CN204966601U - Realize black device that starts of zinc bromine liquid stream system battery - Google Patents
Realize black device that starts of zinc bromine liquid stream system battery Download PDFInfo
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- CN204966601U CN204966601U CN201520747718.7U CN201520747718U CN204966601U CN 204966601 U CN204966601 U CN 204966601U CN 201520747718 U CN201520747718 U CN 201520747718U CN 204966601 U CN204966601 U CN 204966601U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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- Y02E60/30—Hydrogen technology
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Abstract
The utility model belongs to the technical field of zinc bromine redox flow battery, specifically speaking is a realize black device that starts of zinc bromine liquid stream system battery. Start jar and the negative pole starts jar including zinc bromine battery pile, positive pole, and wherein the positive pole starts jar to start with the negative pole and jar sets up in the top of zinc bromine battery pile, and the S4 interface that solenoid valve an and zinc bromine battery pile are passed through to bottom that the positive pole starts jar communicates, bottom that the negative pole starts jar loop through mixing valve and solenoid valve b and the S1 interface intercommunication of zinc bromine battery pile, negative pole start -up jar interior active complex compound discharges inside reaction of zinc bromine battery pile with the electrolyte that comes from positive pole start -up jar by in the bottom outflow and getting into zinc bromine battery pile under the action of gravity to realize the black start -up of zinc bromine liquid stream system battery. The utility model discloses under the condition with the help of the external power not, realize that the oneself of zinc bromine redox flow battery system starts.
Description
Technical field
The utility model belongs to zinc-bromine flow battery technical field, specifically a kind of device realizing zinc bromine liquid fluid system battery black starting-up.
Background technology
In the prior art, because zinc-bromine flow battery can overcome the impact of lead-acid battery on environment, being separated simultaneously due to active material reacting environment and reacting environment, has stopped the possibility of battery body blast at all, has possessed and have extended cycle life, electric energy density is high, volume is little, and cost is low, advantages of environment protection, be subject to again the promotion of energy storage demand in recent years, zinc-bromine bettery more and more comes into one's own.But zinc-bromine flow battery technology is ripe not enough at present, there is many problems.
Zinc-bromine flow battery system and other non-flow battery systems are characterised in that zinc-bromine bettery must provide power by magnetic drive pump for its liquid-way system circulates the most significantly.System is once power-off is shut down, and depart from the support of outer net or stand-by power supply, magnetic drive pump cannot work, and fluid path circulation cannot recover, and then causes zinc-bromine bettery system cannot start (namely cannot black starting-up).Black starting-up is one of important indicator weighing reliability of battery system.
Utility model content
In order to overcome above-mentioned the deficiencies in the prior art, the purpose of this utility model is to provide a kind of device realizing zinc bromine liquid fluid system battery black starting-up.
To achieve these goals, the utility model is by the following technical solutions:
A kind of device realizing zinc bromine liquid fluid system battery black starting-up, comprise zinc-bromine bettery pile, anode starts tank and negative electrode starts tank, the top of described zinc-bromine bettery pile is provided with S1, S3 interface, bottom is provided with S2, S4 interface, wherein S1, S2 interface is connected with cathode circulation system, S3, S4 interface and anode circulation system, described anode starts tank and negative electrode starts the top that tank is arranged at described zinc-bromine bettery pile, the S4 orifice of electromagnetically operated valve a and described zinc-bromine bettery pile is passed through in the bottom of described anode startup tank, the bottom that described negative electrode starts tank is successively by the S1 orifice of mixing valve and electromagnetically operated valve b and described zinc-bromine bettery pile, described mixing valve starts tank simultaneously top with described negative electrode is communicated with, under described zinc bromine liquid fluid system off-position, opens solenoid valve a and electromagnetically operated valve b, the described negative electrode activated complex started in tank is flowed out by bottom and after mixing in mixing valve with upper strata electrolyte under gravity, enter in zinc-bromine bettery pile by electromagnetically operated valve b, and discharge at zinc-bromine bettery pile internal-response with the electrolyte coming from anode and start tank, thus realize the black starting-up of zinc bromine liquid fluid system battery.
Pipeline between the S1 interface of described electromagnetically operated valve b and described zinc-bromine bettery pile is provided with unidirectional valve d further.
Described negative electrode starts bottom that tank and anode start tank and is more than or equal to 2.8m, to ensure there is enough circulation pressure reduction in described zinc-bromine bettery pile apart from the centre-height of described zinc-bromine bettery pile.
