CN1930055A - Method and apparatus for packaging glass substrates - Google Patents

Method and apparatus for packaging glass substrates Download PDF

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Publication number
CN1930055A
CN1930055A CNA2005800069843A CN200580006984A CN1930055A CN 1930055 A CN1930055 A CN 1930055A CN A2005800069843 A CNA2005800069843 A CN A2005800069843A CN 200580006984 A CN200580006984 A CN 200580006984A CN 1930055 A CN1930055 A CN 1930055A
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CN
China
Prior art keywords
substrate
packing
glass substrate
container
glass
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Pending
Application number
CNA2005800069843A
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Chinese (zh)
Inventor
F·T·科波拉
M·J·马申斯基
D·A·特玛罗
Y·石
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Corning Inc
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Corning Inc
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Publication of CN1930055A publication Critical patent/CN1930055A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/30Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure
    • B65D85/48Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure for glass sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Food Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Packaging Frangible Articles (AREA)
  • Packages (AREA)
  • Buffer Packaging (AREA)

Abstract

Packages ( 11 ) of glass substrates ( 13 ) are provided in which the surfaces of the substrates are coated with a water-removable protective coating and then sealed in an air-sealing container ( 19 ), e.g., a polymer bag or a polymer wrapping, having an internal volume which is vacuumed, filled with an inert atmosphere, or filled with humidity-controlled air prior to sealing. In this way, the substrates can be stored for at least 6 months in an ambient environment having a relative humidity of 90 percent at 50 DEG C. without substantial degradation of the protective coating.

Description

The method and apparatus of packaging glass substrates
Related application
The application requires the preceence of No. the 10/795th, 590, the U. S. application submitted on March 8th, 2004, and its content is incorporated by reference into herein.
Invention field
The present invention relates to glass substrate, for example be used to make the substrate of Liquid Crystal Display (LCD) (LCD), plasma display, electroluminescent display etc.More particularly, the present invention relates to be used for packaging glass substrates, make the minimized method and apparatus of damage in transportation and the storage process.
In order to illustrate, below the glass substrate that is used for LCD display is discussed, be to be understood that the present invention can be used for being used in the glass substrate in other purposes equally.
Background of invention
LCD makes the glass substrate that need have high-quality surface.In the process of finishing, storage and the transportation of LCD glass substrate, be easy on glass surface, introduce particle, cut and organic contaminant.These glass surface defectives can cause the LCD fault.Therefore, need be in the process of finishing, storage and transportation the cover glass surface.
Common guard method at present is to use pressure sensitive adhesive to apply polyethylene film on a face of LCD glass sheet, coating static polymer film on another side.Before using, need peel off protective film, clean glass surface then to remove adhesives and other loose adsorbed contaminants.The method cost that water cleans is low, environmental hazard is less, can remove organic effectively and inorganic pollutant, is preferred method of cleaning therefore.Representative type water ablution is to scrub with ultrasonic cleaning with alkaline detergent (for example 2% the SEMICLEANKG aqueous system) to combine.
Although membrane coat can provide gratifying protection, also be attended by many problems.At first, because the difference of coating process and/or the difference in storage and transportation conditions and/or the cleaning process may not removed adhesives fully.Secondly, membrane coat is to apply after the edge delineation beaded glass of the glass of new formation.Therefore, membrane coat can't provide protection in beaded glass delineation process.
The 3rd, for big glass sheet (for example 8 ' * 6 ') and/or thin glass sheet (for example≤0.4 millimeter),, may cause high breakage rate being combined in adhesives when membrane coat on the glass sheet peels off.In addition, the material of membrane coat method and the use of this method is very expensive.Therefore, membrane coat may not be to be used for protecting the best of LCD glass or general-duty to select.
