CN201258577Y - Strengthened composite floor and manufacturing equipment thereof - Google Patents

Strengthened composite floor and manufacturing equipment thereof Download PDF

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Publication number
CN201258577Y
CN201258577Y CNU2008200592790U CN200820059279U CN201258577Y CN 201258577 Y CN201258577 Y CN 201258577Y CN U2008200592790 U CNU2008200592790 U CN U2008200592790U CN 200820059279 U CN200820059279 U CN 200820059279U CN 201258577 Y CN201258577 Y CN 201258577Y
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China
Prior art keywords
veneer
floor
model
utility
layer
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CNU2008200592790U
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Chinese (zh)
Inventor
陆葛
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SHANGHAI FINE FURNITURE CO Ltd
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SHANGHAI FINE FURNITURE CO Ltd
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Abstract

The utility model provides a laminate composite floor which subsequently comprises a base plate layer (3), a face plate layer (2) arranged above the base plate layer (3) and a surface paint layer (1) above the face plate layer (2) from bottom side to surface. The utility model also provides a device for preparing and steeping the laminate composite floor; the device comprises a steeping fluid preparation stirring unit (4) and a steeping solidifying tank (6); and the steeping solidifying tank (6) is arranged in the downstream of the steeping fluid preparation stirring unit (4). The utility model provides the laminate composite floor with higher surface hardness, good anti-impact and wear resistant performance and more elegant color, and the device for manufacturing the floor.

Description

A kind of strengthening composite floor and manufacturing equipment thereof
Technical field
The utility model relates to the building field, relates to higher strengthening composite floor and the manufacturing equipment thereof of a kind of surface strength (hardness and shock resistance) particularly.
Background technology
Present employed composite floor board can be divided into solid wood dash board veneer composite floor board and impregnated paper veneer composite floor board substantially.The former is owing to be subjected to the Effect on Performance of timber own, and hardness is low, shock resistance is little, and is not wear-resisting, is not suitable for the public arena.This is because the hardness of timber own is not high, is subjected to colliding with or pressing mill of hard material, can stay impression, add top layer paint and wear no resistance, after use a period of time, in case paint film and color layers are worn through, expose the solid wood dash board, make the floor local color difference occur, not attractive in appearance.After then the person is of low grade, do not have solid wood dash board veneer composite floor board good decorating effect.
In sum, this area lacks that a kind of case hardness is higher, shock resistance and anti-wear performance is good, color is more attractive in appearance strengthening composite floor, and makes the equipment on this floor.
The utility model content
First purpose of the present utility model is to provide that a kind of case hardness is higher, shock resistance and anti-wear performance is good, color is more attractive in appearance strengthening composite floor.
Second purpose of the present utility model is to obtain a kind ofly to be used to make that case hardness is higher, the equipment of shock resistance and the strengthening composite floor that anti-wear performance is good, color is more attractive in appearance.
The utility model first aspect provides a kind of strengthening composite floor, and described floor comprises in regular turn from the bottom surface to the surface:
-substrate layer (3),
-be located at the panel layer (2) of described substrate layer (3) top; And
-be located at the surface oil enamelled coating (1) of described panel layer (2) top.
In a specific embodiment of the present utility model, described panel layer (2) is the panel layer that the resin impregnation toughening fragil veneer of individual layer forms, or is moulded by two-layer or two-layer above resin impregnation toughening fragil veneer and to close the panel layer that forms.
In a specific embodiment of the present utility model, the resin in the described resin impregnation toughening fragil veneer is selected from acrylic resin, vinyl acetate resin, styrene resin or its combination.
In a specific embodiment of the present utility model, the veneer in the described resin impregnation toughening fragil veneer is the veneer of solid wood material.
In a specific embodiment of the present utility model, described surface oil enamelled coating (1) is the clean oil enamelled coating.
In a specific embodiment of the present utility model, described substrate layer (3) is selected from one or more layers sheet material, and described sheet material is selected from veneer, shaving board, density board, core-board or its combination.
Preferably, described veneer is a poplar plywood.
In a specific embodiment of the present utility model, the number of plies of described substrate layer (3) is the even level veneer of 6,8,10,12 layers of unsymmetric structure.
Second aspect of the present utility model provides a kind of equipment that is used to make strengthening composite floor, and described equipment comprises:
-maceration extract dosing agitating unit (4),
-dipping solidifies jar (6), and described dipping solidifies the downstream that jar (6) are arranged on described maceration extract dosing agitating unit (4).
