CN1973021A - Use of organic polysulfides against corrosion by acid crudes - Google Patents
Use of organic polysulfides against corrosion by acid crudes Download PDFInfo
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- CN1973021A CN1973021A CNA2005800194186A CN200580019418A CN1973021A CN 1973021 A CN1973021 A CN 1973021A CN A2005800194186 A CNA2005800194186 A CN A2005800194186A CN 200580019418 A CN200580019418 A CN 200580019418A CN 1973021 A CN1973021 A CN 1973021A
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- China
- Prior art keywords
- compound
- described method
- hydrocarbon stream
- sulphur
- crude oil
- Prior art date
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- 230000007797 corrosion Effects 0.000 title claims abstract description 19
- 238000005260 corrosion Methods 0.000 title claims abstract description 19
- 150000008116 organic polysulfides Chemical class 0.000 title description 5
- 239000002253 acid Substances 0.000 title description 3
- 238000000034 method Methods 0.000 claims abstract description 30
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 3
- 239000010779 crude oil Substances 0.000 claims description 20
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 9
- 239000005864 Sulphur Chemical group 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 125000005842 heteroatom Chemical group 0.000 claims description 6
- 238000007670 refining Methods 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
- LNMBCRKRCIMQLW-UHFFFAOYSA-N 2-tert-butylsulfanyl-2-methylpropane Chemical compound CC(C)(C)SC(C)(C)C LNMBCRKRCIMQLW-UHFFFAOYSA-N 0.000 claims description 2
- 239000002283 diesel fuel Substances 0.000 claims description 2
- 238000004821 distillation Methods 0.000 claims description 2
- 125000004434 sulfur atom Chemical group 0.000 claims 1
- 239000005077 polysulfide Substances 0.000 abstract description 5
- 229920001021 polysulfide Polymers 0.000 abstract description 5
- 150000008117 polysulfides Polymers 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract 1
- 125000005608 naphthenic acid group Chemical group 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 8
- 229910052742 iron Inorganic materials 0.000 description 8
- 239000002480 mineral oil Substances 0.000 description 6
- 235000010446 mineral oil Nutrition 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- -1 poly-alkyl sulfur Chemical compound 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002903 organophosphorus compounds Chemical class 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- NHHSUCWHDQEHTJ-UHFFFAOYSA-N 2-(tert-butyltetrasulfanyl)-2-methylpropane Chemical compound CC(C)(C)SSSSC(C)(C)C NHHSUCWHDQEHTJ-UHFFFAOYSA-N 0.000 description 1
- NYLJHRUQFXQNPN-UHFFFAOYSA-N 2-(tert-butyltrisulfanyl)-2-methylpropane Chemical compound CC(C)(C)SSSC(C)(C)C NYLJHRUQFXQNPN-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BELBBZDIHDAJOR-UHFFFAOYSA-N Phenolsulfonephthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2S(=O)(=O)O1 BELBBZDIHDAJOR-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229960003531 phenolsulfonphthalein Drugs 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G75/00—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
- C10G75/02—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general by addition of corrosion inhibitors
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G7/00—Distillation of hydrocarbon oils
- C10G7/02—Stabilising gasoline by removing gases by fractioning
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The inventive method for controlling corrosion of the refinery metal walls produced by naphthenic acids consists in using alkyl polysulfide radical containing from 2 to 5 carbon atoms.
Description
The present invention relates to the process field of sour crude oil in the refinery.More specifically, the objective of the invention is a kind of refining unit (unit é de raffinage) corroding method that prevents to handle sour crude oil, this method comprises uses specific polysulfide.
When oil refinery need be handled some described sour crude oil, they may run into serious etching problem.These sour crude oil mainly contain naphthenic acid, and they are the roots that produce this very special corrosion phenomenon, because it occurs in the liquid medium of non-Ampereconductors.These naphthenic acid are corresponding to the saturated cyclic hydrocarbons that has one or more carboxyls.According to ASTM D664-01 standard, measure definite crude oil acidity by stdn.This acidity with in and the needed potassium hydroxide mg of 1g oil numerical table show, be referred to as TAN (total acid value).Those skilled in the art know, being higher than 0.2 crude oil TAN qualitative is tart, and it may cause damage in refinery's equipment.
Local condition is greatly depended in this corrosion reaction, for example as the temperature of relevant device wall and metallic character, the space velocity of hydrocarbon, the existence at gas/liquid interface.Therefore, even after the refiner carries out extensive work with regard to this problem, expect that great corrosion reaction and location thereof also can run into great difficulty.
