CN1948607A - High polymer coated multi functional coating fabric and its production method - Google Patents

High polymer coated multi functional coating fabric and its production method Download PDF

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Publication number
CN1948607A
CN1948607A CN200610154437.6A CN200610154437A CN1948607A CN 1948607 A CN1948607 A CN 1948607A CN 200610154437 A CN200610154437 A CN 200610154437A CN 1948607 A CN1948607 A CN 1948607A
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parts
portions
coating
toluene
dimethyl formamide
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CN100560854C (en
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吴新初
楚伟峰
王悦群
左金华
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ZHEJIANG JINDA NEW MATERIAL CO Ltd
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ZHEJIANG JINDA NEW MATERIAL CO Ltd
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Abstract

The invention relates to a production method of multifunctional high polymer covering woven. The weight proportion of coated cover is 100 portions chemical decomposition granules, 10-30 portions toluene, 5-30 portions dimethyl formamide, 0.05-0.5 portions Hydroxypolyether modified poly-dimethyl-siloxane 1-10 portions toner and 0.01-0.5 portions function assistant. The weight proportion of chemical decomposition granules is 100 portions thermoplastic polyurethane granules, 10-60 portions solvent dimethyl formamide, 20-50 portions liquefier toluene. The weight proportion of coated adhesion layer is 100 portions dineric polyurethane resin ,100 portions toluene, 5-30 portions solvent dimethyl formamide DMF, 5-30 portions butanone, 1-10 portions toner, 0.01-0.5 portions function assistant. The method is characterized in that the products has versatility including waterproof, rainproof, aeration, moisture, diaphoresis, dry, electrostatic prevention, flame retarded and uvioresistant etc. Especially, watertighting can reach over 5000mmH2O, and moisture can reach over 5000g/m2.24h.

