CN203883782U - A thin film bulk acoustic wave resonator used for ultraviolet detection - Google Patents
A thin film bulk acoustic wave resonator used for ultraviolet detection Download PDFInfo
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- CN203883782U CN203883782U CN201420295036.2U CN201420295036U CN203883782U CN 203883782 U CN203883782 U CN 203883782U CN 201420295036 U CN201420295036 U CN 201420295036U CN 203883782 U CN203883782 U CN 203883782U
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Abstract
The utility model discloses a thin film bulk acoustic wave resonator used for ultraviolet detection. The thin film bulk acoustic wave resonator used for the ultraviolet detection comprises a piezoelectric vibration pile and an acoustic wave reflecting layer stacked on a same substrate to be integrated into one body. The piezoelectric vibration pile comprises a bottom electrode, a piezoelectric layer and a top electrode which are sequentially deposited from the bottom up. Materials for the top electrode are a metal thin film which is with ultraviolet transmissivity and which can from a Schottky junction with the piezoelectric layer, and convenience is provided for ultraviolet light to penetrate through the top electrode to irradiate on the piezoelectric layer. When the ultraviolet light irradiates on the top electrode, electron-hole pairs can be induced by light quantum to appear in a ZnO depletion zone; concentration of carriers in the materials is raised; and diffusing speed of bulk acoustic waves in the piezoelectric vibration pile is lowered, so that resonant frequency of the thin film bulk acoustic wave resonator changes. The thin film bulk acoustic wave resonator used for the ultraviolet detection in the utility model is relatively small in size, low in manufacturing costs, simple in preparation technology and can be used repeatedly.
Description
Technical field
The utility model relates to a kind of thin film bulk acoustic resonator for ultraviolet detection, belongs to microelectronics technology.
Background technology
Ultraviolet detection is emerging Detection Techniques that grow up after infrared acquisition and laser acquisition, can be widely used in the fields such as scientific research, military affairs, environmental protection, medical treatment.Military aspect, as far back as 20th century six the seventies, the U.S. has just started to survey at ultraviolet band the research work of intercontinental missile transmitting, and obtains certain progress.First ultraviolet ray alarm device AAR-47 is used for the C-130S of USN helicopter and P-3S transporter in the world, and drops in the Gulf War in 1991, and various countries are actively in the development of new ultra-violet detector at present.Civilian aspect, ultraviolet detection has been used to detection of gas and analysis, flame sensing, pollution monitoring, mercury sterilization, engine and boiler are controlled (for identifying the ultraviolet ray of hot background).
Along with social development, people more and more pay close attention to radiation and the measurement of ultraviolet light, growing to the demand of ultraviolet detector.At present extensive use be ultraviolet detector prepared by photon detection principle, existing ultraviolet detector mainly faces the difficulty of 3 aspects: first, the silicon device of solid probe, has the light frequency response range beyond ultraviolet band; Secondly, in semiconductor the production of charge carrier and recombination time longer, make the sensitivity of ultraviolet detector lower; Finally, photo-generated carrier is very little for the change amount of electric current, needs high and small detection system to carry out sensed current signal.
Thin film bulk acoustic resonator (FBAR) due to its high operate frequency, high quality factor (Q value), low-temperature coefficient, high power bearing capacity, can be integrated and feature that volume is little, earn widespread respect in recent years, and be widely used at wireless communication field.Because the resonance frequency of FBAR is relevant with the propagation velocity of bulk acoustic wave, utilize ultraviolet ray to be radiated in effective coverage, make the inner electron hole pair that produces of semiconductor, change the concentration of the inner charge carrier of semiconductor, reduce its resistance and sound velocity of wave propagation, use it for ultraviolet detection.The people such as X.Qiu of the vertical university of State of Arizona, US are at " Film bulk acoustic wave resonator (FBAR) based ultraviolet sensor " (Solid-State sensors, Actuators and Microsystems Conference, 2009. Transducers 2009, mentioning in International) and using ZnO film bulk acoustic wave resonator is 600 in 365nm, intensity
under the irradiation of ultraviolet light, frequency offset is 9.8KHz, for detection of uitraviolet intensity under be limited to 6.5nW, this studies have shown that the feasibility of the FBAR of use based on ZnO film for ultraviolet detection, but the Au of this use 200nm is as the method for top electrode, make ultraviolet penetration capacity become very faint, as ultraviolet detection, use, its sensitivity is less.
