CN106281198A - A kind of glass baseplate ultraviolet curing transfer adhesive - Google Patents
A kind of glass baseplate ultraviolet curing transfer adhesive Download PDFInfo
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- CN106281198A CN106281198A CN201510275565.5A CN201510275565A CN106281198A CN 106281198 A CN106281198 A CN 106281198A CN 201510275565 A CN201510275565 A CN 201510275565A CN 106281198 A CN106281198 A CN 106281198A
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- glass baseplate
- ultraviolet curing
- glue
- curing transfer
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Abstract
The invention discloses a kind of glass baseplate ultraviolet curing transfer adhesive, including aliphatic polyurethane acrylate, esters of acrylic acid reactive diluent, light trigger, acrylate analog assistant, silane coupler.Mechanical property, anti-wear performance, solvent resistant, cold-hot impact and glue-line that the glass baseplate ultraviolet curing transfer adhesive of the present invention has had are good with substrate bonding, particularly after decocting in water test, glue-line and the adhesive force of base material still ＞ 4B, environmental pollution are little.Solve that existing ultra-violet curing transfer glue cementability is poor, not water boiling resistance, the most solvent-proof problem, meet industry requirement, reduce enterprise's production cost, for enterprise getting profit.
Description
Technical field
The present invention relates to transfer glue technical field, particularly relate to a kind of glass baseplate ultraviolet light polymerization and turn
Print glue, can be used for the inorganic material surfaces such as glass, solves existing transfer glue and can be only applied to organic film
Problem.
Background technology
Ultraviolet light polymerization curing transfer glue have easy to use, curing rate is fast, light transmittance is high, operation
Convenient, advantages of environment protection, has been widely used for various plastic sheeting industry.Ultraviolet light polymerization
Curing transfer glue formula generally comprises: activity dilution property monomer, light trigger, esters of acrylic acid pre-polymerization
Thing, auxiliary agent etc..
UV solidification i.e. ultra-violet curing, UV is the english abbreviation of ultraviolet, and solidification refers to that material is from low point
Son is changed into high molecular process, utilize in UV ultraviolet light polymerization, shortwave under uv radiation, liquid
Light trigger irriate in state UV material becomes free radical or cation, thus causes containing activity official
The macromolecular material (resin) that can roll into a ball aggregates into the process of insoluble insoluble solid paint film, is a kind of 20
That the sixties in century rises, environmental protection, the new technique of basic VOC free discharge.General UV-curing
Changing and refer to the wavelength invisible light wave in the range of 0-400nm, UV solidifies the ultraviolet used
Wavelength is at 200-400nm.
UV solidification generally refers to need with the coating (paint) of ultraviolet curing, ink, adhesive (glue
Water) or the condition of cure of other embedding sealant or requirement, its be different from heating cure, glue crosslinking agent (Gu
Agent) solidification, spontaneous curing etc..Depend primarily on light trigger and curing process two aspect, resin
Cross-linking reaction speed and the compatibility of color stuffing also function to important function to a certain extent.Make now
Curing mode mostly be the middle pressure mercury-arc lamp that electric power excites, energy is at 400-600j/cm2, initiator
Many use benzoins and derivant, benzil and derivant thereof, 1-Phenylethanone. and derivant thereof, acyl group
Phosphoric-oxygenic compound.
A kind of light-cured type one pack system single voxel glue of ultraviolet light polymerization curing transfer glue, passes through mould
It is thin that tool takes shape in the plastics such as Merlon, polyethylene terephthalate and thermoplastic elastic polyurethane
Film base material surface；Existing ultraviolet light polymerization curing transfer glue is typically only used for Merlon, gathers benzene
The plastic film substrate surface of the organic materials such as naphthalate and thermoplastic elastic polyurethane.And
Glass baseplate is inorganic material, is different from the organic materials such as plastic sheeting, causes existing UV-curing
Change curing transfer glue and be difficult to apply to glass baseplate.The most existing ultraviolet light polymerization curing transfer glue
Glass material does not only exist especially prominent difficult attachment and is weak to the problem of boiling water boiling, also
Exist and be weak to the chemical attack problems such as ethanol, acetone, ethyl acetate.
The technical problem that existing ultraviolet curing transfer adhesive exists has 3 points, the most attached
It is poor to put forth effort.The most resistance to boiling water boiling poor performance.Ethanol-tolerant, acetic acid the most on the glass substrate
The chemical corrosion resistances such as ethyl ester are poor.Therefore, a kind of novel ultraviolet light curing transfer glue of necessary research and development,
For inorganic material surfaces such as glass.
Summary of the invention
It is an object of the invention to provide a kind of glass baseplate ultraviolet curing transfer adhesive, it combines high score
Sub-composites technology, design uniqueness, rationally, preparation is convenient, the most attached for composition
Put forth effort excellence, improve the resistance to boiling water boiling performance on glass material, improve ethanol-tolerant, ethyl acetate etc.
