CN108157613A - A kind of polysaccharide fermentation montmorillonite and preparation method thereof, application - Google Patents

A kind of polysaccharide fermentation montmorillonite and preparation method thereof, application Download PDF

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Publication number
CN108157613A
CN108157613A CN201810143809.8A CN201810143809A CN108157613A CN 108157613 A CN108157613 A CN 108157613A CN 201810143809 A CN201810143809 A CN 201810143809A CN 108157613 A CN108157613 A CN 108157613A
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parts
montmorillonite
extract
biology
core material
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吕宏刚
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Herd International Agricultural Group Co Ltd
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Herd International Agricultural Group Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/20Inorganic substances, e.g. oligoelements
    • A23K20/28Silicates, e.g. perlites, zeolites or bentonites
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K10/00Animal feeding-stuffs
    • A23K10/30Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/10Organic substances
    • A23K20/163Sugars; Polysaccharides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/10Organic substances
    • A23K20/189Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/20Inorganic substances, e.g. oligoelements
    • A23K20/30Oligoelements
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • A23L5/273Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption using adsorption or absorption agents, resins, synthetic polymers, or ion exchangers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/80Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
    • Y02P60/87Re-use of by-products of food processing for fodder production

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Animal Husbandry (AREA)
  • Zoology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Molecular Biology (AREA)
  • Mycology (AREA)
  • Physiology (AREA)
  • Fodder In General (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention discloses a kind of polysaccharide fermentation montmorillonite, its key points of the technical solution are that according to the mass fraction, SiO256 60 parts, Al2O318 22 parts, Fe2O33.8 4.2 parts, 2.8 3.2 parts of CaO, 0.8 1.2 parts of MgO, K20.4 0.6 parts of O, 1.5 2.5 parts of manna oligosacchride, 1.5 2.5 parts of beta glucan, biology block 4.5 5.5 parts of core material, reach and stringenter restriction is carried out to natural smectite, is selected, and the cooperation of core material is blocked with polysaccharide and biology, montmorillonite obtained is allowed to have the function of preferably to adsorb and block mould, meet the requirement used in feed, make feed safer, it is more healthy after livestock edible.

