CN203884686U - Functional film composite particle and filter stick formed by functional film composite particle - Google Patents
Functional film composite particle and filter stick formed by functional film composite particle Download PDFInfo
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- CN203884686U CN203884686U CN201420001481.3U CN201420001481U CN203884686U CN 203884686 U CN203884686 U CN 203884686U CN 201420001481 U CN201420001481 U CN 201420001481U CN 203884686 U CN203884686 U CN 203884686U
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- functional film
- filter
- composite particle
- particle
- functional membrane
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- 239000011246 composite particle Substances 0.000 title claims abstract description 37
- 239000012528 membrane Substances 0.000 claims description 42
- 239000002131 composite material Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229920006239 diacetate fiber Polymers 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 abstract description 45
- 239000002245 particle Substances 0.000 abstract description 28
- 235000019504 cigarettes Nutrition 0.000 abstract description 20
- 241000196324 Embryophyta Species 0.000 abstract description 13
- 238000002360 preparation method Methods 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 10
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 8
- 235000003130 Arctium lappa Nutrition 0.000 abstract description 7
- 235000008078 Arctium minus Nutrition 0.000 abstract description 7
- 244000046146 Pueraria lobata Species 0.000 abstract description 7
- 235000010575 Pueraria lobata Nutrition 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 6
- 239000001257 hydrogen Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000000779 smoke Substances 0.000 abstract description 5
- 239000001913 cellulose Substances 0.000 abstract description 4
- 229920002678 cellulose Polymers 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 229920002472 Starch Polymers 0.000 abstract description 3
- 239000008107 starch Substances 0.000 abstract description 3
- 235000019698 starch Nutrition 0.000 abstract description 3
- 229920001661 Chitosan Polymers 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 240000005528 Arctium lappa Species 0.000 abstract 1
- 239000011236 particulate material Substances 0.000 description 15
- 239000010408 film Substances 0.000 description 14
- 239000008187 granular material Substances 0.000 description 13
- 244000269722 Thea sinensis Species 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 11
- 241000208125 Nicotiana Species 0.000 description 9
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 239000003337 fertilizer Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- 239000003546 flue gas Substances 0.000 description 7
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- 241000208843 Arctium Species 0.000 description 6
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- 239000000654 additive Substances 0.000 description 4
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- 238000002955 isolation Methods 0.000 description 3
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- 229920002223 polystyrene Polymers 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
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- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000019733 Fish meal Nutrition 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
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- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
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- 229920002554 vinyl polymer Polymers 0.000 description 2
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- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 150000003722 vitamin derivatives Chemical class 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ZAMLGGRVTAXBHI-UHFFFAOYSA-N 3-(4-bromophenyl)-3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoic acid Chemical compound CC(C)(C)OC(=O)NC(CC(O)=O)C1=CC=C(Br)C=C1 ZAMLGGRVTAXBHI-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
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- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
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- NMGYKLMMQCTUGI-UHFFFAOYSA-J diazanium;titanium(4+);hexafluoride Chemical compound [NH4+].[NH4+].[F-].[F-].[F-].[F-].[F-].[F-].[Ti+4] NMGYKLMMQCTUGI-UHFFFAOYSA-J 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
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- 235000010413 sodium alginate Nutrition 0.000 description 1
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Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The utility model discloses a functional film composite particle. The functional film composite particle consists of a particle material and a functional film which wraps the particle material, wherein the particle material is made of natural plants which are rich in cellulose and starch composition such as kudzu vine roots or burdock; the functional film is formed by mixing polyvinyl alcohol with chitosan. A preparation method of the functional film composite particle comprises the step of wrapping the particle material with the functional film through a fluidizing and spraying method by the aid of hydrogen bonds formed between molecular chains. The functional film composite particle can be used for manufacturing a filter stick. According to the prepared composite particle filter stick, the environmental protection effect, the aroma enhancement effect and the moisture keeping effect of the natural plants can be brought into full play, and harmful organic substances in cigarette smoke can also be effectively adsorbed.
Description
Technical field
The utility model relates to a kind of granular adsorption material that is coated with film material and as the application of cigarette filter material.
Background technology
By powder stock granulation material, by a film of the peripheral parcel of particulate material, particulate material is used alone as to sorbing material, particulate material is embedded in fibrous material as accordance filtering adsorbing material, to reach the objects such as absorption, filtration, slowly-releasing or shielding, these technology are technological means that the fields such as tobacco industry, chemical industry, mechanotronics or agricultural often adopt.