Resistance to chemical corrosion.
For reaching above-mentioned purpose, the technical solution used in the present invention is: a kind of glass baseplate ultraviolet light
Curing transfer glue, by weight, composed of the following components:
In technique scheme, described aliphatic polyurethane acrylate is hydroxyl modification bifunctional resin
Fat adoption urethane acrylate, carboxy-modified trifunctional aliphatic urethane acrylate, six senses
Group's aliphatic urethane acrylate.The carboxyl acid modified trifunctional of commerce and trade company limited is tieed up in such as Guangzhou nine
Degree aliphatic urethane acrylate UA-787LV, this resin mean molecule quantity is 6000-12000,
Acid number is 200-220mgKOH/g, the hydroxyl modification two of Shenzhen You Yang Science and Technology Ltd. can roll into a ball fat
Adoption urethane acrylate T-7120, T-7128, the six functional groups aliphatic poly ammonia of Changchun Chemical Group
Ester acrylate 5290；Six degree of functionality group aliphatic polyurethane CN9006 of Sartomer.
Resin is the major embodiment person of transfer glue performance, its not only play self bonding, heat shock resistance,
The key property such as weather-proof, more importantly coordinates the compatibility of all components in glue, makes between each component
Play interfacial effect, reach synergism, it is to avoid a certain component is incompatible brings overall performance to decline
Defect.Rationally, aliphatic urethane acrylate toughness is good, contraction for the resin system composition of the present invention
Reactivity that rate is low, higher and degree of functionality, close with the polarity of glass baseplate, can be with glass base
Material has certain adhesive force, also has the performance of the chemical attack such as ethanol-tolerant, ethyl acetate；Solve
Transfer glue difficult attachment issue on the glass substrate, improves water boiling resistance and ethanol-tolerant, ethyl acetate etc.
The problem of resistance to chemical attack.
In technique scheme, described acrylated phosphate analog assistant is methacrylic acid phosphoric acid ester, 2-
One or more in hydroxyethyl methacrylic acid phosphate ester, methylacryoyloxyethyl phosphate ester；Excellent
Select 2-hydroxyethyl methacrylic acid phosphate ester；The high acid value acrylate analog assistant of the present invention is with abundant
Polar group, reactive strong, when transfer glue accepts ultraviolet light polymerization, acrylate analog assistant institute
The biggest work can be formed with the siliconoxygen bond generation chemical reaction in the inorganic substrates such as glass with group
Firmly, it is effectively increased the adhesive force of transfer glue and glass baseplate, solves prior art transfer glue
The difficult problem of strong active force cannot be formed with inorganic substrate.
In technique scheme, described esters of acrylic acid activity diluting monomer is acrylic acid-2-hydroxyl second
Ester, iso-bornyl acrylate, 2-hydroxypropyl acrylate, 1, in 6-hexanediyl ester
Or the most several a kind of mixture.In the present invention, diluting monomer can be with regulation system viscosity so that
Each component is uniformly dispersed, and increases the interface interaction between each component, improves the concertedness of system, thus
Obtain the ultra-violet curing transfer glue of high comprehensive performance；Simultaneously as with active group diluent its
Upper functional group and the inorganic substrate such as resin body institute band group and glass (such as its internal siliconoxygen bond)
Chemical bond can form chemical bond power, significantly increase the adhesive force of transfer glue and base material.
In technique scheme, described light trigger is 2-hydroxyl-2 methyl isophthalic acid phenyl-1-acetone, peace
Breath fragrant double methyl ether, 2,4,6-trimethylbenzoy-dipheny phosphine oxides, 1-hydroxy-cyclohexyl-phenyl
Ketone, benzophenone, 2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone, phenyl are double
A kind of or the most several mixture in (2,4,6-trimethylphenyl acyl group).The present invention's is light-initiated
Agent and UV Spectral matching, not by remaining component light inhalation effects, can at utmost play light-initiated work
With, light source can be fully absorbed, produce free radical cross-linking reaction, transfer glue is fully cured, it is ensured that
Its performance.
In technique scheme, described silane coupler is gamma-aminopropyl-triethoxy-silane, γ-ammonia
(2,3-expoxy propane) propyl trimethoxy silicane, γ-(methacryloxypropyl) propyl trimethoxy
A kind of or the most several mixture in silane.The coupling agent consumption of the present invention is less, but its
Can increase the intermolecular force of each compound in transfer glue system, filling up as try to make a match is high
The gap of molecular compound interchain, is effectively improved the water boiling resistance performance after transfer glue solidification.
