CN104905409A - Healthcare cigarette filter tip composite adsorbent with functions of relieving cough and reducing sputum and preparation method thereof - Google Patents

Healthcare cigarette filter tip composite adsorbent with functions of relieving cough and reducing sputum and preparation method thereof Download PDF

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Publication number
CN104905409A
CN104905409A CN201510300510.5A CN201510300510A CN104905409A CN 104905409 A CN104905409 A CN 104905409A CN 201510300510 A CN201510300510 A CN 201510300510A CN 104905409 A CN104905409 A CN 104905409A
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China
Prior art keywords
parts
adsorbent
relieving cough
filter tip
cigarette filter
Prior art date
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Pending
Application number
CN201510300510.5A
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Chinese (zh)
Inventor
黄幼兵
杜威
郑鸿雁
何良原
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Chuzhou Cigarette Materials Factory
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Chuzhou Cigarette Materials Factory
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Publication date
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Priority to CN201510300510.5A priority Critical patent/CN104905409A/en
Publication of CN104905409A publication Critical patent/CN104905409A/en
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/165—Natural alumino-silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

The invention discloses a healthcare cigarette filter tip composite adsorbent with functions of relieving cough and reducing sputum. The healthcare cigarette filter tip composite adsorbent is characterized by being prepared from the following raw materials in parts by weight: 30-40 parts of polyvinyl alcohol, 3-5 parts of lily, 2-4 parts of platycodon grandiflorum, 2-4 parts of loquat leaf, 3-5 parts of konjac flour, 0.05-0.1 parts of lauryl sodium sulfate, 5-10 parts of corn starch, 3-5 parts of sodium alginate, 0.3-0.5 parts of silane coupling agent A-151 and 5-10 parts of modified inorganic powder body. The cigarette filter tip composite adsorbent can highly efficiently filter and adsorb harmful substances of smokes, so that the effects of reducing tar and toxicity are achieved, and meanwhile, the taste of the smoke is kept; furthermore, the adsorbent has the efficacies of nourishing the heart and tranquilizing mind, moistening lung and arresting cough, and relieving sore throat and eliminating phlegm, and also has the excellent healthcare efficacy.

