CN205073984U - Make device that mixes diesel oil - Google Patents
Make device that mixes diesel oil Download PDFInfo
- Publication number
- CN205073984U CN205073984U CN201520804231.8U CN201520804231U CN205073984U CN 205073984 U CN205073984 U CN 205073984U CN 201520804231 U CN201520804231 U CN 201520804231U CN 205073984 U CN205073984 U CN 205073984U
- Authority
- CN
- China
- Prior art keywords
- tank
- outlet
- inlet
- water
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 72
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 104
- 239000000126 substance Substances 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims description 39
- 238000013019 agitation Methods 0.000 claims description 31
- 230000006641 stabilisation Effects 0.000 claims description 28
- 238000011105 stabilization Methods 0.000 claims description 28
- 238000007599 discharging Methods 0.000 claims description 27
- 239000008367 deionised water Substances 0.000 claims description 24
- 229910021641 deionized water Inorganic materials 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 238000010992 reflux Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000446 fuel Substances 0.000 abstract description 21
- 238000004945 emulsification Methods 0.000 abstract description 6
- 238000005352 clarification Methods 0.000 abstract description 2
- 230000010354 integration Effects 0.000 abstract description 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 34
- 239000003054 catalyst Substances 0.000 description 23
- 239000011259 mixed solution Substances 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 238000011161 development Methods 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 229910052613 tourmaline Inorganic materials 0.000 description 7
- 229940070527 tourmaline Drugs 0.000 description 7
- 239000011032 tourmaline Substances 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 6
- 239000000295 fuel oil Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000007957 coemulsifier Substances 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000009700 powder processing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The utility model relates to a make device that mixes diesel oil. The utility model discloses a make device that mixes diesel oil can utilize chemical catalytic effect for oil and water surmount the integration that the ion attitude had do not been realized to the molecular level, have obtained a new molecular structure's mixed diesel oil, the complete transparent clarification of outward appearance, and the water oil separating phenomenon of emulsification situation thoroughly disappears, has the same viscosity and proportion with common fuel moreover.
Description
Technical Field
The utility model relates to a device for manufacturing mixed diesel oil.
Background
With the rapid development of the industrial and agricultural industry and the transportation industry in China, the demand for diesel oil is increasing day by day, hundreds of millions of tons of diesel oil and gasoline are consumed in China every year, and imported crude oil and finished oil become heavy burdens on the finance of China. Internationally, natural petroleum reserves are limited and mankind faces an increasingly serious energy crisis. In addition to energy issues, environmental issues are also important issues in the petroleum industry. Floating carbon, hydrocarbons, carbon monoxide, nitrogen oxides, sulfides and solid particles emitted by improper fuel combustion become the main air pollutant sources in large and medium-sized cities, and the ecological environment, the human health and the economic development are seriously influenced. Therefore, due to the energy requirement and the environmental protection requirement, the development of new fuel oil formulas and the development of novel diesel fuel with low pollution are imperative.
Since the 70 s of the 20 th century, the oil crisis has greatly stimulated the development of fuel watering technology. The fuel oil water mixing technology is also set as a national key development research project in each country in succession. In nearly twenty years, the fuel oil technology in China has been greatly developed, and the research on emulsified diesel oil is more. However, common emulsified oil belongs to a thermodynamically unstable system, and unstable phenomena such as oil-water separation, deformation, emulsion breaking and the like can occur along with the change of environmental conditions and the prolonging of the standing time, so that the use effect is influenced; meanwhile, the emulsification needs a high-power emulsification maintaining device, the preparation is complex, and the energy is consumed, so that the technical defects of the common emulsified diesel oil begin to be gradually obvious along with the development of the technology and the improvement of the quality requirement of people on the diesel oil, and the popularization and the use of the common emulsified diesel oil are seriously influenced.
The research of microemulsion fuel oil is started in the 80 th of the 20 th century, so that the field enters a new development period. The microemulsion is a thermodynamic stable system, can be spontaneously formed, has small particle size, has small difference with the viscosity of the fuel oil without water, and can stably exist for a long time. The basic mechanism is that the emulsifier and the co-emulsifier enter an oil-water two-phase to perform a sufficient mixing reaction, and water is suspended in the oil phase in a form of particles under the action of machinery or non-machinery to form a mixed liquid phase with a nano (transparent) particle size.