Preferably, by weight, described glass baseplate ultraviolet curing transfer adhesive is by following components
Composition:
The invention also discloses the preparation method of a kind of glass baseplate ultraviolet curing transfer adhesive, including
Following steps:
(1) by weight, by some aliphatic polyurethane acroleic acid fat, part propylene esters of gallic acid activity
Diluent, light trigger and HEMA phosphate adjuvant are sequentially added in container mixed
Close, disperse, filter, obtain host；
(2) by weight, by residual acrylic acid esters activity diluting monomer, silane coupler and residue
Aliphatic polyurethane acrylate is sequentially added in container mixing, disperses, filters, obtains adjuvant；
(3) in mass ratio 1: 1 mixing host and adjuvant, disperses, filters, and i.e. obtains glass baseplate and uses
Ultraviolet curing transfer adhesive.
In technique scheme, step (1), dispersion rate is that 1000-1500 turns/min, and the time is
1-4 hour；Step (2), dispersion rate is that 200-500 turns/min, and the time is 1-4 hour；Step
(3), dispersion rate is that 200-500 turns/min, and the time is 0.5-1 hour.
In the preparation process of the present invention, step (1), step (2) and the central dispersion of step (3)
Border is lucifuge, ventilated environment, and temperature is 15-35 DEG C.
Transfer glue construction and film forming procedure in some physics, chemical change can occur, these change and
The character of transfer glue itself, by construction and the application performance of appreciable impact transfer glue.After transfer glue coating,
There will be new interface, if the interfacial tension at the liquid/solid interface between transfer glue and ground is higher than ground
Critical surface tension, transfer glue just cannot sprawl on ground, and nature will produce flake, shrinkage cavity
Etc. defect；Transfer glue solidification time solvent volatilization can cause between film surface and inside produce temperature,
Density and surface tension are poor, these differences and then result in the turbulent motion within paint film, form institute
Meaning vortex, vortex can result in Pericarpium Citri Reticulatae；In the system containing more than one component, if each component
There is some difference for mobility, and vortex also likely causes loose colour and grows dim, and vertical construction can cause
Silking；In curing system, there is more than a kind of resin, it is possible to produce insoluble at solidification process
Micelle, cause surface tension gradient to be formed.It is especially in the presence of that each to carry abundant reactive group many
During kind of compound, reactive uncertain between macromolecule, little molecule, transfer glue preparation process,
, all there is multiple reaction in ultraviolet light polymerization process, this situation can cause transfer glue to coat to inorganic material
During surface, and the active force between inorganic material is the most weak, even without the group of energy interreaction, leads
Cause transfer glue and inorganic substrate poor adhesive force.And the compound of every kind of band reactive group is not the most independent
Exist, all can affect simultaneously also by other compounds affect, system reaction can be caused uncontrollable, storage
Property is poor.
The invention devise new transfer glue system, resin and additive, particular with
Between remaining compound of active group, the compatibility is good, it is to avoid transfer glue is organic with when solidifying in preparation
Produce too much reaction between thing, it is ensured that transfer glue Organic substance and the reactivity of inorganic material, improve organic
Inorganic interface active force, is effectively increased the bonding force of transfer glue/ground；Transfer glue system stability is good,
Being unlikely to deteriorate, after storage, viscosity B coefficent is little, on performance without impact；During solidification, reactivity is good, for base
The coating performance of material is good, highly polished；After solidification, solvent resistant corrodes, and the weatherability having had, long
Time invariant color, non-yellowing；Transfer glue-line after solidification has the bonding force of excellence.Solve existing
What transfer glue existed is difficult on the inorganic substrates such as glass a difficult problem for attachment.
It addition, prior art is in order to improve the interfacial effect of transfer glue and base material, reduce above-mentioned lacking as far as possible
Fall into, can be to base material pretreatment before coating transfer glue；The present invention, without to base material pretreatment, directly will
Printing element in newly-designed transfer glue, the transfer glue-line after solidification is good with substrate bonding, lacks without interface
Fall into, it is ensured that while product appearance U.S., be effectively increased water boiling resistance and ethanol-tolerant, the acetic acid of base material
The resistance to chemical attack abilities such as ethyl ester.
Owing to technique scheme is used, the present invention compared with prior art has the advantage that
1. the glass baseplate ultraviolet curing transfer adhesive that the present invention is first public, design uniqueness, composition
Rationally, preparation is convenient, there is excellence with base material adhesive force, improving transfer glue cementability performance
Simultaneously, it is ensured that the workability of transfer glue, water boiling resistance, chemical resistance, simultaneously dirty to environment
Contaminate little.
Glass baseplate ultraviolet curing transfer adhesive the most disclosed by the invention only needs the thinnest glue-line, it is only necessary to
8 microns, still achieve cementability and water boiling resistance, chemical resistance, the boiling water boiling 10 points of excellence
Clock non-whitening, adhesive force still more than 4B, overcomes the thicker glue-line of existing needs and still can not improve
Chemical resistance, the defect of water boiling resistance, achieve beyond thought technique effect.
