CN202265970U - Ceramic-based ultraviolet-curing film-coated decoration plate - Google Patents
Ceramic-based ultraviolet-curing film-coated decoration plate Download PDFInfo
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- CN202265970U CN202265970U CN201120401031XU CN201120401031U CN202265970U CN 202265970 U CN202265970 U CN 202265970U CN 201120401031X U CN201120401031X U CN 201120401031XU CN 201120401031 U CN201120401031 U CN 201120401031U CN 202265970 U CN202265970 U CN 202265970U
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Abstract
The utility model belongs to the field of building material decoration plates, and relates to a ceramic-based ultraviolet-curing film-coated decoration plate which is produced by coating ultraviolet-curing painting on the surface of a ceramic substrate. According to the ceramic-based ultraviolet-curing film-coated decoration plate, an ultraviolet-curing closed primer coating is arranged on the surface of the ceramic substrate; an ultraviolet-curing glue layer is arranged on the surface of the ultraviolet-curing closed primer coating; a pattern obtained by transferring through an ultraviolet-curing transferring film is arranged on the surface of the ultraviolet-curing glue layer; a polypropylene or polyethylene protection thin film is arranged on the surface of the pattern; and an ultraviolet-curing glue layer and an ultraviolet-curing varnish coating are sequentially arranged on the surface of the pattern and between the surface of the pattern and the polypropylene or polyethylene protection thin film. The ceramic-based ultraviolet-curing film-coated decoration plate has the advantages of high strength, high weather resistance, high environment friendliness, rich color and pattern, full film, high hardness, anti-scratching performance and the like, and is easy to clean and difficult to combust.
Description
Technical field
The utility model belongs to constructional materials decorative panel field, relates to the ceramic base ultraviolet light curing overlay film decorative panel of producing through the application ultraviolet-curing paint on the surface of ceramic substrate.
Background technology
At present; Domestic various building and ornament materials occur like insulation composite material for decoration, fire-retardant decorative material in succession, mainly contain the decoration as exterior wall or interior wall etc. such as fiber reinforced cement board, fiber reinforced calcium silicate board, fiber reinforcement magnesium oxide plate, lightweight chloro-magnesium cement plate, magnesite plate, gypsum plank.Present general construction technology is comparatively complicated, and particularly high-building construction is difficult, and the cycle is long, and cost is high.CN200820079231.6 discloses a kind of ultraviolet light curing overlay film decorative board for wall, but owing to the reason of substrate itself has caused this decorative panel can not use in the part occasion, like the environment at high humidity, so the use of this decorative panel has received certain restriction.
Summary of the invention
It is abundant that the purpose of the utility model provides a kind of color pattern, the ornamental and strong ceramic base ultraviolet light curing overlay film decorative panel of protectiveness.
The ceramic base ultraviolet light curing overlay film decorative panel of the utility model is that a kind of surface at pottery (like ceramic tile etc.) type substrate produces the ultraviolet light curing overlay film decorative panel that obtains through the application ultraviolet-curing paint.It is that ultraviolet light polymerization seal coat coating is arranged on the surface of ceramic substrate; There is the ultraviolet light polymerization glue-line on surface in described ultraviolet light polymerization seal coat coating; On the surface of described ultraviolet light polymerization glue-line the pattern that obtains through the transfer printing of ultra-violet curing transfer film is arranged, be useful on the protection body surface on the surface of described pattern and avoid scuffing, abrasive polypropylene protective film or polyvinyl protective film.
The ultraviolet light polymerization glue-line is further arranged successively and as the ultraviolet light polymerization varnish coat of topping on the surface of pattern between the surface of above-mentioned pattern and polypropylene protective film or polyvinyl protective film.
Described ceramic substrate is selected from a kind of in ceramic wafer (like ceramic tile), potter's clay plate, type ceramic wafer, type potter's clay plate etc.
The thickness of described ultraviolet light polymerization seal coat coating is 10～150 μ m.
The thickness of described ultraviolet light polymerization glue-line is 2～50 μ m.
The thickness of described ultraviolet light polymerization varnish coat is 5～250 μ m.
The gloss of described ultraviolet light polymerization varnish coat is that 5～100 degree are adjustable, with 60 degree gloss meters.
It is the disclosed ultra-violet curing transfer film of CN101941339A that described ultra-violet curing transfer film can be notification number.