The current mechanisms for (micro) emulsification are mainly:
single molecule adsorption film theory: namely, the emulsifier is formed by forming a W/O emulsion with two-phase films wrapping water.
Multi-molecule adsorption film theory: in this theory, the encapsulating film is composed of a strongly penetrating complex of an emulsifier and a dispersed phase. The film is thick, the intensity is large, the emulsion breaking is difficult, and the coalescence is prevented.
Theory of diffused electric double layer: suitable for ionic emulsifier, and the outer layer with homogeneous charge can prevent the liquid drop from approaching.
Regardless of the theory, they share a common place, namely the formation and theoretical appearance of an emulsion. The oil and water are two immiscible phases which form fine particles under agitation or other shock, which are unstable due to the surface tension of the two phases. The added emulsifier with the hydrophilic and oleophilic properties is coated on the interface of the two phases, so that the surface tension is reduced, and the stability of the dispersed particles is improved, thereby achieving the emulsification effect.
In the practical use of emulsified diesel oil, the following problems which cannot be overcome in principle occur:
firstly, the existence of the emulsifier and the co-emulsifier can cause the viscosity of the emulsified fuel to rise, and finally cause the rise of the ignition point, so that the continuous operation of the subsequent combustion process can be ensured only by improving or even increasing a preheating system for part of combustion devices using the emulsified fuel; meanwhile, the calorific value of the emulsified fuel is obviously reduced compared with that of the original fuel, and more fuel may be added to achieve the same use effect, so that the fuel cost burden cannot be effectively reduced substantially.
Finally, there is a fundamental problem in that both emulsified and microemulsified fuels have a shelf life beyond which oil-water separation must occur. The current longest emulsified fuel can achieve a stabilization period of about 9 months, and when the stabilization period is exceeded, oil and water begin to separate, so that the quality and the heat value of the added water fuel are reduced. The separated moisture may cause clogging of fuel pipes and the like due to freezing in cold seasons, or may be corroded after interaction with metallic materials of the pipes. Therefore, the previously emulsified fuel must be stored separately and cannot be used with the usual fuel.
Therefore, there is still a need for a new fuel processing technology to overcome the problems of the existing emulsion fuels.
SUMMERY OF THE UTILITY MODEL
To the above problem, the utility model provides a device for making mixed diesel oil.
The utility model discloses the mixed diesel oil of making is different with former emulsified diesel oil. The utility model provides a mixed diesel oil utilizes chemical catalysis's effect for oil and water surpass the molecular level and have realized the integration of ionic state, have obtained the fuel of a new molecular structure, and the outward appearance is transparent clarification completely, and the water oil separating phenomenon of emulsification situation thoroughly disappears, has the same proportion with general fuel moreover.
