CN211972469U

CN211972469U - Hypochlorous acid disinfectant generating system adopting ion membrane electrolysis method

Info

Publication number: CN211972469U
Application number: CN202020606724.1U
Authority: CN
Inventors: 兰东祥; 刘志永
Original assignee: Beijing Delinda Technology Development Co ltd
Current assignee: Beijing Delinda Technology Development Co ltd
Priority date: 2020-04-21
Filing date: 2020-04-21
Publication date: 2020-11-20
Anticipated expiration: 2030-04-21

Abstract

The application provides a hypochlorous acid disinfectant generating system adopting an ionic membrane electrolysis method, which comprises an electrolysis device, a salt dissolving device, an electric control device, a water injector, a reaction device and a hypochlorous acid storage device; the electric control device mainly provides electric energy for the electrolysis device to electrolyze the saturated salt water; the electrolysis device comprises an electrolysis bath body, and an anode and a cathode which are arranged in the electrolysis bath body; the electrolytic bath body is provided with a dosing pipe and a return pipe; the salt dissolving device is connected with the electrolytic bath body through the dosing pipe and the return pipe to form circulation and is used for providing the saturated salt water dissolved by the salt dissolving device for the electrolytic device and recovering the dilute salt water; an ionic membrane is arranged between the anode and the cathode of the electrolysis device and is used for separating electrolysis products of the two electrodes; the salt dissolving device is connected with the reaction device through a pipeline and a water ejector, and the water ejector is used for separating to obtain chlorine; the reaction device is provided with a water inlet pipe, so that chlorine and water react in the water inlet pipe to form hypochlorous acid solution which enters the hypochlorous acid storage device. The disinfectant generated by applying the system has stable hypochlorous acid content, high concentration and high efficiency.

Description

Hypochlorous acid disinfectant generating system adopting ion membrane electrolysis method

Technical Field

The application belongs to the technical field of hypochlorous acid preparation, and particularly relates to a hypochlorous acid disinfectant generation system with an ion membrane electrolysis method.

Background

In the field of disinfection of water bodies such as drinking water, sewage and the like, hypochlorous acid disinfectant is a new disinfection product and has been demonstrated to be one of safe, effective and environment-friendly disinfection and sterilization products.

At present, hypochlorous acid generators which are applied more are equipment for preparing hypochlorous acid disinfectant by electrolyzing saline solution. The working principle of the existing hypochlorous acid generator is as follows: a diaphragm-free electrolytic cell is adopted, the current is generally output by an electrolytic power supply, and a sodium chloride aqueous solution with the concentration of 3-5% is circularly electrolyzed in the electrolytic cell to prepare the hypochlorous acid disinfectant with the concentration of about 2-5%. The specific process flow is as follows: salt → strong brine → dilute brine → filtration → electrolysis in diaphragm-free electrolytic cell → hypochlorous acid solution; and stopping the machine at regular intervals, cleaning the polar plate by using hydrochloric acid for descaling → discharging waste acid.

In the above-mentioned electrolytic cell, there is no diaphragm between the cathode and anode, and the cathode and anode are usually discharged in a barrel-shaped electrode chamber, and dilute brine is electrolyzed to produce hypochlorous acid solution. However, the preparation technology has low salt utilization rate (about 60 percent), low generated hypochlorous acid concentration (2-3ppm) and high power consumption; and because the scaling reason, need pickling polar plate scale removal, production efficiency is lower.

SUMMERY OF THE UTILITY MODEL

In view of this, the application provides a hypochlorous acid disinfectant generating system of ion membrane electrolysis method, uses this hypochlorous acid disinfectant generating system, can produce the hypochlorous acid antiseptic solution of high concentration, and salt power consumption is low, need not the pickling polar plate, can reduce disinfection cost by a wide margin.

The application provides a hypochlorous acid disinfectant generating system adopting an ionic membrane electrolysis method, which comprises an electrolysis device, a salt dissolving device, an electric control device, a water injector, a reaction device and a hypochlorous acid storage device; the electric control device mainly provides electric energy for the electrolysis device to electrolyze saturated salt water;

the electrolysis device comprises an electrolysis bath body, and an anode and a cathode which are arranged in the electrolysis bath body; the electrolytic bath body is provided with a dosing pipe and a return pipe; the salt dissolving device is connected with the electrolytic bath body through a medicine adding pipe and a return pipe to form circulation and is used for providing dissolved saturated salt water for the electrolytic device and recovering weak salt water; an ionic membrane is arranged between the anode and the cathode in the electrolysis device and is used for separating electrolysis products of the two electrodes; the salt dissolving device is connected with the reaction device through a pipeline and a water ejector, and the water ejector is used for separating to obtain chlorine; the reaction device is provided with a water inlet pipe, so that chlorine generated and separated by electrolysis reacts with water in the reaction device to form hypochlorous acid solution;

the hypochlorous acid storage device is communicated with the reaction device and is used for storing hypochlorous acid solution.

Preferably, the hypochlorous acid storage device is connected with the reaction device to form a circulation and is provided with a circulation pump; the hypochlorous acid storage device is also provided with a vent pipe for pressure balance.

Preferably, the hypochlorous acid disinfectant generating system with the ionic membrane electrolysis method further comprises a water softening device, and the electrolysis bath body is provided with a water inlet pipe connected with the water softening device.

Preferably, the electrolytic bath body is provided with an exhaust pipe and an intake pipe for exhausting hydrogen generated by electrolysis and maintaining the air pressure in the bath body balanced.

Preferably, the hypochlorous acid disinfectant generating system with the ion membrane electrolysis method further comprises a sodium hydroxide storage device connected with the electrolysis device and used for storing sodium hydroxide generated by electrolysis.

