CN201195718Y - Novel gasification furnace propitious to recycle heat - Google Patents

Novel gasification furnace propitious to recycle heat Download PDF

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Publication number
CN201195718Y
CN201195718Y CNU2008200565859U CN200820056585U CN201195718Y CN 201195718 Y CN201195718 Y CN 201195718Y CN U2008200565859 U CNU2008200565859 U CN U2008200565859U CN 200820056585 U CN200820056585 U CN 200820056585U CN 201195718 Y CN201195718 Y CN 201195718Y
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China
Prior art keywords
vertical container
vapourizing
vapourizing furnace
furnace
gasification furnace
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Expired - Lifetime
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CNU2008200565859U
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Chinese (zh)
Inventor
龚欣
代正华
郭晓鐳
梁钦锋
刘海峰
陈雪莉
李伟锋
王辅臣
于广锁
王亦飞
周志杰
王兴军
于遵宏
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East China University of Science and Technology
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East China University of Science and Technology
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Priority to CNU2008200565859U priority Critical patent/CN201195718Y/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

Abstract

The utility model discloses a novel gasification furnace, which is beneficial for reclaiming heat and comprises a vertical container, a plurality of burner nozzle chambers which are arranged outside the vertical container, are located on the lower middle portion, and are opposite mutually, and a refractory lining which is arranged inside the vertical container, wherein a synthesis gas and fly ash outlet and a cooling medium inlet are arranged on the upper portion of the vertical container, and a liquid slag outlet is arranged on the lower portion. Carbon compounds in the slurry state (such as coal water slurry, oil coke slurry, sludge, discard solution and the like) or in the powder state (such as pulverized coal, solid waste, biomass and the like) can be gasified through adopting the gasification furnace, the raw material applicable range is wide, the processing load of the gasification furnace is big, the energy comprehensive availability ratio of a system which is composed of the gasification furnace and subsequent devices or techniques is high, the synthesis gas which is produced can be directly used in reduced ironmaking, IGCC power generation, chemical material gas, fuel gas, hydrogen production, liquid fuel synthesis and the like, and the use is extremely wide.

