CN204222315U - A kind of silver-colored LOW-E glass of gold list of high transmission rate - Google Patents

A kind of silver-colored LOW-E glass of gold list of high transmission rate Download PDF

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Publication number
CN204222315U
CN204222315U CN201420675012.XU CN201420675012U CN204222315U CN 204222315 U CN204222315 U CN 204222315U CN 201420675012 U CN201420675012 U CN 201420675012U CN 204222315 U CN204222315 U CN 204222315U
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China
Prior art keywords
layer
glass
silver
transmission rate
high transmission
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Withdrawn - After Issue
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CN201420675012.XU
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Chinese (zh)
Inventor
魏佳坤
林改
郑梅鹏
宋晓群
郑凯永
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JIEYANG HONGGUANG COATED GLASS CO Ltd
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JIEYANG HONGGUANG COATED GLASS CO Ltd
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Priority to CN201420675012.XU priority Critical patent/CN204222315U/en
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Abstract

The utility model discloses a kind of silver-colored LOW-E glass of gold list of high transmission rate, include glass substrate, it is characterized in that: be adjacent to successively from inside to outside be compounded with seven retes on the composite surface of glass substrate, wherein the first rete and innermost layer are SSTZrO xlayer, the second layer is AZO layer, and third layer is Si layer, and the 4th layer is AZO layer, and layer 5 is Ag layer, and layer 6 is CrN xo y, outermost layer is SnO2 layer.The utility model object overcomes the deficiencies in the prior art, provides a kind of transmitance high, and bright in colour, radiance is low, and energy-saving effect is remarkable, the silver-colored LOW-E glass of gold list of the high transmission rate that production cost is low.

Description

A kind of silver-colored LOW-E glass of gold list of high transmission rate
[technical field]
The utility model relates to a kind of silver-colored LOW-E glass of gold list of high transmission rate.
[background technology]
Coated glass has the double effects of energy-saving and emission-reduction and decorative curtain wall.And aurene is as a unconventional kind of coated glass, be loved by the people.But due to golden coated glass product existing on market, tone is dim and production cost is high, and great majority are sunlight controlling coated glass.
[utility model content]
The utility model object overcomes the deficiencies in the prior art, provides a kind of transmitance high, and bright in colour, radiance is low, and energy-saving effect is remarkable, the silver-colored LOW-E glass of gold list of the high transmission rate that production cost is low.
The utility model is achieved through the following technical solutions:
The silver-colored LOW-E glass of gold list of high transmission rate, includes glass substrate 1, it is characterized in that: be adjacent to successively from inside to outside be compounded with seven retes on the composite surface of glass substrate, wherein the first rete and innermost layer are SSTZrO xlayer 21, the second layer is AZO layer 22, and third layer is the 23, four layer, Si layer is AZO layer 24, and layer 5 is Ag layer 25, and layer 6 is CrN xo y26, outermost layer is SnO 2layer 27.
The silver-colored LOW-E glass of gold list of high transmission rate as above, is characterized in that described first rete SSTZrO xthe thickness of layer 21 is 30 ~ 40nm.
The silver-colored LOW-E glass of gold list of high transmission rate as above, is characterized in that the thickness of described second layer AZO layer 22 is 10 ~ 15nm, the thickness 10 ~ 20nm of the 4th layer of AZO layer 24.
The silver-colored LOW-E glass of gold list of high transmission rate as above, is characterized in that the thickness of described third layer Si layer 23 is 3 ~ 5nm.
The silver-colored LOW-E glass of gold list of high transmission rate as above, is characterized in that the thickness of described layer 5 Ag layer 25 is 10 ~ 15nm.
The silver-colored LOW-E glass of gold list of high transmission rate as above, is characterized in that described layer 6 CrN xo y26 and Floor 12 CrN xo ythe thickness of layer 212 is 3nm.
The silver-colored LOW-E glass of gold list of high transmission rate as above, is characterized in that described outermost layer SnO 2the thickness of layer 27 is 60nm.
Compared with prior art, the utility model has the following advantages:
1, the silver-colored LOW-E glass of the gold list of the utility model special film system, bright in colour, and also light transmittance is high, reaches more than 70%; .
2, compared with the gold that the utility model and employing gold is produced as functional layer, Si is as the cost of functional layer less than the one thousandth with gold, and the radiance of product only 0.02, energy-saving effect is remarkable.
3, the utility model adopts silicon as functional layer, and the LOW-E glass cost than common while ensure that gold effect is lower.
[accompanying drawing explanation]
Fig. 1 is the utility model structural representation.
[detailed description of the invention]
The silver-colored LOW-E glass of gold list of high transmission rate, includes glass substrate 1, and the composite surface of glass substrate is adjacent to from inside to outside be successively compounded with seven retes, wherein the first rete and innermost layer are SSTZrO xlayer 21, the second layer is AZO layer 22, and third layer is the 23, four layer, Si layer is AZO layer 24, and layer 5 is Ag layer 25, and layer 6 is CrN xo y26, outermost layer is SnO 2layer 27.
Described first rete and innermost layer are SSTZrO xlayer 21, namely mixes zirconium oxidation stainless steel layer, by mixing zirconium in stainless steel, improving the refractive index of rete, reach about 2.0 when reactive sputtering, thus promote the transmitance of compound film system.Make adjustments golden color layers, more yellow gold effect can be obtained.SSTZrO xthe thickness of layer 21 is 30 ~ 40nm, and preferred 35nm, nm are nanometers, 1m=10 9nm.
Described second layer AZO layer 22, i.e. the zinc oxide film of aluminium doping, levelling blanket, level and smooth Si layer, for Si, Ag layer makes place mat, reduces radiance.The thickness of AZO layer is 10 ~ 15nm.Preferred 12nm.
Described third layer Si layer 23, i.e. silicon layer is functional layer, is used as golden providing layer.The thickness of Si layer is 3 ~ 5nm, preferred 4nm.
Described 4th layer of AZO layer 24, i.e. the zinc oxide film of aluminium doping, levelling blanket, owing to becoming tufted structure after Si sputtering, by with the level and smooth Si layer of AZO layer, for lower floor plating Ag plays bottoming effect.For Ag layer makes place mat, reduce radiance.The thickness of AZO layer is 10 ~ 20nm.Preferred 15nm.
Described layer 5 Ag layer 25, i.e. metallic silver layer, be functional layer, metallic silver layer provides lower radiance, plays environmental protection and energy saving.The thickness of Ag layer is 10 ~ 15nm, preferred 12nm.
Described layer 6 CrN xo ylayer 26, i.e. nitrogen chromium oxide layer, high temperature oxidation resistance when raising rete wearability, raising light transmittance, raising tempering.CrN xo ythe thickness of layer 26 is 3nm.
Described layer 7 SnO 2layer 27, i.e. zinc oxide film is middle dielectric layer, protective layer.SnO 2the thickness of layer 27 is 60nm.
Low-E glass is also called low radiation coated glass.
Prepare the method for the silver-colored LOW-E glass of gold list of high transmission rate, comprise the steps:
(1) magnetron sputtering SSTZrO xlayer, make with interchange intermediate frequency power supply, oxygen the stainless steel target Fe:Zr=80:20 that zirconium is mixed in reacting gas sputtering, argon oxygen is than being 400SCCM ~ 420SCCM:450SCCM ~ 500SCCM, and in this step, argon oxygen is than the quality determining film forming;
(2) magnetron sputtering oxygen AZO layer, sputters ceramic Zn target with midfrequent AC power supply, i.e. AZO target, with argon gas as sputter gas, mixes a small amount of O 2, argon oxygen ratio is: 400SCCM-420SCCM:20 ~ 40SCCM, for Si, Ag layer makes place mat;
(3) magnetron sputtering Si layer, AC power sputters, with Ar gas as sputter gas, gas flow 500 ~ 550SCCM;
(4) magnetron sputtering AZO layer, sputters ceramic ZnAZO target with midfrequent AC power supply, with argon gas as sputter gas, mixes a small amount of O 2, argon oxygen ratio is 400SCCM-420SCCM:20 ~ 40SCCM, for Ag layer makes place mat;
(5) magnetron sputtering Ag layer, dc source sputters, and makes reacting gas, gas flow 500 ~ 550SCCM with argon gas;
(6) magnetron sputtering C rN xo ylayer, with dc source sputtering, does reacting gas with nitrogen, oozes a small amount of oxygen;
(7) magnetron sputtering SnO 2layer, makes reacting gas sputtering for Sn target with interchange intermediate frequency power supply, oxygen, and argon oxygen is than being 400SCCM ~ 420SCCM:450SCCM ~ 500SCCM, and in this step, argon oxygen is than the quality determining film forming.