According to an embodiment of the present application, there is provided an apparatus for manufacturing a hybrid diesel, the apparatus including:
an oil agitation tank 1 provided with a first oil inlet 11, an oil outlet 12, a first agitator 13 and a first heater 14, wherein the first oil inlet 11 is used for receiving raw national standard diesel oil, the oil outlet 12 is used for discharging processed raw national standard diesel oil, the first agitator 13 is used for agitating the raw national standard diesel oil in the oil agitation tank, and the first heater 14 is used for keeping the raw national standard diesel oil in the oil agitation tank 1 at a constant temperature;
a water agitation tank 2 provided with a first water inlet 21, a first water outlet 22, a second agitator 23 and a second heater 24, wherein the first water inlet 21 is used for receiving deionized water, the first water outlet 22 is used for discharging treated deionized water, the second agitator 23 is used for agitating deionized water in the water agitation tank, and the second heater 24 is used for keeping the deionized water in the water agitation tank 2 at a constant temperature;
a venturi 3 provided with a second oil inlet 31 for receiving treated diesel oil from the oil agitation tank 1, a second water inlet 32 for receiving treated deionized water from the water agitation tank 2, and a venturi outlet 33 for discharging a mixture a mixed by the venturi 3;
a reaction tank 4 provided with a reaction tank inlet 41 and a reaction tank outlet 42, wherein the reaction tank inlet 41 is used for receiving the mixture a from the venturi 3, and the reaction tank outlet 42 is used for discharging the mixed liquid b reacted by the reaction tank 4;
a rectifying tank 5 provided with a rectifying tank inlet 51, a return inlet 52, a rectifying tank outlet 53, a return outlet 54, and a return pump 55, wherein the rectifying tank inlet 51 is used for receiving the mixed liquid b from the reaction tank 4, and the return inlet 52, the return outlet 54, and the return pump 55 return part of the mixed liquid in the rectifying tank 5; the rectifying tank outlet 53 is used for discharging rectified mixed liquid c;
a pressure tank 6 provided with a pressure tank inlet 61 for receiving the mixed liquid c from the rectifying tank 5, a pressure tank outlet 62 for discharging the pressurized mixed liquid d, and a pressurizing pump 63 for maintaining the pressure of the pressure tank 6;
a stabilization tank 7 provided with a stabilization tank inlet 71, a mixed diesel outlet 72 and a second water outlet 73, wherein the stabilization tank inlet 71 is used for receiving the substance from the pressure tank 6, the mixed diesel outlet 72 is used for discharging the mixed diesel, and the second water outlet 73 is used for discharging the separated 2-time water;
wherein the second oil inlet 31 of the venturi 3 is connected to the oil outlet 12 of the oil agitation tank 1, and the second water inlet 32 of the venturi 3 is connected to the first water outlet 22 of the water agitation tank 2;
said reaction chamber inlet 41 of said reaction chamber 4 is connected to the venturi outlet 33 of said venturi 3;
the rectifying tank inlet 51 of the rectifying tank 5 is connected to the reaction tank outlet 42 of the reaction tank 4; the return inlet 52 of the rectifying tank 5 and the return outlet 54 of the rectifying tank 5 are connected;
the pressure tank inlet 61 of the pressure tank 6 is connected to the surge tank outlet 52 of the surge tank 5;
the stabilization tank inlet 71 of the stabilization tank 7 is connected to the pressure tank outlet 62 of the pressure tank 6,
preferably, the second water outlet 73 of the stabilization tank 7 is connected to the first water inlet 21 of the water agitation tank 2.
Preferably, the device further comprises a filter 8 provided with a filter inlet 81, a filter outlet 82, wherein the filter inlet 81 is used for receiving the mixed diesel from the stabilization tank 7, and the filter outlet 82 is used for discharging the filtered mixed diesel;
wherein the filter inlet 81 of the filter 8 is connected with the mixed diesel outlet 72 of the stabilization tank 7.
Preferably, the rectifying tank, the pressure tank and the stabilizing tank may have reflux devices known in the art, and each reaction tank (tank), the stirring tank, the pipeline and the like may further include conventional material inlets and outlets, pressure gauges, flow meters, throttle valves and other common devices known in the art, and thus, the details are not repeated herein.
The method for producing the mixed diesel by using the device of the utility model comprises the following steps:
1) treating the national standard diesel oil with the catalyst A at the temperature of 0-50 ℃ and under normal pressure for 0.5-3 hours, wherein the mass space velocity of the national standard diesel oil is 2.5-4h-1；
2) Treating raw material deionized water with a catalyst A at the temperature of 0-50 ℃ and normal pressure for 0.5-3 hours, wherein the mass space velocity of the deionized water is 2.5-4h-1；
3) According to national standard diesel oil: introducing the national standard diesel oil and deionized water treated in the steps 1) and 2) into a venturi together according to the proportion of the deionized water being 1: 0.5-1: 2 to obtain a mixture a;
4) passing the mixture a in the step 3) through a reaction box at the temperature of 0-50 ℃ and the atmospheric pressure of 2-7 in the presence of a catalyst A to obtain a mixed solution b, wherein the mass space velocity of the mixture a is 2.5-4h-1；
5) Making the mixed liquid b obtained in the step 4) pass through a rectifying tank which refluxes at normal temperature and normal pressure to obtain mixed liquid c, wherein the treatment time in the rectifying tank is 0.5-3 hours;
6) pressurizing the mixed solution c obtained in the step 5) in a pressure tank at normal temperature and 10-50 atmospheric pressures for 15-40 minutes in the presence of a catalyst B to obtain a mixed solution d, wherein the mass space velocity of the mixed solution c is 2.5-4h-1；
7) Standing and layering the mixed solution d obtained in the step 6) in a stabilization tank to obtain a water layer and a mixed diesel oil layer, and separating to obtain 2 times of water and mixed diesel oil.