Description

A kind of polysaccharide fermentation montmorillonite and preparation method thereof, application
Technical field
The present invention relates to montmorillonite processing technique field, more particularly to a kind of polysaccharide fermentation montmorillonite and preparation method thereof, Using.
Background technology
Mineral name, also referred to as.Montmorillonite, montmorillonite.It is by igneous rock alterations in alkaline environment such as volcano condensation rocks The bentonitic chief component formed.
The existing Chinese patent that can refer to Publication No. CN105192325A, it discloses a kind of montmorillonites of livestock and poultry Expect agent, which is made of the raw material that following weight parts match:100 parts of natural smectite, 10-50 parts of salt, carboxylic first 0.2-0.8 part of base sodium cellulosate, 20-30 parts of water.
All it is to be sold by natural smectite to be processed mostly in practical montmorillonite manufacture field, but this Kind of mode will especially influence different batches, different sources montmorillonite product quality, montmorillonite product is difficult to accomplish have Uniform quality, using effect also are difficult to ensure.Therefore how montmorillonite is preferably limited, is allowed per a batch of natural illiteracy It is that all montmorillonite fields have the problem of to be solved that de- stone, which all has better adsorption function,.
Invention content
The object of the present invention is to provide a kind of polysaccharide fermentation montmorillonites, play and stringenter limit is carried out to natural smectite Determine, select, and the cooperation of core material is blocked with polysaccharide and biology, allow montmorillonite obtained that there is better absorption and block mould Function, meet the requirement used in feed, make feed safer, it is more healthy after livestock edible.
The present invention above-mentioned technical purpose technical scheme is that:A kind of polysaccharide fermentation montmorillonite, According to the mass fraction, SiO256-60 parts, Al2O318-22 parts, Fe2O33.8-4.2 parts, 2.8-3.2 parts of CaO, MgO 0.8- 1.2 parts, K20.4-0.6 parts of O, 1.5-2.5 parts of manna oligosacchride, 1.5-2.5 parts of beta glucan, biology block core material 4.5-5.5 Part.
Through the above technical solutions, carrying out stringenter restriction to natural smectite, selecting, and hindered with polysaccharide and biology The cooperation of disconnected core material allows montmorillonite obtained to have the function of preferably to adsorb and block mould, meets and used in feed Requirement, make feed safer, it is more healthy after livestock edible.
Preferably, biology blocks core material to include mycotoxin catabolic enzyme, Chinese herbal medicine extract, mycotoxin catabolic enzyme Mass ratio with Chinese herbal medicine extract is 3:2.
Preferably, include corter pseudolaricis extract, dwarf sheareria herb extract, citrus bark extract, fourth in Chinese herbal medicine extract Fragrant extract.
Preferably, in Chinese herbal medicine extract, corter pseudolaricis extract, dwarf sheareria herb extract, citrus bark extract, cloves extraction The mass ratio of object is 2:1:1:1.
Preferably, SiO258 parts, Al2O320 parts, Fe2O34 parts, 3 parts of CaO, 1 part of MgO, K20.5 part of O, sweet dew are few 1.5 parts of sugar, 1.5 parts of beta glucan, biology block 5 parts of core material.
Preferably, SiO258 parts, Al2O320 parts, Fe2O34 parts, 3 parts of CaO, 1 part of MgO, K20.5 part of O, sweet dew are few 2.5 parts of sugar, 2.5 parts of beta glucan, biology block 5.5 parts of core material.Vomitoxin is preferably, SiO258 parts, Al2O320 parts, Fe2O34 parts, 3 parts of CaO, 1 part of MgO, K20.5 part of O, 2 parts of manna oligosacchride, 2 parts of beta glucan, biology block core material 5.5 Part.
The purpose of the present invention two:A kind of application of polysaccharide fermentation montmorillonite in field of fodder.
The purpose of the present invention three:A kind of preparation method of polysaccharide fermentation montmorillonite, includes the following steps:
S1:The montmorillonite mineral of Chifeng area is chosen as montmorillonite raw material, selects the day that montmorillonite meets claim 1 requirement Right montmorillonite;
S2:Selection by winnowing cleans, and processing is blowed to the montmorillonite raw material selected using hair-dryer, understands sundries, dust;