Common cigarette filter material (filter stick, filter tip) is to do filter core with fibrous material, some new technology is embedded with the granular material of specific function in fibrous material, to improve adsorptivity, to improve and inhale taste or reduce health risk, but on raw material choose, preparation method and implementation result, also there are some problems.
Number of patent application is 00816349.9 " Irreversible coating particles and the composition that contains these particles ", relate to stable coating particles, it contains (a) by the charged material of self-faced and the core that can form the material of the material production potential electrometer gravitation of oppositely charged and the peripheral matrix thin layer that (b) contains polymer, polymer selects free polyethylene phosphoric acid or polystyrene phosphoric acid, polyvinyl sulfuric acid or polystyrene sulfuric acid, polyvinyl sulfonic acid or polystyrolsulfon acid, polyvinylphosphonic acid or polystyrene phosphonic acids, the group that polyacrylic acid and their salt separately form, with non-imposed ultra-fine grain, wherein core granule is irreversible and separately by overlay film.
Number of patent application has been 200710059266.3 disclosure of the invention a kind of " in the method for magnetic-particle surface coating titanium dioxide crystalline film ", by following step, formed: (1) by nanometer or micron order for magnetic-particle ethanol, water clean successively, after dry, immerse in the aqueous solution of ionic surfactant, soak 8-12h, from solution, Magnetic Isolation goes out particle; (2) be placed in the ammonium titanium fluoride aqueous solution, drip wherein boric acid aqueous solution, stirring reaction 6-10h at 20-80 ℃, Magnetic Isolation goes out the magnetic-particle that surface is coated with nano titanium oxide, at 300-600 ℃, roasting 1-4h; (3) with concentrated hydrochloric acid washing, Magnetic Isolation, is dried, and can obtain the magnetic-particle of surperficial coating titanium dioxide crystalline film.A kind of method at magnetic-particle surface coating titanium dioxide crystalline film of the present utility model can make thin film of titanium oxide that magnetic core surface is covered completely, and thin film of titanium oxide compact structure, can shield the diffusion mass transfer of magnetic core and external environment completely.
Number of patent application be 200510044330.1 disclosure of the invention " coated micro particle feed for fry of Cynoglossus semilaevis Gunther ", it is characterized in that it is by raw material fish meal, fodder yeast, seawood meal, vitamin, mineral matter, shrimp med, lecithin, dregs of beans, peanut meal, phagostimulant, fish oil carries out respectively, after ultramicro grinding processing, taking by weight percentage fish meal 30~70%, fodder yeast 1~10%, seawood meal 1~10%, vitamin 0.1~5%, mineral matter 0.1~5%, shrimp med 1~10%, lecithin 1~10%, dregs of beans 1~30%, peanut meal 1~30%, phagostimulant 0.1~5%, fish oil 1~20%, and adopt three-dimensional mixer fully to mix raw material, 0.1~6% feed adhesive is dissolved to rear and above-mentioned mixed raw material hybrid bonding, make micro-granulated feed, and after dissolving with 0.1~6% feed adhesive to the microparticle coating of spraying, oven dry makes, the utility model obviously improves feed water stability, guarantee feed nutrition is tired, and strengthens seed physique, improves survival rate.
Number of patent application is that 200610036325.0 invention relates to coating controlled-release fertilizer field, discloses a kind of " preparation method of coated release-controlled granular fertilizer ".Comprise: 2~4 kinds of organic compounds are mixed to form to mixed solution; Add film forming exciting agent and film forming accelerating to form film forming mixed liquor; At-20~50 ℃, by film forming mixed liquor, evenly spray is to granular fertilizer surface, and film forming mixed liquor consumption is, behind 1~20%, 5~120 minutes of granular fertilizer weight, on granular fertilizer surface, to form coating.The utility model utilizes chemical reaction, and organifying compound is in granular fertilizer surface in situ film forming, and needed equipment is simple, energy consumption is low, coating efficiency is high, can in closed environment, operate, and can not cause environmental problem.Rete characteristic, as thickness, permeability, pore size, voidage etc. all can conveniently regulating and controllings.Artificially Exact Design rate of release and pattern and Different Crop absorb the coating controlled-release fertilizer matching.Required exciting agent and promoter easily obtain, and obtained coating controlled-release fertilizer stable performance, can preserve for a long time.
