CN106280687A - Aramid paper UV base gravure ink - Google Patents
Aramid paper UV base gravure ink Download PDFInfo
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- CN106280687A CN106280687A CN201510275648.4A CN201510275648A CN106280687A CN 106280687 A CN106280687 A CN 106280687A CN 201510275648 A CN201510275648 A CN 201510275648A CN 106280687 A CN106280687 A CN 106280687A
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- aramid paper
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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Abstract
The invention discloses a kind of aramid paper UV base gravure ink, first, light trigger, organic solvent is added in inking vessel, stir with agitator, until without granule, add monomer afterwards, stirring 10min, is subsequently adding resin (containing urethane acrylate, polyester acrylate, modified epoxy acrylic ester etc.), stirring 30min, add flatting silica stirring 30min afterwards, be subsequently adding organic solvent, stir 10min, last discharging, seal, pack, finished product, for aramid paper UV type intaglio plate dumb light ink.With UV base gravure ink composition rationally, each component harmony is good, system excellent combination property, and viscosity is applicable to silk screen printing, depot good for the aramid paper of invention.The system of the present invention is without components such as additives, it is to avoid it is to product appearance, the adverse effect of light-proofness；And merely through one-step print, under the thickness of 78 microns, just meet product ethanol-tolerant, scratch-resistant requirement, achieve beyond thought technique effect.
Description
Technical field
The present invention relates to technical field of ink, particularly relate to a kind of aramid paper UV base gravure ink, can
For intaglio printing, there is the ethanol-tolerant of excellence, scratch-resistant performance.
Background technology
General ultraviolet light refers to the wavelength invisible light wave in the range of 0-400nm, and UV solidifies institute
The ultraviolet wavelength used is at 200-400nm.UV solidification i.e. ultra-violet curing, UV is the English of ultraviolet
Literary composition abbreviation, solidification refers to that material is changed into high molecular process from low molecule, utilize in UV ultraviolet light,
Shortwave under uv radiation, the light trigger irriate in liquid UV material become free radical or sun from
Son, thus cause the macromolecular material (resin) containing active function groups to aggregate into insoluble insoluble solid
The process of film, is rise a kind of sixties in 20th century, environmental protection, low VOC emission new skill
Art, was developed rapidly in China in 80 years 20th century later.UV solidification generally refers to need to use ultraviolet
Coating (paint), ink, adhesive (glue) or the solidified bars of other embedding sealant of line solidification
Part or requirement, it is different from heating cure, glue crosslinking agent (firming agent) solidification, spontaneous curing etc..
The solidification of UV printing-ink depends primarily on light trigger and curing reaction two aspect, resin
The compatibility of cross-linking reaction speed and additive also functions to important function to a certain extent.Use now
Curing mode mostly be the middle pressure mercury-arc lamp that electric power excites, energy is at 400-600j/cm2, initiator is many
Use benzoin and derivant, benzil and derivant thereof, 1-Phenylethanone. and derivant thereof, acyl group phosphorus
Oxygen compound.
Aramid paper has mechanical performance and the high-temperature insulation performance of excellence, is the spy of a kind of high added value
Plant fibrous insulation paper and lightweight structural material, be the global optimal insulant generally acknowledged.As aramid paper
From the point of view of adhesive tape, color, with base material as true qualities, is white or flaxen, the most single, it is impossible to full
Foot requirement, arise at the historic moment is a kind of mute black coating result, not only excellent performance, and outward appearance is excellent
Refined, finished product maintains higher yield during using.
UV printing-ink relies on its energy-conserving and environment-protective, efficiency advantages of higher, at electronic equipment and packing timber
The printing aspect tool of material is widely used.On market, existing UV type dumb light ink typically has two kinds of printings
Mode, printing of rotary press and intaglio printing.The step of two kinds of mode of printings is essentially identical, is all first to exist
One or more layers end ink is printed, then at one layer of UV type dumb light ink of its surface printing on aramid paper.
Using the UV type dumb light ink of printing of rotary press, properties can meet test request, but
Preparing operation complexity before its printing, and can only carry out the narrow printing of 30cm-40cm, efficiency is low,
Cannot meet customer need；And the UV type dumb light ink of another kind of use intaglio printing, although can
Carry out 100cm-120cm wide cut printing, but its physical property is poor, particularly ethanol-tolerant test, damage resistant
Test all cannot meet requirement.