Preferably, the electrolysis apparatus further comprises a cooler for ensuring the temperature of the electrolyte; the electrolytic tank body is also provided with a sewage discharge pipe connected with a drainage facility.

Preferably, the electrolytic cell body has a flange-type box structure; the anode has a mesh structure.

Preferably, the salt dissolving device is of a box type structure and is used for isolated salt feeding and salt dissolving to form saturated salt water.

Preferably, a circulating pump is arranged on a pipeline connecting the salt dissolving device and the chemical feeding pipe of the electrolysis device; the water ejector is connected with the reaction device to form circulation and is provided with a circulating pump.

Compared with the prior art, in the hypochlorous acid disinfectant generating system adopting the ion membrane electrolysis method, the salt dissolving device dissolves salt and supplies saturated salt solution to the electrolysis device for electrolysis, and the anode generates Cl in the electrolysis process₂Generating NaOH and H at the cathode₂(ii) a An ionic membrane is arranged between the anode and the cathode in the electrolytic cell body, and only Na is allowed⁺And H⁺Smoothly pass through the cathode without passing through chloride ions. The chlorine generated by the anode is dissolved in the light salt water and flows back to the salt dissolving device, the chlorine is obtained by separation of a water injector, the chlorine and water are subjected to chemical combination/disproportionation reaction in the reaction device to generate hypochlorous acid, and the hypochlorous acid is stored in a hypochlorous acid storage device and can be used for disinfecting water bodies and the like. The system can electrolyze saturated salt water in an ionic membrane mode, and has high raw material conversion rate and low power consumption, so that the disinfection cost is greatly reduced. The generated hypochlorous acid disinfectant has stable content and can reach the concentration of 1000ppm, and more prominently, the electrode plate is not easy to scale and does not need acid pickling.

Meanwhile, the ionic membrane in the electrolytic device strictly separates the cathode and the anode in the electrolytic cell body, and Cl generated by the anode₂And H generated at the cathode₂Absolutely do not mix, and avoid Cl in the electrolyzer₂And H₂The danger of explosion of the cell due to the occurrence of strong redox reactions. In addition, the method can also reduce the link of proportioning dilute brine, thereby reducing fault points.

Drawings

FIG. 1 is a schematic flow diagram of a hypochlorous acid disinfectant generating system according to an embodiment of the present disclosure;

FIG. 2 is a front view of an electrolytic device according to some embodiments of the present application;

FIG. 3 is a side view of FIG. 2;

FIG. 4 is a top view of FIG. 2;

FIG. 5 is a schematic view of the internal structure of an electrolyzer in some embodiments of the present application;

FIG. 6 is a front view of a salt dissolving device according to some embodiments of the present disclosure;

FIG. 7 is a side view of FIG. 6;

FIG. 8 is a top view of FIG. 6;

FIG. 9 is a rear view of the structure of the portion of the salt dissolving bin of FIG. 7;

Detailed Description

The technical solutions in the embodiments of the present application are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present application, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.

By applying the hypochlorous acid disinfectant generating system, the generated disinfectant has stable hypochlorous acid content, high concentration and low salt power consumption, does not need to pickle a polar plate, and can greatly reduce the disinfection cost.

Referring to fig. 1, fig. 1 is a schematic flow diagram of a hypochlorous acid disinfectant generating system device provided in an embodiment of the present application. Wherein, 1 is an electrolysis device which can be connected with pure water or softened water; 2, a salt dissolving device, wherein NaCl is added; 3 is an electric control device, 4 is a sodium hydroxide storage device, wherein hydrogen can be discharged outdoors at high altitude; 5, a reaction device is connected with clear water; 6 is a hypochlorous acid storage device; t1, T2, T3 and T4 are all magnetic circulating pumps; z1 is a water ejector.

The basic structure of the hypochlorous acid disinfectant generating system is five parts, and comprises: the device comprises an electrolysis device 1, a salt dissolving device 2, an electric control device 3, a reaction device 5 and a hypochlorous acid storage device 6. Wherein, the electrolysis device 1 is the core part of the hypochlorous acid disinfectant generating system; the electrolyte in the electrolysis device is saturated salt solution, so that the saturated salt solution is electrolyzed.

Referring to fig. 2-4, fig. 2 is a front view of an electrolyzer in some embodiments of the present application; FIG. 3 is a side view of FIG. 2; fig. 4 is a top view of fig. 2. Wherein 11 is an electrolytic bath body, 12 is a dosing pipe, 13 is an exhaust pipe, 14 is a return pipe, 15 is a water supplementing pipe, 16 is a water inlet pipe, 17 is an air inlet pipe, 18 is a sewage discharge pipe, and 19 is a circulating pump suction pipe.

In a particular embodiment of the present application, the electrolysis device essentially comprises: an electrolytic bath body 11 and an electrolytic electrode provided inside thereof. The electrolytic bath body 11 is preferably of a flange type box structure, is easy to disassemble and convenient to maintain; the tank body shell is made of corrosion-resistant reinforced polyvinyl chloride (PVC) material. In this application, this structure fundamentally eliminates electrolyte leakage and cell body corrosion problems.

The electrolysis electrode described herein is divided into an anode and a cathode; the anode preferably has a net structure, chlorine generated by electrolysis is not easy to stay on the surface of the polar plate, the effective area of electrolysis is increased, and the current efficiency is improved. As shown in fig. 5, fig. 5 is a schematic view of the internal structure of the electrolytic device in some embodiments of the present application, wherein 111 is an ionic membrane. In the electrolytic device of the embodiment of the application, an ionic membrane 111, which is an electrolytic diaphragm, preferably a perfluorinated ionic membrane, is arranged between the anode and the cathode, and separates the anode and the cathode to separate two electrode products. Saturated saline solution is injected into the anode chamber, and water is injected into the cathode chamber. Power on, electrolysisIn the process, Cl is generated at the anode₂Generating NaOH and H at the cathode₂(ii) a The provided ionic membrane 111 allows only Na⁺And H⁺The solution smoothly passes through the cathode without passing through chloride ions Cl-.

