CN1960605A - Reinforced bonding method and bonding method between shielding layer of print circuit board and supporting material - Google Patents

Reinforced bonding method and bonding method between shielding layer of print circuit board and supporting material Download PDF

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Publication number
CN1960605A
CN1960605A CN 200510022017 CN200510022017A CN1960605A CN 1960605 A CN1960605 A CN 1960605A CN 200510022017 CN200510022017 CN 200510022017 CN 200510022017 A CN200510022017 A CN 200510022017A CN 1960605 A CN1960605 A CN 1960605A
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China
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silver foil
supporting material
plasma etching
bonding method
screen
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CN 200510022017
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Chinese (zh)
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CN100505988C (en
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刘新才
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Shenzhen Holitech Optoelectronics Co Ltd
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BYD Co Ltd
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Abstract

The method comprises: before the strength enhancing materials joints with the silver foil shielding layer, a plasma etching process is used to make surface treatment for the silver foil in order to increase its surface roughness, and by rough surface, the binding force between silver foil and strength enhancing materials will be increased, the peal strength between the silver foil and strength enhancing materials will be also increased.

Description

Shielding layer of print circuit board strengthens method and the associated methods that combines with supporting material
[technical field]
The present invention relates to strengthen in associated methods, the especially flexible print circuit board between the silver foil shielding material and supporting material in the wiring board a kind of method of the peel strength that combines between silver foil shielding material and the supporting material.
[background technology]
As everyone knows, various electronic equipments are being realized miniaturization and light-weighted while, to multifunction and high speed development.When work, can produce and launch the electromagnetic wave of different frequency and form cross interference.Therefore the effective measures of anti-electromagnetic wave interference are to shield to electronic equipment.This not only can prevent and control the interference of outside incident electromagnetic wave to the electronic equipment of working, and can also stop these equipment launching electromagnetic wave when work to remove to disturb the various electronic equipments of other running status effectively.In this case, the flexible print circuit board (FPC) that is used for electronic equipment assembling also requires to take the electromagnetic wave shielding measure more and more.
At present, the method for the electromagnetic wave shielding of FPC has:
The Copper Foil mode realizes electromagnetic shielding method to the FPC product by hot pressing Copper Foil on product, and this method has shield effectiveness and bending performance preferably preferably, but thickness is big, need be through repeatedly hot pressing, and the cycle is long, the cost height.
Silver slurry mode evenly apply one deck conduction seal coat by modes such as printings on the surface of product, such as the silver slurry is realized the electromagnetic wave shielding to the FPC product.It is low that this method has a cost, the advantage that bending performance is good, but shield effectiveness is relatively poor, easily comes off, and needs technologies such as printing and curing, and the cycle is long.
The silver foil mode; a kind of novel shielding material-silver foil of Japan TATSUTA company exploitation; its structure as shown in Figure 1; form by protective film 1, insulating barrier 2, metal foil layer 3, anisotropy conductiving glue layer 4, release film 5; have excellent shield effectiveness and bending performance; the number of times of pressing simultaneously is few, the cycle short, and the production efficiency height extensively adopts in flexible print circuit board in recent years.
Along with the miniaturization of electronic product, various electronic devices and components also all develop towards miniaturization, miniaturization direction.The flexible print circuit board that carries various electronic devices and components is no exception certainly, towards miniaturization, densification, the development of multifunction aspect.Need to carry various electronic devices and components such as IC, resistance, electric capacity in the flexible print circuit board.For the ease of the assembling of components and parts, need have certain intensity and rigidity for the insertion portion of flexible circuit board, this just requires at these part lamination reinforcement materials of flexible circuit board.Supporting material commonly used has: glass cloth or glass fibre are the epoxy laminate of reinforcing material, as say FR4, heat stable resin moulding product such as PI stiffening plate, aluminium sheet, corrosion resistant plate, perhaps use mould these materials to be struck out the composite reinforcing material of three-dimensional shape.
Be the laminating type that example is introduced supporting material below with the silver foil:
As shown in Figure 2, earlier heat curing-type semi-curing glue 7 is affixed on any one side of stiffening plate 6, lamination sticks on the stiffening plate it at a certain temperature, can take release film 8 off is standard, be processed into then and require the size supporting material, during use release film is taken off, supporting material is affixed on product or the silver foil assigned address carries out hot pressing.But in the pressing process, remove the blue protective film 1 on silver foil surface after, also have the extremely thin transparent diaphragm of one deck very smooth above the silver foil, make it not realize combining closely with supporting material, peel strength does not reach design, instructions for use.
[summary of the invention]
Purpose of the present invention overcomes the deficiencies in the prior art exactly, provides a kind of simple and feasible, obvious results shielding layer of print circuit board to strengthen method and the associated methods that combines with supporting material.
For achieving the above object, the present invention proposes to strengthen between the screen and supporting material in a kind of printed substrate the method that combines, it is characterized in that: before supporting material and the applying of silver foil screen, adopt plasma etching process that silver foil is carried out surface treatment, its surface roughness, surface active groups are increased, combining when strengthening silver foil with the supporting material pressing.
Described plasma etching process condition is as follows: O 2: more than the 300CC/min; CF 4: more than the 300CC/min; Time: more than 3 minutes; Radio-frequency power: 1500~2500W.
