CN203782246U - Device for hydrolyzing amino acid - Google Patents
Device for hydrolyzing amino acid Download PDFInfo
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- CN203782246U CN203782246U CN201420087322.XU CN201420087322U CN203782246U CN 203782246 U CN203782246 U CN 203782246U CN 201420087322 U CN201420087322 U CN 201420087322U CN 203782246 U CN203782246 U CN 203782246U
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- raw material
- amino acid
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- 150000001413 amino acids Chemical class 0.000 title claims abstract description 53
- 230000003301 hydrolyzing effect Effects 0.000 title abstract 2
- 239000002994 raw material Substances 0.000 claims abstract description 46
- 239000012295 chemical reaction liquid Substances 0.000 claims abstract description 36
- 238000006243 chemical reaction Methods 0.000 claims abstract description 31
- 239000002699 waste material Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 230000007062 hydrolysis Effects 0.000 claims description 34
- 238000006460 hydrolysis reaction Methods 0.000 claims description 34
- 239000003513 alkali Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 1
- 239000000376 reactant Substances 0.000 abstract description 28
- 238000005868 electrolysis reaction Methods 0.000 abstract description 16
- 239000000203 mixture Substances 0.000 abstract description 8
- 238000006386 neutralization reaction Methods 0.000 abstract description 5
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 229940024606 amino acid Drugs 0.000 description 42
- 235000001014 amino acid Nutrition 0.000 description 42
- 241000196324 Embryophyta Species 0.000 description 12
- 210000003746 feather Anatomy 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 108090000623 proteins and genes Proteins 0.000 description 8
- 102000004169 proteins and genes Human genes 0.000 description 8
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 7
- 239000003337 fertilizer Substances 0.000 description 7
- 235000018102 proteins Nutrition 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 101710200191 Feather keratin Proteins 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- 102000011782 Keratins Human genes 0.000 description 4
- 108010076876 Keratins Proteins 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 238000005903 acid hydrolysis reaction Methods 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000000050 nutritive effect Effects 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004471 Glycine Substances 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QIVBCDIJIAJPQS-UHFFFAOYSA-N Tryptophan Natural products C1=CC=C2C(CC(N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- 229960004799 tryptophan Drugs 0.000 description 2
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- OYIFNHCXNCRBQI-UHFFFAOYSA-N 2-aminoadipic acid Chemical class OC(=O)C(N)CCCC(O)=O OYIFNHCXNCRBQI-UHFFFAOYSA-N 0.000 description 1
- 241000432824 Asparagus densiflorus Species 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000272496 Galliformes Species 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- 239000006035 Tryptophane Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000000539 amino acid group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229940000635 beta-alanine Drugs 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 125000001493 tyrosinyl group Chemical group [H]OC1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/28—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from natural products
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Fertilizers (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The utility model relates to a device for hydrolyzing amino acid, which comprises a first reaction tank, a first raw material tank, a second reaction tank, an electrolysis device and a second raw material tank. The first reaction tank can store and mix fur waste, an alkaline reaction solution, and water. The first raw material tank is communicated with the first reaction tank in a unidirectional manner and can store and convey an alkaline reaction solution to the first reaction tank to obtain a premix. The second reaction tank is in one-way communication with the first reaction tank and is capable of holding a premix. An electrolysis device is connected to the second reaction tank and is capable of electrolyzing the pre-mixture to obtain a first reactant. The second raw material tank is communicated with the second reaction tank in a unidirectional way and can store and convey the acidic reaction liquid to the second reaction tank, so that the acidic reaction liquid and the first reactant generate acid-base neutralization reaction to obtain a second reactant, namely a hydrolyzed amino acid finished product.
Description
Technical field
The utility model mainly discloses a kind of device of hydrolysis amino acid.
Background technology
Feather after various butchering fowls and being unsuitable for is made the fur waste of down products and must be dealt carefully with, and to avoid stench and causes environmental pollution.Processing mode mainly be take and is incinerated or bury as main, but fur is difficult for burning, and can cause atmospheric pollution while burning.In addition, bury and expend equally soil and utilize space.Incinerate and bury processing and all cannot reach the object of waste recycling.