The system adopts the electrolytic device added with the ionic membrane, can electrolyze saturated salt water, improves the conversion rate of raw materials and reduces the salt consumption. The application can also reduce the link of proportioning dilute brine, thereby reducing the fault points. The electrolysis electrode is adopted, the electrolysis voltage is controlled in the chloride ion discharge interval of 5-8V, and the electrolysis voltage is lower than that of the conventional hypochlorous acid generator, so that the power consumption is greatly reduced, and the disinfection cost is greatly reduced. In addition, the hypochlorous acid content of the generated disinfectant is stable and adjustable due to the adoption of the ionic membrane electrolysis device and the like; the electrode plate is not scaled and does not need acid pickling.

The ionic membrane in the electrolytic device strictly separates the anode and the cathode in the electrolytic cell body, and Cl generated by the anode₂And H generated at the cathode₂Absolutely do not mix, and avoid Cl in the electrolyzer₂And H₂The danger of explosion of the cell due to the occurrence of strong redox reactions.

In the present application, the anode has a high chlorine evolution activity and the cathode has a high hydrogen evolution activity. The cathode and the anode have good electrochemical stability, corrosion resistance and long service life. The electrode is of a conventional plate-shaped structure, and different types of electrodes correspond to different structural sizes of the polar plate; the ionic membrane is not particularly limited in porosity and other parameters. Furthermore, the electrolysis apparatus 11 includes a cooler for ensuring the temperature of the electrolyte. The cooler can be made of titanium tubes, has a high heat exchange effect, and ensures that the temperature of the electrolyte is always less than 45 ℃ in the electrolysis process.

Specifically, in some embodiments of the present application, the electrode reaction formula is as follows:

and (3) anode reaction:

and (3) cathode reaction:

as shown in fig. 2 to 4, the electrolytic bath body 11 in the present embodiment is provided with: a dosing pipe 12, an exhaust pipe 13, a return pipe 14, a water replenishing pipe 15, a water inlet pipe 16, an air inlet pipe 17, a sewage discharge pipe 18 and a circulating pump suction pipe 19. The electrolysis device 1 is connected with the salt dissolving device 2 through a dosing pipe 12 and a return pipe 14 and forms a circulation. In the embodiment of the application, the hypochlorous acid disinfectant generating system comprises a salt dissolving device 2, wherein salt (NaCl) added is dissolved to form saturated salt water, the saturated salt water is sent to an electrolysis device 1 through a drug adding pipe 12, and electrolyzed light salt water flows back to the salt dissolving device 2 through a return pipe 14. In addition, a magnetic circulating pump T1 can be arranged in the pipeline of the dosing pipe 12.

In the embodiment of the present application, the salt dissolving device 2 may be a box-type structure and welded with high-quality PVC. Preferably, the salt dissolving device 2 has an isolated salt feeding and dissolving structure, and the raw salt is dissolved into a saturated salt solution, and is connected to the electrolysis device 1 through a pipe to form a circulation.

The salt dissolving device in the preferred embodiment of the application comprises a shell, a salt storage bin and a salt dissolving bin are arranged in the shell from top to bottom, the salt storage bin and the salt dissolving bin are communicated with each other in a break-make way through a salt feeding valve, the top of the shell is provided with a salt adding port communicated with the salt storage bin in an opening-closing way, the shell is provided with a chemical feeding pipe for introducing saturated salt solution into an external electrolysis device from the salt dissolving bin, a return pipe for returning unsaturated salt solution electrolyzed by the external electrolysis device to the salt dissolving bin, a water inlet pipe for communicating the salt dissolving bin with external water supply equipment and a salt flushing pump for pumping liquid into the salt storage bin from the salt dissolving bin, the shell is also provided with an air inlet pipe communicated with the salt dissolving bin, the salt dissolving bin and the external atmospheric environment and an air suction pipe communicated with the salt storage bin, the salt dissolving bin and the external water ejector to perform gas-liquid separation.

In the operation and use process of the preferable salt dissolving device, the salt storage bin and the salt dissolving bin are independently arranged, so that when salt adding operation is required, salt added from the salt adding port is firstly placed into the salt storage bin, the salt adding valve is in a closed state at the moment, the salt storage bin and the salt dissolving bin are mutually isolated, the sterilizing gas in the salt dissolving bin cannot be introduced into the salt storage bin and cannot escape from the salt storage bin and the salt adding port, the health of operators in the salt adding process is ensured, and the waste of the sterilizing gas is avoided; after the salt adding operation is finished, closing the salt adding port, operating a salt flushing pump to send liquid in the salt dissolving bin into the salt storing bin, simultaneously connecting a salt feeding valve to flush the salt in the salt storing bin and bring the salt into the salt dissolving bin, after the flushing operation is finished, closing the salt flushing pump to fully mix and dissolve the salt and the liquid brought into the salt dissolving bin to form saturated salt solution, then sending the salt solution into an electrolysis device through a medicine adding pipe (also called a water outlet pipe) to carry out electrolysis to generate disinfection gas such as chlorine and the like, then returning the liquid with the disinfection gas to the salt dissolving bin through a return pipe to enable the disinfection gas dissolved in the liquid to escape, then utilizing the negative pressure generated by the water flow through a water ejector, extracting the disinfection gas contained in the salt dissolving bin after escaping through an air suction pipe, sucking the disinfection gas through the water ejector to generate hydration and disproportionation reaction with water, adding into water to be treated to complete disinfection. In the process, air is respectively supplemented into the salt storage bin and the salt dissolving bin through the air inlet pipe, so that the air pressure inside the salt dissolving bin is balanced, and the continuous and stable extraction process of the sterilizing gas is ensured.