3. each component compatibility of glass baseplate ultraviolet curing transfer adhesive that the present invention provides is good, organic
Between thing, harmony is good, without aggregation phenomenon, it is to avoid the collaborative paint film globality brought of a certain component
The defect that can decline；Simultaneously under reactive group effect effect, resin system solidification effect is good, it is thus achieved that
Certain heat-resisting, chemically-resistant, mechanical property improves, and special Organic substance and mineral surfaces occur anti-
Should, interface interaction power is high, thus it is comprehensive to have obtained adhesive force, rub resistance, solvent resistant, weatherability etc.
The transfer printing adhesive film of excellent performance.
4. the invention by acrylate analog assistant, esters of acrylic acid reactive diluent, silane
Coupling agent adds in aliphatic urethane acrylate, is sequentially added into, and each component supplements and complements each other, and is carried
Polar group can increase respective intermolecular forces, but will not overreaction, it is ensured that organic-compound system with
The reactivity of inorganic substrate, thus while improving organic transfer glue and unorganic glass adhesive force, Gu
Transfer glue combination property after change is the most excellent.
5. the glass baseplate ultraviolet curing transfer adhesive that the present invention provides uses and stores conveniently, and
On the premise of meeting high bonding requirements, only need to once be coated with, thickness is thin, and consumption is few, to environment
Polluting less, the injury to human body is lower；And due to resin composition rationally, transfer glue curing reaction
Property is good, the glue-line good combination property after solidification, is more suitable for industrialized production.
Accompanying drawing explanation
Fig. 1 be embodiment one transfer glue solidification after through adhesive force test before and after outside drawing；
Fig. 2 be embodiment two transfer glue solidification after through decocting in water test before and after outside drawing；
Fig. 3 be embodiment three transfer glue solidification after through chemically-resistant test before and after outside drawing.
Detailed description of the invention
Below in conjunction with the accompanying drawings and embodiment the invention will be further described:
Embodiment one
The preparation method of glass baseplate ultraviolet curing transfer adhesive, comprises the following steps:
By weight, by 30 part nine dimension commerce and trade carboxyl group three-functionality-degree resin UA-787LV,
13 portions of iso-bornyl acrylate reactive diluents, 1 part 2,4,6-trimethylbenzoy-dipheny oxygen
Change phosphine, 3 parts of 1-hydroxy-cyclohexyl-phenyl ketones, 3 parts of HEMA phosphate esters help
Agent is sequentially added in stirring dispersion machine, normal pressure, 35 DEG C, lucifuge, be dried, ventilated environment, in 1000
Rev/min stirring 4 hours, dispersed with stirring is uniform, filters clean impurity, lucifuge, packs, for
Host；
By weight, by 8 parts of 2-Hydroxy ethyl acrylates, 2 parts of γ-ammonia (2,3-expoxy propane) third
Base trimethoxy silane, 3 parts of γ-(methacryloxypropyl) propyl trimethoxy silicanes, 10 parts of Changchun
5290,5 parts of the six degree of functionality polyurethane acroleic acid fat of chemical industry excellent sun science and technology bifunctionality polyurethane
Acrylate T-7120,22 parts of iso-bornyl acrylates time add in stirring dispersion machines, normal pressure, 25 DEG C,
Lucifuge, dry, ventilated environment, stir 3 hours in 500 revs/min, and dispersed with stirring is uniform, filters
Clean impurity, lucifuge, packs, for adjuvant；
Taking above-mentioned host and adjuvant respectively, mass ratio is 1: 1, is sequentially added in stirring dispersion machine,
Normal pressure, 35 DEG C, lucifuge, be dried, ventilated environment, in 400 revs/min stir 1 hour, stirring point
Dissipate uniformly, filter clean impurity, i.e. obtain glass baseplate ultraviolet curing transfer adhesive.
Embodiment two
The preparation method of glass baseplate ultraviolet curing transfer adhesive, comprises the following steps:
By weight, by 25 part nine dimension commerce and trade carboxyl group three-functionality-degree resin UA-787LV,
5290,13 parts of iso-bornyl acrylates of six degree of functionality polyurethane acroleic acid fat of 5 parts of Changchun chemical industry are lived
Property diluent, 1 part 2,4,6-trimethylbenzoy-dipheny phosphine oxides, 3 parts of 1-hydroxy-cyciohexyl-
Phenyl ketone, 3 parts of HEMA phosphate adjuvant are sequentially added in stirring dispersion machine,
Normal pressure, 35 DEG C, lucifuge, be dried, ventilated environment, in 1000 revs/min stir 4 hours, stirring
It is uniformly dispersed, filters clean impurity, lucifuge, pack, for host；
By weight, by 8 parts of 2-Hydroxy ethyl acrylates, 2 parts of γ-ammonia (2,3-expoxy propane) third
Base trimethoxy silane, 3 parts of γ-(methacryloxypropyl) propyl trimethoxy silicanes, 15 parts of excellent sun
Science and technology bifunctionality polyurethane acroleic acid fat T-7120,22 parts of iso-bornyl acrylates time add
In stirring dispersion machine, normal pressure, 25 DEG C, lucifuge, be dried, ventilated environment, in 500 revs/min of stirrings
3 hours, dispersed with stirring was uniform, filtered clean impurity, lucifuge, packed, for adjuvant；
Taking above-mentioned host and adjuvant respectively, mass ratio is 1: 1, is sequentially added in stirring dispersion machine,
Normal pressure, 15 DEG C, lucifuge, be dried, ventilated environment, in 300 revs/min stir 0.8 hour, stirring
It is uniformly dispersed, filters clean impurity, i.e. obtain glass baseplate ultraviolet curing transfer adhesive.
