CN202189808U - Patterned solar photovoltaic panel - Google Patents
Patterned solar photovoltaic panel Download PDFInfo
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- CN202189808U CN202189808U CN2011202102181U CN201120210218U CN202189808U CN 202189808 U CN202189808 U CN 202189808U CN 2011202102181 U CN2011202102181 U CN 2011202102181U CN 201120210218 U CN201120210218 U CN 201120210218U CN 202189808 U CN202189808 U CN 202189808U
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- electronic board
- solar opto
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/10—Photovoltaic [PV]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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Abstract
A patterned solar photovoltaic panel comprises a transparent substrate, a semiconductor material layer, a protective and/or reflective material layer, a package board, a bonding layer and a pattern layer, wherein the semiconductor material layer is formed on the transparent substrate, the protective and/or reflective material layer covers the semiconductor material layer, the bonding layer is positioned between the transparent substrate and the package board, and the pattern layer is formed on the surface of or inside of optional one of the transparent substrate, the protective and/or reflective material layer, the package board and/or the bonding layer, or the pattern layer are disposed between optional two of the transparent substrate, the semiconductor material layer, the protective and/or reflective layer, the package board or the bonding layer. The patterned solar photovoltaic panel can be mounted in a common ground type solar power plant, can also be integrated to coverings of a building such as walls, a roof or the like, beautifies the solar power plant or the appearance of the building, increases added values of beautifying the building and the environment, and is both a power generating device and an ornamental art device.
Description
Technical field
The utility model relates to a kind of solar opto-electronic board with pattern, and its major function is to transform daylight to become electric power, possesses simultaneously to beautify the environment or the surcharge of facade.
Background technology
Environmental consciousness comes back in recent years, adds that the energy starved subject under discussion is suggested frequently, so various countries drop into manpower one after another and material resources develop oligosaprobic alternative energy source, what wherein attract most attention just belongs to the solar energy power technology.Need a large amount of land areas yet solar opto-electronic board is installed, this area, capital at populous and an inch of land is an inch of gold just becomes development bottleneck.Therefore follow-up have the people that solar photoelectric and Building technology are integrated again, the integrated solar photovoltaic system of building (Building-Integrated Photovoltaic, notion BIPV) and develop.
Because solar opto-electronic board is to be used being converted into electric energy after the sunlight absorption; Therefore the transparency carrier as the irradiation face generally all is a glass of as far as possible selecting for use light transmittance high in design; Color and appearance are comparatively dull, only have the enterprise development of minority to go out colored solar opto-electronic board.Though this type colored solar electro-optical package changes on color, the often shortcoming of concomitant loss generated output, and still dull in appearance no change for the user who follows the fashion with aesthetic feeling, is a big shortcoming in fact.The utility model is the product of developing in order to solve this shortcoming.
The utility model content
For improving the shortcoming of prior art; The purpose of the utility model is to provide a kind of solar opto-electronic board with pattern; Under the prerequisite that does not influence generating efficiency, on solar opto-electronic board, form various decorative pattern, pattern, literal, symbol or look the demand assistant with decorative article.
To achieve these goals, the utility model provides a kind of solar opto-electronic board with pattern, and this solar opto-electronic board comprises:
One transparency carrier;
Semiconductor material layer group, it is formed on this transparency carrier;
One protection and/or layer of reflective material covers on the semiconductor material layer group;
One encapsulation sheet material;
One cementing layer, it is at this transparency carrier and should encapsulate between the sheet material; And
One design layer; Be formed at the arbitrary surfaces or the inside of said transparency carrier, protection and/or layer of reflective material, encapsulation sheet material and/or cementing layer; Perhaps, this design layer be arranged at said transparency carrier, semiconductor material layer group, protection and/or layer of reflective material, encapsulation sheet material or cementing layer arbitrarily between the two.
Above-mentioned solar opto-electronic board, wherein, this design layer is formed at the surperficial or inner of said transparency carrier.
Above-mentioned solar opto-electronic board, wherein, this design layer has the transparency carrier of the specific region of different degree of roughness for the surface.