S3:Montmorillonite after cleaning is carried out to the particle tentatively broken, acquisition granularity is 0.3-0.5cm;
S4:Using wet purification, purification processes are carried out to montmorillonite;
S5:Montmorillonite after purification carries out natural drying processing, makes its water tariff collection in 20%-30%;
S6:The S5 montmorillonites obtained are dried between 80-90 DEG C, after drying, montmorillonite moisture reaches 7%-9%;
S7:Pressure is processed using Raymond machine to the montmorillonite obtained in S6, allows the granularity of montmorillonite in 200-600 mesh;
S8:Proportionally addition polysaccharide component and biology block core material;
S9:The detection of ingredient, water content, granularity, content of beary metal is carried out to product, after data fit requirement, packing and storing.
In conclusion the invention has the advantages that:
1st, montmorillonite contains macro- and trace-element necessary to the animal growths such as Mg, Al, K, Ca, Fe, in supplement trace While element, enzyme and hormone in animal alimentary canal can also be activated;
2nd, the component cooperation in the present invention has very strong adsorption capacity, germ is made to be easier to be adsorbed between montmorillonite layer, no Only there is effect, and feed nutrient can be made fully to be contacted with animal intestinal mucosa to prevention enterogastric diseases, feed can be effectively improved Utilization rate and digestibility;
3rd, the montmorillonite in the present invention realizes effective place of mycotoxin by physics, biological adsorption and blocking agent collective effect Reason;
4th, raw material mycotoxin because of caused by fermentation process is reduced to endanger;
5th, increase raw material free-running property, improve the finished product rate of recovery;
6th, the speed of growth and health status of raising animal are promoted.
Specific embodiment
The present invention is described in further detail below.
Embodiment 1, a kind of polysaccharide fermentation montmorillonite, based on quality Kg numbers, SiO260Kg、Al2O3 22Kg、Fe2O34.2Kg、 CaO 3.2Kg、MgO 1.2Kg、K2O 0.6Kg, manna oligosacchride 2.5Kg, beta glucan 2.5Kg, biology block core material 5.5Kg, biology block core material to include mycotoxin catabolic enzyme, Chinese herbal medicine extract, mycotoxin catabolic enzyme and Chinese herbal medicine The mass ratio of extract is 3:2, in Chinese herbal medicine extract, corter pseudolaricis extract, dwarf sheareria herb extract, citrus bark extract matter Amount is than being 2:1:1:1.
Embodiment 2, a kind of polysaccharide fermentation montmorillonite, based on quality Kg numbers, SiO2 56Kg、Al2O3 18Kg、Fe2O3 3.8Kg、CaO 2.8Kg、MgO 0.8Kg、K2O 0.4Kg, manna oligosacchride 1.5Kg, beta glucan 1.5Kg, biology block core Expect 4.5Kg, biology blocks core material to include mycotoxin catabolic enzyme, Chinese herbal medicine extract, mycotoxin catabolic enzyme and medium-height grass The mass ratio of medicament extract is 3:2, in Chinese herbal medicine extract, corter pseudolaricis extract, dwarf sheareria herb extract, citrus bark extract Mass ratio is 2:1:1:1.
Embodiment 3, a kind of polysaccharide fermentation montmorillonite, based on quality Kg numbers, SiO2 58Kg、Al2O3 20Kg、Fe2O3 4Kg、 CaO3Kg、MgO 1Kg、K2O 0.5Kg, manna oligosacchride 2Kg, beta glucan 2Kg, biology block core material 5Kg, and biology blocks core Heart material includes mycotoxin catabolic enzyme, Chinese herbal medicine extract, and the mass ratio of mycotoxin catabolic enzyme and Chinese herbal medicine extract is 3:2, in Chinese herbal medicine extract, corter pseudolaricis extract, dwarf sheareria herb extract, citrus bark extract mass ratio be 2:1:1:1.
Embodiment 4, a kind of polysaccharide fermentation montmorillonite according to claim 1, SiO2 58Kg、Al2O3 20Kg、 Fe2O3 4Kg、CaO 3Kg、MgO 1Kg、K2O 0.5Kg, manna oligosacchride 1.5Kg, beta glucan 1.5Kg, biology block core material 5Kg, biology block core material 5Kg, and biology blocks core material to include mycotoxin catabolic enzyme, Chinese herbal medicine extract, mould poison The mass ratio of plain catabolic enzyme and Chinese herbal medicine extract is 3:2, in Chinese herbal medicine extract, corter pseudolaricis extract, dwarf sheareria herb extract, The mass ratio of citrus bark extract is 2:1:1:1.