The ceramic base ultraviolet light curing overlay film decorative panel of the utility model can prepare through following method:
(1). the processing of ceramic substrate: sand milling, dedusting;
(2). at the external coating ultraviolet light polymerization seal coat of the ceramic substrate of step (1), ultraviolet light polymerization; The application mode can adopt modes such as roller coat, blade coating, spraying, showering or brushing, and coating layer thickness is 10～150 μ m.
(3). sand milling, dedusting;
(4). at the external coating ultraviolet cured adhesive of the ultraviolet light polymerization seal coat of step (3), ultraviolet light polymerization; The application mode can adopt modes such as roller coat, brushing or blade coating, and the thickness of coating is 2～50 μ m;
(5). the surface at the ultraviolet cured adhesive of step (4) overlays ultra-violet curing transfer film, ultraviolet light polymerization; The workpiece that overlays gets into the ultraviolet tube (high-pressure sodium lamp) that 1～6 9.6～16.8kw is housed; Carry out illumination in the photo solidification machine of the metal halogen fluorescent tube of 0～5 3～20kw (Iodine gallium light, iron lamp, dysprosium lamp etc.); Light solidifying coating is solidified, and the transmission speed of photo solidification machine is 5～50 meters/minute;
(6). remove the base load film in the ultra-violet curing transfer film;
(7). check;
(8). paste protective film;
(9). packing.
Or
(10). application ultraviolet cured adhesive again on the basis of above-mentioned steps (6), ultraviolet light polymerization; The application mode can adopt modes such as roller coat, brushing or spraying, and the thickness of coating is 2～50 μ m;
(11). application ultraviolet light polymerization varnish on the basis of step (10), ultraviolet light polymerization; But the application mode adopts modes such as roller coat, showering or spraying, and the thickness of coating is 5～250 μ m, and gloss is that 5～100 degree are adjustable, with 60 degree gloss meters;
(12). check;
(13). paste protective film;
(14). packing.
Used ultraviolet light polymerization condition was after application ultraviolet light polymerization seal coat, application ultraviolet cured adhesive, application ultraviolet light polymerization varnish and ultra-violet curing transfer film were fitted:
Be coated with the workpiece that installs and get into the ultraviolet tube (high-pressure sodium lamp) that 1～6 3～20kw is housed; Carry out illumination in the photo solidification machine of the metal halogen fluorescent tube of 0～3 3～20kw (Iodine gallium light, iron lamp, dysprosium lamp etc.); Light solidifying coating is solidified, and the transmission speed of photo solidification machine is 5～50 meters/minute.
Employed ultraviolet light polymerization seal coat, ultraviolet cured adhesive, ultra-violet curing transfer film and ultraviolet light polymerization varnish all are known product in the utility model; Wherein:
By weight percentage, described ultraviolet light polymerization seal coat is made up of acrylic ester prepolymer 30～80%, acrylate monomer 10～60%, light trigger 1～6%, auxiliary agent 0～2% and 0～50% of filler.
By weight percentage, described ultraviolet cured adhesive is made up of acrylic ester prepolymer 30～80%, acrylate monomer 10～60%, light trigger 1～5% and 0～5% of auxiliary agent.
By weight percentage, described ultraviolet light polymerization varnish is made up of fluorine-containing modified prepolymers, acrylic ester prepolymer or their mixture 30～80%, fluorinated acrylate monomer, acrylate monomer or their mixture 10～60%, light trigger 1～5%, auxiliary agent 0～2% and 0～50% of filler.
Described fluorine-containing modified prepolymers is selected from least a in the group that fluorine-containing epoxy acrylate, fluorine-containing epoxy methacrylates, fluorochemical urethane acrylic acid ester, fluorochemical urethane methacrylate, fluorine-containing polyester acrylate, fluorine-containing polyester methacrylate, fluorine-containing amino acrylates, fluorine-containing amino methyl acrylic acid ester, fluoro-acrylate copolymer form.
Described acrylic ester prepolymer is selected from least a in the group that epoxy acrylate, urethane acrylate, polyester acrylate, amino acrylates, acrylate copolymer form.
Described fluorinated acrylate monomer is selected from least a in the group that trifluoroethyl methacrylate, acrylic acid trifluoro ethyl ester, methacrylic acid hexafluoro butyl ester, acrylic acid hexafluoro butyl ester, methacrylic acid ten difluoro heptyl esters, dodecafluorhe-ptylacrylate form.