Protein content in feather generally account for the total composition of feather 80%～90% between, main component is the Keratin sulfate (α-keratin) of disulfide linkage (S-S-), feather keratin is comprised of amino acid, sulfur-containing amino acid (Cys, Met etc.) accounts for 11%～12%, and sulphur atom is wherein the basis that forms disulfide linkage.Major part is hydrophobic amino acid, and hydrophobic amino acid is distributed in keratic periphery, and a small amount of hydrophilic amino acid and group are contained within the inside of peptide bond and protein skeleton.Peptide bond is right hand alpha-helix (alpha-helices), article 3, right hand alpha-helix is combined into the left hand helix of rope form and forms protofibril (Protofibril), in protofibril between 3 peptide bonds by disulfide linkage mutual connection, 9 set between protofibril form giant fibres (Macrofibril), the giant fibres of numerous parallel shapes mutually combines by disulfide linkage, has formed the elementary cell of feather.
Keratin peptide interchain has abundant disulfide linkage (S-S-) to connect, and forms solid reticulated structure closely, so natural feather Keratin sulfate is water-fast, traditional Keratin sulfate method for hydrolysis has Physical, chemical method and biological treatment haply.
Physical is for directly by feather grinds powder and apply to farm crop fertilizer, but feather powder particle slightly causes being difficult for being absorbed by farm crop, and amino acid contained not yet conversion of feather can directly absorb for plant.
Chemical method is that certain density sour heating hydrolysis protein can destroy tryptophane (tryptophan), and Serine and tyrosine part are destroyed, and traditional acid hydrolysis method temperature is about 110～120 ℃.Yet due to traditional acid hydrolysis method excess Temperature, cause protein to produce qualitative change in the time of 80 ℃ molecular structure is destroyed, the hydrolysis amino acid that therefore traditional acid hydrolysis method obtains will cause plant to be difficult to absorb for plant fertilising.
Biological treatment is with the hydrolysis of microorganism or ferment, and it can cracked disulfide bond and expose protein and dissolve completely, is feather keratin.But the amino acid obtaining with microorganism decomposition only can be used separately and cannot add other compositions, avoids other compositions to suffer microorganism decomposition, the utilization scope of greatly having limited to hydrolysis amino acid.
Because the problem of above-mentioned prior art cannot effectively solve and overcome, so the applicant proposes present patent application, to solve problem point.
Utility model content
The technical problem that the utility model institute wish solves is: the method for making of traditional hydrolysis amino acid and the resulting hydrolysis amino acid of the device directly excess Temperature in as fertilizer sources use and manufacturing processed cause amino acid qualitative change.
For this reason, the device of a kind of hydrolysis amino acid provided by the utility model, it comprises:
First reactive tank, it can deposit and mix fur waste, alkali reaction liquid and water;
First raw material tank, its uniaxially is communicated with this first reactive tank and can deposits and carry pH value is that 10～12 alkali reaction liquid is to this first reactive tank, the weight percent of fur waste, alkali reaction liquid and water is sequentially: 30～40%, 5～8% and 52～65%, and fur waste in this first reactive tank, alkali reaction liquid and water are mixed 12～48 hours and obtain premixture;
Second reactive tank, its uniaxially is communicated with this first reactive tank and can deposits the premixture that is delivered to this second reactive tank by this first reactive tank;
An electrolyzer, its be connected in this second reactive tank and can this second reactive tank of electrolysis in premixture and obtain first set reaction thing; And
Second raw material tank, its uniaxially is communicated with this second reactive tank and can deposits and carry pH value is that 3～6 acid-reaction liquid is to this second reactive tank, the weight percent of acid-reaction liquid and first set reaction thing is sequentially: 3～5% and 95～97%, make acid-reaction liquid react and obtain reactant for the second time with first set reaction deposits yields acid-base neutralisation, it is hydrolysis amino acid finished product.