The way of this etching problem of a kind of industrial solution is to use the equipment of being made by stainless steel, in other words uses by iron alloy, particularly the equipment made of the alloy of iron and chromium and molybdenum.Yet this terms of settlement is still seldom used because of cost of investment is high.Refinery in addition,, but also needs suitable Infrastructure, so also should preferably consider this selection when designing because these stainless mechanical propertys are not so good as to use usually the mechanical property of carbon steel.
Therefore, handling these sour crude oil has the result of these technological difficulties to be, these crude oil are sold to the refiner with the price level that is lower than benchmark crude.
The terms of settlement that these refiners adopt another kind to handle the sour crude oil problem in the reality is to dilute this sour crude oil with another kind of nonacid crude oil, thereby obtain harmonic(-)mean acidity, for example be lower than the 0.2TAN threshold value, in this case, the concentration of naphthenic acid should be hanged down is enough to reach acceptable corrosion speed.Yet this way still has certain scope.In fact, the TAN of some sour crude oil is higher than 2, makes the top limit of using these sour crude oil reach like this and enters 10% of refinery crude total amount at the most.In addition, some blends of crudes even appearance and expectation reverse effect sometimes after dilution, i.e. naphthenic acid accelerated corrosion reaction.
The another kind of method that prevents this etching problem is to add chemical additive in pending sour crude oil, and this additive can suppress or prevent the metallic walls of chemical erosion relevant device.Point out that with using the front method of special steel or alloy compares, this method is very economical often.
Experimental study, for example (" corrosion " (Corrosion), in November, 1998, the 54th volume, o. 11th, the 922nd page) experimental study, imagination is added (0.1%) hydrogen sulfide on a small quantity in order to reduce the corrosive nature of naphthenic acid to Turnbull in this crude oil.Yet this terms of settlement is not useable in the refinery, because hydrogen sulfide at room temperature is highly toxic, makes like this these leak the result and all become extremely dangerous that this has also limited the use of hydrogen sulfide.In addition, under higher temperature, the corrodibility that hydrogen sulfide itself also becomes very high, it also can make general corrosion phenomenon worsen more in other place of refinery.
US 5 182 013 has described to solving the sulfocompound that this same etching problem uses other, promptly contains the alkyl polysulfide of 6-30 carbon atom.
Patent EP 742 277 has described the restraining effect of trialkyl phosphates and organic polysulfide and usefulness.US 5 552 085 recommends to use sulfo-P contained compound, for example organosulfur substituted phosphate or thiophosphite.Patent AU 693 975 disclosed trialkyl phosphates and with the mixture of lime neutral phenol red phosphide as inhibitor.
Yet, because organophosphorus compound is handled very thorny because of its high toxicity.In addition, they are poisonous substances that hydrotreating catalyst is installed from the hydrocarbon-fraction of normal pressure and vacuum distilling for purifying.Owing to this two reasons at least, organophosphorus compound is unsatisfactory in the refining Application for Field.
Astoundingly, people have found to use the organic polysulfide of certain kinds, and each alkyl carbon atoms number of these poly-alkyl sulfur compoundss is 2-5, and they can suppress the corrosion of these naphthenic acid, the height of the present known organic polysulfide of its efficiency ratio, nor need to add phosphorous inhibitor.
Therefore, the objective of the invention is a kind of method that prevents naphthenic acid (acides naphth é niques) corrosion refining unit metallic walls, it is characterized in that this method comprises toward containing hydrocarbon compound with one or more following formulas that add significant quantity in this device processes hydrocarbon stream:
In the formula:
-n is the integer of 2-15, and
-symbol R
1And R
2, identical or different, representative contains the straight or branched alkyl of 2-5 carbon atom separately, and these bases randomly contain one or more heteroatomss as oxygen or sulphur and so on; Or
-R
1And R
2, identical or different, representative contains the cycloalkyl of 3-5 carbon atom separately, and these bases randomly contain one or more heteroatomss as oxygen or sulphur and so on.
According to itself known method preparation formula (I) polysulfide, for example US 2 708 199, US 3,022 351 and US 3 038 013 described methods.Some has been commodity.
Preferably, R
1And R
2Be the straight or branched alkyl, n is 2-6.
According to another preferred specific embodiments, according to the improvement stability of corresponding formula (I) compound, R
1And R
2Be identical.