Description

A kind of novel vapourizing furnace that helps heat recuperation
Technical field
The present invention relates to the equipment of gasification of carbonaceous material, be specifically related to the vapourizing furnace of carbonaceous material slurry attitude (as coal water slurry, petroleum charred slurry, mud, waste liquid etc.) or powder attitude (as fine coal, solid waste, biomass etc.) charging.
Background technology
Gasification is that the coal cleaning transforms and the efficient leading core technology of utilizing, entrained flow bed gasification technology is used widely with its production intensity height, efficiency of carbon conversion height, environment amenable advantage, as production chemical product, IGCC generating, direct reduction iron making, Poly-generation, hydrogen manufacturing etc.In order to be complementary with its derived product demand and process characteristic, obtain maximum capacity usage ratio and economic return, water chilling-type vapourizing furnace and synthetic gas cooled vapourizing furnace have been proposed in succession.Representative water chilling-type vapourizing furnace is the coal slurry gasifier (ZL 94193847.6) of GE company and the multi-nozzle opposed type coal water slurry or the powder coal gasification furnace (ZL 98110616.1) of East China University of Science; What Shell company vapourizing furnace (ZL 90103807.5) then adopted is the circulation synthetic gas type of cooling.
When the synthetic gas after the gasification was used for IGCC generating or direct reduction iron making, the raising of synthetic gas temperature helped improving the efficiency of utilization of system.But if adopt water Quench mode that the high-temperature synthesis gas temperature is reduced to about 220 ℃ in this case, this obviously is uneconomic.For this reason, this patent has proposed a kind of novel vapourizing furnace that helps heat recuperation.
The vapourizing furnace of patent ZL 90103807.5 inventions is provided with a plurality of nozzles in its underpart, nozzle is in become the cut Small angle to install with the vapourizing furnace body of heater; High-temperature synthesis gas is discharged from vapourizing furnace top, and adds entry at 4~6 times of diameter places of distance outlet or gas cools off high-temperature synthesis gas.Its heat-eliminating medium is the cold cycle synthetic gas in the practical application.Its nozzle setting angle of the vapourizing furnace of this structure is difficult to accurate realization on engineering, installation deviation easily causes vapourizing furnace furnace wall scaling loss, influences vapourizing furnace work-ing life; It is long that heat-eliminating medium inlet that the said vapourizing furnace of patent upper end is provided with and high-temperature synthesis gas export distance, and the useful space of vapourizing furnace is increased, and the increase of heat transfer ratio surface-area causes production intensity reduction, thermosteresis to increase; The lime-ash that carries of high-temperature synthesis gas needs the natural temperature-fall period of one section longer distance on the other hand, and slag phase transformation after fixing in this process easily condenses in wall and makes that cross section of fluid channel is long-pending to be reduced, and the gas take-off rate improves, and the phenomenon of carrying scum silica frost secretly is even more serious.
The vapourizing furnace of patent ZL 01131780.9.5 invention, its underpart burner hearth is a horizontal type structure, is provided with a plurality of nozzles, vapourizing furnace top is the vertical cylindrical structure that has dwindled diameter.On the cylinder on vapourizing furnace top, spray into the secondary coal dust and go into stove,, outlet synthetic gas temperature is minimized by the gasification reaction of secondary coal dust.But because the residence time of secondary coal dust in vapourizing furnace that sprays into is too short, be in cryogenic reaction zone again, these coal dusts have little time to react completely and just are synthesized gas and carry and come out of the stove, and methane content rises and contains tar in the reaction product under the cold zone condition, will directly cause the quality of synthetic gas to descend.
Summary of the invention
In order to overcome the deficiency of above-mentioned technology, the present invention proposes a kind of novel vapourizing furnace that helps heat recuperation, to satisfy the higher demand of system capacity comprehensive utilization ratio that vapourizing furnace and postorder equipment or technology constitute.
A kind of vapourizing furnace that helps heat recuperation that the utility model proposes comprises:
Vertical container, a plurality of opposed burners chamber, slag (molten ash) outlet, synthetic gas and flying dust outlet and heat-eliminating medium inlet; Synthetic gas and flying dust outlet, heat-eliminating medium inlet are arranged on the top of vertical container, and the bottom of vertical container is a slag exit; Heat-eliminating medium inlet is positioned at the top, last tapering of vertical container, with synthetic gas and flying dust outlet apart from very near, the phase transformation that helps the timely cooling of high-temperature synthesis gas and tiny slag with separate;
The vertical container inside is provided with refractory liner;
The burner chamber is arranged on the middle and lower part of vertical outside of containers, and quantity is even number, in twos to being set to 180 °; The burner chamber is preferably 4.