The coating that water-based coating or available water are removed can replace membrane coat, is used for protecting LCD glass.The example of water-based coating can be referring to the common people's such as Foster that transfer the possession of US Patent the 6th, 233, No. 972, people's such as Birch US Patent the 6th, 379, No. 746, people's such as He U.S. Patent Application Publication US2003/0110800 number, and No. 2003/0186065, people's such as Hou U.S. Patent Application Publication US, the content of these patents all is incorporated by reference into herein.As described in these lists of references, the preferred positions that applies protective coat is the bottom of the drawing device of glass shaper (for example fusion draw machine), makes substantially after forming of glass applying coating at once, thus the probability minimum that glass surface is polluted.
The advantage of the coating of the material that available water is removed is, can before the beaded glass delineation, they be applied in by (for example) spraying or dip-coating on glass, so can be in the delineation process and in the process of finishing, storage and transportation the cover glass surface.The removal of the common specific viscosity mixture of the removal of water-based coating is easier, and this is because water-based coating can be removed by the water ablution of routine, does not need to peel off.In addition, described coating and technology are usually than membrane coat cheapness.
Unfortunately, the material removed of available water issues the natural disposition qualitative changeization in the existence of water and moisture easily.For example, under the high humidity (for example 50 ℃, relative humidity 〉=90%) that may occur in storage and transportation, the coating of being made by water material becomes sticky easily.In addition, if with the conventional papery partition between the glass sheet that the glass sheet of coating is packaging together, these paper may be bonded on the coating under high humidity, make to be difficult to paper is separated with glass.
Except these problems, for example the surface of Pen Tu glass sheet is always covered fully, and for example, coating may comprise needle pore defect.High humidity can make and form chemical bond between the glassy zone of glass chip and exposure, make chip can't remove from glass sheet basically.
Another problem of the coating that available water is removed is that germ can go up growth at some Biodegradable materials (for example starch) that is used for this coating.Microbial growth depends on water activity, and high humidity can promote its growth usually.
Therefore as can be seen, by various mechanism, high humidity can form the glass surface defective on the glass substrate of water-based coating coating.The present invention is devoted to address this problem.Specifically, the present invention be devoted to provide a kind of solve water-based coating in transportation and storage process owing to the method that is exposed to the problem that high humidity and/or moisture degrade.
The invention summary
According to first aspect; the invention provides the glass substrate of a kind of LCD of packing glass sheet and so on; be used under high humidity storing and the method for transportation; each substrate has the surface of two substantially flats; scribble the protective coat that available water is removed on these surfaces, described method comprises the step that next coming in order carry out:
(A) glass substrate with coating is stacked into one folded (block);
(B) this laminated glass substrate is packaged in the container (for example air tight polymer pouches or poly-mer big envelope (wrapping)), has the leak free internal environment in the described container, can prevent that the protective coat that available water is removed from degrading because of humid environment.
Initial stack of substrates is built up one folded in, can have the angle and the edge of exposure.In the preferred embodiment of the present invention; in step (B) before; the angle of the substrate that the protection of use vibration-absorptive material exposes and/or the edge of the substrate that at least a portion exposes (preferably, the edge that uses vibration-absorptive material while diagonal sum at least a portion to expose is protected).
According to second aspect, the invention provides the packing of glass substrate, it comprises:
(A) build up folded a large amount of glass substrates, described substrate has the surface of two substantially flats separately, is coated with the protective coat that available water is removed on these surfaces;
(B) surround the container (for example air-tightness polymer pouches or poly-mer big envelope) of a described laminated glass substrate, this container has formed the leak free internal environment, and the protective coat that the protection available water is removed makes it avoid degrading owing to making moist.
In first aspect, the packing of glass substrate preferably also comprises the angle that is applied to substrate and/or the vibration-absorptive material (preferably, vibration-absorptive material is applied on angle and at least a portion edge simultaneously) at least a portion edge.