Embodiment three
The preparation method of glass baseplate ultraviolet curing transfer adhesive, comprises the following steps:
By weight, by 30 part nine dimension commerce and trade carboxyl group three-functionality-degree resin UA-787LV,
13 portions of iso-bornyl acrylate reactive diluents, 1 part 2,4,6-trimethylbenzoy-dipheny oxygen
Change phosphine, 3 parts of 1-hydroxy-cyclohexyl-phenyl ketones, 3 parts of HEMA phosphate esters help
Agent is sequentially added in stirring dispersion machine, normal pressure, 35 DEG C, lucifuge, be dried, ventilated environment, in 1000
Rev/min stirring 4 hours, dispersed with stirring is uniform, filters clean impurity, lucifuge, packs, for
Host；
By weight, by 2 parts of γ-ammonia (2,3-expoxy propane) propyl trimethoxy silicane, 3 parts of γ-
(methacryloxypropyl) propyl trimethoxy silicane, six degree of functionality polyurethane third of 10 parts of Changchun chemical industry
5290,5 part 1 of olefin(e) acid fat, 6-hexanediyl ester, 8 parts of 2-Hydroxy ethyl acrylates, 22 parts
Iso-bornyl acrylate time adds in stirring dispersion machine, normal pressure, 25 DEG C, lucifuge, be dried, ventilate
Environment, stirs 3 hours in 500 revs/min, and dispersed with stirring is uniform, filters clean impurity, lucifuge,
Pack, for adjuvant；
Taking above-mentioned host and adjuvant respectively, mass ratio is 1: 1, is sequentially added in stirring dispersion machine,
Normal pressure, 35 DEG C, lucifuge, be dried, ventilated environment, in 300 revs/min stir 0.8 hour, stirring
It is uniformly dispersed, filters clean impurity, i.e. obtain glass baseplate ultraviolet curing transfer adhesive.
Embodiment four
The preparation method of glass baseplate ultraviolet curing transfer adhesive, comprises the following steps:
By weight, by 18 part nine dimension commerce and trade carboxyl group three-functionality-degree resin UA-787LV,
16 portions of iso-bornyl acrylate reactive diluents, 1.5 part 2,4,6-trimethylbenzoy-dipheny
Phosphine oxide, 3.5 parts of 1-hydroxy-cyclohexyl-phenyl ketones, 2 parts of HEMA phosphoric acid
Ester auxiliary agent is sequentially added in stirring dispersion machine, normal pressure, 30 DEG C, lucifuge, be dried, ventilated environment, in
1200 revs/min are stirred 4 hours, and dispersed with stirring is uniform, filter clean impurity, lucifuge, pack,
For host；
By weight, by 3 parts of γ-ammonia (2,3-expoxy propane) propyl trimethoxy silicane, 2 parts of γ-
(methacryloxypropyl) propyl trimethoxy silicane, six degree of functionality polyurethane third of 8 parts of Changchun chemical industry
5290,4.5 part 1 of olefin(e) acid fat, 6-hexanediyl ester, 8 parts of 2-hydroxypropyl acrylates, 24
Part iso-bornyl acrylate time adds in stirring dispersion machine, normal pressure, 25 DEG C, lucifuge, be dried, logical
Wind environment, stirs 3 hours in 500 revs/min, and dispersed with stirring is uniform, filters clean impurity, lucifuge,
Pack, for adjuvant；
Taking above-mentioned host and adjuvant respectively, mass ratio is 1: 1, is sequentially added in stirring dispersion machine,
Normal pressure, 35 DEG C, lucifuge, be dried, ventilated environment, in 300 revs/min stir 0.8 hour, stirring
It is uniformly dispersed, filters clean impurity, i.e. obtain glass baseplate ultraviolet curing transfer adhesive.
Embodiment five
By above-mentioned glass baseplate ultraviolet curing transfer adhesive point at simple glass or safety glass material
On, plastic covering sheet die, then by the tight pressing of rubber roll.Then ultraviolet light polymerization, ultraviolet
Photocuring energy: 1200MJ/cm2.Throw off mould, carry out glue adhesive force, water boiling resistance, ethanol-tolerant,
The quantitative measurements such as ethyl acetate.