Generally speaking, Modern Communication System is to miniaturization, integrated, intensive multiplexingization future development, with low cost, simple operations, can integrated mode realize high-quantum efficiency, large area, high-resolution, wide dynamic range, at a high speed, low noise, response wave length completely the ultraviolet detector in ultraviolet spectra become a kind of urgent demand.Therefore, need the FBAR of little, simple in structure, the high Q value of a kind of volume for ultraviolet detection.
Utility model content
Object: in order to overcome the deficiencies in the prior art, the utility model provides a kind of thin film bulk acoustic resonator for ultraviolet detection can improve and maintain voltage under the prerequisite that does not affect protective device trigger voltage, avoids latch-up.
Technical scheme: for solving the problems of the technologies described above, the technical solution adopted in the utility model is:
A thin film bulk acoustic resonator for ultraviolet detection, is characterized in that: comprise and be stacked on continuously piezoelectric vibration heap and the acoustic reflection layer becoming one on same substrate; Wherein, piezoelectric vibration heap comprises from bottom to top hearth electrode, piezoelectric layer and the top electrode of deposition successively; The material of described top electrode is have ultraviolet transmission and can form the metallic film of schottky junction with piezoelectric layer, is convenient to ultraviolet light and is radiated on piezoelectric layer through top electrode;
Described acoustic reflection layer comprises that the supporting layer, the piezoelectric vibration heap that on substrate, substrate, deposit are deposited on supporting layer; Described acoustic reflection layer is air-gap structure or Bragg reflecting layer structure or back of the body chamber etching structure; When acoustic reflection layer is for back of the body chamber etching structure, on described substrate, be provided with the air chamber that etching forms.
The material of described piezoelectric layer is ZnO, and thickness is 500-5000nm.
The transmissivity at ultraviolet band of described top electrode metallic film is greater than 60%.
The material of described hearth electrode is Al or Au, and thickness is 10-300nm.
The material of described top electrode is the Ag of lattice-shaped structure, adopts the mode of direct current reaction magnetron sputtering or radio frequency reaction magnetron sputtering to deposit formation, and thickness is 50-150nm.
The material of described top electrode can be also Au, adopts the mode of electron beam evaporation or thermal evaporation to deposit formation, and thickness is 5-50nm.
The utility model also provides the preparation method of the described thin film bulk acoustic resonator for ultraviolet detection, comprises the following steps: first use grow on the substrate supporting layer silicon dioxide of 100-500nm of the method for heat growth; Use the positive glue stripping technology of standard and the method plated metal hearth electrode of electron beam evaporation thereupon; Then adopt the method growth piezoelectric layer thin film ZnO of direct current reaction magnetron sputtering; Along with after piezoelectric film deposition finishes, substrate is carried out to the operation of short annealing for the first time, to increase the particle size of ZnO, reduce the interfacial state between hard power and rete of drawing between film; After annealing operation finishes, use the processing step identical with hearth electrode to form top electrode, and piezoelectric layer thin film is graphical, etch through hole, finally use the method for deep reaction ion etching to etch air chamber, form acoustic reflection layer with substrate and supporting layer.
Beneficial effect: the thin film bulk acoustic resonator for ultraviolet detection that the utility model provides, adopts broad stopband, visible light-responded minimum ZnO semi-conducting material.For second difficulty, by the method for repeatedly annealing, reduce the defect state of material internal and the interfacial state of material surface, simultaneously the hard power of material internal and the hard power between material and material.Make UV-irradiation at material surface, the frequency offset of resonator is larger.For the 3rd difficulty, solution is to adopt to see through largely the metal material of ultraviolet light or the electrode structure of lattice-shaped, and top electrode can form with piezoelectric membrane ZnO the metal material of schottky junction, make more ultraviolet light can see through the surface that top electrode is irradiated to piezoelectric ZnO, and ZnO material has the characteristic of oxygen uptake and oxygen release, under the irradiation of ultraviolet light, can make the frequency offset of resonator increase.There is integration, high Q value and improve photoresponse intensity and the semiconductor transducer of time, the preparation method of this semiconductor transducer is provided simultaneously.In the utility model, for the thin film bulk acoustic resonator of ultraviolet detection, adopt stacks of thin films structure, do not occupy in addition the area of substrate, cost-saving, and simple and reliable for structure, can be used for relating to the radio systems such as filter, duplexer of frequency band adjustments.