Above-mentioned solar opto-electronic board, wherein, this design layer is through being surface or inner transparency carrier with specific region of different optical scattering and refraction.
Above-mentioned solar opto-electronic board, wherein, this design layer is formed between this protection and/or layer of reflective material and this cementing layer.
Above-mentioned solar opto-electronic board, wherein, this design layer is formed between this cementing layer and the encapsulation sheet material.
Above-mentioned solar opto-electronic board, wherein, this design layer is formed at the surperficial or inner of this encapsulation sheet material.
Above-mentioned solar opto-electronic board, wherein, this design layer is through having the encapsulation sheet material of the specific region of different degree of roughness for the surface.
Above-mentioned solar opto-electronic board, wherein, this design layer is surface or inner encapsulation sheet material with specific region of different optical scattering and refraction.
Above-mentioned solar opto-electronic board; Wherein, This design layer is formed at one of four corners and/or at least four edges of said transparency carrier, protection and/or layer of reflective material, encapsulation sheet material or cementing layer; And this design layer is the part in the complete pattern, so that a plurality of solar opto-electronic board adjacent set is fashionable, adjoiner can be pieced together and form a complete pattern.
Above-mentioned solar opto-electronic board wherein, also further comprises decoration, and this decoration is attached at the surface of this solar opto-electronic board.
Above-mentioned solar opto-electronic board wherein, also further comprises one or more light sources.
Above-mentioned solar opto-electronic board, wherein, this light source is attached at the surface of this encapsulation sheet material.
Above-mentioned solar opto-electronic board wherein, also further comprises a diffuser plate, and it is attached at the surface of encapsulation sheet material, and device has one or more light sources on the diffuser plate.
Above-mentioned solar opto-electronic board wherein, also further comprises a LGP, and it is attached at the surface of encapsulation sheet material.
Above-mentioned solar opto-electronic board, wherein, this lamp source is for embedding the inside of this solar opto-electronic board side or encapsulation sheet material.
Above-mentioned solar opto-electronic board wherein, also further comprises a LGP, and it is positioned at the inside of this solar opto-electronic board.
The utility model become by solar opto-electronic board possess fashion, the TRT of aesthetic feeling and modernization design sense; The utility model can be installed on general terrestrial solar power plant; Also can be integrated into the lining material such as metope or roof of building; Can significantly beautify solar power plant itself or facade, make solar opto-electronic board except basic electricity generate function, more increase the surcharge of beautifying constructure and environment; Make no longer just TRT of solar power system, and also can be the artistic device of a tool ornamental value simultaneously.
The formation of the pattern that the utility model solar opto-electronic board outward appearance is manifested can be accomplished through many methods, as: sandblast, laser, chemical etching, print, paste, stealthy engraving etc.Take to be used for forming the method for pattern, be prerequisite not influence the solar opto-electronic board generating as far as possible, will in following embodiment, explain.
Below in conjunction with accompanying drawing and specific embodiment the utility model is described in detail, but not as the qualification to the utility model.
Description of drawings
Figure 1A: the front view of solar opto-electronic board 100;
Figure 1B: the structure cutaway view of solar opto-electronic board 100;
Fig. 2 A: the sketch map of forming a complete pattern by four solar opto-electronic boards 100;
Fig. 2 B: the sketch map of forming a complete pattern by two solar opto-electronic boards 100;
Fig. 3 A, 3B: solar opto-electronic board 100 different angles can manifest the sketch map of different pattern;
Fig. 4: the structural representation of flat-plate light source 60;
Fig. 5: the structure cutaway view that flat-plate light source 60 is sticked in encapsulation sheet material 50 surfaces;
Fig. 6: the structure cutaway view that flat-plate light source 60 is packaged in solar opto-electronic board 100 inside.