In a specific embodiment of the present utility model, described dipping curing jar (a 6) top also is provided with compensating tank (7), and that carries out when being used for causing liquid level to descend after the liquid in the dipping curing jar immerses wood single-plate replenishes.
In a specific embodiment of the present utility model, described dosing agitating unit (4) and described dipping solidify between jar (6) and also are provided with holding vessel (5), are used to store the dipping back and reclaim unnecessary maceration extract and recycle.
The beneficial effects of the utility model are:
1, the utility model production obtains the good dipping intensified panel solid wooden compound floor of a kind of case hardness height, shock resistance and anti-wear performance.
2, in a preference of the present utility model, surface layer plate in the utility model is formed by the resin impregnation toughening fragil veneer of single or multiple lift, this resin impregnation toughening fragil veneer is owing to adopted unsaturated-resin monomer that panel impregnates after thermal-initiated polymerization, nontoxic, reach world's environmental protection requirement fully, and can effectively be filled into behind this resin polymerization in the test-tube baby and conduit of timber, make panel have better dimensional stability.
4, in a preference of the present utility model, surface layer plate in the utility model is formed by the resin impregnation toughening fragil veneer of single or multiple lift, this dipping intensified veneer is after dipping curing is handled, self-colored veneer has been preserved the texture and the color and luster of original timber, the veneer full wafer veneer color homogeneous of dip dyeing, inside and outside unanimity, the ratio of red by adjusting, yellow, black three kinds of dyestuffs can provide versicolor dip dyeing veneer.
5, in a preference of the present utility model, surface layer plate in the utility model is formed by the resin impregnation toughening fragil veneer of single or multiple lift, after veneer dipping of the present utility model curing is handled, to glue spreading of base plate veneer hot pressing then, behind the sanding mortise, do not need to dye separately again, therefore direct surface is covered with paint, lacquer, colour wash, etc. celluloid paint, just can obtain versicolor dipping intensified panel composite floor board.
6, in a preference of the present utility model, the surface layer plate in the utility model is formed by the resin impregnation toughening fragil veneer of single or multiple lift, and the surface layer plate has very high hardness and shock resistance, improves at least three times than untreated veneer.Therefore in use, be subjected to the colliding with and press mill of hard material after, can not stay impression.Can be widely used in commercial public arena.
7, in a preference of the present utility model, surface layer plate in the utility model is formed by the resin impregnation toughening fragil veneer of single or multiple lift, the resin impregnation toughening fragil veneer has possessed color, and color divergence is even, therefore floor whole front panel layer inside and surface color are even, color is constant after the sanding, does not need painted separately during paint finishing again.And in use, after paint was worn through, still color is constant to expose veneer, and was forever wear-resisting, improved application life greatly.
Description of drawings
Fig. 1 is the structural representation of composite floor board of the present utility model.
Fig. 2 is the annexation schematic diagram of equipment of the present utility model.
The specific embodiment
The utility model people is through extensive and deep research, by improving preparation technology, obtained that case hardness is higher, shock resistance and anti-wear performance is good, color is more attractive in appearance strengthening composite floor, and makes the equipment on this floor.Finished the utility model on this basis.In a specific embodiment of the present utility model, the surface layer plate in the utility model is formed by the resin impregnation toughening fragil veneer of single or multiple lift, and is compound with substrate again, thereby reaches the hardness that increases the floor, surperficial shock resistance and performance such as wear-resisting.
Strengthening composite floor
Strengthening composite floor of the present utility model comprises in regular turn from the bottom surface to the surface:
-substrate layer (3),
-be located at the panel layer (2) of described substrate layer (3) top; And
-be located at the surface oil enamelled coating (1) of described panel layer (2) top.
Below each layer of strengthening composite floor described in detail:
Substrate layer (3)
Described substrate layer (3) does not have concrete restriction, can adopt the substrate of the general composite floor board in this area.For example: poplar substrate, Eucalyptus, birch, weedtree substrate, or the combination of several timber.Substrate also comprises density board, shaving board or other veneer and so on.
The number of plies of the substrate sheet material in the described substrate layer is not specifically limited, and can be the traditional number of plies in this area, and example includes but not limited to one deck particularly.
Can adopt the traditional binder in this area to glue together between described substrate layer and the panel layer, only otherwise utility model purpose of the present utility model is produced restriction to get final product.For example adopt the Lauxite binder particularly.Described gluing method also can adopt the traditional gluing method in this area, only otherwise utility model purpose of the present utility model is produced restriction to get final product.The upper surface of common described substrate and the soffit of panel gummed.