Simultaneously, the present invention proposes the associated methods between the screen and supporting material in a kind of printed substrate, comprise the steps: A) remove the silver foil release film, with silver foil screen and printed substrate hot binding; B) remove the silver foil diaphragm, plasma etching is carried out on the silver foil surface; C) with supporting material and etched the hot binding of silver foil of processing through plasma etching.
Described supporting material is formed through false applying of lamination by prepreg and stiffening plate.
Described plasma etching process condition is as follows: O 2: more than the 300CC/min; CF 4: more than the 300CC/min; Time: more than 3 minutes; Radio-frequency power: 1500~2500W.
Owing to adopted above scheme, gas molecule such as CF 4And O 2, destroying down in " ionization " effect that is being subjected to powerful electric power, generation utmost point polyion free radical (Free Radicals) with accessory substance, is added the mixture that numerous particle such as original uncracked molecule is formed.When in the plasma etching cavity, being full of the grain (Species) of various strong activity, its various ions or free radical or accessory substance etc., when not destroying its material property, structure, sheet material is produced bombardment (Bombardment) effect, and also can produce the variation of chemistry and physics aspect respectively to various nonmetallic materials.Through the silver foil of plasma etch process, surface roughness increases on the one hand, and surface active groups increases on the other hand, thus with the pressing process of supporting material in, the peel strength between silver foil and the supporting material increases substantially, and reaches designing requirement fully.
This method technology of the present invention is simple and easy to realize, easy to operate, suitable volume production.
[description of drawings]
The structural representation of Fig. 1, silver foil,
The supporting material structure chart that Fig. 2, heat curing-type prepreg combine with stiffening plate,
Fig. 3, product structure schematic diagram,
Test structure figure is peeled off in Fig. 4, reinforcement,
Wherein 1, blue protective film, 2, insulating barrier, 3, metal silver foil layer 4, anisotropy conductiving glue layer, 5, release film, 6, stiffening plate, 7, semi-curing glue, 8, release film, 9, FPC, 10, silver foil.
[embodiment]
The following example is to further explanation of the present invention and explanation.
Embodiment one: please in conjunction with Fig. 1, Fig. 2, shown in Figure 3, a FPC product surface applying silver foil (adopting the Japanese TATSUTA SF-PC1000 of company) shields, the silver foil surface release film 5 that processes profile is torn, itself and product 9 are combined closely at 160 ℃ of temperature, pressure 250PSI vacuum hotpressing 100min.Tear the blue diaphragm 1 on silver foil surface after the hot pressing, carry out plasma etching silver foil surface (coming down to the insulating barrier 2 of silver foil is carried out alligatoring) carried out alligatoring, the following (O of plasma process condition 2: 325CC/min; CF 4: 325CC/min; Time: 5 minutes; Radio-frequency power: 2000W), the release film of prepreg 7 (adopting platform rainbow BS-25) one side is torn, fit on the stiffening plate and carrying out becoming supporting material after lamination is fitted stiffening plate 6 (surging FR-4 is built in employing) and prepreg 7 vacations under 120 ℃ with small-sized laminating machine, be processed into the size that needs, prepreg another side release film 8 is torn, and supporting material is affixed on the place's hot pressing of product silver foil reinforcement applying mark line.As shown in Figure 4, the good product of pressing is gone up supporting material that test is combined into by stiffening plate 6 and prepreg 7 and the peel strength between the silver foil 10 at 180 degree peel strength testers (adopting the World Trusu Technology FL-X90 of company).Test result is listed table 1 in.
Embodiment two: please in conjunction with Fig. 1, Fig. 2, shown in Figure 3, a FPC product surface applying silver foil (adopting the Japanese TATSUTA SF-PC1000 of company) shields, the silver foil surface release film 5 that processes profile is torn, itself and product are combined closely at 160 ℃ of temperature, pressure 250PSI vacuum hotpressing 100min.Tear the blue diaphragm 1 on silver foil surface after the hot pressing, carry out plasma etching alligatoring is carried out on the silver foil surface, the following (O of plasma process condition 2: 375CC/min; CF 4: 375CC/min; Time: 3 minutes; Radio-frequency power: 2000W), prepreg 7 (adopt the FR1500 of Du Pont) directly fitted on the stiffening plate 6 with the fast press of vacuum becomes supporting material after pressing 30S under the condition of 80 degree 10kgf makes stiffening plate 6 (surging FR-4 is built in employing) and prepreg 7 false applyings, be processed into the size that needs, the centrifugal film 8 of prepreg another side is torn, and reinforcement is affixed on the place's hot pressing of product silver foil reinforcement applying mark line.As shown in Figure 4, the good product of pressing is gone up supporting material that test is combined into by stiffening plate 6 and prepreg 7 and the peel strength between the silver foil 10 at 180 degree peel strength testers (the World Trusu Technology FL-X90 of company).Test result is listed table 1 in.
Embodiment three: with the difference of embodiment one be: the radio-frequency power of the plasma etching process that this is routine is 1500W, and be 8 minutes process time, and test result is as shown in table 1.
Embodiment four: with the difference of embodiment one be: the radio-frequency power of the plasma etching process that this is routine is 1800W, and be 5 minutes process time, and test result is as shown in table 1.
Comparative example: a FPC product surface applying silver foil (the Japanese TATSUTA SF-PC1000 of company) shields, and the silver foil surface release film that processes profile is torn, and at 160 ℃ of temperature, pressure 250PSI vacuum hotpressing 100min itself and product is combined closely.Tear the blue diaphragm on silver foil surface after the hot pressing; the centrifugal paper of prepreg (adopting platform rainbow BS-25) one side is torn; fit on the stiffening plate and carrying out becoming supporting material after lamination makes the false applying of stiffening plate (surging FR-4 is built in employing) and prepreg under 120 ℃ the temperature with small-sized laminating machine; be processed into the size that needs; the centrifugal film of prepreg another side is torn, and reinforcement is affixed on the place's hot pressing of product silver foil reinforcement applying mark line.The product that pressing is good is gone up the peel strength of testing between reinforcement and the silver foil at 180 degree peel strength testers (the World Trusu Technology FL-X90 of company).Test result is listed table 1 in.Test result as table 1 shows that surface treated product reinforcing peel strength increases substantially, and reaches designing requirement fully.
Table 1, stiffening plate and silver foil peel strength test result
Scheme Peel strength test result (N/CM)
Embodiment 1 9.8 11.2 12.4 20.1 13.8
Embodiment 2 10.9 12.1 16.7 12.3 17.8
Embodiment 3 9.4 8.9 10.0 12.2 12.6
Embodiment 4 7.8 9.6 8.7 11.0 9.8
Comparative example 1.8 1.5 1.4 1.8 2.9