Described cathode circulation system comprises the first magnetic drive pump and negative electrode fluid reservoir, described first magnetic force pump intake is communicated with bottom with the top of negative electrode fluid reservoir with the second ball valve respectively by the first ball valve, the S2 orifice of described first magnetic force delivery side of pump and zinc-bromine bettery pile, the S1 interface of described zinc-bromine bettery pile is communicated with negative electrode fluid reservoir; Described anode circulation system comprises the second magnetic drive pump and anode fluid reservoir, and wherein the second magnetic force pump intake is communicated with the bottom of described anode fluid reservoir by the 3rd ball valve, the S4 orifice of described second magnetic force delivery side of pump and described zinc-bromine bettery pile.
Described cathode circulation system comprises unidirectional valve a and cross valve further, described first magnetic force delivery side of pump is connected with the L interface of cross valve by unidirectional valve a, the U of described cross valve, D interface respectively with S1, S2 orifice of zinc-bromine bettery pile, the R interface of described cross valve is communicated with described negative electrode fluid reservoir, realizes flowing to switching by described cross valve.
Described negative electrode starts tank further by the outlet of unidirectional valve c with the first magnetic drive pump, and described anode startup tank is further by unidirectional valve b and the second magnetic drive pump outlet.
Described first magnetic force delivery side of pump accesses triple valve further, and described triple valve is connected with described unidirectional valve c and unidirectional valve a respectively.
Described negative electrode starts tank top and is provided with blow vent K1, and this blow vent K1 is communicated with the top of negative electrode fluid reservoir; Described anode starts tank top and is provided with blow vent K2, and this blow vent K2 is communicated with the top of anode fluid reservoir.
Advantage of the present utility model and beneficial effect are:
The utility model, when not by external power, relies on electrolyte Action of Gravity Field that active material is sent into pile, and reaction electric discharge, starts magnetic drive pump, and the oneself realizing zinc-bromine flow battery system starts.The utility model safety, stable, simple, without the need to stand-by power supply.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
Wherein: 1 is the first magnetic drive pump, 2 is triple valve, and 3 is unidirectional valve a, and 4 is cross valve, 5 is zinc-bromine bettery pile, and 6 is negative electrode fluid reservoir, and 7 is the first ball valve, 8 is the second ball valve, and 9 is the 3rd ball valve, and 10 is the second magnetic drive pump, 11 is unidirectional valve b, and 12 is anode fluid reservoir, and 13 is electromagnetically operated valve a, 14 is anode startup tank, and 15 is that negative electrode starts tank, and 16 is mixing valve, 17 is electromagnetically operated valve b, and 18 is unidirectional valve c, and 19 is unidirectional valve d.
Embodiment
Below in conjunction with accompanying drawing, the utility model is described in further detail.
As shown in Figure 1, a kind of device realizing zinc bromine liquid fluid system battery black starting-up that the utility model provides, comprise zinc-bromine bettery pile 5, anode starts tank 14 and negative electrode starts tank 15, the top of described zinc-bromine bettery pile 5 is provided with S1, S3 interface, bottom is provided with S2, S4 interface, wherein S1, S2 interface is connected with cathode circulation system, S3, S4 interface and anode circulation system.Described anode starts tank 14 and negative electrode starts the top that tank 15 is arranged at described zinc-bromine bettery pile 5, and the S4 orifice of electromagnetically operated valve a13 and described zinc-bromine bettery pile 5 is passed through in the bottom of described anode startup tank 14.The bottom of described negative electrode startup tank 15 passes through the S1 orifice of mixing valve 16 and electromagnetically operated valve b17 and described zinc-bromine bettery pile 5 successively, and described mixing valve 16 starts tank 15 simultaneously top with described negative electrode is communicated with; Under described zinc bromine liquid fluid system off-position, opens solenoid valve a13 and electromagnetically operated valve b17, the described negative electrode activated complex started in tank 15 is flowed out by bottom and after mixing in mixing valve 16 with upper strata electrolyte under gravity, enter in zinc-bromine bettery pile 5 by electromagnetically operated valve b17, and discharge at zinc-bromine bettery pile 5 internal-response with the electrolyte coming from anode and start tank 14, thus realize the black starting-up of zinc bromine liquid fluid system battery.