Number of patent application is 89108377.4 " particulate sorbent smoke filter ", comprise the filter bar being formed by the cigarette filter material that is added with particulate additive, wherein at least partly particulate additive concentrates on of combining with other filtering materials or limited yarn and/or band, and said additive adhesion is on said yarn and/or band.
Number of patent application is " containing filter stick of tobacco particle and preparation method thereof " of 201010241592.8, in the filter core of filter stick, be added with tobacco particle, it is primary raw material that this tobacco particle adopts tobacco leaf, offal, by pulverizing, after the PROCESS FOR TREATMENT such as anticorrosion, granulation, stifling, perfuming, as additive, divide and spread in filter stick tow, then adopt filter-stick forming device to be prepared from containing tobacco particle filter stick or composite construction filter stick.This filter stick can strengthen efficacy of adsorption, reducing tar and reducing harm, and the fragrance of tobacco particle can also filter the cigarette fragrance decline causing to filter stick and effectively compensate.Meanwhile, this filter stick is cut easily, environmentally friendly.
Number of patent application is " a kind of filter stick flavouring tea granule and preparation method thereof " of 201210280047.9, get one or more in white tea, black tea, yellow tea, black tea, green tea, blue or green tea and their discarded object tea dust, tea stalk, in 55 ℃ of following pulverizing, through screening, obtain 120-200 object fine powder; In gained fine powder, add the aqueous solution of hydrophilic macromolecule adhesive, stir and obtain intermediate, then through comminutor with 20 order net granulations, screening obtains 20-60 order particle; Gained particle is dried at 10-55 ℃ or air-dry to moisture 6%-14%.Described tea granule is comprised of the tea powder of 97%-99.5% part and the hydrophilic macromolecule adhesive of 0.5%-3% part.Hydrophilic macromolecule adhesive is cellulose ethers, natural polymer and derivative class thereof or polypropylene-based synthetic high score subclass.Gained particle is held fragrance can be good, and specific area is large, fully contacts and wash-out particle surface tea is fragrant gradually with flue gas, and granule interior tea perfume (or spice) is discharged gradually, plays the effect of enriching cigarette flavor; Meanwhile, good processability after particle, addition is easy to control, does not have the risk that enters oral cavity with dust form.
Number of patent application is " granular materials and preparation method thereof for a kind of cigarette filter rod " of 201210385682.3, relates to cigarette filter rod, adsorption particle material adding in especially a kind of cigarette filter rod tow and preparation method thereof.Granular materials and preparation method thereof for a kind of cigarette filter rod of the present utility model, is characterized in that this granular materials carries fragrant five steps by come unstuck flaxen fiber powder, microcrystalline cellulose, nano-calcium carbonate, water soluble chitosan and tobacco extract by mixing of materials, grain forming, dry, preparation tobacco extract and particle and is prepared from.This invention has the advantages such as high absorption property, high retention rate, high security, high-bond and selective absorption.
Number of patent application is that 201320034315.9 utility model discloses a kind of " being filled with the cigarette of plants particles material ", composite filter comprises composite filter element, internal layer forming paper and outer forming paper, described composite filter element is by the fine filter rod segments of at least one vinegar or/and at least one paper is chewed the excellent section of combined filtration body forming with at least one plant granule filter rod segments, and described plant granule filter rod segments is evenly to add plant granule formation in cellulose acetate tow or paper mouth rod paper using.It is carrier that the utility model be take Celluloseacetate cigarette filter tow or paper mouth rod paper using, plants particles material is evenly added in filter stick, make the multi-element composite filter sticks such as binary, ternary with the fine filter stick of common vinegar or furrowfilter rod, can effectively adsorb the harmful substances such as tar in cigarette smoke.