Ultraviolet curing transfer adhesive film after above-mentioned solidification is carried out outward appearance detection, thickness 8-9 micron,
Meeting mould lines, without obvious impurity, glue-line is free of pinholes, trachoma, contracting oil etc. bad.
After above-mentioned glue curing glue-line hardness all >=1H；Testing tool and method: pushing away of load 500g
Vehicle type pencil hardometer；Rhizoma Sparganii pencil: hardness 1H.
After above-mentioned glue curing, the glue-line acetone of resistance to acetic acid result is: glue-line the most now turns white, glue-line defect,
The bad phenomenon such as come off.Testing tool and method: after three groups of embodiment glue curing, to place 24 little for room temperature
Shi Hou, is placed in the acetone soln of ventilation, cool place, 25 DEG C of environment immersion 10min by glue.
After above-mentioned glue curing glue-line adhesive force test result all >=4B；Testing tool and method: use
The sharp cutter (knife edge angle 15～30 °) film surface after embodiment solidifies draws 10 × 10
The square small grid of 1mm × 1mm, every deep and glue-line bottom of ruling, touches glass surface.Make
The fragment of test zone is cleaned clean with banister brush, then use No. 600 adhesive tapes of 3M company (viscous
Attached power 300～400g/cm2) firmly cling net region 30 seconds, hold adhesive tape one end, hanging down
Nogata shuts down rapidly adhesive tape to (90 °).Same position, tests 3 times equally.Criterion:
With reference to GB " scratch experiment of GBT9286-1998 paint and varnish paint film ".Accompanying drawing 1 is embodiment
One transfer glue solidification after through adhesive force test before and after outside drawing, the left side for test before, the right for survey
After examination, it can be seen that after adhesive force test, film surface does not now substantially come off, sticks up skin.
After above-mentioned glue curing, glue-line high-temp resisting high-humidity resisting result is: embodiment glue-line the most now turns white, glue
The bad phenomenon such as break damages, come off.Testing tool and method: after room temperature is placed 24 hours, be placed in temperature
Spend 85 DEG C, place 72 hours under humidity 85% environment.
After above-mentioned glue curing, glue-line high-low temperature resistant result is: embodiment glue-line the most now turns white, glue-line
Defect, the bad phenomenon such as come off.Testing tool and method: by the glue after three groups of embodiment solidifications first
Placing-16 DEG C of environment and keep 30min, being then rapidly heated, to keep 30min to 80 DEG C be 1 circulation,
Totally 10 circulations.
The test of glue-line resistance to boiling water boiling and result after above-mentioned glue curing, after embodiment glue curing, room temperature is put
After putting 24 hours, put into 100 DEG C of thermostat water bath 10min, then stand and dry 4 hours, glue-line
Surface without turning white, the bad phenomenon such as defect, decocting in water postadhesion power test >=4B.Accompanying drawing 2 is embodiment
Two transfer glue solidification after through decocting in water test before and after outside drawing, the left side for test before, the right for test
After, it can be seen that after decocting in water is tested glue-line have no substantially turn white, come off, defect phenomenon.
After above-mentioned glue curing, 150 DEG C of baking 30min resistance to boiling water boiling tests and result: embodiment glue
After room temperature is placed 24 hours after water cure, it is then placed in baking oven, toasts 30 points in 150 DEG C of constant temperature
Clock, naturally cools to room temperature, is then placed in 100 DEG C of thermostat water bath 30min, uses water absorbing capacity good
Dust-free paper to dry film surface water stain, find film surface without turning white, the bad phenomenon such as defect, then
Still >=4B is tested through adhesive force.
After above-mentioned glue curing, the chemical attack test of ethanol-tolerant and result: after embodiment glue curing
After room temperature is placed 24 hours, use white cloth, dip in ethanol and encase wear-resisting reference test bar lower end base,
Then wear resistant instrument is used to test.Condition is: load 500g (containing measuring bar deadweight), friction frequency
Rate: 30 cycles per minute, distance 4cm.After having tested, find film surface without turning white, defect etc.
Bad phenomenon.
After above-described embodiment glue curing, the chemical attack test of resistance to ethyl acetate and result: embodiment
After room temperature is placed 24 hours after glue curing, use white cloth, dip in ethyl acetate and encase wear-resisting
Reference test bar lower end base, then uses wear resistant instrument to test.Condition is: load 500g is (containing measuring
Bar is conducted oneself with dignity), rub frequency: 30 cycles per minute, distance 4cm.After having tested, find glue-line table
Face without turning white, the bad phenomenon such as defect.Accompanying drawing 3 be embodiment three transfer glue solidification after through resistance to acetic acid
Outside drawing before and after the chemical attack test of ethyl ester, before the left side is for test, after the right is for test, permissible
Find out through resistance to ethyl acetate chemical attack test after glue-line lines have no significant change, turn white, defect,
The bad phenomenon such as dissolving.