Wherein,
the catalyst A in the steps 1), 2) and 4) is tourmaline, such as tourmaline/tourmaline powder obtained from Brazil or from Guanyu mineral processing factories of Shijiazhuang,
the catalyst B in the step 6) comprises a main catalyst and an auxiliary catalyst, wherein the main catalyst is tourmaline, the auxiliary catalyst comprises a palladium simple substance and an oxide of copper/titanium/iron, the mass ratio of the main catalyst to the auxiliary catalyst is 5:1 to 15:1, preferably 8:1 to 12:1, more preferably 10:1, and in the auxiliary catalyst, the mass ratio of titanium oxide: copper oxide: iron oxide: palladium simple substance ═ (5 ± 1): (5. + -. 1): (1 ± 0.2): (1 + -0.2), wherein the valence of titanium, copper and iron in each oxide may be the conventional valence state they can take, for example, titanium may be +2, +3, +4, copper may be +1, +2, iron may be +2, +3, and may be in the form of a mixture of different valencies, e.g., iron may be in the form of ferroferric oxide. Preferably, the oxides of titanium, copper and iron are in the form of the highest valence, i.e. titanium dioxide, copper monoxide and ferric oxide, and the catalyst B is, for example, a tourmaline catalyst produced by a mineral powder processing plant in Ling county, North Hebei province.
Preferably, the mixing temperature in the step 1) is 10-40 ℃, and the mixing time is 1-2 hours; more preferably, the mixing temperature is 20-30 ℃; most preferably 25 ℃;
preferably, the mixing temperature in the step 2) is 10-40 ℃, and the mixing time is 1-2 hours; more preferably, the mixing temperature is 20-30 ℃; most preferably 25 ℃;
preferably, the mixing ratio of the national standard diesel oil and the deionized water in the step 3) is 1:0.8 to 1: 1.2; more preferably 1:0.9 to 1: 1.1; most preferably 1: 1;
preferably, the reaction temperature in step 4) is 10-40 ℃; more preferably, the reaction temperature is 20-30 ℃; most preferably 25 ℃;
preferably, the treatment time in the rectifying tank in the step 5) is 0.5 to 2 hours;
preferably, the pressure of the pressure tank in step 6) is 20 to 40 atmospheres;
preferably, the 2 times water separated in the step 7) can be returned to the step 2) to be used as raw material water,
preferably, the method further comprises step 8): filtering the mixed diesel oil obtained in the step 7) to obtain filtered mixed diesel oil.
Adopt the utility model discloses a mixed diesel oil of device production possesses following characteristics:
1. the use is easy: the product oil has simple manufacturing process and high equipment reliability, is suitable for large-scale automatic production, and the prepared mixed diesel oil can be randomly mixed with conventional diesel oil for use.
2. Energy conservation: the fuel consumption can be effectively saved;
3. and (3) environmental protection: due to the change of the molecular structure of the crude oil, the novel diesel oil can effectively improve the emission of related equipment, particularly the sulfur content.
4. And (3) stabilizing: the product has stable characteristics, excellent indexes such as cetane number, flash point, freezing point, viscosity, distillation range, ash content and the like, and lower acidity and corrosivity.
The application range is wide: the diesel oil engine is suitable for agricultural machinery, generators and other mechanical equipment such as various engineering vehicles, heavy trucks, ships, tractors and the like taking diesel oil as fuel, and does not need any special modification.