The invention that number of patent application is 201210159088.2 provides a kind of " filter tip of preset bulky grain material ", by filter core, bulky grain material, forming paper or also have channel form cellulose paper to form.Forming paper is wrapped in filter core, and bulky grain material is embedded in filter core in advance.The particle diameter of bulky grain material is between 1.0-4.0mm, and the aspiration end of embedding positional distance filter tip is greater than 6.0mm.Bulky grain material contains the composition of spices, or also has the composition of sorbing material.Bulky grain material outer surface or have layer of surface film, skin covering of the surface is when filter tip is sucked, and the temperature of flue gas is broken it, and taste easily comes out, or easily plays suction-operated.When being connected in one, the filter tip of several preset bulky grain material can form the filter stick of preset bulky grain material.The filter tip of this invention can increase the fragrance of cigarette, or increases the adsorption capacity of flue dust.Built-in bulky grain material can not miss in suction inlet, and in producing and depositing, it is fine that its fragrance and adsorption capacity are preserved, and when suction, can give play to due effect.
Number of patent application is a kind of " coffee or cocoa composite particles filter stick and preparation method thereof " of 201210577937.6, this invention relates to filter stick technical field, a kind of composite particles filter stick is disclosed, comprise acetate fiber base material and be wrapped in the forming paper outside acetate fiber base material, on acetate fiber base material, being compounded with treated coffee or cocoa particle.The utility model is successfully by suitable proportion and the acetate fiber base material that is compound to filter stick through the coffee suitably processed or cocoa particle, the resistance to suction that filter stick produces is very suitable, can remove preferably assorted gas and excitant in flue gas, improve the fine and smooth degree of flue gas, to inhaling taste, have improved action; Cigarette smoke brings out the fragrance of foodstuff solid particle, when enriching cigarette note, produces the rich and varied sense of taste and experience in oral cavity.
Above-mentioned patented technology or patented product have advantages of separately, but it is restricted also to exist application, shape of product or structure are more complicated, and production craft step is more, the cost of raw material is higher, peculiar smell is heavier, inadequate health environment-friendly, easily lost efficacy, etc. various defects.Can not large-scale application in the production practices of cigarette filter rod or cigarette filter tip.
Summary of the invention
The first utility model object: overcome existing particulate adsorbent material or composite filter material can not large-scale application shortcoming in filter stick or cigarette filter tip are produced, a kind of environmental protection flavouring humectation effect that has is provided, effectively adsorbs again a kind of functional membrane composite particles of harmful substances from flue gases.
The first technical scheme: functional membrane composite particles of the present utility model, by the functional membrane of particulate material and enwrapped granule material, formed, particulate material accounts for that weight 85% ~ 95%, functional membrane account for weight 5% ~ 10%, other composition accounts for weight 0 ~ 5%, and all compositions add up to 100%; This particulate material is that the natural plants that is rich in cellulose and starch component is made, and functional membrane is that the blended complex of polyvinyl alcohol and shitosan is made, and the ratio of polyvinyl alcohol and shitosan is 0.1 ~ 0.9:1; The size of this functional membrane composite particles is 20 order ~ 80 orders (comprise more than 90% for this reason the situation of specification limit).
Described particulate material is preferably the natural plants that contains the root of kudzu vine or burdock fiber and makes (in the root of kudzu vine or burdock fiber, being rich in cellulose and starch component), it is abundant that primary raw material has source, the root of kudzu vine to human body there is step-down, heat-clearing, quench one's thirst, the health care such as antidiarrheal, burdock to human body there is diuresis, defaecation, prevent and treat hemorrhoid, the effect of toxin expelling, blood-clearing face-beautifying, adjusting blood pressure and blood lipoid, hypotensive, norcholesterol, strengthening the spleen and stomach and tonifying kidney and strengthening yang.Meanwhile, both have not too strong peat-reek.
Described functional membrane material is composited by polyvinyl alcohol and shitosan, has good flue gas and sees through and adsorptivity, can effectively adsorb phenol, aldehydes, hydrogen cyanide material in flue gas.Polyvinyl alcohol, shitosan and string and between can form a lot of hydrogen bonds, can utilize the active force between hydrogen bond, functional membrane material is tightly coated in particulate material.
In functional membrane, can be added with sodium alginate or gelatin, make film material mechanical strength, stability, all increase to some extent with the adhesiveness of particle, flexibility etc.