Referring to fig. 6 to 9, fig. 6 is a front view of a salt dissolving device according to an embodiment of the present disclosure; FIG. 7 is a side view of FIG. 6; FIG. 8 is a top view of FIG. 7; fig. 9 is a rear view of the structure of the salt dissolving bin portion of fig. 7. Wherein, the device comprises a shell 21, a salt adding port 211, a sealing cover 212, an observation window 213, a salt storage bin 22, a salt dissolving bin 23, an overflow pipe 231, a drain pipe 232, a salt throwing valve 24, an air inlet pipe 251, an air suction pipe 252 and a liquid level sensor 26.

In the concrete implementation mode, the salt dissolving device is a salt dissolving box, which comprises a casing 21, a salt storage bin 22 and a salt dissolving bin 23 are arranged in the casing 21 from top to bottom, the salt storage bin 22 and the salt dissolving bin 23 are communicated with each other through a salt feeding valve 24 in an on-off manner, a salt adding port 211 communicated with the salt storage bin 22 is arranged at the top of the casing 21 in an openable manner, a water outlet pipe for introducing saturated salt solution from the salt dissolving bin 23 to an external electrolysis device, a return pipe for returning unsaturated salt solution electrolyzed by the external electrolysis device to the salt dissolving bin 23, a water inlet pipe for communicating the salt dissolving bin 23 with external water supply equipment, and a salt flushing pump for sending the salt solution from the salt dissolving bin 23 to the salt storage bin 22 are arranged on the casing 21, the casing 21 is further provided with an air inlet pipe 251 for communicating the salt storage bin 22, the salt dissolving bin 23 and the external atmosphere environment, and an air suction pipe 252 for communicating the salt storage bin 22, the salt dissolving bin 23 and the water ejector for gas-liquid separation.

In the operation and use process, the salt storage bin 22 and the salt dissolving bin 23 are independently arranged, so that when salt adding operation is required, salt added from the salt adding port 211 is firstly placed into the salt storage bin 22, the salt adding valve 24 is in a closed state at the moment, the salt storage bin 22 and the salt dissolving bin 23 are mutually isolated, the sterilizing gas in the salt dissolving bin 23 cannot be introduced into the salt storage bin 22 and cannot escape from the salt storage bin 22 and the salt adding port 211, the health of operators in the salt adding process is ensured, and the waste of the sterilizing gas is avoided; after the salt adding operation is finished, the salt adding port 211 is closed, then the salt flushing pump is operated to send the liquid in the salt dissolving bin 23 into the salt storage bin 22, the salt throwing valve 24 is connected at the same time, so that the salt in the salt storage bin 22 is flushed and carried into the salt dissolving bin 23, after the flushing operation is finished, the salt flushing pump is closed, so that the salt and the liquid brought into the salt dissolving bin 23 are fully mixed and dissolved to form saturated salt solution, then the salt solution is sent into the electrolysis device through the water outlet pipe to be electrolyzed to generate chlorine and other sterilizing gases, then the liquid with the sterilizing gases is sent back into the salt dissolving bin 23 through the return pipe to be kept still, so that the sterilizing gases dissolved in the liquid escape, and then the sterilizing gases which escape and are contained in the salt dissolving bin 23 can be pumped to downstream gas equipment through the air suction pipe 252 by utilizing equipment such as a water ejector and the like to implement the sterilizing operation by utilizing the sterilizing, air can be supplemented into the salt dissolving bin 23 through the air inlet pipe 251 in the process of extracting the sterilizing gas, so that the air pressure inside the salt dissolving bin 23 is ensured to be balanced, and the continuous and stable sterilizing gas extraction process is ensured.

It should be noted that for the general equipment assembly structure, the specific assembly position of the salt flushing pump can refer to the notch position at the lower right corner of the component structure in fig. 9. Certainly, the specific assembly position of the salt flushing pump is not limited to this, and the specific assembly positions of other components not explicitly labeled in the figures in this document also do not need to be specifically limited, and in practical application, a worker can flexibly select the specific assembly positions of the components such as the salt flushing pump according to specific working condition requirements, and in principle, the salt flushing pump can be any pump as long as the stable and reliable operation of the components can be ensured and the actual working operation requirements of the salt dissolving device can be met.

Further, the bottom of the housing 21 is provided with an overflow pipe 231 and a drain pipe 232 which communicate the dissolved salt bin 23 with the external environment. When the liquid in each chamber in the shell 21, especially in the salt dissolving bin 23, is too much, part of the liquid can be discharged through the overflow pipe 231, so that the liquid amount in the chamber is in a stable and proper range, and the concentration of the salt solution and the operation efficiency of the equipment are ensured; meanwhile, liquid which cannot be used any more can be quickly discharged through the drain pipe 232, and then a new water body can be supplemented into the salt dissolving device through the water supply pipe, so that subsequent salt solution preparation and electrolysis operation can be continuously carried out.

Specifically, a liquid level sensor 26 cooperatively matched with the salt storage bin 22, the salt dissolving bin 23 and the salt flushing pump is arranged on the shell 21. The liquid level sensor 26 can monitor and feed back the liquid level and the saturated salt solution state in each chamber of the salt dissolving device in real time, so that a worker can correspondingly operate a salt flushing pump or other components to drain or supplement liquid for the corresponding chambers, and the liquid level in each chamber, especially the salt dissolving bin 23, is ensured to be in a stable and proper state, so that the overall operation efficiency and the working performance of the salt dissolving device are ensured.