Claims (5)

1, strengthens the method that combines in a kind of printed substrate between screen and the supporting material, it is characterized in that: before supporting material and the applying of silver foil screen, adopt plasma etching process that silver foil is carried out surface treatment, its surface roughness, surface active groups are increased, combining when strengthening silver foil with the supporting material pressing.
2, the method for claim 1 is characterized in that: described plasma etching process condition is as follows: O 2: more than the 300CC/min; CF 4: more than the 300CC/min; Time: more than 3 minutes; Radio-frequency power: 1500~2500W.
3, the associated methods between screen and the supporting material in a kind of printed substrate comprises the steps: A) remove the silver foil release film, with silver foil screen and printed substrate hot binding; B) remove the silver foil diaphragm, plasma etching is carried out on the silver foil surface; C) with supporting material and etched the hot binding of silver foil of processing through plasma etching.
4, method as claimed in claim 3 is characterized in that: described supporting material is formed through false applying of lamination by prepreg and stiffening plate.
5, as claim 3 or 4 described methods, it is characterized in that: described plasma etching process condition is as follows: O 2: more than the 300CC/min; CF 4: more than the 300CC/min; Time: more than 3 minutes; Radio-frequency power: 1500~2500W.
CNB2005100220178A 2005-11-01 2005-11-01 Bonding method between shielding layer of print circuit board and supporting material Active CN100505988C (en)