Embodiment 5, SiO2 58Kg、Al2O3 20Kg、Fe2O3 4Kg、CaO 3Kg、MgO 1Kg、K2O 0.5Kg, sweet dew are few Sugared 2.5Kg, beta glucan 2.5Kg, biology block core material 5.5Kg, biology block core material include mycotoxin catabolic enzyme, The mass ratio of Chinese herbal medicine extract, mycotoxin catabolic enzyme and Chinese herbal medicine extract is 3:2, in Chinese herbal medicine extract, corter pseudolaricis Extract, dwarf sheareria herb extract, citrus bark extract mass ratio be 2:1:1:1.
Embodiment 6, SiO2 58Kg、Al2O3 20Kg、Fe2O3 4Kg、CaO 3Kg、MgO 1Kg、K2O 0.5Kg, sweet dew are few Sugared 2Kg, beta glucan 2Kg, biology block core material 5.5Kg, and biology blocks core material to include mycotoxin catabolic enzyme, medium-height grass The mass ratio of medicament extract, mycotoxin catabolic enzyme and Chinese herbal medicine extract is 3:2, in Chinese herbal medicine extract, corter pseudolaricis extraction Object, dwarf sheareria herb extract, citrus bark extract mass ratio be 2:1:1:1.
Preparation example 1:A kind of preparation method of polysaccharide fermentation montmorillonite, includes the following steps:
S1:The montmorillonite mineral of Chifeng area is chosen as montmorillonite raw material, selects the natural smectite for meeting embodiment requirement;
S2:Selection by winnowing cleans, and processing is blowed to the montmorillonite raw material selected using hair-dryer, understands sundries, dust;
S3:Montmorillonite after cleaning is carried out to the particle tentatively broken, acquisition granularity is 0.3-0.5cm;
S4:Using wet purification, purification processes are carried out to montmorillonite;
S5:Montmorillonite after purification carries out natural drying processing, makes its water tariff collection in 20%-30%;
S6:The S5 montmorillonites obtained are dried between 85 DEG C, montmorillonite moisture is up to 8% after drying;
S7:Pressure is processed using Raymond machine to the montmorillonite obtained in S6, allows the granularity of montmorillonite in 400 mesh;
S8:Proportionally addition polysaccharide component and biology block core material;
S9:The detection of ingredient, water content, granularity, content of beary metal is carried out to product, after data fit requirement, packing and storing.
Comparative example 1:It is crushed and is added as in feed using natural smectite.
Adsorption experiment
Adsorption experiment is referring in particular to GB13078-2001, GB13078.3-2007, GB13078.2-2006, adsorbance unit Ppb, adsorbance experimental period is 72 hours during content of toxins 50ppb, Ph difference.
Table one is each embodiment and comparative example adsorbance after different PH and different adsorption times and adsorption rate statistical form.
Ph6 adsorption rates Ph6 adsorbances Ph5 adsorbances Ph5 adsorption rates Adsorbance after 6h Adsorption rate after 6h
Embodiment 1 0.9352 46.76 46.81 0.9362 36.21 0.7242
Embodiment 2 0.9334 46.67 46.79 0.9358 36.57 0.7314
Embodiment 3 0.9302 46.51 46.78 0.9356 35.93 0.7186
Embodiment 4 0.9368 46.84 46.76 0.9352 36.46 0.7292
Embodiment 5 0.9442 47.21 46.75 0.9350 36.06 0.7212
Embodiment 6 0.9378 46.89 46.77 0.9354 35.79 0.7158
Comparative example 1 0.8550 42.75 42.10 0.8420 31.89 0.6378
Table two is the adsorbance statistical form of each embodiment and comparative example when toxin difference.
Aflatoxin b1 adsorbances Vomitoxin adsorbance Zearalenone adsorbance
Embodiment 1 46.74 47.34 46.85
Embodiment 2 46.38 46.23 47.51
Embodiment 3 47.72 46.18 46.67
Embodiment 4 49.90 45.46 46.42
Embodiment 5 45.21 49.34 45.85
Embodiment 6 46.21 45.31 48.79
Comparative example 1 42.06 41.31 40.73
By above-mentioned two table it can be found that in the case of slightly sour, each embodiment has good adsorption effect, Therefore the montmorillonite in the invention is suitable for various fermented type feeds;It is de- when covering simultaneously in montmorillonite is adjusted after each ingredient When stone is in the state of embodiment 4, montmorillonite has good adsorption effect to aflatoxin b1;And implement when montmorillonite is in During the state of example 5, montmorillonite has good adsorption effect to vomitoxin;When montmorillonite is in the state of embodiment 6, cover De- stone has zearalenone good adsorption effect.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, people in the art Member can as needed make the present embodiment the modification of no creative contribution after this specification is read, but as long as at this It is all protected in the right of invention by Patent Law.