Wherein, Reference numeral
100 solar opto-electronic boards
101 patterns
10 transparency carriers
The surface of 10a transparency carrier
20 semiconductor material layer groups
30 protection and/or reflection function material layers
The surface of 30b protection and/or reflection function material layer
40 cementing layers
The surface of 40a cementing layer
The surface of 40b cementing layer
41 second cementing layers
50 encapsulation sheet materials
The surface of 50a encapsulation sheet material
The surface of 50b encapsulation sheet material
60 flat-plate light sources
61 LGPs
62 strip light sources
Embodiment
The utility model solar opto-electronic board 100 (shown in Figure 1A, Figure 1B) can comprise a transparency carrier 10, semiconductor material layer group 20, a protection and/or reflection function property material layer 30, a cementing layer 40 and an encapsulation sheet material 50.This semiconductor material layer group 20 is formed on the transparency carrier 10, then is coated with layer of protecting and/or reflection function property material layer 30.The last transparency carrier 10 that will form semiconductor material layer group 20 with cementing layer 40 again is packaged as a whole with the process of encapsulation sheet material 50 through high-temperature pressurizing.
When solar opto-electronic board 100 was light-permeable, transparency carrier 10 comprised transparent materials such as glass, plastic plate, acrylic board with the material of encapsulation sheet material 50.Semiconductor material layer group 20 comprises preceding electrode layer, light absorbing zone, dorsum electrode layer etc., and the material of preceding electrode layer or dorsum electrode layer comprises: zinc oxide, tin oxide, tin indium oxide or other metal oxide transparent conducting layer etc.; Light absorbing zone comprises: the combination of amorphous silicon membrane, microcrystalline silicon film, I-III-VI group element compound film (like CIGS, CIS, CZTS etc.), cadmium sulphide membrane, cadmium antimonide film etc. or above-mentioned material.Protection and/or reflection function property material layer 30 can be used for protecting semiconductor material layer, and its material comprises the acrylic co-polymer.The material of cementing layer 40 comprises polyvinyl butyral resin (PVB), ethylene-vinyl acetate copolymer (EVA) etc.The utility model is not as limit.
Further, when the utility model solar opto-electronic board 100 was light-permeable, the material of transparency carrier 10 comprised transparent materials such as glass, plastic plate, acrylic board.Semiconductor material layer group 20 comprises preceding electrode layer, light absorbing zone, dorsum electrode layer etc., and the material of preceding electrode layer comprises: zinc oxide, tin oxide, tin indium oxide or other metal oxide transparent conducting layer etc.; Light absorbing zone comprises: the combination of amorphous silicon membrane, microcrystalline silicon film, I-III-VI group element compound film (like CIGS, CIS, CZTS etc.), cadmium sulphide membrane, cadmium antimonide film etc. or above-mentioned material; The material of dorsum electrode layer comprises: zinc oxide, tin oxide, tin indium oxide, other metal oxide, and/or comprise metal levels such as aluminium, silver, gold, copper, molybdenum, tantalum.After semiconductor material layer group storehouse is accomplished, to comprise modes such as laser the material of the semiconductor material layer group of regional area is removed again, cause local light-permeable, local lighttight effect.Protection and/or reflection function property material layer 30 can be used for protecting semiconductor material layer group etc., and its material comprises acrylic co-polymer etc.The material of cementing layer 40 comprises polyvinyl butyral resin (PVB), ethylene-vinyl acetate copolymer (EVA) etc.The material of encapsulation sheet material 50 comprises glass, plastic plate, acrylic board etc.The utility model is not as limit.