Pipeline between the S1 interface of described electromagnetically operated valve b17 and described zinc-bromine bettery pile 5 is provided with unidirectional valve d19 further.Described negative electrode starts bottom that tank 15 and anode start tank 14 and is not less than (being namely more than or equal to) 2.8m, to ensure there is enough circulation pressure reduction in described zinc-bromine bettery pile 5 apart from the centre-height H of described zinc-bromine bettery pile 5.
Described cathode circulation system comprises the first magnetic drive pump 1 and negative electrode fluid reservoir 6, the suction inlet of described first magnetic drive pump 1 is communicated with bottom with the top of negative electrode fluid reservoir 6 with the second ball valve 8 respectively by the first ball valve 7, the described outlet of the first magnetic drive pump 1 and the S2 orifice of zinc-bromine bettery pile 5, the S1 interface of described zinc-bromine bettery pile 5 is communicated with negative electrode fluid reservoir 6; Described anode circulation system comprises the second magnetic drive pump 10 and anode fluid reservoir 12, wherein the suction inlet of the second magnetic drive pump 10 is communicated with the bottom of described anode fluid reservoir 12 by the 3rd ball valve 9, the outlet of described second magnetic drive pump 10 and the S4 orifice of described zinc-bromine bettery pile 5.
Described cathode circulation system comprises unidirectional valve a3 and cross valve 4 further, the outlet of described first magnetic drive pump 1 is connected with the L interface of cross valve 4 by unidirectional valve a3, the U of described cross valve 4, D interface respectively with S1, S2 orifice of zinc-bromine bettery pile 5, the R interface of described cross valve 4 is communicated with described negative electrode fluid reservoir 6, realizes flowing to switching by described cross valve 4.
Described negative electrode starts the outlet of tank 15 further by unidirectional valve c18 and the first magnetic drive pump 1, the outlet of described first magnetic drive pump 1 further with the A orifice of triple valve 2, B, the C interface of described triple valve 2 are connected with described unidirectional valve c18 and unidirectional valve a3 respectively, carry out the operation of cathode circulation system and start the switching that tank 15 carries out between feed operation for described negative electrode by triple valve 2.Described anode starts tank 14 further by unidirectional valve b11 and the second magnetic drive pump 10 outlet, namely the outlet electrolyte of the second magnetic drive pump 10 separates two-way after unidirectional valve b11, one tunnel directly enters the S4 interface of zinc-bromine bettery pile 5, and another road enters anode through electromagnetically operated valve a13 and starts in tank 14.
Described negative electrode starts tank 15 top and is provided with blow vent K1, and this blow vent K1 is communicated with the top of negative electrode fluid reservoir 6; Described anode starts tank 14 top and is provided with blow vent K2, and this blow vent K2 is communicated with the top of anode fluid reservoir 12.Described negative electrode starts tank 15 and anode starts blow vent K1, the blow vent K2 on tank 14 top except ventilation effect, can also excessive electrolyte in startup tank (negative electrode starts tank 15 or anode starts tank 14) be recovered in fluid reservoir (negative electrode fluid reservoir 6 or anode fluid reservoir 12), maintain the liquid level equilibrium started in tank.
Said apparatus realizes the method for zinc bromine liquid fluid system battery black starting-up:
When the circulatory system of described zinc bromine liquid fluid system battery quits work in power-off, described electromagnetically operated valve a13 and electromagnetically operated valve b17 opens automatically, the activated complex that negative electrode starts in tank 15 is flowed out by bottom under gravity, and after mixing in mixing valve 16 with upper strata electrolyte, enter in zinc-bromine bettery pile 5 by electromagnetically operated valve b17, unidirectional valve d19, and discharge at zinc-bromine bettery pile 5 internal-response with the electrolyte coming from anode and start tank 14, then power into the circulatory system of described zinc bromine liquid fluid system battery after being changed by transducer; After the circulatory system steady operation of described zinc bromine liquid fluid system battery, shut electromagnetic valve a13 and electromagnetically operated valve b17.
The activated complex that described negative electrode starts in tank 15 is provided by the cathode circulation system of described zinc bromine liquid fluid system battery, and the electrolyte that described anode starts in tank 14 is provided by the anode circulation system of described zinc bromine liquid fluid system battery.
The utility model, when not by external power, relies on electrolyte Action of Gravity Field that active material is sent into pile, and reaction electric discharge, starts magnetic drive pump, and the oneself realizing zinc-bromine flow battery system starts.The utility model safety, stable, simple, without the need to stand-by power supply.