In a preference, described substrate layer (3) is selected from one or more layers sheet material, and described sheet material is selected from veneer, shaving board, density board, core-board or its combination.
In a preference, described substrate layer (3) is the even level veneer of 6,8,10,12 layers of unsymmetric structure for the number of plies.
Panel layer (2)
The utility model panel layer (dash board) can be arranged on the substrate by traditional method (for example gluing method).In a preference, described panel layer (2) is the panel layer that the resin impregnation toughening fragil veneer of individual layer forms, or is moulded by two-layer or two-layer above resin impregnation toughening fragil veneer and to close the panel layer that forms.Also promptly, described panel layer can be composited by one or more layers veneer.
Described veneer can be the veneer that this area composite plate commonly used is used, and is not specifically limited.In a preference, the veneer in the described resin impregnation toughening fragil veneer is the veneer of solid wood material.For example be toothed oak veneer, maple veneer, Jia Tuoba veneer or its combination particularly.Its number of plies is not specifically limited, only otherwise utility model purpose of the present utility model is produced restriction to get final product.Be generally 1~4 layer, be preferably 1~2 layer.
In a preference, the resin in the described resin impregnation toughening fragil veneer is selected from acrylic resin, vinyl acetate resin, styrene resin or its combination.
In the preparation process of panel layer, described one or more layers veneer floods in maceration extract and the panel that obtains flooding.
Particularly, during fabrication, wherein panel layer is by with the method for " vacuum---pressurization " unsaturated-resin monomer and finely dispersed dyestuff being impregnated panel inside, pressurized, heated is solidified then, it is even to obtain inside and surface color, veneer is closed in moulding that hardness is higher, and overlays then on substrate, obtains dipping intensified panel composite floor board.
More specifically, impregnating-reinforced composite floorboard of the present utility model is made by the method that comprises the steps:
One or more layers veneer and maceration extract are provided, wherein said maceration extract comprises polymer monomer (for example acrylic monomer or the styrene monomer of 100 weight portions, described acrylic monomers comprises methyl methacrylate, vinyl acetate or its combination, described styrene monomer comprises the styrene monomer of replacement or non-replacement), the initator of 0~0.5 weight portion, the oil-soluble dyes of 0~10 weight portion, the floor used additives of 0~10 weight portion;
Confined space is provided, in described confined space, makes behind described one or more layers veneer of described maceration extract immersion, cause the polymerization of the polymer monomer in the described maceration extract, obtain the panel of dipping;
Described panel and substrate glue together, and obtain described impregnating-reinforced composite floorboard.The floor that obtains is made up of substrate, the panel that is composited by one or more layers veneer that is arranged on the substrate.
Surface oil enamelled coating (1)
The surface oil enamelled coating can adopt the traditional paint in this area to apply and obtain at floor surface.
In a preference, described surface oil enamelled coating (1) is the clean oil enamelled coating.
Below the performance of strengthening composite floor of the present utility model is described:
Impregnating-reinforced composite floorboard of the present utility model, described floor comprise substrate, be arranged on the panel that is composited by one or more layers veneer on the substrate, and described floor shock resistance is 10.07~10.33mm, with the GB/T17657-1999 standard test.
Preferably, the panel on described floor is a toothed oak wood, and the hardness on described floor is 18180N ± 100N, presses GB/T1927~1943-1991 standard test.
Preferably, the panel on described floor is a look wood, and the hardness on described floor is 17120N ± 100N, presses GB/T1927~1943-1991 standard test.
Preferably, the panel on described floor is a maple, and the hardness on described floor is 14210N ± 100N, presses GB/T1927~1943-1991 standard test.
Be used to prepare the equipment of strengthening composite floor
Described equipment of the present utility model comprises:
-maceration extract dosing agitating unit;
-dipping solidifies jar, and described dipping solidifies the downstream that jar is arranged on described maceration extract dosing agitating unit.
Below to the preparation strengthening composite floor equipment describe in detail:
Maceration extract dosing agitating unit
Described maceration extract dosing agitating unit can also be equipped with weighs and metering system.
In a specific embodiment, described weigh and metering system be Agitation Tank, it is made up of electronic weighing instrument, stirring system, infusion pipeline etc.
Dipping solidifies jar
Preferably, described dipping solidifies on the jar and can also be provided with:
-vacuum pressure device, described vacuum pressure device provides vacuum to press for described dipping solidifies jar
Power;
-cooling unit, described cooling unit are arranged on around the tank body of described dipping curing jar.