Described acrylate monomer is selected from least a in the group that two (diethylene glycol) diacrylates of EMA, ethyl acrylate, butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer, hydroxyethyl methacrylate, hydroxy-ethyl acrylate, tri (propylene glycol) diacrylate, propylene glycol diacrylate, neopentylglycol diacrylate, the third oxidation neopentylglycol diacrylate, phthalic acid, 1,6 hexanediyl ester, trimethylolpropane triacrylate, ethoxyquin trimethylolpropane triacrylate, the third oxidation trimethylolpropane triacrylate, pentaerythritol triacrylate, dipentaerythritol acrylate form.
Described light trigger is selected from see at least a in the group that oxygen compound photoinitiator and benzoic ether photoinitiator formed of benzoin ether photoinitiator, benzil ketals photoinitiator, acetophenones light trigger, anthraquinone photoinitiator, thioxanthone photoinitiator, Benzophenones light trigger, acyl group.
Described benzoin ether photoinitiator is selected from least a in the group that benzoin methyl ether, benzoin ethylether and benzoin isopropyl ether etc. are formed.
Described benzil ketals photoinitiator is a benzil dimethyl ketal etc.
Described acetophenones light trigger is selected from acetophenone, 2; 2-dimethoxy-2-phenyl acetophenone, 2; 2-diethoxy-2-phenyl acetophenone, 1, at least a in 1-dichloroacetophenone, 1-hydroxy acetophenone, 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxy-2-methyl-1-acetone, 1-[4-(2-hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone, 2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone and the 2-benzyl-2-dimethylamino-1-group that (4-morpholinyl phenyl)-1-butanone etc. is formed.
Described anthraquinone photoinitiator is selected from least a in the group that 2-tert-butyl group anthraquinone, 1-chloroanthraquinone and 2-amyl anthraquinone etc. are formed.
Described thioxanthone photoinitiator is selected from 2; 4-dimethyl thia anthrone, 2; 4-diethyl thioxanthone, 2-isopropyl thioxanthone, 4-isopropyl thioxanthone, 2-chloro thioxanthone and 2, at least a in the group that 4-diisopropyl thioxanthone etc. is formed.
Described Benzophenones light trigger is selected from benzophenone, 4-chlorobenzophenone, at least a in methyldiphenyl ketone and the group that 4-benzoyl-4 '-dimethyl diphenyl sulfide etc. is formed.
The described acyl group oxygen compound photoinitiator of seeing is selected from 2,4,6-trimethylbenzoyl diphenyl phosphine oxide, two (2; 4, the 6-trimethylbenzoyl)-phenyl phosphine oxide, two (2, the 6-dimethylbenzoyl)-2; 4; 4-tri-methyl-amyl phosphine oxide and 2,4, at least a in the group that 6-trimethylbenzoyl phenyl ethoxy phosphine oxide etc. is formed.
Described benzoic ether photoinitiator is benzoylbenzoic acid methyl esters, methyl o-benzoylbenzoate or their mixture etc.
Described auxiliary agent is selected from least a in the group that the antifoaming agent (like BYK052, BYK055 or their mixture etc.) of the levelling agent (like BYK306, BYK358 or their mixture etc.) of German Bi Ke chemical company, German Bi Ke chemical company and wetting dispersing agent (like Disperbyk 103, Disperbyk163 or their mixture etc.) of German Bi Ke chemical company etc. formed.
Described filler is selected from the mixing of one or more arbitrary proportions in the powder body materials such as French chalk, calcium carbonate, barium sulfate, flatting silica.
The preparation method of the ceramic base ultraviolet light curing overlay film decorative panel of the utility model has that required production site is little, equipment investment is low, production efficiency is high, less energy consumption and advantage such as pollution-free; Used ultraviolet photocureable material is the environment-friendly and green coating that does not contain the volatile organic compound in the ceramic base ultraviolet light curing overlay film decorative panel of the utility model; Ultraviolet light polymerization has that curing rate is fast, energy consumption is low, equipment investment is low and advantage such as the place area occupied is little; The ceramic base ultraviolet light curing overlay film decorative panel of the utility model has intensity height, good weatherability, the feature of environmental protection is good, color pattern is abundant, paint film is plentiful, hardness is high, scratch resistance, be prone to cleaning and advantage such as nonflammable.The alternative marble of ceramic base ultraviolet light curing overlay film decorative panel of the utility model, ceramic tile etc.