More specifically, the side wall of the casing 21 is provided with an observation window 213 aligned with the salt storage bin 22 and the salt dissolving bin 23, and the observation window 213 is made of transparent acrylic. In the operation process of the equipment, the staff can also visually know the liquid amount and/or the salt storage amount in each chamber through each observation window 213 so as to correspondingly implement operations of liquid supplementing, liquid draining, salt adding and the like, and ensure that the preparation of the salt solution and the supply of the corresponding electrolyte are sufficient and stable.

The observation window 213 is an elongated hole whose longitudinal direction coincides with the vertical direction. The long hole structure arranged along the vertical direction in the length direction helps to further improve the effective observation range of the observation window 213, so that the staff can observe the liquid amount and/or the salt inventory in the cavity more accurately and efficiently in real time, and the accuracy and the regulation effect of subsequent corresponding operation are ensured.

On the other hand, a salt storage tank communicated with the salt storage bin 22 and communicated with the outlet end of the return pipe in an alignment manner is arranged in the salt dissolving bin 23. After the operation of adding salt is accomplished, some newly-added salt can be fallen into the salt storage tank by storing up salt storehouse 22, later when implementing the scouring operation, the liquid that is extracted by towards salt pump autolysis salt storehouse 13 bottom can flow through in proper order and erode and store up salt storehouse 22 and salt storage tank, in order to further improve the solution efficiency and the effect of liquid to salt through storing up salt storehouse 22 and two positions of salt storage tank in with the salinity, after the completion of scouring, the liquid that has some undissolved salt secretly converges and stews in dissolving the salt storehouse, so that salt and liquid further fully dissolve the mixture, form saturated salt solution, later directly concentrate the extraction in the autolysis salt storehouse by the outlet pipe and in order to supply with the electrolysis, thereby further improve the supply and the transport efficiency of electrolyte, guarantee the continuous high-efficient implementation of follow-up electrolysis operation.

In addition, a cover 212 is detachably screwed to the salting port 211. This kind of threaded connection simple structure is reliable, and dismouting operating efficiency is higher, can guarantee the closing cap 212 to adding the reliable encapsulation of salt mouth 211 in, effectively reduce the operation degree of difficulty of adding salt in-process staff, improve operating efficiency.

Of course, the above-mentioned mating form of the cover 212 and the salting opening 211 is not limited to the above-mentioned screw connection in practical application, and any adapter and assembling structure can be used as long as the adapter and the assembling structure can ensure the reliable sealing of the cover 212 to the salting opening 211.

The salt dissolving device and the electrolysis device in the above embodiment of the application are matched with each other, so that the phenomenon of escape of the sterilizing gas can not occur, and the working and running processes are safe and efficient.

Further, the electrolytic bath body 11 in the present embodiment is provided with an exhaust pipe 13 for discharging hydrogen gas generated from the cathode; and an air inlet pipe 17 is correspondingly arranged to maintain the air pressure balance in the groove body. In the embodiment of the application, an advanced hydrogen discharging mode of the electrolytic cell body is adopted, so that the danger of the electrolytic cell explosion due to hydrogen is completely avoided. The water replenishing pipe 15 arranged on the electrolytic bath body 11 is a water replenishing pipe of a salt feeding and dissolving device, and is also provided with a circulating pump suction pipe 19.

Preferably, the hypochlorous acid disinfectant generating system with the ion membrane electrolysis method further comprises a water softening device, wherein the water softening device is water pretreatment equipment for the electrolysis device and is used for providing low-hardness water (namely providing pure water or softened water) for the electrolysis process, so that the smooth electrolysis is facilitated; the electrolytic bath body 11 is correspondingly provided with a water inlet pipe 16 connected to the water softening device. In the particular embodiment of the present application, the electrolytic cell body 11 is also provided with a waste pipe 18, typically located in the cathode compartment, which is connected to a drain facility.

In the embodiment of the application, the hypochlorous acid disinfectant generating system comprises an electric control device 3 which mainly provides electric energy for the electrolysis device 1 to electrolyze saturated saline solution. The electric control device 3 mainly comprises a direct current electrolysis power supply; the direct current electrolysis power supply can be connected with the electrode plate component of the electrolysis bath body through the copper bar to provide direct current electric energy for the electrolysis bath body.

Specifically, the direct current electrolytic power supply has complete self-diagnosis and protection functions, and the protection items are as follows: overcurrent protection: when the output current exceeds a set limit value, the protection circuit automatically turns off the electrolysis power supply; temperature protection: when the temperature of the thyristor reaches the upper limit value, the protection circuit automatically turns off the electrolysis power supply; overvoltage protection: when the output voltage value exceeds a set limit value, the protection circuit automatically turns off the electrolysis power supply; phase loss protection: when the control loop is out of phase, the protection circuit automatically turns off the electrolysis power supply.

In the hypochlorous acid disinfectant generating system by the ion membrane electrolysis method provided by the embodiment of the application, a sodium hydroxide storage device 4 connected with the electrolysis device 1 is preferably further included, and the sodium hydroxide generated by electrolysis is stored. The sodium hydroxide storage device is not particularly limited in the application, and the hydrogen discharged by the electrolysis device 1 can be discharged out of the hydrogen chamber at high altitude through the storage device. In addition, the sodium hydroxide storage device 4 can be connected with the electrolysis device to form a circulation, and a magnetic circulation pump T2 is added.