The device of the utility model hydrolysis amino acid more comprises a supply unit, and this supply unit comprises first delivery groups, second delivery groups and the 3rd delivery groups;
This first delivery groups is connected between this first reactive tank and this first raw material tank and comprises first pump and two the first pipelines, these two first pipelines are connected between this first reactive tank and this first pump and between this first pump and this first raw material tank, this first reactive tank is communicated with this first raw material tank uniaxially and alkali reaction liquid can be delivered to this first reactive tank by the first raw material tank;
This second delivery groups is connected between this first reactive tank and this second reactive tank and comprises second pump and two the second pipelines, these two second pipelines are connected between this first reactive tank and this second pump and between this second pump and this second reactive tank, this first reactive tank is communicated with this second reactive tank uniaxially and premixture can be delivered to this second reactive tank by this first reactive tank;
The 3rd delivery groups is connected between this second raw material tank and this second reactive tank and comprises the 3rd pump and two the 3rd pipelines, these two the 3rd pipelines are connected between this second raw material tank and the 3rd pump and between the 3rd pump and this second reactive tank, this second raw material tank is communicated with this second reactive tank uniaxially and acid-reaction liquid can be delivered to this second reactive tank by this second raw material tank.
More preferably, this first reactive tank comprises an agitating unit, and this agitating unit comprises a CD-ROM drive motor and an agitating vane, and this CD-ROM drive motor connects this agitating vane and can drive this agitating vane in this first reactive tank, to rotate stirring.
This first reactive tank comprises a conveying belt, and this conveying belt can be delivered to fur waste this first reactive tank.
The device of the utility model hydrolysis amino acid more comprises a pan tank, this pan tank uniaxially is communicated with this second reactive tank, this electrolyzer can again carry out electrolysis and obtain reactant for the third time the reactant for the second time of this second reactive tank, and this pan tank can be deposited the reactant for the third time that is delivered to this pan tank by this second reactive tank.
This supply unit more comprises the 4th delivery groups, the 4th delivery groups is connected between this second reactive tank and this pan tank and comprises the 4th pump and two the 4th pipelines, these two the 4th pipelines are connected between this second reactive tank and the 4th pump and between the 4th pump and this pan tank, this second reactive tank is communicated with this pan tank uniaxially and reactant for the third time can be delivered to this pan tank by this second reactive tank.
The device of the utility model hydrolysis amino acid more comprises a framework, this first reactive tank, this first raw material tank, this second reactive tank, this electrolyzer, this second raw material tank, this supply unit and this pan tank are arranged in this framework, this framework comprises two edge strips and first control enclosure and second control enclosure, this first control enclosure is arranged at this two edges, and one of them is also electrically connected to this first pump, this second pump and this electrolyzer, make this first control enclosure can control this first pump, the running of this second pump and this electrolyzer, this second control enclosure is arranged at another edge strip and is electrically connected to the 3rd pump and the 4th pump, make this second control enclosure can control the running of the 3rd pump and the 4th pump.
Technical characteristics of the present utility model is: rely on electrolytic reaction, make fur waste at room temperature can generate a large amount of reactants for the second time, its have tiny molecule and separately as fertilizer sources use or can add separately other additives uses, and significantly reduce the volume or weight of fur waste, fur changing rejected material to useful resource is recycled.
Other objects, advantage and novel characteristics of the present utility model will be more obvious from the following detailed description and related drawings.
Accompanying drawing explanation
Fig. 1: be the stereo appearance figure of the device of the utility model hydrolysis amino acid;
Fig. 2: be the use schematic diagram of the device of the utility model hydrolysis amino acid, represent that fur waste sees through conveying belt and is concentrated to the first reactive tank, and alkali reaction liquid enter the first reactive tank by the first raw material tank;
Fig. 3: be the continuity of Fig. 2, represent that alkali reaction liquid, fur waste and water are obtained by mixing premixture in the first reactive tank;
Fig. 4: be the continuity of Fig. 3, represent that premixture enters the second reactive tank;
Fig. 5: be the continuity of Fig. 4, represent the premixture in electrolyzer electrolysis the second reactive tank;
Fig. 6: be the continuity of Fig. 5, represent to obtain first set reaction thing after premixture electrolysis, and acid-reaction liquid enter the second reactive tank by the second raw material tank;
Fig. 7: be the continuity of Fig. 6, represent that acid-reaction liquid reacts with first set reaction deposits yields acid-base neutralisation and obtains reactant for the second time;
Fig. 8: be the continuity of Fig. 7, represent the reactant for the second time in electrolyzer electrolysis the second reactive tank and obtain reactant for the third time, and reactant enters pan tank by the second reactive tank for the third time.