According to a preferred specific embodiments, use the mixture of poly-di-t-butyl sulfide as formula (I) compound.From industrial source, these products for example come from the reaction of sulphur and tert-butyl mercaptan.These reaction conditionss can prepare the Industrial products of being made up of the mixture of the polysulfide that contains 3-10 sulphur atom, and its number average value is to be 2-6.
Generally speaking the amount of adding one or more formulas (I) compound in the hydrocarbon stream of handling toward refining unit is 1-5000ppm, preferably 5-500ppm corresponding to the amount of representing with the sulphur equivalent of described compound in hydrocarbon stream weight.When remaining in this concentration range, may when starting the inventive method, be fixed on high-content, then this content is reduced to the level of keeping.
The inventive method can advantageously be handled hydrocarbon stream, and especially TAN is higher than 0.2, preferably is higher than 1 crude oil.
The temperature of implementing this method produces the temperature of these corrosion reactions corresponding to naphthenic acid, generally speaking is 200-450 ℃, more particularly 250-350 ℃.
At the processing upper reaches of described equipment, near the position that corrosion reaction takes place or under lower temperature, adding type (I) compound in this hydrocarbon stream.Therefore can adopt any method known to those skilled in the art to carry out this interpolation, guarantee that by nozzle or mixing tank control injects flow and the additive good distribution at hydrocarbon.
Adopt the inventive method can prevent that it is any wall that can contact with pending acid hydrocarbon stream that corrosive refining unit metallic walls should be appreciated that.Therefore, also relate to proper equipment inwall, for example be normal pressure and vacuum tower, or its inner member surface, for example their sieve plate or filler, or its peripheral components, for example their water shoot and inlet pipe, pump, preheating oven or heat exchanger are 200-450 ℃ as long as these elements are raised to local temperature.
As the limiting examples of the pending hydrocarbon stream of the inventive method, it comprises crude oil, air distillation resistates, from the diesel oil distillate of normal pressure and vacuum distilling, and from the overhead product and the vacuum residue of vacuum distilling.
Following embodiment only is used to explain the present invention, and should not explain its objective is the restriction this
Scope of invention.
In these embodiments, it is as follows to carry out the condition of corrosion test.
The explanation of corrosion test:
The iron powder of simulation metallic surface and the naphthenic acid mixture dissolved mineral oil of simulation sour crude oil stream are used in this test.The feature of these reactants is as follows:
The white mineral oil of-density 0.838
The spherical iron granules powder of-granularity-40+70 order (promptly about 212-425 μ m)
-the naphthenic acid mixture of 10-18 carbon atom is arranged, boiling point is 270-324 ℃, average molar mass 244g/mol.
Add following material in the 150ml glass reactor, this reactor is equipped with funnel and water condenser, and is equipped with stirring and temperature measuring system:
-70ml (being 58.8g) mineral oil,
-2g iron powder,
-2.8g naphthenic acid mixture.
The initial TAN of reaction mixture equals 10.
Under 250 ℃ of dry nitrogen atmosphere and temperature, allow these reactants keep in touch 2 hours, to avoid oxidizing reaction.
When off-test, ordinary method, this residue of employing enforcement sample mineralising is dissolved in the acidified water and uses plasma measurement, can measure the concentration of iron that is dissolved in this medium.
The iron powder corrosion speed that the naphthenic acid mixture is caused in this dissolved iron concentration (representing with ppm) and the mineral oil is directly proportional.
Embodiment 1: the controlled trial of unrestraint agent
Adding type (I) compound does not carry out in preceding test, repeats 2 times.
These the results are shown in down in the Table I.
(Table I)
| Concentration of iron (ppm) | |
| Test 1 | 180 |
| Test 2 | 227 |
| Mean value | 203.5 |
Embodiment 2: the test of poly-alkyl sulfur compounds is arranged
Repeat embodiment 1, but reactor is when reinforced, the dissimilar poly-alkyl sulfur compounds of interpolation in this mineral oil.Calculate the addition of these derivatives, so that reach the concentration 500ppm that in the mineral oil of reactor, represents with the sulphur equivalent.
Obtain the result that in following Table II, compiles.
In this table, also listed by the naphthenic acid mixture and caused the corrosive inhibiting rate.This inhibiting rate is represented with %, and is defined with following formula:
[iron] is the concentration of measuring dissolved iron when being with or without inhibitor in the formula, and according to embodiment 1, the concentration of iron of unrestraint agent equals 203.5ppm.
