BG3168U1 - Installation for permanent mixing of oil, petroleum products, petroleum sludge and petroleum waste with ionized aqueous solutions - Google Patents

Abstract

The utility model relates to an installation for the permanent mixing of oil, petroleum products, petroleum sludge and petroleum waste with ionized aqueous solutions and the production of environmentally friendly fuel thereof. The obtained ecological fuels are homogeneous and can be used as fuel in various combustion plants and engines. According to the utility model, the installation for permanent mixing of petroleum sludge and waste from refineries with ionized aqueous solutions and obtaining fuel from them, consists of several technological units. The first technological unit includes tanks for primary preparation of hydrocarbon with heaters, for tempering (1 and 3) and electric paddle stirrers (4 and 5); high pressure gear pump (2), catalytic converter (13) and taps (12). The second technological unit consists of a mixer (10), along with taps (7, 9, 11) and a pump (8). The third technological unit consists of a water ionizer (14), a filter (24), a tap (17 and 21); pH sensors (15 and 16), dispenser (18) and pumps (19 and 20). The fourth technological unit consists of a vessel for the finished product (23), taps (22 and 25). The installation uses a highly ionized aqueous solution with a specific chemical polarity, which is mixed with petroleum waste, sludge and products.

Description

The utility model refers to an installation for permanent mixing of oil, oil products, oil sludge and oil waste with ionized aqueous solutions and production of ecological fuel from them. The obtained ecological fuels are homogeneous and can be used as fuel in various combustion plants and engines.

BACKGROUND OF THE INVENTION

A similar installation is known which can mix fuel oil with water. It consists of pumps, pipelines, fuel and water heaters, a mixer, water and fuel oil tanks, and other units and assemblies [1]. The disadvantages of this installation are that it has a complex structure and high production costs. The resulting water-oil emulsion is volatile and disintegrates within a few hours. The resulting fuel must be burned immediately, otherwise the water separates from the fuel and it becomes unusable.

Technical essence of the utility model

The task of this utility model is to create an installation for the production of a new type of sustainable environmentally friendly fuel, which is produced from petroleum waste, petroleum sludge, petroleum products mixed with ionized water-based technical salts. The new installation features a simplified construction and low production costs.

The problem is solved by creating the following installation, consisting of several blocks connected to each other in a technological scheme.

The first technological unit includes tanks for primary preparation of hydrocarbons with heaters, for tempering and vane electric stirrers, as well as a high-pressure gear pump for supplying hydrocarbons to a catalyst vessel, as well as a system of pipelines. The second technological unit consists of a mixer, together with taps, pumps and pipelines. The third technological unit consists of a water ionizer, a filter, taps and pH sensors. The fourth technological unit consists of a tank for finished products with taps and pipelines to it.

The installation uses a highly ionized aqueous solution with a specific polarity, which is mixed with petroleum waste, sludge and products.

Explanation of the attached figures

The exemplary implementation of an installation for permanent mixing of oil sludge and oil waste with ionized aqueous solutions, object of the present utility model is shown in the attached figures, where:

Figure 1 shows the general view of the installation for permanent mixing of oil sludge and oil waste with ionized aqueous solutions;

Figure 2 - spectrum M100, starting material;

Figure 3 is a photomicrograph of the raster of the source fuel oil;

Figure 4 is a spectrum of the converted fuel oil containing 25% ionized water-based technical salts;

Figure 5 is a micrograph of the raster of the converted fuel oil.

Exemplary implementation of the utility model

The installation for permanent mixing of oil, oil products, oil sludge and oil waste with ionized aqueous solutions includes a first technological unit, which consists of a first tank with a heater, the outlet of which is connected by a pipeline and a high pressure gear pump to the inlet of a second tank. with a heater, the first tank with heater 1 has a first paddle electric stirrer 4 and the second tank with heater See a second paddle electric stirrer 5. A catalytic vessel 13 is connected to the inlet of the second tank with heater 3 by a first tap 12 and a second tap 12.1. Catalytic vessel 13 through the first valve 12 is also connected to the mixer 10, which is part of the second technology

4037 Descriptions to certificates for registration of utility models № 06.2 / 28.06.2019. The mixer 10 through a third tap 9, a first pump 8 and a fourth tap 7 is connected to the outlet of a second tank with heater 3. The third process unit consists of a first pH sensor 15, a second pH sensor 16 and a filter 24 and are connected to an ionizer of water 14, the second pH sensor 16 through the fifth tap 17 is connected to the dispenser 18, and the first pH sensor 15 through the second pump 20 and the sixth tap 21 is connected to the mixer 10, the dispenser 18 through the third pump 19 is also connected with the mixer 10, to the first pump 8 through the fifth tap 22 is connected the inlet of a container for storage of finished products 23 with a sixth tap 25, which are part of the fourth technological unit.