Can be seen that mechanical property that the glass baseplate ultraviolet curing transfer adhesive of the present invention had,
The impact of anti-wear performance, solvent resistant, cold-hot and glue-line are good with substrate bonding, and particularly decocting in water is surveyed
After examination, glue-line and the adhesive force of base material still ＞ 4B, environmental pollution are little.Solve existing ultraviolet solid
Change that transfer glue cementability is poor, not water boiling resistance, the most solvent-proof problem, meet industry requirement, reduce and look forward to
Industry production cost, for enterprise getting profit.
Claims (10)
1. a glass baseplate ultraviolet curing transfer adhesive, it is characterised in that by weight, by
Following components forms:
Glass baseplate ultraviolet curing transfer adhesive the most according to claim 1, it is characterised in that:
Described aliphatic polyurethane acrylate, for hydroxyl modification difunctional fat adoption urethane acrylate,
Carboxy-modified trifunctional aliphatic urethane acrylate, six functional groups aliphatic urethane acrylate
In one or more.
Glass baseplate ultraviolet curing transfer adhesive the most according to claim 1, it is characterised in that:
Described acrylated phosphate analog assistant is methacrylic acid phosphoric acid ester, 2-hydroxyethyl methacrylic acid phosphoric acid
One or more in ester, methylacryoyloxyethyl phosphate ester.
Glass baseplate ultraviolet curing transfer adhesive the most according to claim 1, it is characterised in that:
Described esters of acrylic acid activity diluting monomer be 2-Hydroxy ethyl acrylate, iso-bornyl acrylate, third
Olefin(e) acid-2-hydroxy propyl ester, ring trimethylolpropane dimethoxym ethane acrylate, 1,6-hexanediyl ester,
Isosorbide-5-Nitrae-hexanediyl ester, BDO diacrylate, N,N-DMAA, two
A kind of or the most several mixture in tetramethylolmethane six acrylate.
Glass baseplate ultraviolet curing transfer adhesive the most according to claim 1, it is characterised in that:
Described light trigger is 2-hydroxyl-2 methyl isophthalic acid phenyl-1-acetone, benzoin dimethylether, 2,4,6-trimethyls
Benzoyl-diphenyl phosphine oxide, 1-hydroxy-cyclohexyl-phenyl ketone, benzophenone, 2-methyl isophthalic acid-[4-
(methyl mercapto) phenyl]-2-morpholinyl-1-acetone, in phenyl double (2,4,6-trimethylphenyl acyl group) one
Kind or the most several mixture.
Glass baseplate ultraviolet curing transfer adhesive the most according to claim 1, it is characterised in that:
Described silane coupler is gamma-aminopropyl-triethoxy-silane, γ-ammonia (2,3-expoxy propane) propyl group three
A kind of or the most several in methoxy silane, γ-(methacryloxypropyl) propyl trimethoxy silicane
Mixture.
Glass baseplate ultraviolet curing transfer adhesive the most according to claim 1, it is characterised in that
By weight, described glass baseplate ultraviolet curing transfer adhesive is composed of the following components:
8. any one glass baseplate system of ultraviolet light polymerization curing transfer glue described in claim 1-7
Preparation Method, it is characterised in that comprise the following steps:
(1) by weight, by some aliphatic polyurethane acroleic acid fat, part propylene esters of gallic acid activity
Diluent, light trigger and HEMA phosphate adjuvant are sequentially added in container mixed
Close, disperse, filter, obtain host；
(2) by weight, by residual acrylic acid esters activity diluting monomer, silane coupler and residue
Aliphatic polyurethane acrylate is sequentially added in container mixing, disperses, filters, obtains adjuvant；
(3) in mass ratio 1: 1 mixing host and adjuvant, disperses, filters, and i.e. obtains glass baseplate and uses
Ultraviolet curing transfer adhesive.
9. the preparation method of glass baseplate ultraviolet curing transfer adhesive described in claim 8, its feature
Being: step (1), dispersion rate is that 1000-1500 turns/min, and the time is 1-4 hour；Step (2),
Dispersion rate is that 200-500 turns/min, and the time is 1-4 hour；Step (3), dispersion rate is 200-500
Turning/min, the time is 0.5-1 hour.