Description

A kind of multi-functional coatings fabric and production method of polymer coating
Technical field
The invention belongs to the fabric coating field, especially a kind of multi-functional coatings fabric and production method of polymer coating.
Background technology
Fabric coating is the new industry that China develops rapidly in recent ten years.Coated fabric then is to be base cloth with all kinds of textiless, the special material with function of shielding that forms coated with immersion coating materials processing.Development is very fast on this series products both at home and abroad, because its special function of shielding makes it be widely used in civilian (life is used), industrial or agricultural (especially transportation building), health care and military various aspects.
The top finish of fabric is an important branch of after-finishing of textile products technology, and the main application of coating product can be divided into three major types: clothes, shoes and hats class, industrial dry goods, decorating cloth class, wherein clothes, shoes and hats class consumption maximum.
Coating is given the function of fabric and is not only shielding, also has other, promptly when a certain function of shielding is provided, also will take into account other one or more functions.With the closely-related raincoat of the people's livelihood or other protective clothings, in shielding rainwater or other invaders, must take into account and wet in the market, make the wearer feel comfortable.Yet owing to technical elements or otherwise reason, when requiring water pressure resistance very high and when being strictly on guard against invader, this take into account just very difficult.The related coatings product mainly makes with direct coating macromolecular material or MULTILAYER COMPOSITE forms, and protection efficiency and water vapour permeability can not be taken into account; In addition, feel hard partially, wear the time slightly length will feel sultry.Thereby " Waterproof Breathable " fabric, " ventilative " fabric be still very important part in the coated fabric at present, and it also is the direction and goal of our enterprise technology development, Product Renewal.For remedying many deficiencies that this series products in use exists and better adapting to market demand, through sufficient market watch and investigation, I take charge of conscientious research and analysis, decision is with the existing advanced coating apparatus of company, in conjunction with advanced factory formula and technology, carry out a kind of exploitation and production application of high polymer multi-functional coatings fabric.
Summary of the invention
The objective of the invention is to overcome the deficiency of said structure, and a kind of multi-functional coatings fabric and production method of polymer coating are provided.
The technical solution adopted for the present invention to solve the technical problems.The multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10~30 parts, dimethyl formamide (DMF): 5~30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05~0.5 part, toner: 1~10 part and function additive: 0.01~0.5 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10~60 parts, diluent toluene: 20~50 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10~50 parts, solvent dimethyl formamide DMF:5~30 parts, butanone (MEK): 5~30 parts, toner: 1~10 part, function additive: 0.01~0.5 part.
The multi-functional coatings manufacturing method of fabrics of this polymer coating mainly comprises the steps:
1), pellet dissolves: dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10~60 parts, diluent toluene: 20~50 parts, viscosity control: 8000~50000cps;
2), slurry preparation: its coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10~30 parts, dimethyl formamide (DMF): 5~30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05~0.5 part, toner: 1~10 part and function additive: 0.01~0.5 part, viscosity control: 2000~5000cps; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10~50 parts, solvent dimethyl formamide DMF:5~30 parts, butanone (MEK): 5~30 parts, toner: 1~10 part, function additive: 0.01~0.5 part; Viscosity control: 5000~10000cps;
3), the used base cloth of product is Woven Fabrics, woven cloth or knitted cloth, thickness is 0.2~0.6mm; Release liners at first goes up coating machine through the check back, carries out the surface layer coating then, coating weight 50~250g/m 2, weight in wet base, cutter then enters oven drying, 90~150 ℃ of temperature, time 2~5min apart from 0.05~0.2mm;
4), the surface layer after the oven dry is proceeded adhesion layer coating, coating weight 50~250g/m 2, weight in wet base, cutter carries out base cloth then and fits 30~80 ℃ of binding temperatures, pressure 0.1~2kgf/cm apart from 0.05~0.2mm 2Product after posting enters the baking oven preliminarily dried, 90~120 ℃ of temperature, time 0.5~3min and cure crosslinking curing, 130~160 ℃ of temperature, time 2~5min; Cool off at last to peel off and obtain the finished product coated fabric.
1), this product is to be base cloth with the Woven Fabrics effect that the present invention is useful is:, soft, snugness of fit is good, has overcome old product Boardy Feeling, the narrow defective of the scope of application.2), adopt good high-performance coating agent and special addition agent, through optimizing preparation, played the remarkable environmental effect, azo class material, content of beary metal meet European EN14362-2003 environmental protection standard.3), the best adjustment of adopting the transfer heat posted technology of novelty and carrying out technological parameter produces this product, changed old technology and directly be coated with the various drawbacks (even as became uneven, appearance style is poor, and functional parameter is low etc.) of scraping band rice.4), outstanding behaviours is multifunctionality and good surface appearance style because the innovation of above aspect improves, product can reach waterproof, rainproof, ventilative, wet thoroughly, multifunctionalities such as perspire, dry and comfortable, antistatic, fire-retardant and uvioresistant; Especially water pressure resistance can reach 5000mmH 2More than the O, vapor transfer rate can reach 5000g/m 2.24h more than.5), the multifunctionality of product has been widened its Application Areas, develop into feather dress fabric, sportswear lining, hunting dress lining, medical protective clothing and woollen sweater etc. from raincoat, clothes lining, this product has been filled up domestic blank, has good economic and social benefit.