Claims (7)

1. the silver-colored LOW-E glass of the gold list of high transmission rate, includes glass substrate (1), it is characterized in that: be adjacent to successively from inside to outside be compounded with seven retes on the composite surface of glass substrate, wherein the first rete and innermost layer are SSTZrO xlayer (21), the second layer is AZO layer (22), and third layer is Si layer (23), and the 4th layer is AZO layer (24), and layer 5 is Ag layer (25), and layer 6 is CrN xo y(26), outermost layer is SnO 2layer (27).
2. the silver-colored LOW-E glass of the gold list of high transmission rate according to claim 1, is characterized in that described first rete SSTZrO xthe thickness of layer (21) is 30 ~ 40nm.
3. the silver-colored LOW-E glass of the gold list of high transmission rate according to claim 1, is characterized in that the thickness of described second layer AZO layer (22) is 10 ~ 15nm, the thickness 10 ~ 20nm of the 4th layer of AZO layer (24).
4. the silver-colored LOW-E glass of the gold list of high transmission rate according to claim 1, is characterized in that the thickness of described third layer Si layer (23) is 3 ~ 5nm.
5. the silver-colored LOW-E glass of the gold list of high transmission rate according to claim 1, is characterized in that the thickness of described layer 5 Ag layer (25) is 10 ~ 15nm.
6. the silver-colored LOW-E glass of the gold list of high transmission rate according to claim 1, is characterized in that described layer 6 CrN xo yand Floor 12 CrN (26) xo ythe thickness of layer (212) is 3nm.
7. the silver-colored LOW-E glass of the gold list of high transmission rate according to claim 1, is characterized in that described outermost layer SnO 2the thickness of layer (27) is 60nm.
CN201420675012.XU 2014-11-12 2014-11-12 A kind of silver-colored LOW-E glass of gold list of high transmission rate Withdrawn - After Issue CN204222315U (en)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104369444A (en) * 2014-11-12 2015-02-25 揭阳市宏光镀膜玻璃有限公司 High-light-transmittance gold single-silver LOW-E glass and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104369444A (en) * 2014-11-12 2015-02-25 揭阳市宏光镀膜玻璃有限公司 High-light-transmittance gold single-silver LOW-E glass and preparation method thereof
CN104369444B (en) * 2014-11-12 2016-06-08 揭阳市宏光镀膜玻璃有限公司 Golden single silver LOW-E glass of a kind of high transmission rate and preparation method

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AV01 Patent right actively abandoned

Granted publication date: 20150325

Effective date of abandoning: 20160608

C25 Abandonment of patent right or utility model to avoid double patenting