Further, when the utility model solar opto-electronic board 100 when being light tight, the material of transparency carrier 10 comprises transparent materials such as glass, plastic plate, acrylic board.Semiconductor material layer group 20 comprises preceding electrode layer, light absorbing zone, dorsum electrode layer etc., and the material of preceding electrode layer comprises: zinc oxide, tin oxide, tin indium oxide or other metal oxide transparent conducting layer etc.; Light absorbing zone comprises: the combination of amorphous silicon membrane, microcrystalline silicon film, I-III-VI group element compound film (like CIGS, CIS, CZTS etc.), cadmium sulphide membrane, cadmium antimonide film etc. or above-mentioned material; The material of dorsum electrode layer comprises: zinc oxide, tin oxide, tin indium oxide, other metal oxide, and/or comprise metal levels such as aluminium, silver, gold, copper, molybdenum, tantalum.Protection and/or reflection function property material layer 30 can be used for protecting semiconductor material layer and/or increase reflectivity etc., and its material comprises acrylic co-polymer, titanium dioxide etc.The material of cementing layer 40 comprises polyvinyl butyral resin (PVB), ethylene-vinyl acetate copolymer (EVA) etc.The material of encapsulation sheet material 50 comprises glass, plastic plate, acrylic board, metallic plate, backboard (back sheet) etc.The utility model is not as limit.
In one embodiment, this pattern is to be formed at the surperficial 10a of transparency carrier 10 and/or the surperficial 50b of encapsulation sheet material 50 with the sandblast mode.This pattern comprises the combination in any of decorative pattern, lines, pattern, literal, symbol arbitrarily.Further, can make it produce the different surface roughness properties, further form pattern with GTG effect through changing conditions such as the employed sand assortment of sandblast class, sandblast number of times, sandblast angle, sandblast time.
In another specific embodiment; Can laser focusing be exposed to transparency carrier 10 and/or encapsulation sheet material 50 plate surfaces or inside; The position that makes Stimulated Light focus on irradiation receives after the high temperature melt crystallization again or solidifies; Change refraction and the scattering power of this position, use at transparency carrier 10 and/or encapsulation sheet material 50 plate surfaces or the inner pattern that forms to light.
In another specific embodiment; Can pattern be formed at the surperficial 30b of protection and/or reflection function property material layer 30 or the surperficial 50a of the surperficial 40a of cementing layer 40,40b or encapsulation sheet material 50 with the mode of printing; Make pattern be encapsulated in solar opto-electronic board 100 inside, this pattern can be protected.
In another specific embodiment; Can pattern be printed on the thin transparent rubberized fabric in advance; Again this layer transparent rubberized fabric pasted to the surperficial 30b of protection and/or reflection function property material layer 30 or the surperficial 50a of the surperficial 40a of cementing layer 40,40b or encapsulation sheet material 50, made pattern be encapsulated in solar opto-electronic board 100 inner patterns.
In another specific embodiment, can pattern be formed at the surperficial 10a of transparency carrier 10 and/or the surperficial 50b of encapsulation sheet material 50 with the mode of chemical etching.Its practice is to be coated in the zone that desire forms pattern with glass being had corrosive chemical substance; Leaving standstill a period of time lets the glass surface chemical substance corrode transparency carrier 10 or encapsulation sheet material 50; Remove these chemical substances again, these zones that weather will form pattern because of roughness is different at last.
In another specific embodiment, can a complete pattern be divided into four parts of different corners that also place four different solar opto-electronic boards 100 respectively,, four solar opto-electronic boards 100 can form a complete pattern (shown in Fig. 2 A) when being stitched together.Also can a complete pattern be divided into two parts of different corners that also place two different solar opto-electronic boards 100 respectively, when two solar opto-electronic boards 100 are stitched together, can form a complete pattern (shown in Fig. 2 B).
In another specific embodiment; Stealthy engraving technology capable of using is inscribed in the same area with two kinds of different pattern A and B; Watch from right tiltedly the place ahead of solar opto-electronic board 100 showing pattern A (like Fig. 3 A), and from the left side of solar opto-electronic board 100 tiltedly the place ahead watch and can show pattern B (like Fig. 3 B).
In another specific embodiment; Can further paste decorative article on solar opto-electronic board 100 surfaces; This decorative article comprises clear glass or plastic material, sticks in can beautify outward appearance on the surperficial 10a of transparency carrier 10 and not influence solar opto-electronic board 100 generatings.