Description

A kind of relieving cough and reducing sputum health filter-tip of cigarette compound adsorbent and preparation method thereof
Technical field
The present invention relates to cigarette filter tip materials field, be specifically related to a kind of relieving cough and reducing sputum health filter-tip of cigarette compound adsorbent and preparation method thereof.
Background technology
The diseases related caused along with smoking is more and more frequent, and the infringement of smoking to human body becomes common recognition.Main component tar, nicotine and CO etc. in cigarette smoke are all to human body poisonous and harmful, and wherein tar has carcinogenesis to people, and CO causes anoxic, and nicotine easily makes people produce dependence, can also benumb the respiratory center of people, cause angiocardiopathy etc.Filter tip can not only part harmful components in filtering flue gas, and can TPM in effectively catching cigarette mainstream flue gas, reduce tar content, reducing the harm of flue gas to health and environment, is therefore that cigarette is fallen Jiao, fallen harm and manage the most frequently used means to the improvement of cigarette filter tip materials.
At present, the filtering material generally used has Diacetate cellulose tow, polypropylene tows, active carbon, inorganic mineral fiber etc.Suitable filter tip material not only needs optionally to filter and adsorb the harmful substance in flue gas, reduce the stimulation of flue gas to oral cavity and the injury to health, also should be able to keep the mouthfeel of flue gas, retain harmless fragrance component, the development of filter tip material also has larger market prospects and practical value.
Summary of the invention
The object of this invention is to provide a kind of relieving cough and reducing sputum health filter-tip of cigarette compound adsorbent, energy high efficiency filter and the harmful substance of adsorbing in flue gas, reach the effect of falling Jiao, toxicity reduction.
The present invention is achieved by the following technical solutions:
A kind of relieving cough and reducing sputum health filter-tip of cigarette compound adsorbent, it is obtained by the raw material of following weight parts:
Polyvinyl alcohol 30-40, lily 3-5, balloonflower root 2-4, loguat leaf 2-4, konjaku flour 3-5, lauryl sodium sulfate 0.05-0.1, cornstarch 5-10, sodium alginate 3-5, silane coupling A-151 0.3-0.5, modified inorganic powder 5-10;
Described modified inorganic powder is obtained by the raw material of following weight parts: sodium-based montmorillonite 20-30, zeolite powder 4-6, citric acid 1-2, shitosan 0.1-0.2; Citric acid and shitosan add in suitable quantity of water by the preparation method of described modified inorganic powder, 60-80 DEG C is stirred until dissolve completely, more ultrasonic process 20-30min under adding sodium-based montmorillonite and the same temperature of zeolite powder, after filtration, filtration cakes torrefaction is complete, grinding evenly, to obtain final product.
A preparation method for relieving cough and reducing sputum health filter-tip of cigarette compound adsorbent, comprises the following steps:
(1) lily, balloonflower root, loguat leaf and lauryl sodium sulfate are added first 70-80 DEG C of stirring 6-8h in suitable quantity of water, ultrasonic process 10-20min again, cooled and filtered removing filter residue, mix and stirring at normal temperature 4-6h with modified inorganic powder after the filtrate obtained is fully concentrated, complete in 70-80 DEG C of drying after filtration, obtain active powder after grinding evenly;
(2) first press solid-liquid weight ratio 1:15-1:20 polyvinyl alcohol and sodium alginate are mixed with water, 85-95 DEG C is stirred until dissolve completely, then the active powder added in cornstarch, konjaku flour and (1) stirs 2-4h at same temperature, 10-15min is stirred under adding the same temperature of silane coupling A-151 again, finally add the BAS solidification process 12-24h of appropriate calcium chloride, obtain adsorbent matrix, the every 100mL of BAS of described calcium chloride contains 4g boric acid, 5g calcium chloride;
(3) by the adsorbent matrix use water cleaning for several times postlyophilization in (2), pulverizes and grind even after namely obtain cigarette filter compound adsorbent.
Advantage of the present invention is:
Using polyvinyl alcohol, cornstarch, konjaku flour and sodium alginate as base material, with the inorganic particle compound of carrying active composition, first obtain the gel with grid cross-linked structure by solidification process, and the compatibility of gel and oils is improved with silane coupling A-151 modification, improve its adsorption capacity to tar ingredients in flue gas; High hole adsorbing base is obtained again by freeze drying, the compound adsorbent with high-specific surface area, high absorption property is obtained finally by pulverizing milled processed, pass through the composite of active component simultaneously, make this compound adsorbent can high efficiency filter and absorption flue gas in harmful substance, reach the effect of falling Jiao, toxicity reduction, keep the mouthfeel of flue gas simultaneously, also there is mental-tranquilization, moisten the lung and relieve the cough, effect that relieve sore throat eliminates the phlegm, there is good health-care efficacy.
Detailed description of the invention
Non-limiting examples of the present invention is as follows:
A kind of relieving cough and reducing sputum health filter-tip of cigarette compound adsorbent, is prepared from by the component raw material of following weight (kg):
Polyvinyl alcohol 35, lily 4, balloonflower root 3, loguat leaf 3, konjaku flour 4, lauryl sodium sulfate 0.08, cornstarch 8, sodium alginate 4, silane coupling A-151 0.4, modified inorganic powder 8;
Described modified inorganic powder is obtained by the raw material of following weight parts: sodium-based montmorillonite 25, zeolite powder 5, citric acid 1.5, shitosan 0.15; Citric acid and shitosan add in suitable quantity of water by the preparation method of described modified inorganic powder, 80 DEG C are stirred until dissolve completely, more ultrasonic process 20min under adding sodium-based montmorillonite and the same temperature of zeolite powder, after filtration, filtration cakes torrefaction is complete, grinding evenly, to obtain final product.
The preparation method of relieving cough and reducing sputum health filter-tip of cigarette compound adsorbent comprises the following steps:
(1) lily, balloonflower root, loguat leaf and lauryl sodium sulfate are added first 80 DEG C of stirring 6h in suitable quantity of water, ultrasonic process 10min again, cooled and filtered removing filter residue, mix and stirring at normal temperature 4h with modified inorganic powder after the filtrate obtained is fully concentrated, complete in 80 DEG C of dryings after filtration, obtain active powder after grinding evenly;
(2) first press solid-liquid weight ratio 1:15 polyvinyl alcohol and sodium alginate are mixed with water, 95 DEG C are stirred until dissolve completely, then the active powder added in cornstarch, konjaku flour and (1) stirs 2h at same temperature, 10min is stirred under adding the same temperature of silane coupling A-151 again, finally add the BAS solidification process 12h of appropriate calcium chloride, obtain adsorbent matrix, wherein the every 100mL of the BAS of calcium chloride is containing 4g boric acid, 5g calcium chloride;
(3) by the adsorbent matrix use water cleaning for several times postlyophilization in (2), pulverizes and grind even after namely obtain cigarette filter compound adsorbent.
Before filter tip acetate fibres beam forming, by above-mentioned obtained adsorbent by fibre weight 20% addition be evenly sprinkling upon on the synnema of filter stick, be prepared into cigarette filter rod.Smoking result shows, sorbing material does not cause original suction taste style to change, and tarry matters in smoke reduction simultaneously 51%, nitrosamine reduction by 63%, CO reduce by 32%.