In the embodiment of the application, the water ejector can absorb the sterilizing gas and separate the sterilizing gas according to the Venturi principle to obtain chlorine; it can be connected with the reaction device 5 to form a circulation, and a magnetic circulation pump T3 is added.

The hypochlorous acid disinfectant generating system includes a reaction device 5 which is a hypochlorous acid reaction part and may be a hypochlorous acid reaction tank. The salt dissolving device 2 is connected with the reaction device 5 through a pipeline and a water ejector Z1, and the water ejector is used for absorbing the sterilizing gas and separating to obtain chlorine; the reaction device 5 is provided with a water inlet pipe, so that chlorine generated and separated by electrolysis and accessed clean water react in the reaction device 5 to form hypochlorous acid solution.

During the operation of the specific process, when a certain flow rate of water passes through the water ejector Z1, the water ejector Z1 generates negative pressure to mix Cl₂Pumping out the sterilizing gas, fully mixing the sterilizing gas with the accessed clear water in the reaction device 5 to form a sterilizing gas-water mixed solution, and generating water in the reaction device 5And carrying out chemical reaction/disproportionation reaction to generate a hypochlorous acid solution. The hypochlorous acid generation reaction formula is as follows:

the reaction apparatus 5 in the embodiment of the present application is communicated with the hypochlorous acid storage apparatus 6, and the generated hypochlorous acid solution with high concentration enters the hypochlorous acid storage apparatus 6. Preferably, the hypochlorous acid storage device 6 is connected with the reaction device 5 to form a circulation, the high-concentration hypochlorous acid solution enters the hypochlorous acid storage device 6 through a dosing pipe, and the low-concentration hypochlorous acid solution is preferably pumped (by adopting a magnetic circulating pump T4) through a water inlet pipe and returns to the reaction device 5; the embodiment of the application can directly produce hypochlorous acid solution with various concentrations by achieving the preset concentration in a circulating absorption mode, for example, hypochlorous acid disinfectant with the concentration of 1000ppm can be produced. The hypochlorous acid storage device 6 can adopt a medicine storage tank well known in the field; it is also provided with a breather pipe to maintain pressure balance. In addition, this application can also be with the hypochlorous acid disinfectant solution that has generated through throwing the feeder apparatus, according to certain design proportion throw add in waiting to disinfect the water.

In the hypochlorous acid disinfectant generating system of the embodiment of the application, the electric control device 3 further comprises a control unit which is composed of a sensor, an instrument and an actuating mechanism. A manual control and automatic control mode change-over switch is arranged on a control unit panel; the control unit can control the system in a centralized manner, and complete equipment switching control, system self-diagnosis and alarm protection, such as operation control, operation parameter control, circulating pumps and the like, according to the process flow programs of the equipment, so that all the equipment can be automatically monitored under the unattended working condition and can be safely operated for a long time.

The control objects are mainly the effective chlorine yield and the temperature of the electrolytic cell, and the effective chlorine yield can be adjusted on an operation panel of the electrolytic power supply. The temperature of the solution in the electrolytic cell is controlled as follows: when the brine is electrolyzed, heat is generated, and the heat generated by the electrolytic cell is taken away by the electrolytic cell cooler. When the cooler of the electrolytic cell is lack of water, the temperature of the solution of the electrolytic cell needs to be controlled in order to ensure that the material of the cell body of the electrolytic cell is not deformed due to overhigh temperature rise of the electrolyte. When the temperature of the electrolyte is higher than 50 ℃, the electrolysis of the electrolytic cell is stopped, and when the temperature of the solution in the electrolytic cell is lower than 45 ℃, the system is automatically started.

Specifically, the installation and connection method of each device in the embodiment of the present application includes: the electrolysis device is characterized by comprising water inlet pretreatment equipment, a salt dissolving tank, a generation system host, a hypochlorous acid reaction and storage tanks, wherein the storage tanks are stably arranged and have moderate intervals. The devices can be arranged separately or integrally, for example, a salt dissolving device, an electrolysis device and a reaction device are assembled into a device, and the part of the reaction device is communicated with a hypochlorous acid storage device which is arranged separately.

The connection of each pipeline needs to be firm and reliable, and no leakage is ensured. The pipe connection includes:

(1) the pressure water source is respectively connected with a water inlet of the electrolytic device water inlet pretreatment equipment and a main water inlet pipe orifice of the equipment;

(2) connecting a water outlet pipe orifice of the electrolysis device water inlet pretreatment equipment with a water inlet pipe orifice of an electrolysis bath body; or a normal pressure water supply pipe (water pressure is 0.20 MPa-0.45 MPa) is connected with an electrolytic tank water inlet pipe of the device;

(3) connecting a circulating pipe between the salt dissolving tank and the electrolytic bath body and connecting a salt tank water inlet pipe;

(4) the sewage disposal of the water inlet pretreatment equipment of the electrolysis device, the sewage disposal of the salt box and the sewage disposal pipe of the cathode box are respectively connected with a drainage facility;

(5) connecting an upper air suction pipe and a lower air suction pipe of the salt dissolving box with the water ejector respectively;

(6) connecting the dissolved salt box with an electrolytic bath body gas-connecting pipe;

(7) the air inlet pipe of the salt dissolving tank and the air outlet pipe of the cathode tank are respectively connected to the outside by a UPVC (Universal plug and tube) pipe (DN 20);

(8) connecting a medicine feeding pipe (through a water outlet pipe of a water injector) of the device with a hypochlorous acid reaction box;

(9) connecting a sodium hydroxide collecting pipeline of the cathode box with a sodium subhydroxide storage device;

(10) connecting a hypochlorous acid reaction box with the water inlet of a chemical feeding pipe (through the water inlet pipe of a water injector) through a circulating pump; a hypochlorous acid receiving pipe (a valve) is communicated with the hypochlorous acid medicine feeding pipe of the hypochlorous acid medicine storage tank;

(11) connecting a liquid suction port (matched valve) of a DN25 circulating pump at the bottom of the hypochlorous acid storage tank with a liquid suction port of a hypochlorous acid circulating pump at the bottom of a hypochlorous acid reaction tank; connecting DN20 hypochlorous acid medicine storage tank gas-connecting pipe orifice (matched valve) at the upper part of the hypochlorous acid medicine storage tank with an equipment gas inlet pipe; the hypochlorous acid medicine storage tank is connected with the water body to be disinfected through a metering pump;

(12) and connecting the generating system with an electrolytic power supply by using an electrolytic copper bar, and fastening bolts.