In another specific embodiment, when solar opto-electronic board 100 is light-permeable, can on the surperficial 50b of encapsulation sheet material 50, paste one or more light sources.Further, can on the surperficial 50b of encapsulation sheet material 50, attach a diffuser plate, and on diffuser plate, attach one or more light sources, the light that light source sent can be through diffuser plate uniformly dispersing to whole solar opto-electronic board 100.Further; (flat-plate light source is as shown in Figure 4 can on the surperficial 50b of encapsulation sheet material 50, to paste a flat-plate light source 60; The solar opto-electronic board structure is as shown in Figure 5); This flat-plate light source 60 comprises a LGP 61 and the strip light source 62 that is arranged on LGP 61 sides (can be fluorescent tube or a plurality of LED lamps of forming a line) institute and forms, and the light that strip light source 62 is sent can be through LGP 61 conduction uniformly dispersing whole solar opto-electronic board 100 extremely also.Perhaps; Can in the manufacture process of solar opto-electronic board 100, a plurality of LED lamps be placed the surperficial 40b of cementing layer 40, and on a plurality of LED lamps, cover lastblock second cementing layer 41 and encapsulation sheet material 50 again; Encapsulate again, so that a plurality of LED lamps are coated on solar opto-electronic board 100 inside.Further; Can be in the manufacture process of solar opto-electronic board 100; Diffuser plate is placed the surperficial 40b of cementing layer 40, more a plurality of LED lamps are installed on the diffuser plate, and on a plurality of LED lamps, cover one second cementing layer 41 and encapsulation sheet material 50 again; Encapsulate again, so that a plurality of LED lamps are coated on solar opto-electronic board 100 inside.Further, as shown in Figure 6, can flat-plate light source 60 be placed the surperficial 40b of cementing layer 40, cover lastblock second cementing layer 41 and encapsulation sheet material 50 again, encapsulate again, flat-plate light source is packaged in solar opto-electronic board 100 inside.When a plurality of LED lamps or flat-plate light source 60 unlatchings; Especially at night; Can more highlight the pattern on the solar opto-electronic board 100 of previous embodiment,, also possess the function of billboard even let solar opto-electronic board 100 in rayless night, still can possess the effect of decoration.
Certainly; The utility model also can have other various embodiments; Under the situation that does not deviate from the utility model spirit and essence thereof; Those of ordinary skill in the art work as can make various corresponding changes and distortion according to the utility model, but these corresponding changes and distortion all should belong to the protection range of the appended claim of the utility model.
Claims (17)
1. the solar opto-electronic board with pattern is characterized in that, this solar opto-electronic board comprises:
One transparency carrier;
Semiconductor material layer group, it is formed on this transparency carrier;
One protection and/or layer of reflective material covers on the semiconductor material layer group;
One encapsulation sheet material;
One cementing layer, it is at this transparency carrier and should encapsulate between the sheet material; And
One design layer; Be formed at the arbitrary surfaces or the inside of said transparency carrier, protection and/or layer of reflective material, encapsulation sheet material and/or cementing layer; Perhaps, this design layer be arranged at said transparency carrier, semiconductor material layer group, protection and/or layer of reflective material, encapsulation sheet material or cementing layer arbitrarily between the two.
2. solar opto-electronic board according to claim 1 is characterized in that, this design layer is formed at the surperficial or inner of said transparency carrier.
3. solar opto-electronic board according to claim 2 is characterized in that, this design layer has the transparency carrier of the specific region of different degree of roughness for the surface.
4. solar opto-electronic board according to claim 2 is characterized in that, this design layer is through being surface or inner transparency carrier with specific region of different optical scattering and refraction.
5. solar opto-electronic board according to claim 1 is characterized in that, this design layer is formed between this protection and/or layer of reflective material and this cementing layer.
6. solar opto-electronic board according to claim 1 is characterized in that, this design layer is formed between this cementing layer and the encapsulation sheet material.
7. solar opto-electronic board according to claim 1 is characterized in that, this design layer is formed at the surperficial or inner of this encapsulation sheet material.
8. solar opto-electronic board according to claim 7 is characterized in that, this design layer is through having the encapsulation sheet material of the specific region of different degree of roughness for the surface.