Description of reference numerals: 10-the first reactive tank; 11-agitating unit; 111-CD-ROM drive motor; 112-agitating vane; 12-conveying belt; 20-the first raw material tank; 30-the second reactive tank; 40-electrolyzer; 50-the second raw material tank; 60-pan tank; 70-supply unit; 70a-the first delivery groups; 71a-the first pump; 72a-the first pipeline; 70b-the second delivery groups; 71b-the second pump; 72b-the second pipeline; 70c-the 3rd delivery groups; 71c-the 3rd pump 72c-the 3rd pipeline; 70d-the 4th delivery groups; 71d-the 4th pump; 72d-the 4th pipeline; 80-framework; 81-edge strip; 82-the first control enclosure; 83-the second control enclosure; A-fur waste; B-alkali reaction liquid; C-premixture; D-first set reaction thing; E-acid-reaction liquid; F-is reactant for the second time; G-is reactant for the third time.
Embodiment
The technology that relevant the utility model adopts, means and effect thereof, hereby lift a preferred embodiment and coordinate accompanying drawing to describe in detail as after, this,, only for explanation, is not subject to the restriction of this kind of structure in patent application.
Please refer to Fig. 1 to Fig. 8, it is stereo appearance figure and the use schematic diagram of the device of the utility model hydrolysis amino acid.The device of this hydrolysis amino acid comprises first reactive tank 10, one the first raw material tank 20, one the second reactive tank 30, electrolyzer 40, second raw material tank 50, pan tank 60 and a supply unit 70.
Fur waste A (as feather), alkali reaction liquid B and water can be deposited and mix to this first reactive tank 10, and the pH value of general common fur waste A is many between 9～9.5.This first reactive tank 10 comprises an agitating unit 11 and a conveying belt 12, this agitating unit 11 comprises a CD-ROM drive motor 111 and an agitating vane 112, and this CD-ROM drive motor 111 connects this agitating vane 112 and can drive this agitating vane 112 to stir in the interior rotation of this first reactive tank 10.This conveying belt 12 can be delivered to fur waste A this first reactive tank 10.
These the first raw material tank 20 uniaxiallies are communicated with this first reactive tank 10 and can under room temperature, deposit and carry pH value is that 10～12 alkali reaction liquid B is to this first reactive tank 10, better scheme is that the pH value of alkali reaction liquid B is 10.5～11, room temperature is 20～30 ℃, the weight percent of fur waste A, alkali reaction liquid B and water is sequentially: 30～40%, 5～8% and 52～65%, and fur waste A, alkali reaction liquid B in this first reactive tank 10 and water are mixed 12～48 hours and obtain premixture C.The pH value of alkali reaction liquid B is controlled between 10.5～11 and makes the disulfide linkage in the feather keratin in fur waste A effectively destroyed, is one of effective ways that improve feather small molecular amount protein content.But B can destroy amino acid whose opticity due to alkali reaction liquid, produce a large amount of D type amino acid, cannot be absorbed and used by plants, so should avoid using high-alkalinity, the pH value of alkali reaction liquid B is span of control preferably between being controlled in 10.5～11.Moreover, the long meeting of mixing time causes the peptide bond rupture between all amino-acid residues, generates a large amount of dl aminoadipic acids, therefore mixing time is controlled between 12～48 hours, both reached and destroyed disulfide linkage object in feather protein structure, be unlikely to again to generate a large amount of total free aminoacidss.
These the second reactive tank 30 uniaxiallies are communicated with this first reactive tank 10 and can deposit the premixture C that is delivered to this second reactive tank 30 by this first reactive tank 10.
This electrolyzer 40 be connected in this second reactive tank 30 and can this second reactive tank of electrolysis in 30 premixture C and obtain first set reaction thing D, in electrolysis step, temperature remains on and is no more than 50 ℃, electrolysis time is 24 hours, by the molecule cracking of premixture C to how metrical scale and obtain liquid first set reaction thing D.Because temperature in electrolysis step is no more than 50 ℃, so the molecular structure of first set reaction thing D can not destroyed completely and be avoided producing qualitative change.