Description of drawings
Fig. 1. the structure cross-sectional schematic of the ceramic base ultraviolet light curing overlay film decorative panel of the utility model embodiment 1,2.
Fig. 2. the structure cross-sectional schematic of the ceramic base ultraviolet light curing overlay film decorative panel of the utility model embodiment 3,4.
Reference numeral
1. ceramic substrate 2. ultraviolet light polymerization seal coat coatings
3. ultraviolet light polymerization glue-line 4. patterns
5. ultraviolet light polymerization glue-line 6. ultraviolet light polymerization varnish coates
7. polypropylene protective film or polyvinyl protective film
The specific embodiment
Embodiment 1. imitative English red marble decorative boards
See also Fig. 1.There is ultraviolet light polymerization seal coat coating 2 on surface with the ceramic tile blank being ceramic substrate 1; There is ultraviolet light polymerization glue-line 3 on surface in described ultraviolet light polymerization seal coat coating 2; Have through being printed on the marblized pattern 4 of English red that the transfer printing of the marblized UV transfer film of English red obtains on the surface of described ultraviolet light polymerization glue-line 3, polypropylene protective film 7 is arranged on the surface of the marblized pattern of English red.
To be after the sand milling dedusting is carried out on the surface of ceramic substrate 1 with the ceramic tile blank; In its surface roller coating one layer thickness ultraviolet light polymerization seal coat coating 2 that is 10 μ m; 2 9.6kw uviol lamps (high-pressure sodium lamp) are equipped with in entering, and transmission speed is to solidify in 50 meters/minute the photo solidification machine; Roller coat one layer thickness is the ultraviolet light polymerization glue-line 3 of 2 μ m then, gets into 3 9.6kw uviol lamps (high-pressure sodium lamp) are housed, and transmission speed is to solidify in 50 meters/minute the photo solidification machine; Again after the surface of ultraviolet light polymerization glue-line overlays one deck and is printed on the marblized UV transfer film of English red; 6 16.8kw uviol lamps (3 Iodine gallium lights and 3 high-pressure sodium lamps) are equipped with in entering; Transmission speed is to solidify in 50 meters/minute the photo solidification machine, and the base load film of removing above-mentioned UV transfer film obtains the marblized pattern 4 of English red, reaches criterion of acceptability through test rating; Paste polypropylene protective film 7, promptly get and imitate English red emmarble board finished product.Wherein:
By weight percentage; The ultraviolet light polymerization seal coat is: epoxy acrylate 10%, urethane acrylate 20%, TPGDA 10%, TMPTA 2%, French chalk 50%, 2, the mixture of 2-dimethoxy-2-phenyl acetophenone 6%, BYK 055 1% and Disperbyk 103 1%.
By weight percentage, ultraviolet cured adhesive is: the mixture of epoxy acrylate 46%, urethane acrylate 34%, TMPTA 5%, TPGDA 12%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 1%, BYK306 1% and BYK055 1%.
Being printed on the marblized UV transfer film of English red is that notification number is the disclosed ultra-violet curing transfer film of CN101941339A.
Embodiment 2. imitative yellow sandal graining plates
See also Fig. 1.There is ultraviolet light polymerization seal coat coating 2 on surface with the ceramic tile blank being ceramic substrate 1; There is ultraviolet light polymerization glue-line 3 on surface in described ultraviolet light polymerization seal coat coating 2; The pattern 4 that the yellow sandal wood grain that obtains through the UV transfer film transfer printing that is printed on the yellow sandal wood grain is arranged on the surface of described ultraviolet light polymerization glue-line 3 has polypropylene protective film 7 on the surface of the pattern of yellow sandal wood grain
To be after the sand milling dedusting is carried out on the surface of ceramic substrate 1 with the ceramic tile blank; In its surface roller coating one layer thickness ultraviolet light polymerization seal coat coating 2 that is 50 μ m; 1 7.6kw uviol lamp (high-pressure sodium lamp) is equipped with in entering, and transmission speed is to solidify in 5 meters/minute the photo solidification machine; Roller coat one layer thickness is the ultraviolet light polymerization glue-line 3 of 50 μ m then, gets into 2 9.6kw uviol lamps (high-pressure sodium lamp) are housed, and transmission speed is to solidify in 5 meters/minute the photo solidification machine; Again after the ultraviolet cured adhesive surface overlays the UV transfer film that one deck is printed on the yellow sandal wood grain; 4 16.8kw uviol lamps (2 Iodine gallium lights and 2 high-pressure sodium lamps) are equipped with in entering; Transmission speed is for solidifying in meter/minute the photo solidification machine, and the base load film of removing above-mentioned UV transfer film obtains the pattern 4 of yellow sandal wood grain, reaches criterion of acceptability through test rating; Paste polypropylene protective film 7, promptly get and imitate yellow sandal graining board finished product.Wherein:
By weight percentage, the ultraviolet light polymerization seal coat is: epoxy acrylate 11%, urethane acrylate 23%, TPGDA 10%, French chalk 50%, 2,2-dimethoxy-2-phenyl acetophenone 6%, mixture.