Operation principle of the present utility model:
During charge and discharge cycles, the first magnetic drive pump 1 and the second magnetic drive pump 10 start under external power supply effect, and electromagnetically operated valve a13 and electromagnetically operated valve b17 is energized normally closed, and the AC of triple valve 2 flows to conducting.Negative electrode fluid reservoir 6 electrolyte inside enters in zinc-bromine bettery pile 5 through the first magnetic drive pump 1, cross valve 4; Meanwhile anode fluid reservoir 12 electrolyte inside enters in zinc-bromine bettery pile 5 through the second magnetic drive pump 10, unidirectional valve b11, two kinds of electrolyte carry out discharge and recharge reaction in zinc-bromine bettery pile 5, after reacting, catholyte flows back in negative electrode fluid reservoir 6, and anolyte flows back in anode fluid reservoir 12.
After battery charging complete, switch three-way valve 2, the AB of conducting triple valve 2 flows to, open electromagnetically operated valve a13 and electromagnetically operated valve b17 simultaneously, respectively the amount of activated complex compound in negative electrode fluid reservoir 6 being transported to negative electrode starts in tank 15, and the anolyte in anode fluid reservoir 12 is transported to anode and starts in tank 14.After end of operation, triple valve 2, electromagnetically operated valve a13 and electromagnetically operated valve b17 are resetted, system enters black starting-up standby condition.
After zinc-bromine flow battery system dead electricity is shut down, first magnetic drive pump 1 and the second magnetic drive pump 10 dead electricity are shut down, electromagnetically operated valve a13 and electromagnetically operated valve b17 opens automatically, the activated complex that negative electrode starts in tank 15 is flowed out by bottom under gravity, after mixing in mixing valve 16 with upper strata electrolyte, by electromagnetically operated valve b17, unidirectional valve d19 enters in zinc-bromine bettery pile 5, discharge at zinc-bromine bettery pile 5 internal-response with the electrolyte coming from anode and start tank 14, power into the first magnetic drive pump 1 and the second magnetic drive pump 10 after being changed by transducer, the first magnetic drive pump 1 after startup and the second magnetic drive pump 10 open the cathode circulation system of battery system and the circulation of anode circulation system, zinc-bromine bettery pile 5 starts stably externally to discharge.After zinc-bromine flow battery systemic circulation is stable, electromagnetically operated valve a13 and electromagnetically operated valve b17 closes.
In zinc-bromine flow battery system, negative electrode startup tank 15, anode start distance zinc-bromine bettery pile 5 centre-height H bottom tank 14 and are not less than 2.8m, to ensure having enough circulation pressure reduction in zinc-bromine bettery pile 5.In zinc-bromine flow battery system, the effect of unidirectional valve a3 is that the electrolyte stoping negative electrode to start in tank 15 is back in the first magnetic drive pump 1.In system, the effect of unidirectional valve b11 is that the electrolyte stoping anode to start in tank 14 is back in the second magnetic drive pump 10.In native system, the effect of mixing valve 16 negative electrode is started the activated complex bottom tank 15 to mix with the electrolyte on top, forms low concentration mixture, and with the mobility of enhanced activity thing, strengthening activated complex is uniformly distributed in zinc-bromine bettery pile 5.
In sum, the utility model, when not by external power, relies on electrolyte Action of Gravity Field to be sent into by active material in zinc-bromine bettery pile, and reaction electric discharge, starts magnetic drive pump, and the oneself realizing zinc-bromine flow battery system starts.
Claims (8)
1. one kind realizes the device of zinc bromine liquid fluid system battery black starting-up, it is characterized in that, comprise zinc-bromine bettery pile (5), anode starts tank (14) and negative electrode starts tank (15), the top of described zinc-bromine bettery pile (5) is provided with S1, S3 interface, bottom is provided with S2, S4 interface, wherein S1, S2 interface is connected with cathode circulation system, S3, S4 interface and anode circulation system, described anode starts tank (14) and negative electrode starts the top that tank (15) is arranged at described zinc-bromine bettery pile (5), described anode starts the bottom of tank (14) by the S4 orifice of electromagnetically operated valve a (13) with described zinc-bromine bettery pile (5), the bottom of described negative electrode startup tank (15) passes through the S1 orifice of mixing valve (16) and electromagnetically operated valve b (17) and described zinc-bromine bettery pile (5) successively, described mixing valve (16) starts tank (15) simultaneously top with described negative electrode is communicated with, under described zinc bromine liquid fluid system off-position, opens solenoid valve a (13) and electromagnetically operated valve b (17), the described negative electrode activated complex started in tank (15) is flowed out by bottom and after mixing in mixing valve (16) with upper strata electrolyte under gravity, enter in zinc-bromine bettery pile (5) by electromagnetically operated valve b (17), and discharge at zinc-bromine bettery pile (5) internal-response with the electrolyte coming from anode and start tank (14), thus realize the black starting-up of zinc bromine liquid fluid system battery.