Be arranged on the hyperchannel gasification nozzle in the Link Port of gasification nozzle, its effect is to make solid carbon-contg compound and gaseous state vaporized chemical enter reactor, and makes it well blend, carries out gasification reaction;
Said refractory liner can be the water wall lining, also can be lining of fire brick.
A kind of novel vapourizing furnace that helps heat recuperation that the utility model proposes, the preferred coal of carbon compound, carbon compound, refinery coke, biomass, rubbish and other carbonaceous solids waste of can be used for gasifying slurry attitude and dry powder attitude.
Particle diameter is transported to the technology nozzle less than the carbon compound (for example coal) of slurry attitude or the dry powder attitude of 200 μ m, and the carbon compound of slurry attitude is carried with high-pressure pump, and the carbon compound of dry powder attitude is carried as nitrogen, CO with carrier gas 2, synthetic gas etc.; Gasifying medium also enters the technology nozzle simultaneously to be mixed, and with the flow velocity of 30~140 meter per seconds, ejection technology nozzle is coal gas with entering the vaporizer gasification after carbon compound atomizing or the disperse.
Gasification temperature is 1000~1700 ℃, and vapor pressure is 0.5~10.0MPa;
Carbon containing contains 1 part of grey compound weight, 0.4~1.2 part of gasifying medium weight, 0~0.5 part of process steam weight;
Said gasifying medium comprises oxygenant, water vapor and carbonic acid gas;
It is 50~99% oxygen-rich air that oxygenant is selected from oxygen, air or oxygen level;
The parts by weight ratio of carrier gas and carbon compound is: 1 part of carrier gas, 0.02~0.8 part of carbon compound;
This vapourizing furnace is compared with present disclosed vapourizing furnace, the system capacity comprehensive utilization ratio height that vapourizing furnace and postorder equipment or technology constitute, and raw material range is wide, and it is big that vapourizing furnace is handled load; The synthetic gas of producing can be used as direct reduction iron making, IGCC generating, material gas, fuel gas, hydrogen manufacturing, synthetic liquid fuel etc., and purposes is very extensive.Especially for direct reduction iron making, the synthetic gas that goes out vapourizing furnace and flying dust are through mixing with heat-eliminating medium or being cooled to 600~1100 ℃ through radiant boiler, after dedusting and desulfurization, enter the direct reduction iron making stove then, this process has been save the heating installation of synthetic gas, and the system capacity comprehensive utilization ratio is high.
Description of drawings
Fig. 1 is the gasification furnace structure synoptic diagram of embodiment;
Fig. 2 is that the A-A of vapourizing furnace of embodiment is to view.
Embodiment
To help to understand the utility model by the following description of the embodiments, but not limit content of the present utility model.
Embodiment 1
Referring to Fig. 1, a kind of novel vapourizing furnace that helps heat recuperation that the utility model proposes comprises:
Vertical container 1; Ratio D1:H1=0.1~0.7 of the direct tube section length H1 of the furnace diameter D1 of vertical container 1 and vertical container 1.
Be arranged on a plurality of opposed burner chamber 2 in vertical container 1 outside, burner chamber 2 is positioned at the middle and lower part of vapourizing furnace.The height H 2 of burner chamber 2 and ratio H2:H1=0.05~0.5 of the direct tube section length H1 of vertical container 1.
Be arranged on the refractory liner 3 of vertical container inside.Said refractory liner can be the water wall lining, also can be lining of fire brick.The water wall lining can adopt the technology of ZL 200520047972.2 patent disclosures, and lining of fire brick can adopt the technology of ZL 98110601.3 patent disclosures, adopts other refractory liner pattern also can reach purpose of the present invention.
The top of vertical container 1 is synthetic gas and flying dust outlet 4, and outlet 4 awl sections are that α is 30~60 ° with the inclination angle of direct tube section junction, ratio D2:D1=0.1~0.5 of the interior diameter D2 of outlet 4 and the furnace diameter D1 of vertical container 1; The bottom is molten ash outlet 6, and outlet 6 awl sections are 30~60 ° with the angle of inclination beta of direct tube section junction, ratio D3:D1=0.1~0.5 of the interior diameter D3 of outlet 6 and the furnace diameter D1 of vertical container 1.Heat-eliminating medium inlet 5 is positioned at the top, last tapering of vertical container 1, and is very near apart from synthetic gas and flying dust outlet 4.
Referring to Fig. 2, the number of burner chamber 2 is 2 multiple, in twos to being set to 180 °.
Be arranged on the hyperchannel gasification nozzle 7 in the burner chamber 2, the axis of gasification nozzle 7 and burner chamber 2 coaxial lines, the effect of gasification nozzle 7 is to make the solid carbon-contg compound and the gaseous state vaporized chemical of slurry attitude or dry powder attitude enter vapourizing furnace, and makes it well blend, carries out gasification reaction.
Said hyperchannel gasification nozzle 7 refers to the nozzle with a plurality of passages, as when adopting slurry attitude carbon compound to be raw material, the technology of ZL95111750.5 patent disclosure can be adopted, when being raw material, the technology of ZL200420114032.6 patent disclosure can be adopted as employing dry powder attitude carbon compound; And adopt other nozzle, also can reach purpose of the present invention.