By weight percentage, ultraviolet cured adhesive is: epoxy acrylate 21%, acrylate copolymer 14%, TMPTA 48%, TPGDA 12%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 1%, benzil dimethyl ketal 1%, 2-benzyl-2-dimethylamino-1-(4-morpholinyl phenyl)-1-butanone 3%, mixture.
The UV transfer film that is printed on the yellow sandal wood grain is that notification number is the disclosed ultra-violet curing transfer film of CN101941339A.
Embodiment 3. imitative numb stone marble decorative boards
See also Fig. 2.There is ultraviolet light polymerization seal coat coating 2 on surface with the ceramic tile blank being ceramic substrate 1; There is ultraviolet light polymerization glue-line 3 on surface in described ultraviolet light polymerization seal coat coating 2; The pattern 4 that the numb parmelia saxatilis line that obtains through the UV transfer film transfer printing that is printed on numb parmelia saxatilis line is arranged on the surface of described ultraviolet light polymerization glue-line 3; There is ultraviolet light polymerization glue-line 5 on surface at the pattern of numb parmelia saxatilis line; On the surface of ultraviolet light polymerization glue-line 5 ultraviolet light polymerization varnish coat 6 is arranged, polypropylene protective film 7 is arranged on the surface of ultraviolet light polymerization varnish coat 6.
To be after the sand milling dedusting is carried out on the surface of ceramic substrate 1 with the ceramic tile blank; In its surface roller coating one layer thickness ultraviolet light polymerization seal coat coating 2 that is 25 μ m; 1 9.6kw uviol lamp (high-pressure sodium lamp) is equipped with in entering, and transmission speed is to solidify in 12 meters/minute the photo solidification machine; Roller coat one layer thickness is the ultraviolet light polymerization glue-line 3 of 10 μ m then, gets into 1 9.6kw uviol lamp (high-pressure sodium lamp) is housed, and transmission speed is a photocuring in 12 meters/minute the photo solidification machine; Again after the ultraviolet cured adhesive surface overlays the UV transfer film that one deck is printed on numb parmelia saxatilis line; 3 16.8kw uviol lamps (1 Iodine gallium light and 2 high-pressure sodium lamps) are equipped with in entering; Transmission speed is to solidify in 12 meters/minute the photo solidification machine; The base load film of removing above-mentioned UV transfer film obtains the pattern 4 of numb parmelia saxatilis line; Surface roller coating one layer thickness at the pattern 4 of numb parmelia saxatilis line is the ultraviolet light polymerization glue-line 5 of 12 μ m, gets into 1 9.6kw uviol lamp (high-pressure sodium lamp) is housed, and transmission speed is to solidify in 12 meters/minute the photo solidification machine; Surperficial showering one layer thickness at the ultraviolet light polymerization glue-line is 250 μ m again; Gloss is the ultraviolet light polymerization varnish coat 6 of 100 degree (60 degree gloss meter), is levelling 1 minute under 60 ℃ the infrared rays in temperature, gets into 4 16.8kw uviol lamps (1 Iodine gallium light, 1 iron lamp and 2 high-pressure sodium lamps) are housed; Transmission speed is to solidify in 12 meters/minute the photo solidification machine; Reach criterion of acceptability through test rating, paste polypropylene protective film 7, promptly get and imitate numb stone emmarble board finished product.Wherein:
By weight percentage; The ultraviolet light polymerization seal coat is: epoxy acrylate 60%, urethane acrylate 20%, TPGDA 15%, EO-TMPTA 2%, 2, the mixture of 2-dimethoxy-2-phenyl acetophenone 1%, BYK 055 1% and Disperbyk 103 1%.