2. by the device realizing zinc bromine liquid fluid system battery black starting-up according to claim 1, it is characterized in that, the pipeline between described electromagnetically operated valve b (17) and the S1 interface of described zinc-bromine bettery pile (5) is provided with unidirectional valve d (19) further.
3. by the device realizing zinc bromine liquid fluid system battery black starting-up according to claim 2, it is characterized in that, the bottom that described negative electrode starts tank (15) and anode startup tank (14) is more than or equal to 2.8m, to ensure there is enough circulation pressure reduction in described zinc-bromine bettery pile (5) apart from the centre-height of described zinc-bromine bettery pile (5).
4. by the device realizing zinc bromine liquid fluid system battery black starting-up according to claim 1, it is characterized in that, described cathode circulation system comprises the first magnetic drive pump (1) and negative electrode fluid reservoir (6), the suction inlet of described first magnetic drive pump (1) is communicated with bottom with the top of negative electrode fluid reservoir (6) with the second ball valve (8) respectively by the first ball valve (7), the outlet of described first magnetic drive pump (1) and the S2 orifice of zinc-bromine bettery pile (5), the S1 interface of described zinc-bromine bettery pile (5) is communicated with negative electrode fluid reservoir (6); Described anode circulation system comprises the second magnetic drive pump (10) and anode fluid reservoir (12), wherein the suction inlet of the second magnetic drive pump (10) is communicated with the bottom of described anode fluid reservoir (12) by the 3rd ball valve (9), the outlet of described second magnetic drive pump (10) and the S4 orifice of described zinc-bromine bettery pile (5).
5. by the device realizing zinc bromine liquid fluid system battery black starting-up according to claim 4, it is characterized in that, described cathode circulation system comprises unidirectional valve a (3) and cross valve (4) further, the outlet of described first magnetic drive pump (1) is connected with the L interface of cross valve (4) by unidirectional valve a (3), the U of described cross valve (4), D interface respectively with the S1 of zinc-bromine bettery pile (5), S2 orifice, the R interface of described cross valve (4) is communicated with described negative electrode fluid reservoir (6), realize flowing to by described cross valve (4) and switch.
6. by the device realizing zinc bromine liquid fluid system battery black starting-up according to claim 4, it is characterized in that, described negative electrode starts tank (15) further by the outlet of unidirectional valve c (18) with the first magnetic drive pump (1), and described anode starts tank (14) further by unidirectional valve b (11) and the second magnetic drive pump (10) outlet.
7. by the device realizing zinc bromine liquid fluid system battery black starting-up according to claim 5, it is characterized in that, the outlet of described first magnetic drive pump (1) accesses triple valve (2) further, and described triple valve (2) is connected with described unidirectional valve c (18) and unidirectional valve a (3) respectively.
8. by the device realizing zinc bromine liquid fluid system battery black starting-up according to claim 4, it is characterized in that, described negative electrode starts tank (15) top and is provided with blow vent K1, and this blow vent K1 is communicated with the top of negative electrode fluid reservoir (6); Described anode starts tank (14) top and is provided with blow vent K2, and this blow vent K2 is communicated with the top of anode fluid reservoir (12).
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Cited By (8)
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CN106356551A (en) * | 2016-10-28 | 2017-01-25 | 湖南汇锋高新能源有限公司 | All-vanadium redox flow battery system for efficient energy storage |
CN106410248A (en) * | 2016-05-12 | 2017-02-15 | 国网电力科学研究院武汉南瑞有限责任公司 | Redox flow battery |
CN106558722A (en) * | 2015-09-23 | 2017-04-05 | 特变电工沈阳变压器集团有限公司 | A kind of device and method for realizing zinc bromine liquid fluid system battery black starting-up |
WO2017204530A1 (en) * | 2016-05-23 | 2017-11-30 | 롯데케미칼주식회사 | Redox flow battery |
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CN106356551B (en) * | 2016-10-28 | 2020-01-14 | 湖南汇锋高新能源有限公司 | All-vanadium redox flow battery system applied to efficient energy storage |
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