Working principle

The hydrocarbon liquid with a certain viscosity is fed under a pressure of 5-50 bar to the inlet cone of the mixer, the temperature of the liquid is 50-65 ° C, and the flow rate of the mixture is from 0.1 to 2 m ³ / h. The conical shape with variable cross-section of the inlet pipe and the divider creates a stable fertilizer in the mixture and leads to the appearance of strong axial flows in the fertilizer itself and counterflows on the surface of the disk. The mixture is formed under the influence of axial supersonic velocities and vortex formation with the mono-liquid. As a result of the interaction of the fuel flow with the ionized clusters of water-based technical salts, micro and nano regions are created in the form of implosive receipts, in which the pressure and temperature exceed the pressure and temperature of the water-fuel mixture at the mixer inlet. The high pressure and temperature under the accelerating action of a special catalyst for hydrogen attachment applied to the working surfaces of the disk leads to rupture of the hydrocarbon chains of the source fuel, and the ions H3O ⁺ and OH of the aqueous solution, interacting with the conglomerate (H2O) ₅ form new hydrocarbon clusters with H ₃ O ⁺ and OH ^- ions attached to them.

The hydrocarbon mixture is fed by a gear pump to the first channel of the mixer 10, to the second channel of the mixer is fed pre-prepared ionized aqueous solution 14. In the working chamber of the mixer 10 is supercritical connection of ionized technical salts based on water and the hydrocarbon mixture.

This effect is evidenced by the analysis of the obtained spectral images before and after hydrocarbon treatment. After processing in the mixer, which is a closed circuit with a cooling chamber, in the lower part of which is the outlet for the finished mixture. The combined (converted) molecular conglomerates enter the damping vessel with a stirrer. From there they fall into a tank for the finished product.

Numerous experiments have confirmed the possibility of stable mixing and hydration of hydrocarbons with ionized water-based technical salts. Ml00 fuel oil was selected for the tests as the most difficult to achieve result and at the same time the most economically suitable hydrocarbon.

The chromatogram shown in FIG. 2 corresponds to the analysis of a sample of fuel oil Μ-100 with a volume of 0.2 μΐ at the inlet of the device with a flow division of 1:50. The injector temperature is 250 ° C. The column has a 5% -phenyl-95% dimethylpolysiloxane phase. Column thermostat heating program: 35 ° C (1 min), 3 ° C / min to 80 ° C, then 5 ° C / min to 250 ° C, 250 ° C (10 min).

The chromatogram shown in FIG. 4 corresponds to the analysis of a sample of fuel oil Μ100 with ionized technical salts based on water in the ratio 1/4, obtained in the liquid mixer. The sample volume is 0.2 μΐ at the inlet of the device with a flow rate of 1:50. The injector temperature is 250 ° C. The column has a 5% -phenyl-95% dimethylpolysiloxane phase. Column thermostat heating program: 35 ° C (1 min), 3 ° C / min to 80 ° C, then 5 ° C / min to 250 ° C, 250 ° C (10 min).

The test was performed under the following conditions: ionization source temperature 230 ° C. Scanning range: 29-450 a.e.m.

Most of the chromatographic maxima with a retention time after 30 min probably correspond mainly to different fatty esters, bicarboxylic acids, but the convergence of the mass spectra with the database is low. For this reason, I do not present them in a table. These molecules are obtained in the composition of the converted fuel. The difference between the spectra of crude fuel oil and composite fuel treated with the installation is visible.

As a result of the conducted researches it can be claimed that the installation mixes permanently oil

4038 Descriptions to certificates for registration of utility models № 06.2 / 28.06.2019 products, oil sludges and wastes, as well as other various hydrocarbons with ionized technical salts on water basis. The process is characterized by low energy costs. The characteristics of the obtained emulsion cover the quality standards of hydrocarbon fuels for use in engines of river and sea vessels, heating boilers and equipment. The plant can be used to obtain mixed fuels based on vegetable oils and mixed fuels based on petroleum products (fuel oil, diesel, crude oil, oil sludge, etc.).

Claims (1)

Claims Installation for the permanent mixing of petroleum, petroleum products, petroleum sludge and petroleum waste with ionized aqueous solutions, comprising a first tank with a heater, the outlet of which is connected by a pipeline and a high-pressure gear pump to the inlet of a second tank with a heater in that the first tank with heater (1) has a first blade electric stirrer (4), and the second tank with heater (3) has a second blade electric stirrer (5), as to the inlet of the second tank with heater (3) by means of a first tap (12) and a second tap (12.1) a catalytic vessel (13) is connected, which through the first tap (12) is also connected to a mixer (10) and the mixer (10) through a third tap (9) (8) and a fourth tap (7) is connected to the outlet of a second heater tank (3), and a first pH sensor (15), a second pH sensor (16) and a filter (24) are connected to a water ionizer ( 14), the second pH sensor (16) being connected to a dispenser (18) via a fifth tap (17) and the first pH sensor (15) through a second pump (20) and a sixth tap (21) is connected to a mixer (10), the dispenser (18) through a third pump (19) is also connected to the mixer (10) to the first pump (8) through a fifth tap 22) is connected the inlet of a container for storage of finished products (23) with a sixth tap (25) at the outlet.