Description of drawings
Fig. 1 is a process flow diagram of the present invention;
The specific embodiment:
Below in conjunction with drawings and Examples the present invention is further described.
Embodiment 1: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10 parts, dimethyl formamide (DMF): 5 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05 part, toner: 1 part and function additive: 0.01 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10 parts, diluent toluene: 20 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10 parts, solvent dimethyl formamide DMF:5 part, butanone (MEK): 5 parts, toner: 1 part, function additive: 0.02 part.
Described function additive is antiseptic or antistatic additive or ultra-violet absorber, and described antiseptic adopts a kind of in the inorganic antiseptic: nano-TiO 2The titanium series antibacterial agent, salt of phosphoric acid class, zeolites, activated carbon fiber class or smectites silver-series antibacterial agent, perhaps shitosan, chitin or Hinokitiol natural antibacterial agent.Described antistatic additive adopts alkylsulfonate, acid amides, amine, ester, quaternary amine or fatty acid soaps.Described ultra-violet absorber adopts zinc oxide, titanium dioxide, phenyl salicytate, dihydroxy benaophenonel or benzotriazole.
The multi-functional coatings manufacturing method of fabrics of this polymer coating mainly comprises the steps:
1), pellet dissolves: dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10 parts, diluent toluene: 20 parts, viscosity control: 8000~50000cps;
2), slurry preparation: its coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10 parts, dimethyl formamide (DMF): 5 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05 part, toner: 1 part and function additive: 0.02 part, viscosity control: 2000~5000cps; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10 parts, solvent dimethyl formamide DMF:5 part, butanone (MEK): 5 parts, toner: 1 part, function additive: 0.02 part; Viscosity control: 5000~10000cps;
3), the used base cloth of product is Woven Fabrics, woven cloth or knitted cloth, thickness is 0.2~0.6mm; Release liners at first goes up coating machine through the check back, carries out the surface layer coating then, coating weight 50~250g/m 2, weight in wet base, cutter then enters oven drying, 90~150 ℃ of temperature, time 2~5min apart from 0.05~0.2mm;
4), the surface layer after the oven dry is proceeded adhesion layer coating, coating weight 50~250g/m 2, weight in wet base, cutter carries out base cloth then and fits 30~80 ℃ of binding temperatures, pressure 0.1~2kgf/cm apart from 0.05~0.2mm 2Product after posting enters the baking oven preliminarily dried, 90~120 ℃ of temperature, time 0.5~3min and cure crosslinking curing, 130~160 ℃ of temperature, time 2~5min; Cool off at last to peel off and obtain the finished product coated fabric.
Technical indicator:
1) hydraulic pressure 5000~10000mmH 2O (ISO811-1981)
2) wet thoroughly 5000~6000g/m 2.24h (ASTM E96-2000BW)
3) dry-cleaning 4~5 grades of COLOR FASTNESS (ISO105D01-1993)
4) LIGHT COLOR FASTNESS is more than 4 grades (ISO105D02-1994)
5) TENSILE STRENGTH: through 600N, latitude 680N (ISO13934-1-1999)
6) azo, content of beary metal are by the test of EN14362-2003 European standard
Embodiment 2: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 30 parts, dimethyl formamide (DMF): 30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.5 part, toner: 10 parts and function additive: 0.5 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 60 parts, diluent toluene: 50 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 50 parts, solvent dimethyl formamide DMF:30 part, butanone (MEK): 30 parts, toner: 10 parts, function additive: 0.5 part.Function additive is an antiseptic, and described antiseptic adopts a kind of in the inorganic antiseptic: nano-TiO 2The titanium series antibacterial agent, salt of phosphoric acid class, zeolites, activated carbon fiber class or smectites silver-series antibacterial agent, perhaps shitosan, chitin or Hinokitiol natural antibacterial agent.
Embodiment 3: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 20 parts, dimethyl formamide (DMF): 20 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.2 part, toner: 5 parts and function additive: 0.2 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 30 parts, diluent toluene: 35 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 30 parts, solvent dimethyl formamide DMF:15 part, butanone (MEK): 15 parts, toner: 5 parts, function additive: 0.2 part.Described function additive is an antistatic additive, adopts alkylsulfonate, acid amides, amine, ester, quaternary amine or fatty acid soaps.
Embodiment 4: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 15 parts, dimethyl formamide (DMF): 10 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.1 part, toner: 3 parts and function additive: 0.2 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 20 parts, diluent toluene: 30 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 20 parts, solvent dimethyl formamide DMF:10 part, butanone (MEK): 10 parts, toner: 3 parts, function additive: 0.1 part.Described function additive is a ultra-violet absorber, adopts zinc oxide, titanium dioxide, phenyl salicytate, dihydroxy benaophenonel or benzotriazole.
Embodiment 5: the multi-functional coatings fabric of this polymer coating, its the coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 25 parts, dimethyl formamide (DMF): 20 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.3 part, toner: 7 parts and function additive: 0.3 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 40 parts, diluent toluene: 40 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 30 parts, solvent dimethyl formamide DMF:20 part, butanone (MEK): 20 parts, toner: 7 parts, function additive: 0.4 part.