It addition, existing UV ink ultraviolet dry solidification degree is inadequate.After solidifying through UV machine,
It is typically only capable to reach surface drying, deep cure difficulty, therefore causes coating surface to shrink, crack,
Orange peel phenomenon, and paint film deep layer is uncured, affects the overall physical properties of coating, particularly with base material
Adhesive force very poor, heat shock resistance, water boiling resistance, weather-proof, mechanical property are unsuitable for computor-keyboard
Requirement.
Accordingly, it would be desirable to research and develop new formula while meeting wide cut printing, to improve UV recessed with effective
The combination property of printing ink, meanwhile, as ink system, except having high alcohol resistance, in addition it is also necessary to
Good with substrate compatibility, adhesive force is good, state of cure is good, and environmental pollution is little.
Summary of the invention
It is an object of the invention to provide a kind of aramid paper UV base gravure ink, it combines macromolecular material
Composite technology, design uniqueness, rationally, preparation is convenient, good with substrate compatibility for composition, solidification
Degree is high, and environmental pollution is little；And only need to print the scratch-resistant energy of ethanol-tolerant that the most i.e. can reach excellence
Power, technique is simple, and production efficiency is high；Thickness is relatively low, and die-cut yield is high, and product rejection is few, is beneficial to
Reduce cost.
For reaching above-mentioned purpose, the technical solution used in the present invention is: a kind of aramid paper UV intaglio plate
Ink, by weight, composed of the following components:
Described activated monomer is acrylate reactive monomer；
Described resin is aliphatic urethane acrylate resin, polyester acrylate resin, epoxy third
One or several in alkene acid ester resin, dumb light polyurethane acrylate resin.
In technique scheme, described light trigger is 1-hydroxycyclohexyl phenyl ketone, 2-hydroxyl-2-
Methyl isophthalic acid-phenyl-1-acetone, phenyl double (2,4,6-trimethylbenzoyl) phosphine oxide, 2,4,6-trimethyls
One or both mixture in benzoyl-diphenyl phosphine oxide.Light trigger and UV spectrum
Join, not by remaining component light inhalation effects, can at utmost play photoinitiation, can fully absorb
Light source, produces free radical cross-linking reaction, and paint film is fully cured, it is ensured that film performance；In order to obtain
Obtaining more preferable solidification effect, generally select two or more light triggers to mix and join use, addition is 3-6
Part.
Preferably, described acrylate is aliphatic urethane acrylate, polyester acrylate, ring
Oxypropylene acid esters, the mixture of dumb light urethane acrylate.
Resin is the major embodiment person of ink performance, its not only play self bonding, heat shock resistance,
The key property such as weather-proof, more importantly coordinates the compatibility of all components in ink, make each component it
Between play interfacial effect, reach synergism, it is to avoid a certain component is incompatible brings overall performance to decline
Defect.The resin system composition of the present invention is reasonable, six functional groups aliphatic urethane acrylate tree
Fat (such as Guan Xinda Chemical Co., Ltd. of Shenzhen UV2450), difunctional fat adoption urethane propylene
Acid ester resin (such as Rui Sheng new material company limited of Shenzhen RU-205G-85, RU-2021B-1P)
Using as matrix resin, it has excellent wearability and pliability, has good hardness simultaneously
And chemical-resistant, give ink the most wear-resisting alcohol resistance energy；Epocryl is (such as sand
Duo Ma Chemical Co., Ltd. CN119) curing reaction is fast, is conducive to improving the curing performance of ink, and
And adhesive force preferable to base material；Polyester acrylate resin is (such as Sartomer Chemical Co., Ltd.
CN2200) wettability is good, good weatherability, the viscosity of scalable system, it is provided that excellent paintability,
The processability being beneficial to ink improves；Dumb light urethane acrylate (the Guangzhou banyan Thailand chemistry limited public affairs of science and technology
Department EH-5800) without flatting silica, its crosslink density is low, draftability good, with urethane acrylate
Resin, Epocryl, polyester acrylate resin combine use, after can making solidification
Enamelled coating crosslink density is moderate, and fragility is low, pliability is good, it is ensured that the ethanol-tolerant of product, scratch-resistant performance.
