulation similar to chlorine Property gas, and soluble in water, solubility is 5 times of chlorine, unlike chlorine chlorine dioxide in water with pure dissolving The form of gas is present, and hydrolysis does not occur, has efficient oxidation ability and sterilizing ability, and chlorine dioxide extensively should at present Sterilization for running water, secondary water-supply, swimming-pool water, municipal wastewater, recirculated cooling water, hospital sewage and Treated sewage reusing etc. Processing, and the deodorizing and fresh-keeping of food processing storage, aquaculture etc. and sterilizing etc..
At present, domestic existing some manufacturer production chlorine dioxide (ClO2) mixed high-efficient sterilizer equipment, but most of be Chemical law generator.These device structures are simple and crude, cumbersome, and labor intensity and danger are big, and equipment performance is unstable, reaction It can not control, raw material availability is low.With acid and NaClO2(or NaClO3) solution makees raw material, addition and using trouble, storage, purchase Difficulty is bought, price is high, while NaClO2(or NaClO3) quality does not ensure may cause secondary pollution.The chemical method having Device raw material availability is low, and caused sewage quantity is big, and sewage caused by equipment is added to by manufacturer together with sterilization gas In accessing pending water, handled water quality is directly affected, while service life of equipment is short, poor practicability.
Electrolyze table salt (NaCl) method chlorine dioxide (ClO2) mixed high-efficient sterilizer, it is raw material using salt (NaCl), electricity Solution produces disinfectant, and the mono- ﹑ of raw material Jian are easy to get, price is low and quality is secure, but technology has problems with:
1. aerogenesis is unstable, gas production is difficult to control in use.
2. power consumption, salt consumption are big, factor of created gase is low.
3. critical component (electrolyte membrane) uses asbestos cloth or Polypropylene, service life short (being no more than three months) and need Periodic cleaning, and cleaning operation is complicated, it is difficult to it is easily accepted by a user.
4. equipment general structure is unreasonable, fault rate is high, short life, seriously damages user benefit.
5. electrolyte component is unstable:As equipment is electrolysed, anode chamber's salt (NaCl) concentration is gradually reduced, it is impossible to is kept Saturation state, to directly result in equipment gas production unstable for electrolyte component unstable.
Utility model content
In view of this, the purpose of this utility model is to provide a kind of electrolysis chlorine dioxide generator, for overcoming State one or more problems existing for electrolysis chlorine dioxide sterilizer.
The purpose of this utility model is achieved through the following technical solutions:
A kind of electrolysis chlorine dioxide generator, including brine tank, electrolytic cell and electrolysis power, the brine tank top are set There is Jia Yankou, the brine tank connects electrolytic cell by circulation line, magnetic force circulating pump is provided with the circulation line, described Brine tank, magnetic force circulating pump and electrolytic cell group are into electrolyte circulation system;Anode chamber and cathode chamber are provided with the electrolytic cell, electricity Solution groove is connected to water sprayer by the airway tube above it, and the bottom side of electrolytic cell is provided with blow-off pipe, electrolytic cell and electrolysis electricity The both positive and negative polarity connection in source.
Further, anode bodies and neutral body are provided with the anode chamber, cathode is provided with the cathode chamber, in described Electrolyte membrane is set between property body and cathode.
Further, the positive pole of the electrolysis power is connected with anode bodies, and the negative pole of electrolysis power is connected with cathode.
Further, the cathode chamber is connected with row's hydrogen mouth by blast pipe.
Further, the anode chamber of the brine tank connection electrolytic cell, the anode chamber of the airway tube connection electrolytic cell, institute State the cathode chamber of blow-off pipe connection electrolytic cell.
Preferably, the electrolysis power uses silicon controlled rectifier electrolysis power.
Preferably, the electrolyte membrane and the anode bodies, neutral body and cathode are arranged in parallel.
Compared with prior art, the utility model at least has advantages below:
1. the utility model uses corrosion-resistant asymmetric electrolyte membrane, the film in use, can autobalance yin, yang Pole case acid-base value, makes gas producing efficiency reach optimal, stable performance, reduces operating cost.
2. setting magnetic force circulating pump system, keep electrolytic solution component to be in dynamic balance state all the time, ensure equipment fortune Row is stable, it is ensured that the using effect of equipment.
3. use silicon controlled rectifier electrolysis power so that electrolysis chlorine dioxide generator work is more stable, and realizes The full-automatic operation of the equipment;And can remote computer operation or realize automatic closed loop with online flowmeter and chlorine residue instrument Control.
Brief description of the drawings
Fig. 1 is the structure connection diagram of electrolysis chlorine dioxide generator provided by the utility model.
Embodiment
Below in conjunction with the accompanying drawing in the utility model, the technical scheme in the utility model is carried out clearly and completely Description, it is clear that described embodiment is only part of the embodiment of the present utility model, rather than whole embodiments.Base Embodiment in the utility model, the institute that those of ordinary skill in the art are obtained under the premise of creative work is not made There is other embodiment, belong to the scope of the utility model protection.