Claims (6)

1, a kind of multi-functional coatings fabric of polymer coating, it is characterized in that: its coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10~30 parts, dimethyl formamide (DMF): 5~30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05~0.5 part, toner: 1~10 part and function additive: 0.01~0.5 part, wherein dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10~60 parts, diluent toluene: 20~50 parts; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10~50 parts, solvent dimethyl formamide DMF:5~30 parts, butanone (MEK): 5~30 parts, toner: 1~10 part, function additive: 0.01~0.5 part.
2, the multi-functional coatings fabric of polymer coating according to claim 1 is characterized in that: described function additive is antiseptic or antistatic additive or ultra-violet absorber.
3, the multi-functional coatings fabric of polymer coating according to claim 2 is characterized in that: described antiseptic adopts a kind of in the inorganic antiseptic: nano-TiO 2The titanium series antibacterial agent, salt of phosphoric acid class, zeolites, activated carbon fiber class or smectites silver-series antibacterial agent, perhaps shitosan, chitin or Hinokitiol natural antibacterial agent.
4, the multi-functional coatings fabric of polymer coating according to claim 2 is characterized in that: described antistatic additive adopts alkylsulfonate, acid amides, amine, ester, quaternary amine or fatty acid soaps.
5, the multi-functional coatings fabric of polymer coating according to claim 2 is characterized in that: described ultra-violet absorber adopts zinc oxide, titanium dioxide, phenyl salicytate, dihydroxy benaophenonel or benzotriazole.
6, a kind of multi-functional coatings manufacturing method of fabrics of polymer coating is characterized in that: mainly comprise the steps:
6.1), pellet dissolves: dissolve pellet by the following weight proportioning raw material make the thermoplastic polyurethane pellet: 100 parts, solvent dimethyl formamide (DMF): 10~60 parts, diluent toluene: 20~50 parts, viscosity control: 8000~50000cps;
6.2), slurry preparation: its coating surface layer be by the following weight proportioning raw material make, dissolve pellet: 100 parts, toluene: 10~30 parts, dimethyl formamide (DMF): 5~30 parts, hydroxy polyethers modified dimethyl polysiloxane: 0.05~0.5 part, toner: 1~10 part and function additive: 0.01~0.5 part, viscosity control: 2000~5000cps; Its coating adhesion layer be by the following weight proportioning raw material make the two liquid type polyurethane resin: 100 parts, toluene: 10~50 parts, solvent dimethyl formamide DMF:5~30 parts, butanone (MEK): 5~30 parts, toner: 1~10 part, function additive: 0.01~0.5 part; Viscosity control: 5000~10000cps;
6.3), the used base cloth of product is Woven Fabrics, woven cloth or knitted cloth, thickness is 0.2~0.6mm; Release liners at first goes up coating machine through the check back, carries out the surface layer coating then, coating weight 50~250g/m 2, weight in wet base, cutter then enters oven drying, 90~150 ℃ of temperature, time 2~5min apart from 0.05~0.2mm;
6.4), the surface layer after the oven dry proceeds adhesion layer coating, coating weight 50~250g/m 2, weight in wet base, cutter carries out base cloth then and fits 30~80 ℃ of binding temperatures, pressure 0.1~2kgf/cm apart from 0.05~0.2mm 2Product after posting enters the baking oven preliminarily dried, 90~120 ℃ of temperature, time 0.5~3min and cure crosslinking curing, 130~160 ℃ of temperature, time 2~5min; Cool off at last to peel off and obtain the finished product coated fabric.
CNB2006101544376A 2006-10-27 2006-10-27 A kind of multi-functional coatings fabric and production method of polymer coating Expired - Fee Related CN100560854C (en)

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* Cited by examiner, † Cited by third party
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CN101481580B (en) * 2008-12-23 2011-07-13 中国人民解放军总后勤部军需装备研究所 Waterproof, low temperature resistant, soft and moisture permeable coating glue and preparation thereof
CN101311398B (en) * 2007-05-25 2011-09-14 东丽纤维研究所(中国)有限公司 Nanometer durable ultraviolet ray resistant textiles
CN101748607B (en) * 2009-12-18 2011-12-14 安徽安利合成革股份有限公司 Method for producing easy-to-clean high-wearing durable synthetic leather for sofa furniture
CN101294353B (en) * 2007-04-23 2012-05-02 东丽纤维研究所(中国)有限公司 Durable electrostatic resistant textile
CN101586312B (en) * 2009-06-12 2012-05-09 石狮龙祥制革有限公司 Production method of no-yellowing composite leather
CN102102301B (en) * 2009-12-18 2012-09-19 上海华峰超纤材料股份有限公司 Superfine fiber leather and preparation method thereof
CN103388264A (en) * 2012-05-08 2013-11-13 浙江泰普森休闲用品有限公司 Caravan tent fabric and production method thereof
CN103790026A (en) * 2014-01-24 2014-05-14 南通惠通纺织器材有限公司 Neatening method of ultraviolet-proof antistatic fabric
CN103790015A (en) * 2014-01-20 2014-05-14 南通全技纺织涂层有限公司 Anti-static coating fabric
CN103866580A (en) * 2014-03-04 2014-06-18 合肥市安山涂层织物有限公司 Preparation method of anti-static artificial synthetic leather
CN104585906A (en) * 2013-10-30 2015-05-06 株式会社布来亚克 Air tank type down jarket with raised volume feeling and manufacturing method thereof
CN105128466A (en) * 2015-09-01 2015-12-09 海宁杰盛新材料有限公司 Anti-static environment-friendly coating fabric and preparing method thereof
CN105603785A (en) * 2016-01-29 2016-05-25 佛山市聚成生化技术研发有限公司 Preparation method of pre-treatment addition agent of textile printing and dyeing, and pre-treatment addition agent of textile printing and dyeing, prepared by preparation method
CN106364107A (en) * 2016-08-19 2017-02-01 海宁兄弟家具有限公司 Moisture-resistant and flame-retardant fabric
CN107059159A (en) * 2017-05-19 2017-08-18 江苏华昌织物有限公司 A kind of preparation method of anti-aging shading screen cloth
CN107164968A (en) * 2017-05-25 2017-09-15 海盐派特普科技有限公司 A kind of efficient Anti-ultraviolet Garment Fabric and preparation method thereof
CN107700211A (en) * 2017-09-21 2018-02-16 晋江市明仨纺织品科技有限公司 A kind of preparation method of anti-bacterial fibre
CN111482341A (en) * 2020-05-13 2020-08-04 清华大学 Ice-phobic coating and preparation method and application thereof
CN115162019A (en) * 2022-08-03 2022-10-11 常州雅美特窗饰股份有限公司 Manufacturing method of high-sun-exposure curtain fabric