-ventilation installation, described ventilation installation are positioned at the jar mouthful top that dipping solidifies jar.
In a specific embodiment, dipping solidifies jar 6 can adopt traditional airtight tank body, for example by tank body (double-jacket), cover; And be arranged on valve on the tank body, defeated liquid back pipe road, liquid trap, thermocouple and compositions such as temperature pick up, pressure vacuum gauge, heating pipe line and cooling line, veneer frame.
In a specific embodiment of the present utility model, described dipping solidifies a jar top and also is provided with compensating tank, is used to flood liquid in solidifying jar and immerses replenishing that liquid level behind the wood single-plate descends.
Compensating tank can adopt the traditional structure in this area.In a specific embodiment, compensating tank 7 is made up of safety valve, vacuum line, pressure pipeline, release pipeline and magnetic post upset content gauge etc.
Described cooling unit is not specifically limited, and can adopt this area cooling unit commonly used, as long as the low temperature of the storage life that can prolong maceration extract is provided.Heat transfer medium in the described cooling unit is not specifically limited, only otherwise utility model purpose of the present utility model is produced restriction to get final product.For example adopt the chilled water cooling particularly.More specifically, adopt the chilled water of withstand voltage 0~5kg/cm2 to cool off.
Described cooling unit can be installed in dipping by the traditional mounting means in this area and solidify on jar and the holding vessel, as long as can be so that described dipping solidifies jar and holding vessel maintains temperature required.Particularly, described cooling unit is arranged on the tank body interlayer of described dipping curing jar and the coil pipe of storage tank body.
Described vacuum pressure device is not specifically limited, and can adopt this area vacuum pressure device commonly used, only otherwise utility model purpose of the present utility model is produced restriction to get final product.For example adopt vacuum pump, surge tank particularly, the high pressure high pure nitrogen.More specifically, vacuum be-0.05~-vacuum plant and the withstand voltage 50~100kg/cm of 0.1Mpa 2Pressure apparatus.
Described vacuum pressure device can be installed in dipping by the traditional mounting means in this area and solidify on the jar, provides required pressure as long as dipping is solidified jar.Particularly, described vacuum pressure device is installed on the dipping curing jar by welding and flange ways of connecting.
Contain maceration extract in the described dipping curing jar.
In a preference, described maceration extract comprises 100 parts by weight of acrylic class monomers (comprising methyl methacrylate, styrene, vinyl acetate etc.), the initator of 0~0.5 weight portion, the oil-soluble dyes of 0~10 weight portion, the floor used additives of 0~10 weight portion.
In the described maceration extract, initator of the present utility model is not specifically limited, and can adopt the traditional radical polymerization initiator in this area, only otherwise utility model purpose of the present utility model is produced restriction to get final product.For example, radical polymerization initiator can adopt azo-compound, peroxide, acetophenones, diphenyl ketone, ketal (ketal) class, anthraquinone class, thioxanthones (thioxanthone) class, 2,3-dialkyl group dione compounds class, di-sulphide compounds class, thiocarbamoyl (thiuram, i.e. NH 2CS-) radical initiator such as compounds, amine fluoride compound.Described peroxide radical initiator comprises organic peroxide catalyst such as ketone peroxide, ketal peroxide, hydrogen peroxide, peroxidating diallyl, peroxidating diacyl, peroxyester, peroxy dicarbonate.Described azo compound comprises azo-compounds such as azodiisobutyronitrile, azo dicarbonamide.
Preferably described initator is selected from azo compound, for example azodiisobutyronitrile, ABVN or its combination.
The consumption of described initator can be decided according to the consumption of conventional initiator in the polymer monomer.Be generally 0~0.5 weight % of polymer monomer, also promptly contain the initator of 0~0.5 weight portion in the polymer monomer of 100 weight portions; Preferably, be 0.1~0.3 weight portion.
Under the situation that does not contain initator, can also adopt the traditional illumination in this area to cause, heat causes etc. makes described polymer monomer carry out polymerization.