Table II
| Formula (I) compound | Trade(brand)name * | Concentration of iron (ppm) | Inhibiting rate (%) |
| The di-t-butyl trisulphide | TPS44 | 4 | 98％ |
| The di-t-butyl tetrasulfide | TPS54 | 7 | 97％ |
*Supplier: ARKEMA
Claims (8)
1. prevent the method for naphthenic acid corrosion refining unit metallic walls, it is characterized in that this method comprises toward containing hydrocarbon compound with one or more following formulas that add significant quantity in this device processes hydrocarbon stream:
In the formula:
-n is the integer of 2-15, and
-symbol R
1And R
2, identical or different, representative contains the straight or branched alkyl of 2-5 carbon atom separately, and these groups randomly contain one or more heteroatomss, this heteroatoms such as oxygen or sulphur; Or
-R
1And R
2, identical or different, representative contains the cycloalkyl of 3-5 carbon atom separately, and these groups randomly contain one or more heteroatomss, this heteroatoms such as oxygen or sulphur.
2. method according to claim 1 is characterized in that use formula (I) compound, wherein R
1And R
2Be the straight or branched alkyl, n is 2-6.
3. according to the described method of each claim in claim 1 or 2, it is characterized in that use formula (I) compound, wherein R
1And R
2Group is identical.
4. according to the described method of each claim among the claim 1-3, it is characterized in that using the mixture of poly-di-t-butyl sulfide, wherein number of sulfur atoms mean value is 2-6.
5. according to the described method of each claim among the claim 1-4, it is characterized in that the amount of one or more formulas (I) compound is 1-5000ppm, preferably 5-500ppm corresponding to the amount of representing with the sulphur equivalent of described compound in hydrocarbon stream weight.
6. according to the described method of each claim among the claim 1-5, the TAN that it is characterized in that pending hydrocarbon stream is preferably more than 1 greater than 0.2.
7. according to the described method of each claim among the claim 1-6, it is characterized in that this method, more particularly implement down for 250-350 ℃ at temperature 200-450 ℃.
8. according to the described method of each claim among the claim 1-7, it is characterized in that pending hydrocarbon stream be selected from crude oil, air distillation resistates, from the diesel oil distillate of normal pressure and vacuum distilling, and from the overhead product and the vacuum residue of vacuum distilling.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0403838A FR2868787B1 (en) | 2004-04-13 | 2004-04-13 | USE OF ORGANIC POLYSULFIDES AGAINST CORROSION BY ACID BRUTS |
| FR0403838 | 2004-04-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1973021A true CN1973021A (en) | 2007-05-30 |
Family
ID=34944754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005800194186A Pending CN1973021A (en) | 2004-04-13 | 2005-04-08 | Use of organic polysulfides against corrosion by acid crudes |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20070163922A1 (en) |
| EP (1) | EP1756251A1 (en) |
| JP (1) | JP2007532745A (en) |
| KR (1) | KR20070005676A (en) |
| CN (1) | CN1973021A (en) |
| AR (1) | AR050242A1 (en) |
| AU (1) | AU2005235761B2 (en) |
| BR (1) | BRPI0509789A (en) |
| CA (1) | CA2562102A1 (en) |
| EA (1) | EA010668B1 (en) |
| FR (1) | FR2868787B1 (en) |
| MX (1) | MXPA06011863A (en) |
| NO (1) | NO20065183L (en) |
| TW (1) | TWI314952B (en) |
| UA (1) | UA84741C2 (en) |
| WO (1) | WO2005103208A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104152192A (en) * | 2013-05-13 | 2014-11-19 | 刘爱国 | Gasoline and diesel preservative |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101990826B1 (en) | 2019-03-18 | 2019-06-19 | 영화진흥위원회 | Viewing Providing system for Deafness |
| US20210255609A1 (en) * | 2020-02-14 | 2021-08-19 | Exxonmobil Research And Engineering Company | Systems and methods for monitoring and predicting a risk state of an industrial process |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2708199A (en) * | 1951-10-24 | 1955-05-10 | Continental Oil Co | Preparation of organic polysulfides |