Cited By (23)

* Cited by examiner, † Cited by third party
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CN101294353B (en) * 2007-04-23 2012-05-02 东丽纤维研究所(中国)有限公司 Durable electrostatic resistant textile
CN101311398B (en) * 2007-05-25 2011-09-14 东丽纤维研究所(中国)有限公司 Nanometer durable ultraviolet ray resistant textiles
CN101481580B (en) * 2008-12-23 2011-07-13 中国人民解放军总后勤部军需装备研究所 Waterproof, low temperature resistant, soft and moisture permeable coating glue and preparation thereof
CN101586312B (en) * 2009-06-12 2012-05-09 石狮龙祥制革有限公司 Production method of no-yellowing composite leather
CN101748607B (en) * 2009-12-18 2011-12-14 安徽安利合成革股份有限公司 Method for producing easy-to-clean high-wearing durable synthetic leather for sofa furniture
CN102102301B (en) * 2009-12-18 2012-09-19 上海华峰超纤材料股份有限公司 Superfine fiber leather and preparation method thereof
CN103388264B (en) * 2012-05-08 2014-11-26 浙江泰普森休闲用品有限公司 Caravan tent fabric and production method thereof
CN103388264A (en) * 2012-05-08 2013-11-13 浙江泰普森休闲用品有限公司 Caravan tent fabric and production method thereof
CN104585906A (en) * 2013-10-30 2015-05-06 株式会社布来亚克 Air tank type down jarket with raised volume feeling and manufacturing method thereof
CN103790015A (en) * 2014-01-20 2014-05-14 南通全技纺织涂层有限公司 Anti-static coating fabric
CN103790026A (en) * 2014-01-24 2014-05-14 南通惠通纺织器材有限公司 Neatening method of ultraviolet-proof antistatic fabric
CN103866580A (en) * 2014-03-04 2014-06-18 合肥市安山涂层织物有限公司 Preparation method of anti-static artificial synthetic leather
CN103866580B (en) * 2014-03-04 2016-06-15 合肥市安山涂层织物有限公司 A kind of antistatic artificial synthetic leather manufacture method
CN105128466B (en) * 2015-09-01 2017-05-17 海宁杰盛新材料有限公司 Anti-static environment-friendly coating fabric and preparing method thereof
CN105128466A (en) * 2015-09-01 2015-12-09 海宁杰盛新材料有限公司 Anti-static environment-friendly coating fabric and preparing method thereof
CN105603785A (en) * 2016-01-29 2016-05-25 佛山市聚成生化技术研发有限公司 Preparation method of pre-treatment addition agent of textile printing and dyeing, and pre-treatment addition agent of textile printing and dyeing, prepared by preparation method
CN106364107A (en) * 2016-08-19 2017-02-01 海宁兄弟家具有限公司 Moisture-resistant and flame-retardant fabric
CN107059159A (en) * 2017-05-19 2017-08-18 江苏华昌织物有限公司 A kind of preparation method of anti-aging shading screen cloth
CN107164968A (en) * 2017-05-25 2017-09-15 海盐派特普科技有限公司 A kind of efficient Anti-ultraviolet Garment Fabric and preparation method thereof
CN107700211A (en) * 2017-09-21 2018-02-16 晋江市明仨纺织品科技有限公司 A kind of preparation method of anti-bacterial fibre
CN111482341A (en) * 2020-05-13 2020-08-04 清华大学 Ice-phobic coating and preparation method and application thereof
CN111482341B (en) * 2020-05-13 2021-09-03 清华大学 Ice-phobic coating and preparation method and application thereof
CN115162019A (en) * 2022-08-03 2022-10-11 常州雅美特窗饰股份有限公司 Manufacturing method of high-sun-exposure curtain fabric

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