In the described maceration extract, oil-soluble dyes can adopt the traditional oil-soluble dyes in this area, as long as described oil-soluble dyes can carry out painted to plank as required.Those skilled in the art can easily select suitable oil-soluble dyes according to required floor color.For example, can be carbon black, nigrosine, iron black etc. as black dyes.As weld can be such as but not limited to everbright fast yellow, permanent yellow, iron oxide yellow, zinc yellow, cadmium yellow, nickel titanium yellow, Naples yellow, naphthol yellow S, hansa yellow G, hansa yellow 10G, benzidine yellow G, benzidine yellow G R, quinoline yellow, tartrazines, benzimidazolone Huang etc.As orange can be such as but not limited to molybdate orange, cadmium orange, chrome vermilion, permanent orange GTR, Benzidine orange G, dianisidine orange etc.As orchil can be such as but not limited to iron oxide red, madder lake, crimson lake, permanent bordeaux, lithol red, pyrazolone red, C lake red CAN'T D, eosine lake, rhodamine color lake B, alizarine lake, the red B0 of the clean DDP of Yi Erjia etc.As the brown dyestuff such as but not limited to umber, loess, burnt ochre, burnt sienna etc.As cudbear can be such as but not limited to manganese violet, cobalt violet, iron oxide purple, crystal violet color lake, carbazole violet etc.As blue dyes can be such as but not limited to Prussian blue, ultramarine, cobalt blue, alkali blue lake, Victoria blue color lake, phthalocyanine blue, indanthrene blue etc.As green colouring material can be such as but not limited to chrome green, the green B of dyestuff, peacock green color lake, phthalocyanine green, naphthol green etc.As white dyestuff can be such as but not limited to zinc white, titanium dioxide, stibium trioxide, zinc sulfate etc.Above-mentioned dyestuff can use separately, also can two or more be used in combination.
The consumption of described oil-soluble dyes is chosen wantonly, selects according to the color on floor.For example be 0~10 weight % of polymer monomer particularly, also promptly contain the oil-soluble dyes of 0~10 weight portion in the polymer monomer of 100 weight portions.
Can randomly can also add the floor used additives of 0~10 weight portion in the described maceration extract.Described floor used additives can be the traditional auxiliary agent in this area, for example is antioxidant, plasticizing agent, dispersing agent, color-fixing agent, bleeding agent, dye leveller etc. or its combination.
One of characteristics of equipment of the present utility model provide confined space, make in described confined space behind described one or more layers veneer of described maceration extract immersion, cause the polymerization of described polymer monomer, obtain the panel of dipping.Particularly, described confined space solidifies jar for dipping.
It is to operate like this that dipping of the present utility model solidifies jar:
Make in described dipping solidifies jar when described maceration extract immerses described one or more layers veneer that described dipping solidifies and jar feeds a nitrogen, and the pressure that described dipping solidifies jar is 5~30kg/cm 2, pressurize 30~180min fully immerses in the described veneer described maceration extract.
Preferably, before veneer is placed described confined space in, vacuumize 10~30min earlier, remove moisture and air in the veneer, suck maceration extract then.
Particularly, when causing the polymerization of described polymer monomer, add nitrogen to 5~15kg/cm 2, and being heated to 70~90 ℃ of heat cure initiated polymerizations, the heat-insulation pressure keeping time is 60~240min.
Preferably, when obtaining the panel of dipping, cool off described dipping with cooling unit and solidify jar, reclaim the polymer monomer of cooling, and adopt vacuum plant to vacuumize gas residual in the veneer is extracted out, obtain the panel of described dipping to room temperature.
Holding vessel
In a specific embodiment of the present utility model, between solidifying jar, described dosing agitating unit and described dipping also be provided with holding vessel, and be used to store the dipping back and reclaim unnecessary maceration extract and recycle.Preferably, around the described storage tank body cooling system is set, low temperature can prolong the storage life of maceration extract.
Holding vessel can adopt the traditional structure in this area.In a specific embodiment, holding vessel is by tank body, cover, valve, floating ball lever meter, liquid-level switch, observation port; The window lamp; Content gauge, vacuum pressure steam vent, defeated liquid back pipe road etc. are formed according to traditional mounting means.
In a specific embodiment of the present utility model, described manufacturing equipment is running like this:
1. manufacturing and designing of production equipment special: complete equipment comprises the dosing stirring system, and jar, compensating tank, cooling system and ventilation system are solidified in vacuum pressure system, holding vessel, dipping, and has been equipped with advanced person's automated system such as pneumatic, automatically controlled.
2. the configuration of maceration extract: methymethacrylate and the initator azodiisobutyronitrile ratio in 100:0.15 is cooperated, it is the oil-soluble dyes of 0-10% that dyeing product adds impregnation concentration, according to red, yellow, black allotment in proportion, it is even to produce color and luster, versicolor dipping veneer.
3. veneer is put at interval dipping and solidified jar, vacuumize 10~30min earlier, remove moisture and air in the veneer, suck maceration extract then.
4. in impregnating autoclave, feed nitrogen, be forced into 5~30kg/cm 2, pressurize 30~180min fully immerses in the wood single-plate maceration extract.