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CN1960605A true CN1960605A (en) 2007-05-09
CN100505988C CN100505988C (en) 2009-06-24

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101437358B (en) * 2007-11-14 2010-04-14 昆山雅森电子材料科技有限公司 Protection film for printed circuit board and procedure for processing circuit board using the protection film
CN101868118A (en) * 2010-05-28 2010-10-20 珠海国能电力科技发展有限公司 High-frequency circuit substrate and production method thereof
CN101472398B (en) * 2007-12-28 2011-07-06 比亚迪股份有限公司 Multilayer flexible printed circuit board and method of manufacturing the same
CN101772271B (en) * 2010-02-02 2012-05-23 浙江龙威电子科技有限公司 Method for single-sided lamination reinforcement of flexible printed circuit board
CN104582248A (en) * 2014-12-23 2015-04-29 广东生益科技股份有限公司 FR4 reinforcement plate production method and FPC (flexible printed circuit) reinforcement method
WO2015169234A1 (en) * 2014-05-09 2015-11-12 武汉芯宝科技有限公司 Circuit board cross-band veneer with function of absorbing instantaneous high-voltage electric pulse energy and manufacturing method therefor
CN106030770A (en) * 2014-02-27 2016-10-12 株式会社电装 Resin molded article, and manufacturing method for same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6629348B2 (en) * 2001-05-01 2003-10-07 Oak-Mitsui, Inc. Substrate adhesion enhancement to film

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101437358B (en) * 2007-11-14 2010-04-14 昆山雅森电子材料科技有限公司 Protection film for printed circuit board and procedure for processing circuit board using the protection film
CN101472398B (en) * 2007-12-28 2011-07-06 比亚迪股份有限公司 Multilayer flexible printed circuit board and method of manufacturing the same
CN101772271B (en) * 2010-02-02 2012-05-23 浙江龙威电子科技有限公司 Method for single-sided lamination reinforcement of flexible printed circuit board
CN101868118A (en) * 2010-05-28 2010-10-20 珠海国能电力科技发展有限公司 High-frequency circuit substrate and production method thereof
CN101868118B (en) * 2010-05-28 2012-02-01 珠海国能电力科技发展有限公司 High-frequency circuit substrate and production method thereof
CN106030770A (en) * 2014-02-27 2016-10-12 株式会社电装 Resin molded article, and manufacturing method for same
CN106030770B (en) * 2014-02-27 2019-06-18 株式会社电装 Resin-formed body and its manufacturing method
US10395947B2 (en) 2014-02-27 2019-08-27 Denso Corporation Manufacturing method of a resin molded article
WO2015169234A1 (en) * 2014-05-09 2015-11-12 武汉芯宝科技有限公司 Circuit board cross-band veneer with function of absorbing instantaneous high-voltage electric pulse energy and manufacturing method therefor
CN104582248A (en) * 2014-12-23 2015-04-29 广东生益科技股份有限公司 FR4 reinforcement plate production method and FPC (flexible printed circuit) reinforcement method
CN104582248B (en) * 2014-12-23 2017-11-03 广东生益科技股份有限公司 A kind of production method of FR4 stiffening plates and FPC reinforcement

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EE01 Entry into force of recordation of patent licensing contract

Assignee: Shenzhen BYD Electronic Component Co., Ltd.

Assignor: Biyadi Co., Ltd.

Contract fulfillment period: 2008.4.25 to 2015.11.14

Contract record no.: 2008440000067

Denomination of invention: Reinforced bonding method and bonding method between shielding layer of print circuit board and supporting material

License type: Exclusive license

Record date: 20080504

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.4.25 TO 2015.11.14

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Address after: 518119 Guangdong province Shenzhen City Dapeng new Kwai town Yanan Road No. 1 building experimental Byd Co

Patentee after: Shenzhen BYD Electronic Component Co., Ltd.

Address before: Kwai Chung town Yanan Road, BYD Industrial Park in Longgang District of Shenzhen City, Guangdong province 518119

Patentee before: Biyadi Co., Ltd.

CP01 Change in the name or title of a patent holder

Address after: 518119 Guangdong province Shenzhen City Dapeng new Kwai town Yanan Road No. 1 building experimental Byd Co

Patentee after: Shenzhen helitai photoelectric Co., Ltd

Address before: 518119 Guangdong province Shenzhen City Dapeng new Kwai town Yanan Road No. 1 building experimental Byd Co

Patentee before: SHENZHEN BYD ELECTRONIC COMPONENT Co.,Ltd.

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