Listed other features and advantages of the present invention in the detailed description hereinafter, by description of the invention or by according to enforcement the present invention described herein, a part of feature and advantage wherein are conspicuous for those skilled in the art or recognize easily.Provide accompanying drawing with the further the present invention of understanding, accompanying drawing constitutes its part in conjunction with in this manual.Should be appreciated that above summary and following detailed description all only are to be used for exemplarily illustrating of the present invention, be used to provide general survey or framework, be beneficial to understand character of the present invention and feature.
The accompanying drawing summary
Fig. 1 is the schematic cross-section that the present invention piles up the hermetically sealed packaging of glass.
Fig. 2 is the schematic cross-section of the amplification in Fig. 1 upper right corner.
The following object of numeral in the accompanying drawing:
The packing of 11 glass substrates
13 glass substrates
The vibration-absorptive material of 15 softnesses
17 partitions
19 containers (for example air-tight membrane)
The present invention describes in detail
As mentioned above, the invention provides and be used for limiting the method and apparatus that the glass sheet (glass substrate) with coating that available water removes is exposed to moisture (moisture of liquid water form or high humidity form).
In short, will have the substrate stack of the protective coat that available water removes, and be then packed in the gas-tight container of airtight poly-mer and so on, this container can form the internal environment that moisture is controlled.For example, the glass sheet that piles up can be sealed in the container of polymer pouches or big envelope and so on, air in the described container is removed (formation vacuum), and/or the packing can control humidity environment under (for example described environment be lower than 50 ℃, more preferably less than 30 ℃ temperature under, relative humidity preferably less than 40%, is more preferably less than 30% less than 50%, most preferably less than 20%) carry out, make the air that is sealed in this container have required predetermined moisture.Perhaps, can in container, introduce artificial environment, for example can before sealing, in container, introduce the unreactable gas of nitrogen or argon gas and so on.
Preferably air-tightness bag or the big envelope that is consistent substantially with the folded shape of glass substrate, this is owing to can make in transportation or the process that stores the chance minimum that particle contacts with glass sheet surface like this.If necessary, the substrate in airtight bag or the big envelope can be stacked and placed in the rigidity transfer cask (for example Wooden container), for glass sheet provides further mechanical protection.Perhaps do not use flexible sack or big envelope, described gas-tight container can be a rigidity.For example, the glass sheet that piles up directly can be placed in the air-tightness can (for example sealable aluminium vessel).Intensity and the folded size of glass sheet according to used metal or metal alloy; the leak free container can former state be used for transportation and storage; perhaps can be placed in the unencapsulated external container (for example Wooden container); this external container can provide enough structure integrities, to tolerate the application force that can be subjected to usually in transportation and storage process.
Because reach the low humidity condition in the container, no matter how glass sheet forms, store and the process of transportation in, the glass sheet that has applied the material that available water removes can be not adhered to one another or and glass sheet between partition bonding.Similarly, the bonding of glass particle on the glass surface that exposes minimized, and coating have higher antimicrobial properties.
Another advantage of the present invention is that it has enlarged the scope that can be used for the protective coating on the glass substrate, make in the coating to comprise hygroscopic material, and in this class application beyond the present invention, hygroscopic material is inapplicable.Hermetically sealed packaging can use these hygroscopic materials to be owing under high humidity environment, for example in the transoceanic transportation of glass sheet, can be protected their integraty.Because in glass substrate manufacturing (for example) LCD device, hygroscopic material is easy to water and removes, so hygroscopic material is suitable as protective coat.
In the preferred embodiment of the present invention, described airtight container should make glass sheet with coating that available water removes store under greater than 90% humidity environment or transportation at least 6 months at 50 ℃, relative humidity.
Various water-soluble protective coatings can be used for embodiment of the present invention, these coating include but not limited to the compound of polysaccharide, polymeric acid, polyvinyl alcohol, polypropyleneoxide-polyethylene oxide copolymer, inhibiter and two or more above-mentioned materials.Available polysaccharide is starch-based product, methylcellulose, hydroxypropyl methylcellulose, HEMC and alginates.Available polymeric acid is polyacrylic acid and poly-(methyl vinyl ether-maleic acid) alternating polymer.The coating of more than enumerating only is illustrative, but not exhaustive.