Wherein, the installation of electrolysis power is: the electrolytic power supply is placed stably. The installation of the electric appliance is carried out by professional electricians, the good contact of each joint of the circuit is ensured, the phenomena of poor contact of the joints, short circuit of electric wires, electric leakage and the like are avoided, and the electrolytic power supply is grounded. The specific requirements are as follows:

(1) smearing conductive paste on the contact point of the terminal of the copper bar and the electrolytic power supply, and fastening by using a bolt;

(2) grounding an electrolytic power supply ground wire;

(3) connecting a 380V three-phase alternating current power supply with an A, B, C wiring terminal of an air switch in an electrolysis power supply, and connecting a zero line with an N wiring terminal in the electrolysis power supply; the ground wire is connected with a wire connecting terminal in the electrolysis power supply.

The basic conditions for the use of the hypochlorous acid disinfectant generating system comprise:

1. ambient temperature: 0 to 35 ℃; 2. water temperature: 0-20 ℃; 3. water pressure: 0.20MPa to 0.45 MPa; 4. the pressure of a hypochlorous acid liquid outlet is less than: 0.01 MPa; 5. the equipment room is internally provided with a drainage facility and has good ventilation, and any flammable and explosive dangerous goods cannot be placed in the equipment room. Smoking and open fire should not be used in the equipment room. 6. The water quality of the equipment water: meets the GB5749-2006 standard (the hardness is less than 17 mg/L). 7. The quality of the salt used by the generation system meets the refined salt top-grade standard (the content of sodium chloride is not less than 99.1%) in GB/T5461-2016 or GB/T5462-2016 standards.

The initial startup operation of the hypochlorous acid disinfectant generation system comprises the following steps:

1. and (4) checking the state of the valve, wherein the cathode box water supply valve, the cathode box blow-down valve, the salt box water supply valve, the salt box blow-down valve and the hypochlorous acid medicine storage tank water inlet pipe valve are normally closed and opened as required, and the rest are normally opened. 2. The water inlet pipe valve of the hypochlorous acid medicine storage tank is opened, water (tap water or purified water) is added to the hypochlorous acid medicine storage tank as required, and a certain space is required at the upper part of the hypochlorous acid medicine storage tank. 3. The salt adding port on the salt box is unscrewed, 10 kg of salt is added, the salt in the thread of the salt adding port needs to be cleaned up after the salt adding is finished, and then the salt adding port is screwed down. 4. And (3) unscrewing a salt supplementing opening on the electrolytic cell, adding 3-5 kg of salt into the cathode electrolytic cell, cleaning the salt in the thread of the salt adding opening after the salt adding is finished, and screwing the salt adding opening. 5. Opening a valve of the water inlet pipe of the electrolytic cell; opening a water inlet valve of a cathode box and a water inlet valve of a salt box on an operation panel in front of the electrolytic bath, and adding water into the cathode box and the salt box to the upper limit of the liquid level; the water adding is slowly carried out, the water adding of the cathode box and the salt box does not exceed the upper limit of the liquid level, the water does not leave in the water supplementing process, and the water adding valve must be closed in time when the water supplementing is completed. 6. Checking the opening and closing states of various valves of the equipment: the first four valves of the device are in a normally closed state and are opened as required; all other valves are normally open. 7. Power is supplied to the equipment; before power transmission, the switch on the operation panel before the electrolytic power supply is ensured to be in a closed state, and then the air switch on the left side of the equipment is closed; at the moment, the salt tank circulating pump and the hypochlorous acid medicine storage tank circulating pump start to work. 8. And detecting whether each pipeline joint of the equipment has a leakage phenomenon again, and if so, processing in time. 9. The loose joint of the water ejector in the direction vertical to the ground is unscrewed, whether negative pressure exists or not (the existence of the negative pressure indicates that the water ejector works normally) and if no negative pressure exists and the water return phenomenon exists, the reason needs to be found and the water ejector is ensured to work normally. 10. And finally, opening a toggle switch on an operation panel in front of the equipment to a starting gear. 11. The effective chlorine yield setting knob on the front operation panel of the equipment is rotated to set the effective chlorine yield, and specific numerical values are set according to the concentration and quantity requirements of the prepared hypochlorous acid. 12. Checking whether the hypochlorous acid disinfectant liquid enters the storage tank from the hypochlorous acid disinfectant inlet on the hypochlorous acid medicine storage tank. 13. After the operation is finished for 30 minutes, 10 kilograms of salt is added into the salt dissolving box.

In the specific embodiment of the application, the main technical indexes of the hypochlorous acid disinfectant generation system are as follows:

TABLE 1 specific indices of the examples of the present application

The theoretical calculation of the effective chlorine yield of the generating system in the embodiment of the application is as follows:

the plant operating time (hour) is hypochlorous acid concentration (PPM) x hypochlorous acid volume (ton) ÷ effective chlorine production (g/hour).