As shown in figure 1, a kind of electrolysis chlorine dioxide generator proposed for the utility model embodiment, including brine tank 1st, electrolytic cell 2 and electrolysis power 3, the top of brine tank 1 is provided with plus salt mouth 4, brine tank 1 connect electrolytic cell 2 by circulation line, Circulation line is provided with magnetic force circulating pump 5, and brine tank 1, magnetic force circulating pump 5 and electrolytic cell 2 form electrolyte circulation system, electrolysis Fluid circulation ensure that the electrolyte in electrolytic cell 2 is in dynamic balance state all the time.The He of anode chamber 21 is provided with electrolytic cell 2 Cathode chamber 22, electrolytic cell 2 are connected to water sprayer 7 by the airway tube 6 above it, and the bottom side of electrolytic cell 2 is provided with blow-off pipe 8, electrolytic cell 2 is connected with the both positive and negative polarity of electrolysis power 3.
In the present embodiment, anode bodies and neutral body are provided with anode chamber 21, cathode, neutral body are provided with cathode chamber 22 Electrolyte membrane 9 is set between cathode.
Further, the positive pole of electrolysis power 3 is connected with anode bodies, and the negative pole of electrolysis power 3 is connected with cathode.
Further, cathode chamber 22 is connected with row's hydrogen mouth 10 by blast pipe.
Saturated common salt (NaCl) water is electrolysed in electrolytic cell 2, and the mixing such as ClO2, Cl2, O3, H2O2 is produced in anode chamber 21 Sterilizing gas, mixed by water sprayer 7 with staying water, while hydrogen is produced in cathode chamber 22, by airway tube 6 to air Discharge.The purpose of water sprayer 7 is when the water of certain flow rate is by water sprayer 7, can extract mixing sterilizing gas out, reach with The effect of staying water mixing.
Meanwhile sodium hydroxide (NaOH) solution can be also produced in cathode chamber 22, waste liquid is discharged by blow-off pipe 8.
Further, brine tank 1 connects the anode chamber 21 of electrolytic cell 2, and airway tube 6 connects the anode chamber 22 of electrolytic cell 2, row Dirty pipe 8 connects the cathode chamber 22 of electrolytic cell 2.
A kind of optional or be preferably carried out mode as the utility model, electrolysis power 3 is using silicon controlled rectifier electrolysis electricity Source.
Preferably, electrolyte membrane 9 and anode bodies, neutral body and cathode are arranged in parallel.
First, operation principle of the present utility model is described as follows below in conjunction with the accompanying drawings:
Saturated common salt (NaCl) water is electrolysed in the electrolytic cell with special electrolyte membrane, caused to contain ClO2、Cl2、 O3、H2O2Etc. strong oxidizing property sterilizing gas, by water sprayer negative pressure extraction, mix safely, reach at sterilization with pending water body The purpose of reason.
2nd, through actual use and it is demonstrated experimentally that electrolysis chlorine dioxide generator and chemical process CO 2 generator phase Than having following good characteristic:
It is electrolysed using salt (NaCl) and produces chlorine dioxide (ClO2) mixed high-efficient disinfectant, raw material, which is easy to get, is supplied with guarantor Barrier.Chlorine dioxide (ClO2) mixed high-efficient disinfectant is is prepared in situ, onsite application, it is perfectly safe reliable, meanwhile, operating cost It is low.On the other hand, (NaCl) method that electrolyzes table salt production chlorine dioxide (ClO2) mixed high-efficient disinfectant and chemical method production dioxy Change chlorine (ClO2) mixed high-efficient disinfectant compares, electrolyze table salt (NaCl) method, avoids using acid solution, sodium chlorate or sodium chlorite Solution, easy to operation and management and the buying of raw material storage, while liquid waste processing is it also avoid, and also operating cost is low, therefore, Electrolysis chlorine dioxide generator has good practicality.
3rd, the Essential Environment condition that the utility model device uses is as follows:
1st, environment temperature:0 DEG C~50 DEG C;
2nd, water temperature:0 DEG C~35 DEG C;
3rd, hydraulic pressure:0.15MPa~0.45MPa;
4th, dispensing mouth pressure is less than:0.05MPa;
5th, the mainframe box of equipment and electrolysis power locellus are placed;
6th, there is pumping equipment and well-ventilated in equipment room.
Compared with prior art, the utility model at least has advantages below:
1. the utility model uses corrosion-resistant asymmetric electrolyte membrane, the film in use, can autobalance yin, yang Pole case acid-base value, makes gas producing efficiency reach optimal, stable performance, reduces operating cost.
2. setting magnetic force circulating pump system, keep electrolytic solution component to be in dynamic balance state all the time, ensure equipment fortune Row is stable, it is ensured that the using effect of equipment.
3. use silicon controlled rectifier electrolysis power so that electrolysis chlorine dioxide generator work is more stable, and realizes The full-automatic operation of the equipment;And can remote computer operation or realize automatic closed loop with online flowmeter and chlorine residue instrument Control.
It is described above, the only preferable embodiment of the utility model, but the scope of protection of the utility model is not This is confined to, any one skilled in the art can readily occur in the technical scope that the utility model discloses Change or replacement, should all cover within the scope of protection of the utility model.Therefore, the scope of protection of the utility model should It is defined by the protection domain of claims.