9. solar opto-electronic board according to claim 7 is characterized in that, this design layer is surface or inner encapsulation sheet material with specific region of different optical scattering and refraction.
10. solar opto-electronic board according to claim 1; It is characterized in that; This design layer is formed at one of four corners and/or at least four edges of said transparency carrier, protection and/or layer of reflective material, encapsulation sheet material or cementing layer; And this design layer is the part in the complete pattern, so that a plurality of solar opto-electronic board adjacent set is fashionable, adjoiner can be pieced together and form a complete pattern.
11. solar opto-electronic board according to claim 1 is characterized in that, also further comprises decoration, this decoration is attached at the surface of this solar opto-electronic board.
12. solar opto-electronic board according to claim 1 is characterized in that, also further comprises one or more light sources.
13. solar opto-electronic board according to claim 12 is characterized in that, this light source is attached at the surface of this encapsulation sheet material.
14. solar opto-electronic board according to claim 12 is characterized in that, also further comprises a diffuser plate, it is attached at the surface of encapsulation sheet material, and device has one or more light sources on the diffuser plate.
15. solar opto-electronic board according to claim 12 is characterized in that, also further comprises a LGP, it is attached at the surface of encapsulation sheet material.
16. solar opto-electronic board according to claim 12 is characterized in that, this lamp source is for embedding the inside of this solar opto-electronic board side or encapsulation sheet material.
17. solar opto-electronic board according to claim 16 is characterized in that, also further comprises a LGP, it is positioned at the inside of this solar opto-electronic board.
Priority Applications (1)
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CN2011202102181U CN202189808U (en) | 2011-06-17 | 2011-06-17 | Patterned solar photovoltaic panel |
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CN2011202102181U CN202189808U (en) | 2011-06-17 | 2011-06-17 | Patterned solar photovoltaic panel |
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CN202189808U true CN202189808U (en) | 2012-04-11 |
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CN2011202102181U Expired - Fee Related CN202189808U (en) | 2011-06-17 | 2011-06-17 | Patterned solar photovoltaic panel |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105023956A (en) * | 2014-04-28 | 2015-11-04 | 陈彩惠 | Solar panel structure with pattern |
US9371978B2 (en) | 2014-08-07 | 2016-06-21 | Tsai-Hui Chen | Solar panel assembly with a lighting pattern and including conductors sandwiching a dielectric substance |
CN112002776A (en) * | 2019-05-08 | 2020-11-27 | 李翠煌 | Method for manufacturing surface pattern of solar panel and structure thereof |
WO2021162640A1 (en) * | 2020-02-13 | 2021-08-19 | National University Of Singapore | An improved photovoltaic device |
CN114851762A (en) * | 2021-06-19 | 2022-08-05 | 北京劲吾新能源科技有限公司 | Color photovoltaic module with three-dimensional effect and preparation method thereof |
-
2011
- 2011-06-17 CN CN2011202102181U patent/CN202189808U/en not_active Expired - Fee Related
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105023956A (en) * | 2014-04-28 | 2015-11-04 | 陈彩惠 | Solar panel structure with pattern |
WO2015165326A1 (en) * | 2014-04-28 | 2015-11-05 | 陈彩惠 | Patterned solar panel structure |
US9371978B2 (en) | 2014-08-07 | 2016-06-21 | Tsai-Hui Chen | Solar panel assembly with a lighting pattern and including conductors sandwiching a dielectric substance |
CN112002776A (en) * | 2019-05-08 | 2020-11-27 | 李翠煌 | Method for manufacturing surface pattern of solar panel and structure thereof |
WO2021162640A1 (en) * | 2020-02-13 | 2021-08-19 | National University Of Singapore | An improved photovoltaic device |
CN114851762A (en) * | 2021-06-19 | 2022-08-05 | 北京劲吾新能源科技有限公司 | Color photovoltaic module with three-dimensional effect and preparation method thereof |
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Granted publication date: 20120411 Termination date: 20150617 |
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