Drawings
Fig. 1 is a schematic view of an apparatus for manufacturing hybrid diesel according to a preferred embodiment of the present invention.
Detailed Description
EXAMPLE 1 apparatus for producing Mixed Diesel
As shown in fig. 1, the apparatus for producing a hybrid diesel according to the present invention includes:
an oil agitation tank 1 provided with a first oil inlet 11, an oil outlet 12, a first agitator 13 and a first heater 14, wherein the first oil inlet 11 is used for receiving raw national standard diesel oil, the oil outlet 12 is used for discharging processed raw national standard diesel oil, the first agitator 13 is used for agitating the raw national standard diesel oil in the oil agitation tank 1, and the first heater 14 is used for keeping the raw national standard diesel oil in the oil agitation tank 1 at a constant temperature;
a water agitation tank 2 provided with a first water inlet 21, a first water outlet 22, a second agitator 23 and a second heater 24, wherein the first water inlet 21 is used for receiving deionized water, the first water outlet 22 is used for discharging treated deionized water, the second agitator 23 is used for agitating deionized water in the water agitation tank 2, and the second heater 24 is used for keeping the deionized water in the water agitation tank 2 at a constant temperature;
a venturi 3 provided with a second oil inlet 31 for receiving treated diesel oil from the oil agitation tank 1, a second water inlet 32 for receiving treated deionized water from the water agitation tank 2, and a venturi outlet 33 for discharging a mixture a mixed by the venturi 3;
a reaction tank 4 provided with a reaction tank inlet 41 and a reaction tank outlet 42, wherein the reaction tank inlet 41 is used for receiving the mixture a from the venturi 3, and the reaction tank outlet 42 is used for discharging the mixed liquid b reacted by the reaction tank 4;
a rectifying tank 5 provided with a rectifying tank inlet 51, a return inlet 52, a rectifying tank outlet 53, a return outlet 54, and a return pump 55, wherein the rectifying tank inlet 51 is used for receiving the mixed liquid b from the reaction tank 4, and the return inlet 52, the return outlet 54, and the return pump 55 return part of the mixed liquid in the rectifying tank 5; the rectifying tank outlet 53 is used for discharging rectified mixed liquid c;
a pressure tank 6 provided with a pressure tank inlet 61 for receiving the mixed liquid c from the rectifying tank 5, a pressure tank outlet 62 for discharging the pressurized mixed liquid d, and a pressurizing pump 63 for maintaining the pressure of the pressure tank 6;
a stabilization tank 7 provided with a stabilization tank inlet 71, a mixed diesel outlet 72 and a second water outlet 73, wherein the stabilization tank inlet 71 is used for receiving the substance from the pressure tank 6, the mixed diesel outlet 72 is used for discharging the mixed diesel, and the second water outlet 73 is used for discharging the separated 2-time water;
a filter 8 provided with a filter inlet 81 and a filter outlet 82, wherein the filter inlet 81 is used for receiving the mixed diesel from the stabilization tank 7, and the filter outlet 82 is used for discharging the filtered mixed diesel;
wherein the second oil inlet 31 of the venturi 3 is connected to the oil outlet 12 of the oil agitation tank 1, and the second water inlet 32 of the venturi 3 is connected to the first water outlet 22 of the water agitation tank 2;
said reaction chamber inlet 41 of said reaction chamber 4 is connected to the venturi outlet 33 of said venturi 3;
the rectifying tank inlet 51 of the rectifying tank 5 is connected to the reaction tank outlet 42 of the reaction tank 4; the return inlet 52 of the rectifying tank 5 and the return outlet 54 of the rectifying tank 5 are connected;
the pressure tank inlet 61 of the pressure tank 6 is connected to the surge tank outlet 52 of the surge tank 5;
the stabilization tank inlet 71 of the stabilization tank 7 is connected to the pressure tank outlet 62 of the pressure tank 6,
the second water outlet 73 of the stabilization tank 7 is connected to the first water inlet 21 of the water agitation tank 2,
the filter inlet 81 of the filter 8 is connected to the mixed diesel outlet 72 of the stabilization tank 7.