Claims (2)

1. a relieving cough and reducing sputum health filter-tip of cigarette compound adsorbent, is characterized in that, it is obtained by the raw material of following weight parts:
Polyvinyl alcohol 30-40, lily 3-5, balloonflower root 2-4, loguat leaf 2-4, konjaku flour 3-5, lauryl sodium sulfate 0.05-0.1, cornstarch 5-10, sodium alginate 3-5, silane coupling A-151 0.3-0.5, modified inorganic powder 5-10;
Described modified inorganic powder is obtained by the raw material of following weight parts: sodium-based montmorillonite 20-30, zeolite powder 4-6, citric acid 1-2, shitosan 0.1-0.2; Citric acid and shitosan add in suitable quantity of water by the preparation method of described modified inorganic powder, 60-80 DEG C is stirred until dissolve completely, more ultrasonic process 20-30min under adding sodium-based montmorillonite and the same temperature of zeolite powder, after filtration, filtration cakes torrefaction is complete, grinding evenly, to obtain final product.
2. the preparation method of a kind of relieving cough and reducing sputum health filter-tip of cigarette compound adsorbent according to claim 1, is characterized in that, comprise the following steps:
(1) lily, balloonflower root, loguat leaf and lauryl sodium sulfate are added first 70-80 DEG C of stirring 6-8h in suitable quantity of water, ultrasonic process 10-20min again, cooled and filtered removing filter residue, mix and stirring at normal temperature 4-6h with modified inorganic powder after the filtrate obtained is fully concentrated, complete in 70-80 DEG C of drying after filtration, obtain active powder after grinding evenly;
(2) first press solid-liquid weight ratio 1:15-1:20 polyvinyl alcohol and sodium alginate are mixed with water, 85-95 DEG C is stirred until dissolve completely, then the active powder added in cornstarch, konjaku flour and (1) stirs 2-4h at same temperature, 10-15min is stirred under adding the same temperature of silane coupling A-151 again, finally add the BAS solidification process 12-24h of appropriate calcium chloride, obtain adsorbent matrix, the every 100mL of BAS of described calcium chloride contains 4g boric acid, 5g calcium chloride;
(3) by the adsorbent matrix use water cleaning for several times postlyophilization in (2), pulverizes and grind even after namely obtain relieving cough and reducing sputum cigarette filter compound adsorbent.
CN201510300510.5A 2015-06-05 2015-06-05 Healthcare cigarette filter tip composite adsorbent with functions of relieving cough and reducing sputum and preparation method thereof Pending CN104905409A (en)