5. get rid of dipping and solidify a jar interior remaining maceration extract, secondary adds nitrogen to 5~15kg/cm 2, and being heated to 70~90 ℃ of heat cure initiated polymerizations, the heat-insulation pressure keeping time is 60~240min.
6. the cooling dipping solidifies jar to room temperature, reclaims the monomer of cooling, and secondary vacuum pumping, and gas residual in the veneer is extracted out, has promptly obtained the dipping veneer.
7. will flood veneer and base plate bonding is made into composite floor board, and promptly obtain dip dyeing and strengthen compound commercial floor.
Other aspects of the present utility model are because the disclosure of this paper is conspicuous to those skilled in the art.
Below in conjunction with specific embodiment, further set forth the utility model.Should be understood that these embodiment only to be used to the utility model is described and be not used in the restriction scope of the present utility model.The experimental technique of unreceipted actual conditions in the following example usually according to normal condition, or carries out according to the condition that manufacturer advises.Unless otherwise indicated, otherwise all umbers are weight portion, and all percentages are weight percentage.
Unless otherwise defined or explanation, the meaning that all specialties used herein are familiar with scientific words and those skilled in the art is identical.Any in addition method similar or impartial to described content and material all can be applicable in the utility model method.
Embodiment 1
The composition of strengthening composite floor comprises transparent surface oil enamelled coating 1, panel layer 2 and substrate layer 3.As shown in Figure 1, from the bottom surface to the surface be in regular turn: substrate layer 3, be located at the panel layer 2 of described substrate layer 3 tops; And the surface oil enamelled coating 1 that is located at described panel layer 2 tops.
Wherein said surface oil enamelled coating 1 can be transparent.In a specific embodiment, described surface oil enamelled coating comprises transparent priming, putty and finish paint (not shown).Described surface oil enamelled coating 1 is the surface course of strengthening composite floor, is used to improve the anti-impact and the anti-wear performance of strengthening composite floor.
Described panel layer 2 is that 1~4 layer resin impregnation toughening fragil veneer is moulded and closed the panel layer that forms.For example be toothed oak veneer, maple veneer, Jia Tuoba veneer or its combination particularly.Resin in the described resin impregnation toughening fragil veneer can be selected from acrylic resin, vinyl acetate resin, styrene resin or its combination.
The substrate layer 3 of present embodiment can be the full poplar plywood of even level of 6 layers, 8 layers, 10 layers, 12 layers unsymmetric structure, also can be sheet materials such as shaving board, density board, core-board.
Described resin impregnation toughening fragil veneer obtains like this: unsaturated-resin monomer and deployed dyestuff are impregnated into veneer inside with the method for vacuum pressed, and pressurized, heated is solidified then, obtains inside and outside color uniformity, impregnating resin veneer that intensity is higher.In a specific embodiment, adopt following method to obtain described resin impregnation toughening fragil veneer:
Raw material is as follows:
Maceration extract: the part by weight of methyl methacrylate and initator azodiisobutyronitrile being pressed 100:0.15 cooperates, the oil-soluble dyes that add 5% weight portion are (according to red, yellow, black allotment in proportion, methyl methacrylate 100: oiling red 1.84: oiling Huang 0.86: solvent black 0.3).
Veneer #1:(producer: Shanghai is big good, model: 1240 * 106 * 2.1mm, material: toothed oak wood)
Veneer #2:(producer: Shanghai is big good, model: 1240 * 106 * 2.1mm, material: look wood)
Veneer #3:(producer: Shanghai is big good, model: 1240 * 106 * 2.1mm, material: maple.)
Substrate: (producer: Shanghai is big good, model: 1240 * 1240 * 8.5mm, material: poplar.)
(1) veneer #1 is put at interval dipping and solidify jar, vacuumize 10~30min earlier, remove moisture and air in the veneer, suck maceration extract then, guarantee that veneer all submerges in the maceration extract.
(2) in impregnating autoclave, feed nitrogen, be forced into 5~30kg/cm 2, pressurize 30~180min fully immerses in the wood single-plate maceration extract.
(3) get rid of dipping and solidify a jar interior remaining maceration extract, secondary adds nitrogen to 5~15kg/cm 2, and being heated to 70~90 ℃ of heat cure initiated polymerizations, the heat-insulation pressure keeping time is 60~240min.
(4) the cooling dipping solidifies jar to room temperature, reclaims the monomer of cooling, and secondary vacuum pumping, and gas residual in the veneer is extracted out, has promptly obtained the dipping veneer.