By weight percentage, ultraviolet cured adhesive is: the mixture of epoxy acrylate 14.5%, acrylate copolymer 20%, TMPTA 40%, TPGDA 20%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, benzil dimethyl ketal 2%, 2-benzyl-2-dimethylamino-1-(4-morpholinyl phenyl)-1-butanone 1%, BYK306 0.2% and BYK055 0.3%.
By weight percentage; Ultraviolet light polymerization varnish is: urethane acrylate 3%, fluorochemical urethane acrylic acid ester 20%, fluoro-acrylate copolymer 10%, TMPTA 25%, acrylic acid hexafluoro butyl ester 35%, 2, the mixture of 2-dimethoxy-2-phenyl acetophenone 5%, BYK 055 1% and BYK 358 1%.
Be printed on the marblized UV transfer film of numb stone for being that notification number is the disclosed ultra-violet curing transfer film of CN101941339A.
Embodiment 4. imitative rose wood graining plates
See also Fig. 2.There is ultraviolet light polymerization seal coat coating 2 on surface with the ceramic tile blank being ceramic substrate 1; There is ultraviolet light polymerization glue-line 3 on surface in described ultraviolet light polymerization seal coat coating 2; The pattern 4 that the rose wood wood grain that obtains through the UV transfer film transfer printing that is printed on the rose wood wood grain is arranged on the surface of described ultraviolet light polymerization glue-line 3; There is ultraviolet light polymerization glue-line 5 on surface at the pattern of rose wood wood grain; On the surface of ultraviolet light polymerization glue-line 5 ultraviolet light polymerization varnish coat 6 is arranged, polypropylene protective film 7 is arranged on the surface of ultraviolet light polymerization varnish coat 6.
To be after the sand milling dedusting is carried out on the surface of ceramic substrate 1 with the ceramic tile blank; In its surface roller coating one layer thickness ultraviolet light polymerization seal coat coating 2 that is 45 μ m; 1 7.6kw uviol lamp (high-pressure sodium lamp) is equipped with in entering, and transmission speed is to solidify in 10 meters/minute the photo solidification machine; Roller coat one layer thickness is the ultraviolet light polymerization glue-line 3 of 12 μ m then, gets into 1 9.6kw uviol lamp (high-pressure sodium lamp) is housed, and transmission speed is to solidify in 10 meters/minute the photo solidification machine; Again after the ultraviolet cured adhesive surface overlays the UV transfer film that one deck is printed on the rose wood wood grain; 4 16.8kw uviol lamps (2 Iodine gallium lights, 1 iron lamp and 1 high-pressure sodium lamp) are equipped with in entering; Transmission speed is to solidify in 10 meters/minute the photo solidification machine; The base load film of removing above-mentioned UV transfer film obtains the pattern 4 of rose wood wood grain; Surface roller coating one layer thickness at the pattern 4 of rose wood wood grain is the ultraviolet light polymerization glue-line 5 of 15 μ m, gets into 1 9.6kw uviol lamp (high-pressure sodium lamp) is housed, and transmission speed is to solidify in 10 meters/minute the photo solidification machine; Surface roller coating one layer thickness at the ultraviolet light polymerization glue-line is 20 μ m again; Gloss is the ultraviolet light polymerization varnish coat 6 of 5 degree (60 degree gloss meter), is levelling 1 minute under 60 ℃ the infrared rays in temperature, gets into 3 16.8kw uviol lamps (1 Iodine gallium light, 1 iron lamp and 1 high-pressure sodium lamp) are housed); Transmission speed is to solidify in 10 meters/minute the photo solidification machine; Reach criterion of acceptability through test rating, paste polypropylene protective film 7, promptly get and imitate rose wood graining board finished product.Wherein:
By weight percentage; The ultraviolet light polymerization seal coat is: epoxy acrylate 20%, urethane acrylate 30%, TPGDA 10%, EO-TMPTA 20%, French chalk 15%, 2, the mixture of 2-dimethoxy-2-phenyl acetophenone 4.5%, BYK 055 0.2% and Disperbyk 103 0.3%.