Have the following advantages: (1) is owing to adopting stacks of thin films structure, compare with external resolution element or integrated MEMS electric capacity, can reduce device size, reduce costs, simultaneously its volume is little, frequency is high, performance good, can be integrated etc. advantage can reach the frequency of radio circuit requirement, its preparation technology is relatively simple, can be all at Reusability.(2) for the transducer of ultraviolet detection, can under LVPS, work, the wave-length coverage of its detection, completely in ultraviolet spectra district, has higher sensitivity, high response characteristics to light, and strong, the reliable and stable life-span of antijamming capability is long, little power consumption.
Accompanying drawing explanation
Fig. 1 is the profile that adopts the thin-film body resonator of back of the body chamber etching knot in the utility model;
Fig. 2 is the vertical view of p-wave model FBAR in the utility model;
Fig. 3 is the XRD diffraction spectra of piezoelectric layer zinc-oxide film in the utility model;
Fig. 4 is the vertical view of the lattice-shaped electrode structure of employing in the utility model embodiment 1;
Fig. 5 is for the resolution chart of the FBAR device of ultraviolet detection in the utility model embodiment 2.
In figure: top electrode 101, piezoelectric layer 102, hearth electrode 103, supporting layer 104, substrate 105, air chamber 106, piezoelectric vibration heap 107, acoustic reflection layer 108.
Embodiment
Below in conjunction with accompanying drawing and embodiment, the utility model is described in further detail.Following instance is only for more clearly illustrating the technical solution of the utility model.
As depicted in figs. 1 and 2, be a kind of thin film bulk acoustic resonator for ultraviolet detection, be included in and on same substrate, be stacked into continuously piezoelectric vibration heap 107 and the acoustic reflection layer 108 being integrated; Wherein, piezoelectric vibration heap 107 comprises from bottom to top hearth electrode 103, piezoelectric layer 102 and the top electrode 101 of deposition successively; The material of described top electrode 101 is for having ultraviolet transmission and can forming with piezoelectric membrane ZnO the metallic film of schottky junction, be convenient to ultraviolet light and be radiated on piezoelectric layer 102 through metallic film, excite largely piezoelectric layer 102 to produce electron-hole pairs; Described acoustic reflection layer 108 comprises the supporting layer 104 depositing on substrate 105, substrate, and piezoelectric vibration heap is deposited on supporting layer 104; Described acoustic reflection layer 108 is air-gap structure or Bragg reflecting layer structure or back of the body chamber etching structure.Supporting layer 104 is for supporting piezoelectric vibration heap and for reducing the temperature drift of device.On described substrate, be provided with the air chamber 106 that etching forms.
The transmissivity at ultraviolet band of described metallic film is greater than 60%.
The material of described hearth electrode 103 is Al or Au, and thickness is 10-300nm;
The material of piezoelectric layer 102 is ZnO, and thickness is 500-5000nm.
Wherein, the thickness of top electrode is determined by the difference of material, if the material of top electrode is Au, adopts the mode of electron beam evaporation or thermal evaporation to deposit formation, and thickness is 5-50nm.If the metal material Ag that the employing of top electrode is common, and be the electrode structure of lattice-shaped, adopt the mode of magnetically controlled DC sputtering or electron beam evaporation to deposit formation, thickness is 50-150nm.