10. the preparation method of glass baseplate ultraviolet curing transfer adhesive described in claim 8, its feature
It is: the decentralized environment of step (1), step (2) and step (3) is lucifuge, ventilated environment,
Temperature is 15-35 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510275565.5A CN106281198B (en) | 2015-05-26 | 2015-05-26 | A kind of glass baseplate ultraviolet curing transfer adhesive |
| CN201810260834.4A CN108546540B (en) | 2015-05-26 | 2015-05-26 | Preparation method of ultraviolet curing transfer adhesive for glass substrate |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510275565.5A CN106281198B (en) | 2015-05-26 | 2015-05-26 | A kind of glass baseplate ultraviolet curing transfer adhesive |
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| CN201810260834.4A Division CN108546540B (en) | 2015-05-26 | 2015-05-26 | Preparation method of ultraviolet curing transfer adhesive for glass substrate |
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| CN106281198B CN106281198B (en) | 2018-08-28 |
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| CN201810260834.4A Active CN108546540B (en) | 2015-05-26 | 2015-05-26 | Preparation method of ultraviolet curing transfer adhesive for glass substrate |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108517196A (en) * | 2018-04-16 | 2018-09-11 | 苏州市贝特利高分子材料股份有限公司 | Sapphire glass base material with can photosensitive development special grains transfer glue and preparation method thereof |
| CN109266281A (en) * | 2018-08-15 | 2019-01-25 | 瑞声科技(新加坡)有限公司 | UV glue |
| CN109735290A (en) * | 2018-12-27 | 2019-05-10 | 苏州宝瑞德纳米光学材料有限公司 | UV optical cement |
| CN110027339A (en) * | 2019-05-10 | 2019-07-19 | 广东阿特斯科技有限公司 | A kind of sheet printing technology without spraying forced fluid |
| CN110734704A (en) * | 2018-07-19 | 2020-01-31 | 正一龙华特殊材料(深圳)有限公司 | Ultraviolet light curing adhesive |
| CN112235984A (en) * | 2020-10-29 | 2021-01-15 | Oppo广东移动通信有限公司 | Shell, shell preparation method and electronic equipment |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012023181A1 (en) * | 2012-11-28 | 2014-05-28 | Basf Se | Producing two-layer foam plates used for manufacturing rotor blades of wind turbines, comprises bonding two thinner foam sheets to a two-layer foam sheet, where adhesive is applied on one of surfaces of the thinner foam sheets |
| CN104531043A (en) * | 2014-12-23 | 2015-04-22 | 广州市尤特新材料有限公司 | LED-UV curable reinforcing adhesive |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008127545A (en) * | 2006-11-24 | 2008-06-05 | Emulsion Technology Co Ltd | Adhesive resin composition, adhesive tape and method for processing electronic part |
| CN101153127A (en) * | 2007-09-06 | 2008-04-02 | 湖南阳光新材料有限公司 | White composition capable of solidifying by ultraviolet light |
| CN101942277A (en) * | 2010-09-02 | 2011-01-12 | 东莞市贝特利新材料有限公司 | Ultraviolet curing transfer adhesive |
| KR101362869B1 (en) * | 2010-12-29 | 2014-02-14 | 제일모직주식회사 | Adhesive composition for optical film |
| CN103013358A (en) * | 2012-11-30 | 2013-04-03 | 北京航空航天大学 | Low-viscosity low-contact angle cold tolerance ultraviolet light polymerization adhesive for bonding glass and preparation method thereof |
| CN103031066B (en) * | 2012-12-30 | 2014-09-03 | 南通万德科技有限公司 | Photocuring transfer printing material |
| CN104073214A (en) * | 2014-06-26 | 2014-10-01 | 深圳市奥普利斯光电有限公司 | UV glue for pasting dimming film and application method thereof |
-
2015
- 2015-05-26 CN CN201510275565.5A patent/CN106281198B/en active Active
- 2015-05-26 CN CN201810260834.4A patent/CN108546540B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012023181A1 (en) * | 2012-11-28 | 2014-05-28 | Basf Se | Producing two-layer foam plates used for manufacturing rotor blades of wind turbines, comprises bonding two thinner foam sheets to a two-layer foam sheet, where adhesive is applied on one of surfaces of the thinner foam sheets |
| CN104531043A (en) * | 2014-12-23 | 2015-04-22 | 广州市尤特新材料有限公司 | LED-UV curable reinforcing adhesive |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108517196A (en) * | 2018-04-16 | 2018-09-11 | 苏州市贝特利高分子材料股份有限公司 | Sapphire glass base material with can photosensitive development special grains transfer glue and preparation method thereof |
| CN110734704A (en) * | 2018-07-19 | 2020-01-31 | 正一龙华特殊材料(深圳)有限公司 | Ultraviolet light curing adhesive |
| CN109266281A (en) * | 2018-08-15 | 2019-01-25 | 瑞声科技(新加坡)有限公司 | UV glue |
| CN109735290A (en) * | 2018-12-27 | 2019-05-10 | 苏州宝瑞德纳米光学材料有限公司 | UV optical cement |
| CN110027339A (en) * | 2019-05-10 | 2019-07-19 | 广东阿特斯科技有限公司 | A kind of sheet printing technology without spraying forced fluid |
| CN112235984A (en) * | 2020-10-29 | 2021-01-15 | Oppo广东移动通信有限公司 | Shell, shell preparation method and electronic equipment |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108546540A (en) | 2018-09-18 |
| CN108546540B (en) | 2021-04-06 |
| CN106281198B (en) | 2018-08-28 |
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