These the second raw material tank 50 uniaxiallies are communicated with this second reactive tank 30 and can deposit and carry pH value is that 3～6 acid-reaction liquid E is to this second reactive tank 30, the weight percent of acid-reaction liquid E and first set reaction thing D is sequentially: 3～5% and 95～97%, make acid-reaction liquid E and first set reaction thing D produce acid-base neutralisation and react and obtain reactant F for the second time, it is hydrolysis amino acid finished product.Better scheme is that the pH value of acid-reaction liquid H is 4.5～5.PH value by acid-reaction liquid H is 4.5～5 to adjust the pH value of reactant F for the second time with being alkaline first set reaction thing D acid-base neutralisation, makes it be neutral.
These pan tank 60 uniaxiallies are communicated with this second reactive tank 30, this electrolyzer 40 can again carry out electrolysis to the F of reactant for the second time in this second reactive tank 30 and obtain reactant G for the third time, electrolysis time is 24 hours, the molecule of reactant G is more tiny for the third time for this, while making for the third time reactant G as fertilizer sources, can allow plant absorb more fast.This pan tank 60 can be deposited the G of reactant for the third time that is delivered to this pan tank 60 by this second reactive tank 30.
This supply unit 70 comprises a first delivery groups 70a, the second delivery groups 70b, a 3rd delivery groups 70c and a 4th delivery groups 70d.
This first delivery groups 70a is connected between this first reactive tank 10 and this first raw material tank 20 and comprises a first pump 71a and two the first pipeline 72a, this two first pipeline 72a is connected between this first reactive tank 10 and this first pump 71a and between this first pump 71a and this first raw material tank 20, this first reactive tank 10 is communicated with these the first raw material tank 20 uniaxiallies and can utilizes drawing of this first pump 71a that alkali reaction liquid B is delivered to this first reactive tank 10 by the first raw material tank 20.
This second delivery groups 70b is connected between this first reactive tank 10 and this second reactive tank 30 and comprises a second pump 71b and two the second pipeline 72b, this two second pipeline 72b is connected between this first reactive tank 10 and this second pump 71b and between this second pump 71b and this second reactive tank 30, this first reactive tank 10 is communicated with these the second reactive tank 30 uniaxiallies and can utilizes drawing of this second pump 71b that premixture C is delivered to this second reactive tank 30 by this first reactive tank 10.
The 3rd delivery groups 70c is connected between this second raw material tank 50 and this second reactive tank 30 and comprises a 3rd pump 71c and two the 3rd pipeline 72c, this two the 3rd pipeline 72c is connected between this second raw material tank 50 and the 3rd pump 71c and between the 3rd pump 71c and this second reactive tank 30, this second raw material tank 50 is communicated with these the second reactive tank 30 uniaxiallies and can utilizes drawing of the 3rd pump 71c that acid-reaction liquid E is delivered to this second reactive tank 30 by this second raw material tank 50.
The 4th delivery groups 70d is connected between this second reactive tank 30 and this pan tank 60 and comprises a 4th pump 71d and two the 4th pipeline 72d, this two the 4th pipeline 72d is connected between this second reactive tank 30 and the 4th pump 71d and between the 4th pump 71d and this pan tank 60, this second reactive tank 30 is communicated with these pan tank 60 uniaxiallies and can utilizes the reactant G for the third time that draws of the 4th pump 71d to be delivered to this pan tank 60 by this second reactive tank 30.
The device of this hydrolysis amino acid more can comprise a framework 80, this first reactive tank 10, this first raw material tank 20, this second reactive tank 30, this electrolyzer 40, this second raw material tank 50 is arranged in this framework 80 with this supply unit 70, this framework 80 comprises two edge strips 81 and first control enclosure 82 and second control enclosure 83, this first control enclosure 82 is arranged at this two edges 81, and one of them is also electrically connected to this first pump 71a, this the second pump 71b and this electrolyzer 40, make this first control enclosure 82 can control this first pump 71a, the running of this second pump 71b and this electrolyzer 40, this second control enclosure 83 is arranged at another edge strip 81 and is electrically connected to the 3rd pump 71c and the 4th pump 71d, make this second control enclosure 83 can control the running of the 3rd pump 71c and the 4th pump 71d.