Claims (9)

1. novel vapourizing furnace that helps heat recuperation, comprise vertical container and a plurality of burners chamber that is arranged on the vertical outside of containers, it is characterized in that the inboard of described vertical container has refractory liner, top has synthetic gas and flying dust outlet and heat-eliminating medium enters the mouth, the bottom has the molten ash outlet;
Described burner is provided with the hyperchannel gasification nozzle in the chamber.
2. vapourizing furnace according to claim 1 is characterized in that, described burner chamber is positioned at the middle and lower part of this vapourizing furnace, and quantity is even number, and in twos to being set to 180 °.
3. vapourizing furnace according to claim 1 and 2 is characterized in that, described refractory liner is refractory brick or water wall.
4. vapourizing furnace according to claim 3 is characterized in that, the ratio of the furnace diameter D1 of described vertical container and the length H1 of direct tube section is D1:H1=0.1~0.7.
5. according to right 4 described vapourizing furnaces, it is characterized in that described heat-eliminating medium inlet is positioned at the top, last tapering of described vertical container.
6. according to right 4 described vapourizing furnaces, it is characterized in that the height H 2 of described burner chamber is H2:H1=0.05~0.5 with the ratio of the length H1 of described direct tube section.
7. according to right 4 described vapourizing furnaces, it is characterized in that the described synthetic gas and the awl section of flying dust outlet and the inclination alpha of described direct tube section junction are 30~60 °; The interior diameter D2 of described synthetic gas and flying dust outlet and the ratio of described furnace diameter D1 are D2:D1=0.1~0.5.
8. according to right 4 described vapourizing furnaces, it is characterized in that the awl section of described molten ash outlet and the angle of inclination beta of described direct tube section junction are 30~60 °; The interior diameter D3 of described molten ash outlet and the ratio of described furnace diameter D1 are D3:D1=0.1~0.5.
9. vapourizing furnace according to claim 2 is characterized in that, the quantity of described burner chamber is preferably 4.
CNU2008200565859U 2008-03-26 2008-03-26 Novel gasification furnace propitious to recycle heat Expired - Lifetime CN201195718Y (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101775315A (en) * 2009-12-25 2010-07-14 卢秉威 Double-bed sludge gasification furnace
CN101890419A (en) * 2009-05-22 2010-11-24 华东理工大学 Waste incineration fly ash treatment method
CN101920255A (en) * 2009-06-12 2010-12-22 华东理工大学 Method for treating persistent organic pollutants
CN102031150A (en) * 2010-12-31 2011-04-27 中国科学院广州能源研究所 Double-fixed bed gasifier and processing method for organic solid wastes
CN102433162A (en) * 2011-05-06 2012-05-02 华东理工大学 Entrained-flow bed gasifier with staged oxygen feeding and gasification method thereof
CN102453550A (en) * 2011-05-06 2012-05-16 华东理工大学 Multi-nozzle multi-stage oxygen supplying entrained-flow gasifier and gasification method thereof
CN108977228A (en) * 2018-08-02 2018-12-11 廊坊达能新能源技术股份有限公司 Biomass oxygen-rich gasification method and system
TWI660780B (en) * 2018-04-27 2019-06-01 環創源科技股份有限公司 Apparatus for fuelizing waste organic solvent and modular reactor
CN112143525A (en) * 2019-06-28 2020-12-29 国家能源投资集团有限责任公司 Method for producing hydrogen by converting municipal solid waste
CN112940788A (en) * 2021-02-20 2021-06-11 佳达环保工程有限公司 Oil sludge gasification system and method

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101890419A (en) * 2009-05-22 2010-11-24 华东理工大学 Waste incineration fly ash treatment method
CN101920255A (en) * 2009-06-12 2010-12-22 华东理工大学 Method for treating persistent organic pollutants
CN101775315A (en) * 2009-12-25 2010-07-14 卢秉威 Double-bed sludge gasification furnace
CN102031150B (en) * 2010-12-31 2013-05-22 中国科学院广州能源研究所 Double-fixed bed gasifier and processing method for organic solid wastes
CN102031150A (en) * 2010-12-31 2011-04-27 中国科学院广州能源研究所 Double-fixed bed gasifier and processing method for organic solid wastes
CN102433162A (en) * 2011-05-06 2012-05-02 华东理工大学 Entrained-flow bed gasifier with staged oxygen feeding and gasification method thereof
CN102453550A (en) * 2011-05-06 2012-05-16 华东理工大学 Multi-nozzle multi-stage oxygen supplying entrained-flow gasifier and gasification method thereof
CN102453550B (en) * 2011-05-06 2013-12-04 华东理工大学 Multi-nozzle multi-stage oxygen supplying entrained-flow gasifier and gasification method thereof
CN102433162B (en) * 2011-05-06 2013-12-04 华东理工大学 Entrained-flow bed gasifier with staged oxygen feeding and gasification method thereof
TWI660780B (en) * 2018-04-27 2019-06-01 環創源科技股份有限公司 Apparatus for fuelizing waste organic solvent and modular reactor
CN108977228A (en) * 2018-08-02 2018-12-11 廊坊达能新能源技术股份有限公司 Biomass oxygen-rich gasification method and system
CN112143525A (en) * 2019-06-28 2020-12-29 国家能源投资集团有限责任公司 Method for producing hydrogen by converting municipal solid waste
CN112940788A (en) * 2021-02-20 2021-06-11 佳达环保工程有限公司 Oil sludge gasification system and method

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