Claims (7)

1. a kind of electrolysis chlorine dioxide generator, including brine tank, electrolytic cell and electrolysis power, it is characterised in that:The salt It is provided with above water tank plus salt mouth, the brine tank connects electrolytic cell by circulation line, magnetic force are provided with the circulation line Circulating pump, the brine tank, magnetic force circulating pump and electrolytic cell group are into electrolyte circulation system;Anode chamber is provided with the electrolytic cell And cathode chamber, electrolytic cell are connected to water sprayer by the airway tube above it, the bottom side of electrolytic cell is provided with blow-off pipe, electrolysis The both positive and negative polarity of groove and electrolysis power connects.
2. electrolysis chlorine dioxide generator according to claim 1, it is characterised in that:Anode is provided with the anode chamber Body and neutral body, the cathode chamber is interior to be provided with cathode, and electrolyte membrane is set between the neutral body and cathode.
3. electrolysis chlorine dioxide generator according to claim 1, it is characterised in that:The positive pole of the electrolysis power with Anode bodies are connected, and the negative pole of electrolysis power is connected with cathode.
4. electrolysis chlorine dioxide generator according to claim 1, it is characterised in that:The cathode chamber passes through blast pipe The row's of being connected with hydrogen mouth.
5. electrolysis chlorine dioxide generator according to claim 1, it is characterised in that:The brine tank connects electrolytic cell Anode chamber, the anode chamber of airway tube connection electrolytic cell, the cathode chamber of the blow-off pipe connection electrolytic cell.
6. electrolysis chlorine dioxide generator according to claim 1, it is characterised in that:The electrolysis power is using controllable Silicon rectifier electrolysis power.
7. electrolysis chlorine dioxide generator according to claim 2, it is characterised in that:The electrolyte membrane and the sun Polar body, neutral body and cathode are arranged in parallel.
CN201720284500.1U 2017-03-22 2017-03-22 A kind of electrolysis chlorine dioxide generator Expired - Fee Related CN206843595U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201720284500.1U CN206843595U (en) 2017-03-22 2017-03-22 A kind of electrolysis chlorine dioxide generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201720284500.1U CN206843595U (en) 2017-03-22 2017-03-22 A kind of electrolysis chlorine dioxide generator

Publications (1)

Publication Number Publication Date
CN206843595U true CN206843595U (en) 2018-01-05

Family

ID=60791186

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201720284500.1U Expired - Fee Related CN206843595U (en) 2017-03-22 2017-03-22 A kind of electrolysis chlorine dioxide generator

Country Status (1)

Country Link
CN (1) CN206843595U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111456181A (en) * 2019-01-21 2020-07-28 科勒公司 Sanitary ware with electrolytic chlorination device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111456181A (en) * 2019-01-21 2020-07-28 科勒公司 Sanitary ware with electrolytic chlorination device
CN111456181B (en) * 2019-01-21 2022-04-12 科勒公司 Sanitary ware with electrolytic chlorination device

Similar Documents

Publication Publication Date Title
KR101244313B1 (en) Highly Efficient Sodium Hypochlorite Generator With Heat Exchanger
CN204569626U (en) A kind of disinfection system for piped direct-drinking water
CN211972469U (en) Hypochlorous acid disinfectant generating system adopting ion membrane electrolysis method
CN211689254U (en) Sodium hypochlorite generation system adopting ion membrane electrolysis method
US20170174529A1 (en) Flow powered water disinfection
CN201785505U (en) NaCIO generator
CN108505061A (en) A kind of high-concentrated sodium hypochlorite generator
CN102217649B (en) Method and device for preparing faintly acid disinfectant fluid by diaphragm-free electrolysis
CN202193681U (en) Integrated full-automatic drinking water sterilization device
CN109457267A (en) A kind of ozone generating-device module and collection method based on diamond electrode
CN102021602B (en) Sodium hypochlorite generator
CN208414568U (en) A kind of high-concentrated sodium hypochlorite generator
CN206843595U (en) A kind of electrolysis chlorine dioxide generator
CN208151489U (en) A kind of hypochlorite generator
CN206843596U (en) A kind of chlorine dioxide mixed high-efficient sterilizer
KR101371616B1 (en) Naocl dilution structure of generation-system for antiseptic solution including chlorine
CN206127436U (en) Hypochlorite generator is used in disinfection
CN204529992U (en) Water treatment system disinfectant preparation apparatus
CN213203226U (en) Ion membrane electrolysis method hypochlorous acid disinfectant takes place processing system
CN206232822U (en) A kind of Portable miniature high efficiency hydrogen generator
CN210237794U (en) Sodium hypochlorite generator
CN111560622A (en) High-concentration weak-acid hypochlorous acid disinfectant generator for manufacturing stable pH value
CN101891153A (en) Chlorine dioxide compound disinfectant generator and use method thereof
CN206486607U (en) A kind of hypochlorite generator
RU111857U1 (en) ELECTROLYSIS INSTALLATION FOR PRODUCING SODIUM HYPOCHLORITE

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180105

Termination date: 20200322

CF01 Termination of patent right due to non-payment of annual fee