(5) will flood veneer and base plate bonding is made into composite floor board, and promptly obtain dip dyeing and strengthen compound commercial floor #1.
The performance of described floor #1~3 is as follows:
(1) hardness
Pressing GB/T1927~1943-1991 detects: #1 (toothed oak wood) 18180N, #2 (look wood) 17120N, #3 (maple) 14210N.
The preparation on contrast floor: repeat the preparation process of floor #1, difference is that the timber behind the dipping monomer does not adopt dipping to solidify jar dipping but seals with sealed polyethylene plastic.The hardness of the general floorings that obtains is: toothed oak wood flooring 5300N, look wood flooring 5170N, maple floor 6060N.
(2) shock resistance
Shock resistance: detect by GB/T17657-1999: dipping floor #1~3 are 10.07,10.20,10.33mm.
The preparation on contrast floor: repeat the preparation process of floor #1, difference is that the timber behind the dipping monomer does not adopt dipping to solidify jar dipping but seals with sealed polyethylene plastic.The shock resistance of the general floorings that obtains is: toothed oak wood flooring, look wood flooring, the maple floor is 12.6~12.67mm.
The dipping veneer that present embodiment is made is after making the floor, and the Natural color product can keep the true qualities of original timber, and dimensional stability is good, and case hardness improves more than 150%, and shock resistance improves more than 40, and anti-wear performance also has very high raising; The inside and outside solid colour of dyeing product, lovely luster, unity and coherence in writing is attractive in appearance, can be applicable to multiple public arena.
Embodiment 2
As shown in Figure 2, equipment of the present utility model comprises :-maceration extract dosing agitating unit 4, and-dipping solidifies jar 6, and described dipping solidifies the downstream that jar 6 is arranged on described maceration extract dosing agitating unit 4.Described dipping solidifies jar 6 tops and also is provided with compensating tank 7, and that carries out when being used for causing liquid level to descend after the liquid in the dipping curing jar immerses wood single-plate replenishes.Described dosing agitating unit 4 and described dipping also are provided with holding vessel 5 between solidifying jars 6, are used to store the dipping back and reclaim unnecessary maceration extract and recycle.
Complete equipment comprises the dosing stirring system, and jar, compensating tank, cooling system and ventilation system are solidified in vacuum pressure system, holding vessel, dipping, and has been equipped with advanced person's automated system such as pneumatic, automatically controlled.
Equipment of the present utility model is running like this:
1. manufacturing and designing of production equipment special: complete equipment comprises the dosing stirring system, and jar, compensating tank, cooling system and ventilation system are solidified in vacuum pressure system, holding vessel, dipping, and has been equipped with advanced person's automated system such as pneumatic, automatically controlled.
2. the configuration of maceration extract: methymethacrylate and the initator azodiisobutyronitrile ratio in 100:0.15 is cooperated, dyeing product adding impregnation concentration is 3% oil-soluble dyes, according to red, yellow, black allotment in proportion, it is even to produce color and luster, versicolor dipping veneer.
3. veneer is put at interval dipping and solidified jar, vacuumize 10~30min earlier, remove moisture and air in the veneer, suck maceration extract then.
4. in impregnating autoclave, feed nitrogen, be forced into 10kg/cm 2, pressurize 30~180min fully immerses in the wood single-plate maceration extract.
5. get rid of dipping and solidify a jar interior remaining maceration extract, secondary adds nitrogen to 5~7kg/cm 2, and being heated to 70~90 ℃ of heat cure initiated polymerizations, the heat-insulation pressure keeping time is 60~240min.
6. the cooling dipping solidifies jar to room temperature, reclaims the monomer of cooling, and secondary vacuum pumping, and gas residual in the veneer is extracted out, has promptly obtained the dipping veneer.
7. will flood veneer and be made into composite floor board, and promptly obtain dip dyeing and strengthen compound commercial floor with full poplar base plate bonding.
The present embodiment step 2. in maceration extract proportioning process, earlier that oil-soluble dyes are red, yellow, deceive and dissolves in the methyl methacrylate monomer if produce non-Natural color product by 3% concentration, be deployed into shades of colour in proportion with 3% color mother liquor then.
The present embodiment step vacuumizes in 3., and vacuum is reached-0.1Mpa, keeps 10~20min then.Interval 2~3mm when veneer is piled up.
The present embodiment step 4. in nitrogen pressure to 10kg/cm 2, can improve the efficient of impregnating greatly, shorten dip time.