The circulation way of its sound wave can be horizontal transmission, longitudinal propagation or both mixing, different circulation ways is corresponding to its electrode at the different distributing position of piezoelectric layer, and the left and right that above-mentioned circulation way corresponds respectively to electrode distributes the homonymy of piezoelectric layer (), distributes up and down and interdigital structure.The mode that adopts electrode to distribute up and down in the present embodiment describes.
embodiment 1
In the present embodiment, hearth electrode 103 is metal material Al or the Au of thickness between 50-100nm, piezoelectric layer is the ZnO material of thickness between 1um-4um, top electrode is used and can form with piezoelectric membrane ZnO the metal A g of schottky junction, its thickness is 50-100nm, and top electrode adopts the electrode structure of lattice-shaped; Acoustic reflecting layer 108 adopts back of the body chamber etching structure, by air interface, limits sound wave in piezoelectric vibration heap; On substrate 105, etching produces air chamber 106, and supporting layer 104 is for supporting piezoelectric vibration heap and for reducing the temperature drift of device.Fig. 4 is the vertical view that uses lattice-shaped upper electrode arrangement in the present embodiment.
In the present embodiment, the material of piezoelectric layer 102 is zinc-oxide film, ZnO and Au form Schottky contacts, under UV-irradiation, can excite the electronics generation transition in ZnO valence band, the carrier concentration on ZnO surface is increased, and the speed of bulk acoustic wave is relevant with the concentration of its charge carrier in piezoelectric layer, the resonance frequency of FBAR device is directly proportional to the velocity of sound of ZnO again, therefore under the irradiation of ultraviolet light, resonator resonance point can drift about, optical responsivity and the quantum efficiency of based thin film bulk acoustic wave resonator ultraviolet detection according to the side-play amount of frequency and corresponding speed, have been reacted.The preparation method of piezoelectric layer 102 zinc-oxide films is direct current reaction magnetron sputterings, Zn target is bombarded by energetic ion in vacuum chamber, make Zn atom be pounded target material surface, and the oxygen atom that Zn atom passes into when sputter is combined, at substrate surface, generate piezoelectric membrane ZnO, concrete sputtering condition is: base vacuum 3*10
-3, sputter gas Ar and reacting gas O
2ratio be 2:1, reaction pressure is 1Pa, sputter temperature is 200 ℃, the bias voltage of sputter is-75V.The piezoelectric membrane ZnO growing has good c-axis orientation.Be illustrated in figure 3 the XRD diffraction spectra of piezoelectric layer zinc-oxide film in the utility model.
The preparation method of the described thin film bulk acoustic resonator for ultraviolet detection, comprises the following steps:
First use the silicon dioxide layer of low-pressure chemical vapour deposition technique LPCVD or thermal oxidation generation 200-300nm as supporting layer 104, use subsequently positive glue stripping technology to carry out exposure imaging to front side of silicon wafer (burnishing surface), and the mode that adopts electron beam evaporation deposits the Cr of 5nm, the Au of 50nm as hearth electrode 103, peeled off rear formation hearth electrode, wherein Cr is as being adhered layer, for overcoming the shortcoming a little less than Au and substrate adhesiveness.Use the piezoelectric membrane zinc oxide 102 of direct current reaction magnetron sputtering growth 2um left and right.Fig. 3 is the XRD of zinc oxide, shows that ZnO film has c-axis orientation preferentially.Subsequently liner is placed in to quick anneal oven, the condition of annealing is 400 ℃, vacuum, and 10min completes for the first time, after annealing, ZnO graphically etched to through hole.Then ready 6-10 layer graphene wet method is transferred to ZnO upper, uses the method for inductively coupled plasma to etch top electrode 101.Finally by deep reaction ion etching, in substrate 105 bottoms, form air chamber 106, as acoustic reflection layer 108.
1. ultraviolet test
By the FBAR device pressure welding for ultraviolet detection on pcb board for test, PCB linked network analyzer, network analyzer connects computer, uses LabView software to carry out Real-Time Monitoring to the resonance frequency of device.Fix PCB upper, with ultraviolet generator, regulate ultraviolet light irradiation position and intensity of illumination.On network analyzer, set parameter, as span, center etc., open LabView software and start test, after the resonance frequency of device is stablized, open ultraviolet lamp tube, make its effective working region that is radiated at FBAR device, the variation of observation resonant frequency.In the present embodiment, be to survey ultraviolet intensity at 0.04-8.6mW/cm
2between.From this embodiment, along with the increase of uitraviolet intensity, frequency offset increases, and the response of ultraviolet is fast and recovery time is short.