In technique scheme, described organic solvent is ethyl acetate, dehydrated alcohol, acetone, toluene
In one or several.Organic solvent can be with regulation system viscosity so that each component is uniformly dispersed,
Increase the interface interaction between each component, improve the concertedness of system, thus obtain high comprehensive performance
UV type intaglio plate dumb light ink.
In technique scheme, described activated monomer is hexanediyl ester, tripropylene glycol
Diacrylate, trimethylolpropane trimethacrylate, tetramethylol methane tetraacrylate, phthalic acid
One or both mixture in diethylene glycol two propylene olefin(e) acid ester.Activated monomer can regulate resin
, there is compatible reaction with resin system simultaneously, strengthen the physical property of resin, such as pliability, stretching in viscosity
Property, it is also possible to improve radical conversion rate, accelerate curing reaction speed, thus improve efficiency of construction.
In technique scheme, described flatting silica is silicon dioxide OK-520.Silicon dioxide with have unit
Split-phase capacitive is good, will not slacken the combination property of paint film, its surface can to light through row diffuse-reflectance, from
And play photoextinction.
Preferably, by weight, described aramid paper UV base gravure ink is composed of the following components:
The invention also discloses the preparation method of above-mentioned aramid paper UV base gravure ink, it is characterised in that
Comprise the following steps: first, light trigger, part organic solvent are added agitator, stirs；
Add activated monomer afterwards, be again stirring for；It is subsequently adding resin, third time stirring stirring；Add afterwards
Enter flatting silica, the 4th stirring；Being subsequently adding residue organic solvent, finally stirring obtains aramid paper and uses
UV type intaglio plate dumb light ink.
In technique scheme, the time of being again stirring for is 10-15min；Third time is again stirring for the time and is
25-30min；4th mixing time 25-30min；Last mixing time is 10-15min.
In the present invention, first by light trigger (such as IRGACURE 184, DAROCUR 1173,
IRGACURE 127, LUCIRIN TPO) add in solvent, it is uniformly dispersed, adds monomer and enter
Row dispersion, beneficially monomer contact with light trigger, then add resin, during stirring,
Resin forms cladding infiltration to monomer and light trigger, adds the phase of monomer, light trigger and resin
Capacitive, during photocuring, monomer polymerization is uniformly, Jun Heng with the active force of resin, it is to avoid micro-concentration effect
The drawback brought；Then adding flatting silica, flatting silica, also will not be to list while being uniformly dispersed
It is unfavorable that body and light trigger produce, it is to avoid the ink layer defects such as pin hole.
The present invention is without using dispersant, defoamer and the levelling agent that ink system is conventional, by joining
The appropriate design of side and the control of preparation process so that each component compatibility of system is good, after solidification
Product appearance is excellent, good combination property, achieves beyond thought effect.
Ink can occur some physics, chemical change in construction and film forming procedure, these changes and oil
The character of Miboin body, by construction and the application performance of appreciable impact ink.After ink printing, it may appear that
New interface, if the interfacial tension at the liquid/solid interface between ink and ground is higher than the critical table of ground
Surface tension, ink just cannot be sprawled on ground, naturally will produce the defect such as flake, shrinkage cavity；Oil
During ink solidification, the volatilization of solvent can cause producing temperature, density and surface between coating surface and inside
Tension Difference, these differences and then result in the turbulent motion within paint film, form so-called vortex, rotation
Whirlpool can result in Pericarpium Citri Reticulatae；In the system containing more than one component, if the mobility of each component exists
Different, vortex also likely causes loose colour and grows dim, and vertical construction can cause silking；Handing over
In connection curing system, there is more than a kind of resin, it is possible to produce insoluble micelle at solidification process,
Surface tension gradient is caused to be formed.After additive adds ink system, ink system can be aggravated above-mentioned
Flowing and solidification defect, not only affect outward appearance, also damage safeguard function simultaneously, causes as formed shrinkage cavity
Ink film thickness is inadequate, form pin hole can cause the discontinuity of ink layer, and these all can reduce ink
Bonding with base material, the cementability of whole system, ethanol-tolerant, scratch-proofness can be substantially reduced.