The present embodiment step 5. in secondary can reduce the volatilization of monomer with nitrogen pressure, prevent that veneer from meeting the oxidized variable color of air in heating process, also prevent methymethacrylate at high temperature steam contact inflammable and explosive problem with oxygen.Mode of heating adopts the heating of impregnating autoclave jacket steam, homogeneous heating in jar.And adopting automatic controllable temperature system, the diverse location temperature difference is less than 5 ℃ in jar.And in the process of being heating and curing, pile up for the partial monosomy that prevents to flow out in timber goes out to solidify at the discharge opeing mouth of pipe, design unique cooling system and operated pneumatic valve and replaced drainage system, guarantee that the monomer that drips can discharge timely.
The present embodiment step 6. in after thermal-initiated polymerization, in the chuck that dipping solidifies jar, feed cooling water, make the impregnating autoclave cooling, reclaim after the methyl methacrylate monomer cooling liquid of vaporization in jar, can improve the utilization rate of monomer.
The present embodiment step 7. in, the veneer that dipping is good overlays on veneer, and through operations such as sanding, mortise, top finishings, can obtain versicolor dipping intensified compound commercial floor, whole composite floor surface layer color homogeneous (about 2mm is thick), and beautiful texture.
But the maceration extract long term storage for guaranteeing to configure in the present embodiment has increased refrigeration system to stocking system, and the maceration extract temperature is controlled at below 10 ℃.
All quote in this application as a reference at all documents that the utility model is mentioned, just quoted as a reference separately as each piece document.Should be understood that in addition those skilled in the art can make various changes or modifications the utility model after having read above-mentioned instruction content of the present utility model, these equivalent form of values fall within the application's appended claims institute restricted portion equally.

Claims (7)

1. a strengthening composite floor is characterized in that, described floor comprises in regular turn from the bottom surface to the surface:
-substrate layer (3),
-be located at the panel layer (2) of described substrate layer (3) top; And
-be located at the surface oil enamelled coating (1) of described panel layer (2) top.
2, floor as claimed in claim 1 is characterized in that, described panel layer (2) is the panel layer that the resin impregnation toughening fragil veneer of individual layer forms, or is moulded by two-layer or two-layer above resin impregnation toughening fragil veneer and to close the panel layer that forms.
As claim 2 or 3 described floors, it is characterized in that 3, the resin in the described resin impregnation toughening fragil veneer is selected from acrylic resin, vinyl acetate resin, styrene resin or its combination.
As claim 2 or 3 described floors, it is characterized in that 4, the veneer in the described resin impregnation toughening fragil veneer is the veneer of solid wood material.
5, floor as claimed in claim 1 is characterized in that, described surface oil enamelled coating (1) is the clean oil enamelled coating.
6, floor as claimed in claim 1 is characterized in that, described substrate layer (3) is selected from one or more layers sheet material, and described sheet material is selected from veneer, shaving board, density board, core-board or its combination.
7, floor as claimed in claim 1 is characterized in that, the number of plies of described substrate layer (3) is the even level veneer of 6,8,10,12 layers of unsymmetric structure.
CNU2008200592790U 2008-06-02 2008-06-02 Strengthened composite floor and manufacturing equipment thereof Expired - Fee Related CN201258577Y (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102061796A (en) * 2010-11-23 2011-05-18 胡斌 Paint-free solid wood composite floor board and manufacturing method thereof
CN106272784A (en) * 2015-05-28 2017-01-04 安徽中汇木业有限责任公司 A kind of pressurized tank for Wooden modifying and using method thereof
CN107379167A (en) * 2017-07-28 2017-11-24 阜南县中信柳木工艺品有限公司 A kind of processing method for preventing bamboo product from ftractureing
CN111185976A (en) * 2020-02-17 2020-05-22 成都艺听电子商务有限公司 Solid wood resin material and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102061796A (en) * 2010-11-23 2011-05-18 胡斌 Paint-free solid wood composite floor board and manufacturing method thereof
CN102061796B (en) * 2010-11-23 2012-10-10 胡斌 Paint-free solid wood composite floor board and manufacturing method thereof
CN106272784A (en) * 2015-05-28 2017-01-04 安徽中汇木业有限责任公司 A kind of pressurized tank for Wooden modifying and using method thereof
CN107379167A (en) * 2017-07-28 2017-11-24 阜南县中信柳木工艺品有限公司 A kind of processing method for preventing bamboo product from ftractureing
CN111185976A (en) * 2020-02-17 2020-05-22 成都艺听电子商务有限公司 Solid wood resin material and preparation method thereof

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