In one embodiment of the present application, the effective chlorine yield is set to 50 g/h, and the working time of the equipment for preparing the hypochlorous acid solution with various concentrations is as follows, and is adjusted according to the actual inspection result:

table 2 theoretical working time in one embodiment of the present application

In another embodiment of the present application, the effective chlorine yield is set to 100 g/h, and the working time of the equipment for preparing the hypochlorous acid solution with various concentrations is as follows, and is adjusted according to the actual inspection result:

table 3 theoretical working time in another embodiment of the present application

In conclusion, in the hypochlorous acid disinfectant generating system adopting the ion membrane electrolysis method, the salt dissolving device dissolves salt, saturated salt water is supplied to the electrolysis device for electrolysis, and Cl is generated at the anode in the electrolysis process₂Generating NaOH and H at the cathode₂(ii) a An ionic membrane is arranged between the anode and the cathode in the electrolytic cell body, and only Na is allowed⁺And H⁺Smoothly pass through the cathode without passing through chloride ions. Chlorine generated by the anode is dissolved in light salt water and flows back to the salt dissolving device, the chlorine is obtained by absorption and separation of the water ejector, and the chlorine and water are subjected to chemical combination/disproportionation reaction in the reaction device to generate hypochlorous acid, and the hypochlorous acid enters the hypochlorous acid storage device. The hypochlorous acid disinfectant generating system can be widely applied to: sterilizing and disinfecting treatment of circulating water, domestic drinking water, swimming pool water, reclaimed water, oilfield reinjection water, sewage and the like. The system has the characteristics of advanced technical performance, no scaling of the electrode plate, no acid pickling of the electrode plate, safe and reliable operation, no danger of explosion of the electrolytic cell, low power consumption, low salt consumption, high automation degree, no need of preparation of dilute brine, convenient operation and maintenance and the like.

Compared with other devices of the same type, the hypochlorous acid disinfectant generation system adopting the ion membrane electrolysis method is creatively improved in aspects of systems, device structures, process flows, electrode plate structures and the like, and a brand-new device system is formed by adopting a novel process and structure. Through practice, the hypochlorous acid disinfectant generating system is applied, and the generated disinfectant has stable hypochlorous acid content; the hypochlorous acid is simple and quick to prepare, the concentration of the hypochlorous acid is continuously adjustable from 0ppm to 700ppm with the precision of 1 gram per hour. The electrolytic bath body uses low electrolytic voltage which is not more than 12V, so that the energy is saved, the safety is realized, and the power consumption can be greatly reduced. The system electrolyzes saturated salt water, the utilization rate of salt is close to 100%, the salt consumption is greatly reduced, and the salt consumption is only 2 kg when 1 kg of effective chlorine is generated; the power consumption of the salt is greatly reduced, and the disinfection cost is low.

Moreover, the system has high automation degree, the equipment is simple and convenient to operate, dilute saline water is not required to be prepared, and solid salt is directly added into the equipment, so that link failure points in the original preparation process are reduced. The system has long time for operating without fault, does not need acid pickling of polar plates and is simple to maintain. The equipment is modularized, reasonable in layout, convenient to install and maintain and capable of reducing working pressure of operators.

The foregoing is only a preferred embodiment of the present application, and it should be noted that various modifications of the embodiments can be implemented by those skilled in the art without departing from the technical principle of the present application, and these modifications should be considered as the scope of the present application.

Claims

1. A hypochlorous acid disinfectant generating system adopting an ionic membrane electrolysis method is characterized by comprising an electrolysis device, a salt dissolving device, an electric control device, a water injector, a reaction device and a hypochlorous acid storage device; the electric control device mainly provides electric energy for the electrolysis device to electrolyze saturated salt water;

2. The ionic membrane electrolysis hypochlorous acid disinfectant generating system according to claim 1, wherein said hypochlorous acid storage device is connected to the reaction device in a circulation and provided with a circulation pump; the hypochlorous acid storage device is also provided with a vent pipe for pressure balance.

3. The ion membrane electrolysis hypochlorous acid disinfectant generating system according to claim 1, wherein the ion membrane electrolysis hypochlorous acid disinfectant generating system further comprises a water softener, and the electrolytic bath body is provided with a water inlet pipe connected with the water softener.

4. The ion membrane electrolysis hypochlorous acid disinfectant generating system as claimed in claim 1, wherein the electrolytic bath body is provided with an exhaust pipe and an intake pipe for exhausting hydrogen generated by electrolysis and maintaining the air pressure in the bath body balanced.

5. The ion membrane electrolysis hypochlorous acid disinfectant generating system of claim 4, further comprising a sodium hydroxide storage device connected to the electrolysis device for storing the electrolytically generated sodium hydroxide.

6. The ionic membrane electrolysis hypochlorous acid disinfectant generating system according to claim 1, wherein said electrolysis device further comprises a cooler for ensuring the temperature of the electrolyte; the electrolytic tank body is also provided with a sewage discharge pipe connected with a drainage facility.

7. The ion membrane electrolysis hypochlorous acid disinfectant generating system according to claim 1, wherein the electrolytic bath body has a flange-type box structure; the anode has a mesh structure.

8. The ion membrane electrolysis hypochlorous acid disinfectant generating system as claimed in claim 1, wherein said salt dissolving device has a box-type structure for isolated salt feeding and dissolving to form a saturated salt solution.

9. The ionic membrane electrolysis hypochlorous acid disinfectant generating system according to any one of claims 1 to 8, wherein a circulating pump is arranged on a pipeline connecting the salt dissolving device and the drug feeding pipe of the electrolysis device; the water ejector is connected with the reaction device to form circulation and is provided with a circulating pump.