The invention devise new ethanol-tolerant scratch-resistant UV ink system, resin and additive,
And the compatibility is good between resin, it is to avoid ink produces outward appearance, boundary defect when flowing is with solidification,
It is effectively increased the bonding force of ink/ground；Ink system good stability, is unlikely to deteriorate, viscous after storage
Degree change is little, on performance without impact；During solidification, reactivity is good, and the coating performance for base material is good, light
Cleanliness is high；Solvent resistant after solidification corrodes, and the weatherability having had, and long-time invariant color, does not sends out
Yellow；Ink layer after solidification has the alcohol resistance (500gf >=50 time) of excellence, scratch-proofness (15-25gf
No marking)；Without the bad phenomenon such as Pericarpium Citri tangerinae, pin hole.Solidification effect is good, good combination property, adhesive force is good,
Resistance to collapsing property, pliability are good, solve that existing UV base gravure ink exists state of cure is low, ethanol-tolerant
The difficult problem that difference, easily scuffing, fragility, bonding force are weak.
It addition, prior art is in order to improve the interfacial effect of ink and base material, reduce drawbacks described above as far as possible,
Can be to base material pretreatment before printing-ink；The present invention, without to base material pretreatment, directly will newly design
Ink on printing element, the ink layer after solidification is good with substrate bonding, without boundary defect, it is ensured that
While product appearance U.S., it is effectively increased the ethanol-tolerant of base material, scratch-proofness.
Owing to technique scheme is used, the present invention compared with prior art has the advantage that
1. the aramid paper UV base gravure ink that the present invention is first public, design uniqueness, composition is reasonable,
Preparation is convenient, has the ethanol-tolerant of excellence, scratch-resistant performance, and good with base material adhesive force, is improving
While ink ethanol-tolerant, scratch-resistant performance, it is ensured that the cementability of ink, workability, also improve
The state of cure of ink；Environmental pollution is little simultaneously.
Aramid paper UV base gravure ink the most disclosed by the invention is without using the dispersion that ink system is conventional
Agent, defoamer and levelling agent, by appropriate design and the control of preparation process of formula so that
The each component compatibility of system is good, and the omission of the most various additives makes the product appearance after solidification excellent,
Product good combination property, achieves beyond thought effect.
3. the aramid paper each component compatibility of UV base gravure ink that the present invention provides is good, between Organic substance
Dispersibility is good, tangles uniformly after solidification between various polymer segments, and crosslinking points is reasonably distributed, system
Good toughness, it is to avoid the defect that the collaborative paint film overall performance brought of a certain component declines；Exist simultaneously
Under the effect of the materials such as light trigger, ultraviolet can go deep into ink depths, can maximum exciting light
The activity of initiator, it is ensured that the crosslinking curing effect of resinite, thus obtained adhesive force, rub resistance,
The aramid paper of the excellent combination property such as ethanol-tolerant, scratch-proofness UV base gravure ink.
4. the aramid paper UV base gravure ink that the present invention provides uses and stores conveniently, and is reaching
On the premise of the scratch-resistant performance of ethanol-tolerant, only needing one-step print, consumption is few, and the pollution to environment is less,
Injury to human body is lower；Owing to additive amount is low, in resin system, wellability is good, is conducive to
The lifting of product appearance；And the ink of the present invention can carry out the wide cut printing of 100cm-120cm,
Ethanol-tolerant performance and damage resistant are tested, and can effectively solve the deficiency of existing UV dumb light ink, suitableeer
In industrialized production.
Accompanying drawing explanation
Fig. 1 is the outside drawing after the solidification of embodiment one product；
Fig. 2 is to contrast photo figure before and after damage resistant test after embodiment two product solidifies；
Fig. 3 is to contrast photo figure before and after damage resistant test after existing ink product solidifies；
Fig. 4 is contrast photo figure before and after the test of embodiment three products ethanol-tolerant；
Fig. 5 is contrast photo figure before and after the test of existing ink product ethanol-tolerant.
Detailed description of the invention
Below in conjunction with the accompanying drawings and embodiment the invention will be further described:
Embodiment one
According to the composition of table 1, prepare according to following steps, prepare five groups of aramid paper UV type intaglio plates
Dumb light ink.
First, inking vessel add light trigger, organic solvent, stir with agitator,
Until without granule, adding monomer afterwards, stirring 10min, being subsequently adding resin (containing polyurethane propylene
Acid esters, polyester acrylate, modified epoxy acrylic ester, dumb light urethane acrylate etc.), stirring
30min, adds flatting silica stirring 30min afterwards, then adds organic solvent, stir 10min,
Last discharging, seal, pack, finished product, for aramid paper UV type intaglio plate dumb light ink.