To take fur waste A be amino acid carrier to reactant F for the second time, amino acid (Amino acid) is the fundamental unit that forms protein, give protein specific molecular morphosis, protein is after hydrolysis, generate more than 20 kind of a-amino acid, as glycine, Beta Alanine, asparagus fern amino acid, L-GLUTAMICACID etc.And in amino acid whose chemical structure, there is amino (NH
2group), it is organic fine molecule (organic molecules) and can be identified as: basic group (NH2) and acidic-group-carboxylic acid group (COOH group).
Reactant F has 2.6% full nitrogen (N), 3.55% full phosphoric anhydride (P for the second time
2o
5) with 3.6% full potassium oxide (K
2o), therefore reactant F has the three large important elements such as the considerable nitrogen of a large amount of as fertilizer sources (N), phosphorus (P), potassium (K) for the second time, nitrogen can promote the growth of stem and the leaf of plant, phosphorus has the crops precocity of enhancement and full grains effect, and potassium can promote the g and D of plant.
Reactant F for the second time, it is hydrolysis amino acid finished product, due to the characteristic of amino acid itself, to plant-growth particularly photosynthesis there is promoter action, glycine especially, it can increase chlorophyll content of plant, improve the activity of enzyme, promote the infiltration of carbonic acid gas, make photosynthesis more vigorous, to improving crop quality, increase all important roles of VITAMIN and sugared content.
The various nutritive elements of crop growth process need and material, the absorption quantitative proportion of these nutritive elements and material and the equilibrium condition in crop, nutritional-physiological impact on crop is very large, can be directly connected to the quality of crop and fruit, and the crucial composition that amino acid addresses this problem just, amino acid nutrient liquid fertilizer is executed in plant-spraying or filling can increase required various nutritive elements in plant materials, the accumulation of aggravation dry-matter and running speed from leaf portion to other positions and quantity from plant root or, regulate macroelement, ratio and the equilibrium state of micro-and various nutritions, thereby play the effect of regulating plant normal growth.
The three large important elements such as nitrogen (N), phosphorus (P), potassium (K) are to make necessary material in object.Can often there is lacking the symptom of some element in crop; its reason be can be absorbed by crops significant part content very little; and amino acid can with insoluble element generation chelatropic reaction; the required element of crop is produced to provide protection; and generate that solubleness is good, easy inner complex absorbed by crops, thereby be conducive to plant, absorb.At this amino acid, play just the effect of complexing agent.
The device that can summarize the hydrolysis amino acid of the utility model according to the above has the following advantages:
1. the device of the utility model hydrolysis amino acid is by electrolytic reaction, make fur waste A at room temperature can highly selective generate a large amount of F of reactant for the second time, its have tiny molecule and separately as fertilizer sources use or can add separately other additives uses, and significantly reduce the volume or weight of fur waste, fur waste A resource utilization is recycled.
2. the temperature that is installed in electrolysis step of the utility model hydrolysis amino acid remains on and is no more than 50 ℃, and electrolysis time is 24 hours, by the molecule cracking of premixture C to how metrical scale and obtain liquid first set reaction thing D.Because temperature in electrolysis step is no more than 50 ℃, so the molecular structure of first set reaction thing D can not destroyed completely and be avoided producing qualitative change.
Claims (9)
1. a device for hydrolysis amino acid, is characterized in that, comprising:
First reactive tank, it can deposit and mix fur waste, alkali reaction liquid and water;
First raw material tank, its uniaxially is communicated with this first reactive tank and can deposits and carry alkali reaction liquid to this first reactive tank;
Second reactive tank, its uniaxially is communicated with this first reactive tank;
An electrolyzer, it is connected in this second reactive tank; And
Second raw material tank, its uniaxially is communicated with this second reactive tank and can deposits and carry acid reaction solution to this second reactive tank.