The device comprises the following operation steps:
1) treating 500L (418KG) of national standard diesel oil as a raw material with a catalyst A for 2 hours at normal temperature and normal pressure, wherein the mass space velocity of the national standard diesel oil is 3 hours-1；
2) Treating 500L (500KG) of raw deionized water with a catalyst A for 2 hours at normal temperature and normal pressure, wherein the mass space velocity of the deionized water is 3 hours-1；
3) According to national standard diesel oil: introducing the treated national standard diesel oil obtained in the steps 1) and 2) and deionized water into a venturi together according to the proportion of 1:1 to obtain a mixture a;
4) passing the mixture a in the step 3) through a reaction box at room temperature and 5 atmospheric pressures in the presence of a catalyst A to obtain a mixed solution b, wherein the mass space velocity of the mixture a is 3h-1；
5) Passing the mixed solution b obtained in the step 4) through a rectifying tank which refluxes at normal temperature and normal pressure to obtain a mixed solution c, wherein the treatment time in the rectifying tank is 1 hour;
6) pressurizing the mixed solution c obtained in the step 5) in a pressure tank at normal temperature and 20 atmospheric pressures for 25 minutes in the presence of the catalyst B to obtain a mixed solution d, wherein the mass space velocity of the mixed solution c is 3.5h-1；
Wherein,
the catalyst A in the steps 1), 2) and 4) is tourmaline powder purchased from Guanyu mineral processing factories of Shijiazhu,
the catalyst B in the step 6) is a tourmaline catalyst purchased from a vibroflotation mineral powder processing plant in Lingshou county of Hebei province;
7) standing and layering the mixed solution d obtained in the step 6) in a stabilization tank to obtain a water layer and a mixed diesel oil layer, and separating to obtain 2 times of water and mixed diesel oil;
in addition, the 2 times of water separated in the step 7) is connected to a water stirring tank and returned to the step 2) to be used as raw material water;
8) filtering the mixed diesel oil obtained in the step 7) to obtain filtered mixed diesel oil.
Adopt according to the utility model discloses a device makes mixed diesel's result:
adopt the device of this application to make with 500L (418KG) raw materials national standard diesel oil and 500L (500KG) raw materials deionized water and obtain finished product hybrid diesel oil 518 KG.
That is, the gain amount (water-blended oil) of the obtained hybrid diesel oil after the special manufacturing process was: about 100 KG.
Example 2 testing of properties of hybrid diesel
Stability detection
The mixed diesel oil prepared in example 1 was left standing at normal temperature for 180 days, and as a result, no delamination or the like occurred, indicating that the mixed diesel oil was not emulsified diesel oil.
Hybrid usage performance detection
The mixed diesel oil prepared in the example 1 and the common country No. 4 diesel oil are mixed and used in the engine of the great wall HarvarSUV, after 180 days of normal driving, the output power of the engine is not obviously abnormal, and the emission is better than that of the common country No. 4 diesel oil, which shows that the mixed diesel oil can be completely and randomly mixed with the common diesel oil for use.
Other Performance detection
The mixed diesel oil prepared in example 1 was sent for testing and tested according to the regulations of GB 19147-2013. The results are as follows:
inspection report
It can be seen from the above examination reports that the synthesis technology of the environment-friendly mixed diesel oil of the invention is to recombine fuel oil molecules and water molecules by physical methods such as high-speed shearing, pressurizing and the like under the action of a catalyst with specific natural ore as a main component to prepare the environment-friendly mixed diesel oil, the environment-friendly mixed diesel oil does not contain any chemical additive, the product characteristics are stable, the water fusion rate of the technical index can be stabilized at 15-20%, the national test indexes of the diesel oil all reach the standard, wherein the application indexes such as cetane number, flash point, freezing point and the like are all superior to the standard of the used raw diesel oil, and the harmful substances such as sulfur content and the like and various emission indexes are lower than the standard of the raw. Under the condition of not needing to carry out any transformation to the service equipment, not only does not influence the result of use, but also greatly reduced discharges, is a subversive new energy technology.