The table 1 aramid paper UV type intaglio plate concrete formula of dumb light ink
Embodiment two
By above-mentioned UV dumb paint ink print on the aramid paper being printed on black matrix, use UV radiation curing
Film forming, UV energy is (250-350) mj/cm2, and according to standard detection film every of table 2
Performance, concrete testing result is shown in Table 3.
Fig. 1 is the outside drawing after the solidification of embodiment one product, it can be seen that flat after product of the present invention solidification
Whole, smooth, without bright rays, bright spot.
Fig. 2 is that after embodiment two product solidifies, before damage resistant test, (left) (right) afterwards contrasts photo figure,
Fig. 3 is that after existing ink product solidifies, before damage resistant test, (left) (right) afterwards contrasts photo；Substantially
Find out, scratch-resistant test no marking after product of the present invention solidification.
Fig. 4 is (left) (right) afterwards contrast photo figure before the test of embodiment three products ethanol-tolerant, Fig. 5
(left) (right) afterwards contrast photo figure before testing for existing ink product ethanol-tolerant；It is evident that this
After the solidification of invention product, ethanol-tolerant test is the most show-through.
UV type intaglio plate dumb light ink properties detection project and detection method on table 2 aramid paper
The properties of UV type intaglio plate dumb light ink on table 3 aramid paper
The aramid paper of the result above surface present invention with UV base gravure ink composition rationally, coordinate by each component
Property is good, system excellent combination property, and viscosity is applicable to silk screen printing, depot good.The present invention
System without additive, it is to avoid it is to product appearance, the adverse effect of light-proofness；And only warp
Cross one-step print, under the thickness of 7-8 micron, just meet product ethanol-tolerant, scratch-resistant requirement, obtain
Beyond thought technique effect.
Claims (10)
1. an aramid paper UV base gravure ink, it is characterised in that by weight, by following group
It is grouped into:
Described activated monomer is acrylate reactive monomer；
Described resin is aliphatic urethane acrylate resin, polyester acrylate resin, propylene oxide
One or several in acid ester resin, dumb light urethane acrylate.
Aramid paper UV base gravure ink the most according to claim 1, it is characterised in that: described light
Initiator is 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, phenyl pair
In (2,4,6-trimethylbenzoyl) phosphine oxide, 2,4,6-trimethylbenzoy-dipheny phosphine oxides one
Plant or the mixture of two kinds.
Aramid paper UV base gravure ink the most according to claim 1, it is characterised in that: described tree
Fat be aliphatic urethane acrylate resin, polyester acrylate resin, Epocryl,
The mixture of dumb light polyurethane acrylate resin.
Aramid paper UV base gravure ink the most according to claim 1, it is characterised in that: described fat
Fat adoption chlorinated polyethylene is six degree of functionality aliphatic urethane acrylate resin or difunctionalitys
Degree aliphatic urethane acrylate resin；Described polyester acrylate be two functional polyester acrylate or
Trifunctional polyester acrylate；Described Epocryl is to contain epoxide group and carbon carbon pair simultaneously
The polymer of key.
Aramid paper UV base gravure ink the most according to claim 1, it is characterised in that have described in:
Machine solvent is one or several in ethyl acetate, dehydrated alcohol, acetone, toluene.
Aramid paper UV base gravure ink the most according to claim 1, it is characterised in that: described work
Property monomer is hexanediyl ester, tri (propylene glycol) diacrylate, trimethylolpropane tris third
One or two in olefin(e) acid ester, tetramethylol methane tetraacrylate, phthalic acid diethylene glycol two propylene olefin(e) acid ester
The mixture planted.
Aramid paper UV base gravure ink the most according to claim 1, it is characterised in that disappear described in:
Light powder is silicon dioxide flatting silica.
Aramid paper UV base gravure ink the most according to claim 1, it is characterised in that: by weight
Part meter, described aramid paper UV base gravure ink is composed of the following components:
9. any one aramid paper preparation method of UV base gravure ink described in claim 1-8, it is special
Levy and be, comprise the following steps: first, light trigger, part organic solvent are added agitator, stirs
Mix uniformly；Add activated monomer afterwards, be again stirring for；It is subsequently adding resin, third time stirring stirring；
Add flatting silica afterwards, the 4th stirring；Being subsequently adding residue organic solvent, finally stirring obtains aramid fiber
Paper UV type intaglio plate dumb light ink.