By weight percentage, ultraviolet cured adhesive is: the mixture of epoxy acrylate 20%, acrylate copolymer 30%, TMPTA 32.5%, TPGDA 10%, 2-hydroxy-2-methyl-1-phenyl-1-acetone 2%, benzil dimethyl ketal 2%, 2-benzyl-2-dimethylamino-1-(4-morpholinyl phenyl)-1-butanone 3%, BYK306 0.2% and BYK055 0.3%.
By weight percentage; Ultraviolet light polymerization varnish is: urethane acrylate 25%, fluorochemical urethane acrylic acid ester 30%, fluoro-acrylate copolymer 10%, trifluoroethyl methacrylate 10%, PETA 10%, 2, the mixture of 2-dimethoxy-2-phenyl acetophenone 4%, flatting silica 10%, BYK 055 0.2%, BYK 306 0.3% and Disperbyk 103 0.5%.
The UV transfer film that is printed on the rose wood wood grain is that notification number is the disclosed ultra-violet curing transfer film of CN101941339A.
Claims (7)
1. ceramic base ultraviolet light curing overlay film decorative panel; It is characterized in that: described ceramic base ultraviolet light curing overlay film decorative panel is that ultraviolet light polymerization seal coat coating is arranged on the surface of ceramic substrate; There is the ultraviolet light polymerization glue-line on surface in described ultraviolet light polymerization seal coat coating; On the surface of described ultraviolet light polymerization glue-line the pattern that obtains through the transfer printing of ultra-violet curing transfer film is arranged, polypropylene protective film or polyvinyl protective film are arranged on the surface of described pattern.
2. ceramic base ultraviolet light curing overlay film decorative panel according to claim 1 is characterized in that: between the surface of pattern and polypropylene protective film or polyvinyl protective film, ultraviolet light polymerization glue-line and ultraviolet light polymerization varnish coat are arranged on the surface of pattern successively.
3. ceramic base ultraviolet light curing overlay film decorative panel according to claim 1 is characterized in that: described ceramic substrate is selected from a kind of in ceramic wafer, potter's clay plate, type ceramic wafer, type potter's clay plate.
4. ceramic base ultraviolet light curing overlay film decorative panel according to claim 1 is characterized in that: the thickness of described ultraviolet light polymerization seal coat coating is 10～150 μ m.
5. ceramic base ultraviolet light curing overlay film decorative panel according to claim 1 and 2 is characterized in that: the thickness of described ultraviolet light polymerization glue-line is 2～50 μ m.
6. ceramic base ultraviolet light curing overlay film decorative panel according to claim 2 is characterized in that: the thickness of described ultraviolet light polymerization varnish coat is 5～250 μ m.
7. ceramic base ultraviolet light curing overlay film decorative panel according to claim 6 is characterized in that: the gloss of described ultraviolet light polymerization varnish coat is that 5～100 degree are adjustable, with 60 degree gloss meters.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201120401031XU CN202265970U (en) | 2011-10-20 | 2011-10-20 | Ceramic-based ultraviolet-curing film-coated decoration plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201120401031XU CN202265970U (en) | 2011-10-20 | 2011-10-20 | Ceramic-based ultraviolet-curing film-coated decoration plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202265970U true CN202265970U (en) | 2012-06-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201120401031XU Expired - Fee Related CN202265970U (en) | 2011-10-20 | 2011-10-20 | Ceramic-based ultraviolet-curing film-coated decoration plate |
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| CN (1) | CN202265970U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104178019A (en) * | 2014-09-09 | 2014-12-03 | 苏州圣谱拉新材料科技有限公司 | Photocuring coating for ceramic |
| CN107139302A (en) * | 2017-07-01 | 2017-09-08 | 安徽省扬子家居新材料有限公司 | A kind of pretreating process of raw wood for wooden door |
-
2011
- 2011-10-20 CN CN201120401031XU patent/CN202265970U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104178019A (en) * | 2014-09-09 | 2014-12-03 | 苏州圣谱拉新材料科技有限公司 | Photocuring coating for ceramic |
| CN107139302A (en) * | 2017-07-01 | 2017-09-08 | 安徽省扬子家居新材料有限公司 | A kind of pretreating process of raw wood for wooden door |
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