2. the device of hydrolysis amino acid as claimed in claim 1, is characterized in that, more comprises a supply unit, and this supply unit comprises first delivery groups, second delivery groups and the 3rd delivery groups;
This first delivery groups is connected between this first reactive tank and this first raw material tank and comprises first pump and two the first pipelines, these two first pipelines are connected between this first reactive tank and this first pump and between this first pump and this first raw material tank, this first reactive tank is communicated with this first raw material tank uniaxially and alkali reaction liquid can be delivered to this first reactive tank by the first raw material tank;
This second delivery groups is connected between this first reactive tank and this second reactive tank and comprises second pump and two the second pipelines, these two second pipelines are connected between this first reactive tank and this second pump and between this second pump and this second reactive tank, and this first reactive tank is communicated with this second reactive tank uniaxially;
The 3rd delivery groups is connected between this second raw material tank and this second reactive tank and comprises the 3rd pump and two the 3rd pipelines, these two the 3rd pipelines are connected between this second raw material tank and the 3rd pump and between the 3rd pump and this second reactive tank, this second raw material tank is communicated with this second reactive tank uniaxially and acid-reaction liquid can be delivered to this second reactive tank by this second raw material tank.
3. the device of hydrolysis amino acid as claimed in claim 1, it is characterized in that, this first reactive tank comprises an agitating unit, this agitating unit comprises a CD-ROM drive motor and an agitating vane, and this CD-ROM drive motor connects this agitating vane and can drive this agitating vane in this first reactive tank, to rotate stirring.
4. the device of hydrolysis amino acid as claimed in claim 1, is characterized in that, this first reactive tank comprises a conveying belt, and this conveying belt can be delivered to fur waste this first reactive tank.
5. the device of hydrolysis amino acid as claimed in claim 2, is characterized in that, more comprises a pan tank, and this pan tank uniaxially is communicated with this second reactive tank.
6. the device of the hydrolysis amino acid as described in claim 3 or 4, is characterized in that, more comprises a pan tank, and this pan tank uniaxially is communicated with this second reactive tank.
7. the device of hydrolysis amino acid as claimed in claim 5, it is characterized in that, this supply unit more comprises the 4th delivery groups, the 4th delivery groups is connected between this second reactive tank and this pan tank and comprises the 4th pump and two the 4th pipelines, these two the 4th pipelines are connected between this second reactive tank and the 4th pump and between the 4th pump and this pan tank, and this second reactive tank is communicated with this pan tank uniaxially.
8. the device of hydrolysis amino acid as claimed in claim 6, it is characterized in that, this supply unit more comprises the 4th delivery groups, the 4th delivery groups is connected between this second reactive tank and this pan tank and comprises the 4th pump and two the 4th pipelines, these two the 4th pipelines are connected between this second reactive tank and the 4th pump and between the 4th pump and this pan tank, and this second reactive tank is communicated with this pan tank uniaxially.
9. the device of hydrolysis amino acid as claimed in claim 7, it is characterized in that, more comprise a framework, this first reactive tank, this first raw material tank, this second reactive tank, this electrolyzer, this second raw material tank, this supply unit and this pan tank are arranged in this framework, this framework comprises two edge strips, first control enclosure and second control enclosure, this first control enclosure is arranged at this two edges on one of them and is electrically connected to this first pump, this second pump and this electrolyzer, make this first control enclosure can control this first pump, the running of this second pump and this electrolyzer, this second control enclosure is arranged on another edge strip and is electrically connected to the 3rd pump and the 4th pump, make this second control enclosure can control the running of the 3rd pump and the 4th pump.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW102129959 | 2013-08-22 | ||