In the preparation method of above-mentioned functional membrane composite particles, can adopt the preparation technology of following order:
1) root of kudzu vine or burdock natural plants are ground into short fiber or 60 order ~ 150 order powder through pulverizer, then by prilling, prepare 20 order ~ 80 object particulate material;
2) polyvinyl alcohol, shitosan, pure water are mixed, form 2% ~ 20% the functional membrane material aqueous solution;
3) adopt fluid bed granulator and fluidization and spray-drying technique, by compressed ir spray gun, containing the functional membrane material aqueous solution, be sprayed onto just in the particulate material of fluidized state, utilize the hydrogen bond action forming between the strand of functional membrane and natural plant fibre, functional membrane material is coated in particulate material;
4) lower than the temperature of 60 ℃, be dried, while being dried to 40 ℃ ~ 55 ℃, sieve.
The second utility model object: the filter stick that a kind of functional membrane composite particles is provided.
The second technical scheme: the filter stick of described functional membrane composite particles is added in diacetate fiber and made by functional membrane composite particles, diacetate fiber is with forming paper parcel outward, and wherein, the applied amount of functional membrane composite particles is 0.3mg/mm ~ 3 mg/mm.
The filter stick of described functional membrane composite particles can be binary (two segment units) composite filter or ternary (three segment units) composite filter, wherein having a segment unit at least is functional membrane composite particles filter rod segments, remaining element is common filter rod segments (filter stick that does not contain functional membrane composite particles, as furrowfilter rod section, the fine filter rod segments of common vinegar).
Beneficial effect:
Functional membrane composite particles raw material sources of the present utility model are in nature, and cost is controlled, and health environment-friendly has the effects such as not too strong natural flavor and moisturizing, has false proof and high identification, the various diseases of human body is had to the effect of auxiliary curing and health care.
The preparation method of functional membrane composite particles, simple and effective, energy-conserving and environment-protective, shaping particles is good.
Composite particles filter stick prepared by the utility model can be brought into play the environmental protection flavouring humectation health-care efficacy of natural plants, can effectively adsorb again the Organic Hazardous Compounds in cigarette smoke, especially phenol, aldehydes, hydrogen cyanide class material, reduces the smoker's of team harm.
Accompanying drawing explanation
Fig. 1 is a structural representation of the utility model functional membrane composite particles of amplification;
Fig. 2 is production technological process of functional membrane composite particles of the present utility model;
Fig. 3 is the structural representation of a kind of Three-element composite filter core of the present utility model;
In figure, 1, functional membrane; 2, the strand of functional membrane; 3, particulate material; 4, the root of kudzu vine or burdock fiber; 5, hydrogen bond; 6, functional membrane composite particles filter rod segments; 7, furrowfilter rod section; 8, the fine filter rod segments of common vinegar.
The specific embodiment
Example 1:
Functional membrane composite particles as shown in Figure 1, the effect by the functional membrane 1 of particulate material 3 and enwrapped granule material 3 by hydrogen bond (5) forms.Particulate material 3 accounts for that weight 90%, functional membrane 1 account for weight 8%, other composition accounts for weight 2%; This particulate material 3 is that the natural plants that contains the root of kudzu vine or burdock fiber 4 is made; Functional membrane 1 is the blended complex of polyvinyl alcohol, shitosan, gelatin, and wherein the ratio of polyvinyl alcohol and shitosan is 0.5:1; The size of this functional membrane composite particles is 30 order ~ 60 orders.
Example 2:
The filter stick of functional membrane composite particles as shown in Figure 3.Be first by the functional membrane composite particles described in embodiment 1, to be added in diacetate fiber and made functional membrane composite particles filter rod segments 6, wherein, the applied amount of functional membrane composite particles is 1 mg/mm; Furrowfilter rod section 7 and the fine filter rod segments 8 of common vinegar for alternative; Three sections are connected, and peripheral parcel becomes second nature paper and forms Three-element composite filter core.
Claims (2)
1. a filter stick for functional membrane composite particles, is characterized in that: functional membrane composite particles is added in diacetate fiber, peripheral parcel forming paper.
2. the filter stick of functional membrane composite particles as claimed in claim 1, is characterized in that: be binary compound filter candle or Three-element composite filter core, wherein having a segment unit at least is functional membrane composite particles filter rod segments (6).
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105273840A (en) * | 2015-08-06 | 2016-01-27 | 云南中烟工业有限责任公司 | Phoebe spp. particle preparation method and application |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105273840A (en) * | 2015-08-06 | 2016-01-27 | 云南中烟工业有限责任公司 | Phoebe spp. particle preparation method and application |
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