Claims (9)

1. a kind of polysaccharide fermentation montmorillonite, it is characterised in that:According to the mass fraction, SiO256-60 parts, Al2O318-22 parts, Fe2O33.8-4.2 parts, 2.8-3.2 parts of CaO, 0.8-1.2 parts of MgO, K20.4-0.6 parts of O, 1.5-2.5 parts of manna oligosacchride, β- 1.5-2.5 parts of glucan, biology block 4.5-5.5 parts of core material.
2. a kind of polysaccharide fermentation montmorillonite according to claim 1, it is characterised in that:It is mould that biology blocks core material to include The mass ratio of verticillium toxin catabolic enzyme, Chinese herbal medicine extract, mycotoxin catabolic enzyme and Chinese herbal medicine extract is 3:2.
3. a kind of polysaccharide fermentation montmorillonite according to claim 2, it is characterised in that:Include soil in Chinese herbal medicine extract Rose of Sharon bark extract, dwarf sheareria herb extract, citrus bark extract, Flos Caryophylli extract.
4. a kind of polysaccharide fermentation montmorillonite according to claim 3, it is characterised in that:In Chinese herbal medicine extract, corter pseudolaricis Extract, dwarf sheareria herb extract, citrus bark extract, Flos Caryophylli extract mass ratio be 2:1:1:1.
5. a kind of polysaccharide fermentation montmorillonite according to claim 1, it is characterised in that:SiO258 parts, Al2O320 parts, Fe2O34 parts, 3 parts of CaO, 1 part of MgO, K20.5 part of O, 1.5 parts of manna oligosacchride, 1.5 parts of beta glucan, biology block core material 5 parts.
6. a kind of polysaccharide fermentation montmorillonite according to claim 1, it is characterised in that:SiO258 parts, Al2O320 parts, Fe2O34 parts, 3 parts of CaO, 1 part of MgO, K20.5 part of O, 2.5 parts of manna oligosacchride, 2.5 parts of beta glucan, biology block core material 5.5 part.
7. a kind of polysaccharide fermentation montmorillonite according to claim 1, it is characterised in that:SiO258 parts, Al2O320 parts, Fe2O34 parts, 3 parts of CaO, 1 part of MgO, K20.5 part of O, 2 parts of manna oligosacchride, 2 parts of beta glucan, biology block core material 5.5 Part.
8. a kind of application of the polysaccharide fermentation montmorillonite in field of fodder as described in claim 1-7.
9. a kind of preparation method of the polysaccharide fermentation montmorillonite as described in claim 1-7, it is characterised in that:Include the following steps:
S1:The montmorillonite mineral of Chifeng area is chosen as montmorillonite raw material, selects the day that montmorillonite meets claim 1 requirement Right montmorillonite;
S2:Selection by winnowing cleans, and processing is blowed to the montmorillonite raw material selected using hair-dryer, understands sundries, dust;
S3:Montmorillonite after cleaning is carried out to the particle tentatively broken, acquisition granularity is 0.3-0.5cm;
S4:Using wet purification, purification processes are carried out to montmorillonite;
S5:Montmorillonite after purification carries out natural drying processing, makes its water tariff collection in 20%-30%;
S6:The S5 montmorillonites obtained are dried between 80-90 DEG C, after drying, montmorillonite moisture reaches 7%-9%;
S7:Pressure is processed using Raymond machine to the montmorillonite obtained in S6, allows the granularity of montmorillonite in 200-600 mesh;
S8:Proportionally addition polysaccharide component and biology block core material;
S9:The detection of ingredient, water content, granularity, content of beary metal is carried out to product, after data fit requirement, packing and storing.
CN201810143809.8A 2018-02-11 2018-02-11 A kind of polysaccharide fermentation montmorillonite and preparation method thereof, application Pending CN108157613A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112602845A (en) * 2020-12-15 2021-04-06 湖南惠生农业科技开发股份有限公司 Premix and complete feed for nursery pigs
CN112641004A (en) * 2020-12-15 2021-04-13 湖南惠生农业科技开发股份有限公司 Core feed and creep feed for piglets
CN112641005A (en) * 2020-12-15 2021-04-13 湖南惠生农业科技开发股份有限公司 Growing-finishing pig premix and complete feed

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Publication number Priority date Publication date Assignee Title
CN103141685A (en) * 2013-03-12 2013-06-12 北京翰赛柯生物科技有限公司 Mycotoxin detoxication agent for swine feed
CN103875917A (en) * 2012-12-20 2014-06-25 信宜市金方子生物科技有限公司 Feed mildew-removal agent used for livestock
CN104116001A (en) * 2013-04-27 2014-10-29 天津瑞贝特科技发展有限公司 Feed additive capable of reducing mycotoxin and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103875917A (en) * 2012-12-20 2014-06-25 信宜市金方子生物科技有限公司 Feed mildew-removal agent used for livestock
CN103141685A (en) * 2013-03-12 2013-06-12 北京翰赛柯生物科技有限公司 Mycotoxin detoxication agent for swine feed
CN104116001A (en) * 2013-04-27 2014-10-29 天津瑞贝特科技发展有限公司 Feed additive capable of reducing mycotoxin and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112602845A (en) * 2020-12-15 2021-04-06 湖南惠生农业科技开发股份有限公司 Premix and complete feed for nursery pigs
CN112641004A (en) * 2020-12-15 2021-04-13 湖南惠生农业科技开发股份有限公司 Core feed and creep feed for piglets
CN112641005A (en) * 2020-12-15 2021-04-13 湖南惠生农业科技开发股份有限公司 Growing-finishing pig premix and complete feed

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Application publication date: 20180615