| TW102129959A TW201508007A (en) | 2013-08-22 | 2013-08-22 | Method of manufacturing hydrolysis amino acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN203782246U true CN203782246U (en) | 2014-08-20 |
Family
ID=51318451
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310547178.3A Expired - Fee Related CN104419949B (en) | 2013-08-22 | 2013-11-06 | Process for preparing hydrolyzed amino acids |
| CN201420087322.XU Expired - Fee Related CN203782246U (en) | 2013-08-22 | 2014-02-27 | Device for hydrolyzing amino acid |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310547178.3A Expired - Fee Related CN104419949B (en) | 2013-08-22 | 2013-11-06 | Process for preparing hydrolyzed amino acids |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20150053570A1 (en) |
| JP (1) | JP2015040345A (en) |
| KR (1) | KR20150022683A (en) |
| CN (2) | CN104419949B (en) |
| TW (1) | TW201508007A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108101716A (en) * | 2018-03-02 | 2018-06-01 | 广州惠农农业科技有限公司 | A kind of organic fertilizer and preparation method thereof |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51115280A (en) * | 1975-04-03 | 1976-10-09 | Shigeo Otake | Process for treating waste liquid from paste-foods production |
| JPS602393B2 (en) * | 1981-09-25 | 1985-01-21 | 株式会社ユアサコーポレーション | Amino acid production method |
| US4386110A (en) * | 1982-01-08 | 1983-05-31 | Hiroshima Prefecture | Electrical treatment method of soybean protein |
| US4551274A (en) * | 1983-08-22 | 1985-11-05 | Ralston Purina Company | Electrolytic treatment of vegetable protein |
| BE904225A (en) * | 1985-02-14 | 1986-05-29 | Fuji Oil Co Ltd | PROTEIN FRACTIONATION PROCESS. |
| DE3712825A1 (en) * | 1987-04-15 | 1988-11-03 | Diamalt Ag | TOTAL WHITE DEGRADATION PRODUCT |
| JPH01175994A (en) * | 1987-12-28 | 1989-07-12 | Tosoh Corp | Production of partial hydrolyzed product of protein |
| JP2804950B2 (en) * | 1992-07-22 | 1998-09-30 | 開成科学株式会社 | Method for producing amino acid-containing fertilizer |
| CN1209203C (en) * | 2002-12-18 | 2005-07-06 | 吕谦 | Feather powder processing and treating method |
| CN101476134A (en) * | 2007-12-31 | 2009-07-08 | 宁波海硕生物科技有限公司 | Method for producing L-cysteine hydrochloride monohydrate by composite silver plate modified cathode electrolysis |
| CN101372503B (en) * | 2008-08-06 | 2011-06-15 | 西北师范大学 | Method for extracting keratin from feather |
| CN101575749B (en) * | 2009-04-03 | 2010-12-08 | 东华大学 | Keratin crystal whisker enhanced homogeneous composite fiber and preparation method thereof |
| TW201111393A (en) * | 2009-09-18 | 2011-04-01 | Univ Nat Taiwan | Electrolysis for protein modification |
| CN101724376B (en) * | 2009-12-14 | 2011-07-27 | 东北林业大学 | Wood adhesive prepared by degrading soybean protein by utilizing strong basicity and preparation method thereof |
| CN101979428B (en) * | 2010-10-09 | 2012-09-19 | 天津工业大学 | Animal hair solvent and preparation method and use of keratin solution |
| CN102416196A (en) * | 2011-02-14 | 2012-04-18 | 蒙一纯 | Preparation method of keratin material for biomedical engineering |
| CN102370044A (en) * | 2011-09-30 | 2012-03-14 | 哈尔滨工业大学 | Extraction method of high-digestibility rice protein |
| CN102517600B (en) * | 2011-12-07 | 2014-08-13 | 四川大学 | Electro-degradation method for furred animal skin or hair |
| CN102719933B (en) * | 2012-07-11 | 2014-12-17 | 成都起点投资有限公司 | Feather casein fiber preparation method |
| CN102775489A (en) * | 2012-07-31 | 2012-11-14 | 上海全宇生物科技遂平有限公司 | Keratin solid and preparation method thereof |
-
2013
- 2013-08-22 TW TW102129959A patent/TW201508007A/en not_active IP Right Cessation
- 2013-11-06 CN CN201310547178.3A patent/CN104419949B/en not_active Expired - Fee Related
-
2014
- 2014-02-27 CN CN201420087322.XU patent/CN203782246U/en not_active Expired - Fee Related
- 2014-03-30 US US14/229,987 patent/US20150053570A1/en not_active Abandoned
- 2014-08-18 KR KR20140107032A patent/KR20150022683A/en not_active Application Discontinuation
- 2014-08-20 JP JP2014167033A patent/JP2015040345A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| TWI482780B (en) | 2015-05-01 |
| CN104419949A (en) | 2015-03-18 |
| KR20150022683A (en) | 2015-03-04 |
| CN104419949B (en) | 2017-04-26 |
| JP2015040345A (en) | 2015-03-02 |
| US20150053570A1 (en) | 2015-02-26 |
| TW201508007A (en) | 2015-03-01 |
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