Claims (3)
1. An apparatus for manufacturing a hybrid diesel, the apparatus comprising:
an oil agitation tank (1) provided with a first oil inlet (11), an oil outlet (12), a first agitator (13) and a first heater (14), wherein the first oil inlet (11) is used for receiving raw national standard diesel oil, the oil outlet (12) is used for discharging the processed raw national standard diesel oil, the first agitator (13) is used for agitating the raw national standard diesel oil in the oil agitation tank (1), and the first heater (14) is used for keeping the raw national standard diesel oil in the oil agitation tank (1) at a constant temperature;
a water stirring tank (2) provided with a first water inlet (21), a first water outlet (22), a second stirrer (23) and a second heater (24), wherein the first water inlet (21) is used for receiving deionized water, the first water outlet (22) is used for discharging the treated deionized water, the second stirrer (23) is used for stirring the deionized water in the water stirring tank (2), and the second heater (24) is used for keeping the deionized water in the water stirring tank (2) at a constant temperature;
a venturi (3) provided with a second oil inlet (31), a second water inlet (32) and a venturi outlet (33), wherein the second oil inlet (31) is for receiving treated diesel from the oil agitation tank (1), the second water inlet (32) is for receiving treated deionized water from the water agitation tank (2), the venturi outlet (33) is for discharging a mixture a mixed by the venturi (3);
a reaction box (4) which is provided with a reaction box inlet (41) and a reaction box outlet (42), wherein the reaction box inlet (41) is used for receiving the mixture a from the venturi (3), and the reaction box outlet (42) is used for discharging the mixed liquid b reacted by the reaction box (4);
a rectifying tank (5) provided with a rectifying tank inlet (51), a reflux inlet (52), a rectifying tank outlet (53), a reflux outlet (54), and a reflux pump (55), wherein the rectifying tank inlet (51) is used for receiving the mixed liquid b from the reaction box (4), and the reflux inlet (52), the reflux outlet (54), and the reflux pump (55) make part of the mixed liquid in the rectifying tank (5) reflux; the outlet (53) of the rectifying tank is used for discharging rectified mixed liquid c;
a pressure tank (6) provided with a pressure tank inlet (61) for receiving the mixed liquid c from the rectifying tank (5), a pressure tank outlet (62) for discharging the pressurized mixed liquid d, and a pressurizing pump (63) for maintaining the pressure of the pressure tank (6);
a stabilization tank (7) provided with a stabilization tank inlet (71), a mixed diesel outlet (72), a second water outlet (73), wherein the stabilization tank inlet (71) is used for receiving the substance from the pressure tank (6), the mixed diesel outlet (72) is used for discharging the mixed diesel, and the second water outlet (73) is used for discharging the separated 2-time water;
wherein the second oil inlet (31) of the venturi (3) is connected with the oil outlet (12) of the oil agitation tank (1), and the second water inlet (32) of the venturi (3) is connected with the first water outlet (22) of the water agitation tank (2);
the reaction tank inlet (41) of the reaction tank (4) is connected with the venturi outlet (33) of the venturi (3);
the rectifying tank inlet (51) of the rectifying tank (5) is connected with the reaction tank outlet (42) of the reaction tank (4); the return inlet (52) of the rectifying tank (5) and the return outlet (54) of the rectifying tank (5) are connected;
the pressure tank inlet (61) of the pressure tank (6) is connected to the rectifying tank outlet (53) of the rectifying tank (5),
the stabilization tank inlet (71) of the stabilization tank (7) is connected to the pressure tank outlet (62) of the pressure tank (6).
2. The apparatus for manufacturing hybrid diesel according to claim 1,
the second water outlet (73) of the stabilization tank (7) is connected to the first water inlet (21) of the water agitation tank (2).