In the present embodiment, Ag can form schottky junction with ZnO, and the upper electrode arrangement of lattice-shaped, the piezoelectric of part is exposed in air, under the irradiation of ultraviolet light, can produce more electron-hole pair, the optical responsivity of device is increased, be easy to ultraviolet test, for making highly sensitive ultraviolet FBAR transducer.
embodiment 2
Adopt the structure identical with embodiment 1, hearth electrode, piezoelectric layer, but top electrode adopts the Au of 5-50nm, the Au of 50nm for ultraviolet ray still in translucent, and Au can form schottky junction with ZnO, complete top electrode graphical after, be placed on and in quick anneal oven, carry out annealing operation for the second time, finally use deep reaction ion etching to etch back of the body chamber, be formed for the thin film bulk acoustic resonator of ultraviolet detection.Its ultraviolet situation as shown in Figure 5.
The thin film bulk acoustic resonator for ultraviolet detection that the utility model provides, adopts stacked structure, and preparation technology is simple, and quality factor are high, can be repeatedly for the weak ultraviolet light of probing, and be applicable to being applied to field of radio frequency communication.
The above is only preferred implementation of the present utility model; be noted that for those skilled in the art; do not departing under the prerequisite of the utility model principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection range of the present utility model.
Claims (6)
1. for a thin film bulk acoustic resonator for ultraviolet detection, it is characterized in that: comprise and be stacked on continuously piezoelectric vibration heap and the acoustic reflection layer becoming one on same substrate; Wherein, piezoelectric vibration heap comprises from bottom to top hearth electrode, piezoelectric layer and the top electrode of deposition successively; The material of described top electrode is have ultraviolet transmission and can form the metallic film of schottky junction with piezoelectric layer, is convenient to ultraviolet light and is radiated on piezoelectric layer through top electrode;
Described acoustic reflection layer comprises that the supporting layer, the piezoelectric vibration heap that on substrate, substrate, deposit are deposited on supporting layer; Described acoustic reflection layer is air-gap structure or Bragg reflecting layer structure or back of the body chamber etching structure; When acoustic reflection layer is for back of the body chamber etching structure, on described substrate, be provided with the air chamber that etching forms.
2. the thin film bulk acoustic resonator for ultraviolet detection according to claim 1, is characterized in that: the material of described piezoelectric layer is ZnO, and thickness is 500-5000nm.
3. the thin film bulk acoustic resonator for ultraviolet detection according to claim 1, is characterized in that: the transmissivity at ultraviolet band of described top electrode metallic film is greater than 60%.
4. the thin film bulk acoustic resonator for ultraviolet detection according to claim 1, is characterized in that: the material of described hearth electrode is Al or Au, and thickness is 10-300nm.
5. the thin film bulk acoustic resonator for ultraviolet detection according to claim 1, it is characterized in that: the Ag that the material of described top electrode is lattice-shaped structure, adopt the mode of direct current reaction magnetron sputtering or radio frequency reaction magnetron sputtering to deposit formation, thickness is 50-150nm.
6. the thin film bulk acoustic resonator for ultraviolet detection according to claim 1, is characterized in that: the material of described top electrode is Au, adopts the mode of electron beam evaporation or thermal evaporation to deposit formation, and thickness is 5-50nm.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104038177A (en) * | 2014-06-04 | 2014-09-10 | 江苏艾伦摩尔微电子科技有限公司 | Thin film bulk acoustic resonator for ultraviolet detection and preparation method thereof |
| CN104833996A (en) * | 2015-02-03 | 2015-08-12 | 中国工程物理研究院电子工程研究所 | Array-type gamma irradiation dosimeter of FBAR structure on diaphragm |
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2014
- 2014-06-04 CN CN201420295036.2U patent/CN203883782U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104038177A (en) * | 2014-06-04 | 2014-09-10 | 江苏艾伦摩尔微电子科技有限公司 | Thin film bulk acoustic resonator for ultraviolet detection and preparation method thereof |
| CN104833996A (en) * | 2015-02-03 | 2015-08-12 | 中国工程物理研究院电子工程研究所 | Array-type gamma irradiation dosimeter of FBAR structure on diaphragm |
| CN104833996B (en) * | 2015-02-03 | 2017-12-22 | 中国工程物理研究院电子工程研究所 | The array gamma irradiation dosimeter of FBAR structures on diaphragm |
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