10. the preparation method of UV base gravure ink of aramid paper described in claim 9, it is characterised in that:
The time of being again stirring for is 10-15min；The time that is again stirring for for the third time is 25-30min；4th stirring
Time 25-30min；Last mixing time is 10-15min.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510275648.4A CN106280687B (en) | 2015-05-26 | 2015-05-26 | UV gravure ink for aramid paper |
| CN201911361212.1A CN111117341B (en) | 2015-05-26 | 2015-05-26 | Preparation method of UV ink film |
| CN201911361190.9A CN111117340B (en) | 2015-05-26 | 2015-05-26 | UV ink film |
| CN201911361115.2A CN111117339A (en) | 2015-05-26 | 2015-05-26 | Preparation method of UV gravure ink for aramid paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510275648.4A CN106280687B (en) | 2015-05-26 | 2015-05-26 | UV gravure ink for aramid paper |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911361190.9A Division CN111117340B (en) | 2015-05-26 | 2015-05-26 | UV ink film |
| CN201911361115.2A Division CN111117339A (en) | 2015-05-26 | 2015-05-26 | Preparation method of UV gravure ink for aramid paper |
| CN201911361212.1A Division CN111117341B (en) | 2015-05-26 | 2015-05-26 | Preparation method of UV ink film |
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| CN106280687A true CN106280687A (en) | 2017-01-04 |
| CN106280687B CN106280687B (en) | 2019-12-20 |
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| CN201510275648.4A Active CN106280687B (en) | 2015-05-26 | 2015-05-26 | UV gravure ink for aramid paper |
| CN201911361212.1A Active CN111117341B (en) | 2015-05-26 | 2015-05-26 | Preparation method of UV ink film |
| CN201911361190.9A Active CN111117340B (en) | 2015-05-26 | 2015-05-26 | UV ink film |
| CN201911361115.2A Pending CN111117339A (en) | 2015-05-26 | 2015-05-26 | Preparation method of UV gravure ink for aramid paper |
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| CN201911361212.1A Active CN111117341B (en) | 2015-05-26 | 2015-05-26 | Preparation method of UV ink film |
| CN201911361190.9A Active CN111117340B (en) | 2015-05-26 | 2015-05-26 | UV ink film |
| CN201911361115.2A Pending CN111117339A (en) | 2015-05-26 | 2015-05-26 | Preparation method of UV gravure ink for aramid paper |
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| CN109354923A (en) * | 2018-10-23 | 2019-02-19 | 新丰杰力电工材料有限公司 | A kind of dumb light ink and preparation method thereof and shading rubber belt |
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| CN108501490A (en) * | 2018-04-10 | 2018-09-07 | 南通恒鑫新材料有限公司 | A kind of preparation process of the reinforced high double-deck aluminum-plastic composite membrane of masking |
| CN109354923A (en) * | 2018-10-23 | 2019-02-19 | 新丰杰力电工材料有限公司 | A kind of dumb light ink and preparation method thereof and shading rubber belt |
| WO2020215845A1 (en) * | 2019-04-26 | 2020-10-29 | 苏州镓祥新材料科技有限公司 | Multi-layer composite color-coated printed metal board, household appliance shell and decorative material |
| CN110982348A (en) * | 2019-12-18 | 2020-04-10 | 江门市阪桥电子材料有限公司 | Matte black PCB character inkjet ink and preparation method thereof |
| CN111154419A (en) * | 2020-03-03 | 2020-05-15 | 江西科为薄膜新型材料有限公司 | Matte white board film |
| CN115820104A (en) * | 2022-12-23 | 2023-03-21 | 青岛展辰新材料有限公司 | Ultrashort wave cured woodware coating and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106280687B (en) | 2019-12-20 |
| CN111117339A (en) | 2020-05-08 |
| CN111117340B (en) | 2022-07-08 |
| CN111117340A (en) | 2020-05-08 |
| CN111117341A (en) | 2020-05-08 |
| CN111117341B (en) | 2022-07-08 |
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