3. The apparatus for manufacturing a hybrid diesel according to claim 1, wherein said apparatus further comprises:
a filter (8) provided with a filter inlet (81), a filter outlet (82), wherein the filter inlet (81) is used for receiving the mixed diesel from the stabilization tank (7), and the filter outlet (82) is used for discharging the filtered mixed diesel;
the filter inlet (81) of the filter (8) is connected with the mixed diesel outlet (72) of the stabilization tank (7).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520804231.8U CN205073984U (en) | 2015-10-16 | 2015-10-16 | Make device that mixes diesel oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520804231.8U CN205073984U (en) | 2015-10-16 | 2015-10-16 | Make device that mixes diesel oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN205073984U true CN205073984U (en) | 2016-03-09 |
Family
ID=55426424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201520804231.8U Expired - Fee Related CN205073984U (en) | 2015-10-16 | 2015-10-16 | Make device that mixes diesel oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN205073984U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106582458A (en) * | 2015-10-16 | 2017-04-26 | 世能华奇（北京）科技发展有限公司 | Manufacturing method of mixed diesel, mixed diesel manufactured through method and manufacturing device |
-
2015
- 2015-10-16 CN CN201520804231.8U patent/CN205073984U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106582458A (en) * | 2015-10-16 | 2017-04-26 | 世能华奇（北京）科技发展有限公司 | Manufacturing method of mixed diesel, mixed diesel manufactured through method and manufacturing device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20120174472A1 (en) | Fuel Additive and Method for Use for Combustion Enhancement and Emission Reduction | |
| JPWO2009075317A1 (en) | Method for producing emulsified fuel using oil-containing water | |
| CN205073984U (en) | Make device that mixes diesel oil | |
| CN101423777A (en) | Alcohol fuel methanol and ethanol gasoline | |
| CN103254952A (en) | Preparation method of water-based micro-emulsion diesel oil | |
| CN100577778C (en) | Synergist for improving natural gas burning temperature and its apparatus | |
| WO2015037678A1 (en) | Production method for compatible transparent water-containing oil and production device for compatible transparent water-containing oil | |
| CN106582458A (en) | Manufacturing method of mixed diesel, mixed diesel manufactured through method and manufacturing device | |
| CN102127477B (en) | Petrochemical additive and preparation method thereof | |
| CN107629824A (en) | A kind of vehicle lead-free synthetic fuel | |
| CN100357406C (en) | Synthetic vehicular fuel and its preparation method | |
| CA3125557C (en) | Process for the production of an improved diesel fuel | |
| BG112857A (en) | Installation for permanent mixing of oil, petroleum products, petroleum sludge and petroleum waste with ionized aqueous solutions | |
| CN102061202A (en) | High-energy hydrolysis hydrogen series environmentally-friendly liquid fuel | |
| CN104946318A (en) | Alcohol hydrocarbon vehicle fuel and preparation method thereof | |
| RU2691200C1 (en) | Device for preparation and supply of oil-water emulsion into internal combustion engine | |
| CN202625066U (en) | Ventilation cap with fire-resistant function | |
| CN1089363C (en) | Energy-saving fuel oil and its preparation | |
| RU2458971C1 (en) | Method of producing fuel | |
| Vorobiev et al. | The Unique Composition and Stability of Water-Fuel Emulsion | |
| WO2018011819A1 (en) | Fuel supplement to reduce harmful emissions | |
| CN104845686B (en) | Formula of diesel oil micro-emulsified complexing agent and preparation method of emulsified diesel oil | |
| CN203033953U (en) | Catalytic cracking system capable of improving utilization rate of petroleum | |
| BG3168U1 (en) | Installation for permanent mixing of oil, petroleum products, petroleum sludge and petroleum waste with ionized aqueous solutions | |
| Dani | Reduction of NOx in diesel engine using diesel water emulsion |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210107 Address after: 100026 906-c, 8th floor, building 1, C 12, Guanghua Road, Chaoyang District, Beijing Patentee after: Jiyi Huagui (Beijing) Technology Development Co.,Ltd. Address before: 100078 room 2305, No.3, No.5, Liujiayao Nanli, Fengtai District, Beijing Patentee before: SHINENG HUAQI (BEIJING) TECHNOLOGY DEVELOPMENT Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160309 |