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CN201510300510.5A CN104905409A (en) 2015-06-05 2015-06-05 Healthcare cigarette filter tip composite adsorbent with functions of relieving cough and reducing sputum and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105686079A (en) * 2016-03-07 2016-06-22 云南瑞升烟草技术（集团）有限公司 Preparation method of paper filter material capable of reducing gas-phase free radicals in smoke
CN105768212A (en) * 2016-03-29 2016-07-20 陈虎昌 Degradable konjac filter tip and production process thereof
CN112717890A (en) * 2020-12-03 2021-04-30 云南中烟工业有限责任公司 Baked fermented plant konjac glucomannan composite porous particle, preparation method and application thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059267A (en) * 1990-08-25 1992-03-11 长春冶金地质专科学校 Specific adsorbent of cigarette tar and production technology
WO2007086078A2 (en) * 2006-01-30 2007-08-02 Panacea Biotec Ltd. Novel pharmaceutical compositions and process of preparation thereof
CN102090718A (en) * 2010-09-15 2011-06-15 张锐 Cigarette filtering agent for protecting health, relieving cough and refreshing
CN102090720A (en) * 2010-09-15 2011-06-15 张锐 Cigarette filtering agent for health care, body strengthening and cough relief
CN102090719A (en) * 2010-09-15 2011-06-15 张锐 Cigarette filtering agent for protecting health, strengthening body, relieving cough and moisturizing throat
CN103566882A (en) * 2013-09-29 2014-02-12 安徽金叶炭素科技有限公司 High-adsorptivity modified activated carbon and preparation method thereof
CN103584281A (en) * 2013-11-25 2014-02-19 湖北中烟工业有限责任公司 Cigarette filter tip and manufacturing method thereof
CN104437371A (en) * 2014-11-20 2015-03-25 安徽天泰环保科技有限公司 Composite porous activated carbon flue gas adsorbent and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059267A (en) * 1990-08-25 1992-03-11 长春冶金地质专科学校 Specific adsorbent of cigarette tar and production technology
WO2007086078A2 (en) * 2006-01-30 2007-08-02 Panacea Biotec Ltd. Novel pharmaceutical compositions and process of preparation thereof
CN102090718A (en) * 2010-09-15 2011-06-15 张锐 Cigarette filtering agent for protecting health, relieving cough and refreshing
CN102090720A (en) * 2010-09-15 2011-06-15 张锐 Cigarette filtering agent for health care, body strengthening and cough relief
CN102090719A (en) * 2010-09-15 2011-06-15 张锐 Cigarette filtering agent for protecting health, strengthening body, relieving cough and moisturizing throat
CN103566882A (en) * 2013-09-29 2014-02-12 安徽金叶炭素科技有限公司 High-adsorptivity modified activated carbon and preparation method thereof
CN103584281A (en) * 2013-11-25 2014-02-19 湖北中烟工业有限责任公司 Cigarette filter tip and manufacturing method thereof
CN104437371A (en) * 2014-11-20 2015-03-25 安徽天泰环保科技有限公司 Composite porous activated carbon flue gas adsorbent and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105686079A (en) * 2016-03-07 2016-06-22 云南瑞升烟草技术（集团）有限公司 Preparation method of paper filter material capable of reducing gas-phase free radicals in smoke
CN105768212A (en) * 2016-03-29 2016-07-20 陈虎昌 Degradable konjac filter tip and production process thereof
CN112717890A (en) * 2020-12-03 2021-04-30 云南中烟工业有限责任公司 Baked fermented plant konjac glucomannan composite porous particle, preparation method and application thereof

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