| US3022351A (en) * | 1957-03-07 | 1962-02-20 | Phillips Petroleum Co | Production of organic polysulfides |
| US3062612A (en) * | 1959-04-25 | 1962-11-06 | Inst Francais Du Petrole | Method of protecting metals against electrochemical corrosion of the acidic type |
| US3038013A (en) * | 1959-08-25 | 1962-06-05 | Phillips Petroleum Co | Color improvement in synthesis of polysulfides |
| DE3437936A1 (en) * | 1984-10-17 | 1986-04-17 | Peter, Siegfried, Prof.Dr., 8525 Uttenreuth | Process and agent for combating corrosion under reducing conditions |
| US5182013A (en) * | 1990-12-21 | 1993-01-26 | Exxon Chemical Patents Inc. | Naphthenic acid corrosion inhibitors |
| US5500107A (en) * | 1994-03-15 | 1996-03-19 | Betz Laboratories, Inc. | High temperature corrosion inhibitor |
| US5457234A (en) * | 1994-06-20 | 1995-10-10 | Phillips Petroleum Company | Process for treating organic polysulfide compounds |
| US5552085A (en) | 1994-08-31 | 1996-09-03 | Nalco Chemical Company | Phosphorus thioacid ester inhibitor for naphthenic acid corrosion |
| US5464525A (en) * | 1994-12-13 | 1995-11-07 | Betz Laboratories, Inc. | High temperature corrosion inhibitor |
| US5630964A (en) | 1995-05-10 | 1997-05-20 | Nalco/Exxon Energy Chemicals, L.P. | Use of sulfiding agents for enhancing the efficacy of phosphorus in controlling high temperature corrosion attack |
| EP0909299B1 (en) * | 1996-05-30 | 2003-02-19 | Baker Hughes Incorporated | Control of naphthenic acid corrosion with thiophosphorus compounds |
-
2004
- 2004-04-13 FR FR0403838A patent/FR2868787B1/en not_active Expired - Fee Related
-
2005
- 2005-04-08 UA UAA200610725A patent/UA84741C2/en unknown
- 2005-04-08 BR BRPI0509789-4A patent/BRPI0509789A/en not_active IP Right Cessation
- 2005-04-08 WO PCT/FR2005/000861 patent/WO2005103208A1/en active Application Filing
- 2005-04-08 EA EA200601679A patent/EA010668B1/en not_active IP Right Cessation
- 2005-04-08 CA CA002562102A patent/CA2562102A1/en not_active Abandoned
- 2005-04-08 CN CNA2005800194186A patent/CN1973021A/en active Pending
- 2005-04-08 US US11/547,920 patent/US20070163922A1/en not_active Abandoned
- 2005-04-08 JP JP2007507813A patent/JP2007532745A/en not_active Withdrawn
- 2005-04-08 KR KR1020067021376A patent/KR20070005676A/en not_active Application Discontinuation
- 2005-04-08 EP EP05753703A patent/EP1756251A1/en not_active Withdrawn
- 2005-04-08 MX MXPA06011863A patent/MXPA06011863A/en active IP Right Grant
- 2005-04-08 AU AU2005235761A patent/AU2005235761B2/en not_active Expired - Fee Related
- 2005-04-11 TW TW094111355A patent/TWI314952B/en not_active IP Right Cessation
- 2005-04-12 AR ARP050101429A patent/AR050242A1/en active IP Right Grant
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2006
- 2006-11-10 NO NO20065183A patent/NO20065183L/en not_active Application Discontinuation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104152192A (en) * | 2013-05-13 | 2014-11-19 | 刘爱国 | Gasoline and diesel preservative |
| CN104152192B (en) * | 2013-05-13 | 2016-05-25 | 刘爱国 | A kind of petrol and diesel oil anticorrisive agent |
Also Published As
| Publication number | Publication date |
|---|---|
| US20070163922A1 (en) | 2007-07-19 |
| KR20070005676A (en) | 2007-01-10 |
| WO2005103208A1 (en) | 2005-11-03 |
| EA010668B1 (en) | 2008-10-30 |
| BRPI0509789A (en) | 2007-10-23 |
| NO20065183L (en) | 2006-11-10 |
| EP1756251A1 (en) | 2007-02-28 |
| JP2007532745A (en) | 2007-11-15 |
| AR050242A1 (en) | 2006-10-11 |
| CA2562102A1 (en) | 2005-11-03 |
| FR2868787A1 (en) | 2005-10-14 |
| TWI314952B (en) | 2009-09-21 |
| TW200606246A (en) | 2006-02-16 |
| UA84741C2 (en) | 2008-11-25 |
| MXPA06011863A (en) | 2007-04-16 |
| FR2868787B1 (en) | 2006-06-23 |
| AU2005235761A1 (en) | 2005-11-03 |
| EA200601679A1 (en) | 2007-04-27 |
| AU2005235761B2 (en) | 2009-12-17 |
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