Protective coat preferably can be removed from glass substrate by the water ablution; the water ablution as 25-80 ℃, preferred 40-75 ℃, more preferably under 55-75 ℃ the temperature; ultrasonic cleaning is combined with scrubbing, perhaps use alkaline detergent (for example 2% the SEMICLEAN KG aqueous system) to scrub separately.
Glass sheet after the coating can be piled up, and between each glass sheet, do not establish partition.If the use partition, they can be made by paper or polymer film.No matter whether use partition; preferred angle and/or at least a portion edge that all will use soft vibration-absorptive material cover glass sheet; described vibration-absorptive material can be (for example) natural or artificial polymer fiber; natural or regenerated fiber compound; by natural or man-made polymer or fiber natural or that man-made polymer's compound is made, the perhaps combination of above-mentioned material.The example that can be used as the natural polymer of vibration-absorptive material comprises cotton, timber, ramie, wool, silk and flax, and man-made polymer's example comprises poly-acetic acid esters, polyester, polyamide, cellulose ethanoate, acrylic compounds material, rayon, copper ammonia fibre, cover shoe last or hat block (laster) and Modal fibre (modal).
The material that is used for making air-tight package can be any combination that can make the material or the material of gas-tight container.As mentioned above, air-tight package is preferably sack or big envelope.Suitable containers can be made by any poly-mer that can form airtight flexible film that comprises minimum supplementary protection material, and preferably this poly-mer has enough durabilitys, can tolerate the condition that can run into usually in storage and transportation.The example of suitable polymers comprises polyethylene, polypropylene, polyvinylchloride, polyethylene terephthalate, nylon and poly tetrafluoroethylene.Can use the whole bag of tricks known in the art that these polymer films are sealed, form air-tight package.Exemplary example comprises to be made the polymer moieties fusion and uses water proof glue.For rigid container, can use the methods known in the art of packing ring, outer envelope etc. and so on to seal.
Fig. 1 and 2 has shown the example of air-tight package constructed in accordance 11.The glass sheet 13 that is coated with the material that available water removes be stacked form one folded.As shown in these figures, between each glass sheet, use partition 17 (for example scraps of paper or polymer sheet).If necessary, can save partition.
The angle and at least a portion edge that constitute the folded glass sheet of described glass sheet are protected by the vibration-absorptive material 15 of softness.Specifically, in Fig. 1 and Fig. 2, all angles and top margin and base all contact with vibration-absorptive material, but side only partly contacts with vibration-absorptive material.Vibration-absorptive material not only can cover glass angle and/or edge, and can also prevent that the poly-mer big envelope from use being cut.
In case edge and/or angle are protected, just the glass sheet that will pile up is sealed in the airtight container 19 (for example air-tightness polymer film).As mentioned above, can before sealing, from packing, remove air, perhaps can be without deacration, with package encapsulation (for example at 25 ℃, the environment of relative humidity 25%) in the environment that humidity is controlled.Again or, can use one or more unreactable gass of nitrogen and/or argon gas and so on to replace air in the air-tight package.
Bao Zhuan glass sheet can store for a long time under high humidity in this way, for example stores to surpass 1 year under 50 ℃, 90% relative humidity, and can not produce surface deficiency owing to the moisture of environment.
To describe the present invention more fully in the following embodiments, but the present invention is not limited thereto definitely.
Embodiment 1
Dip-coating comprises 10% CRYSTAL TEX 627 (N.J., Bridgewater, National Starch and Chemical Company) of 0.15% sorbic acid on glass sheet.Glass sheet after will applying with brown paper piles up.The edge of a laminated glass sheet that piles up wraps up with non-dust cloth (cleanroomcloth).Then this laminated glass sheet is placed the polyethylene terephthalate bag.At 25 ℃, this sack of environment lower seal of relative humidity 25%.
Embodiment 2
With 5% the polyacrylic acid spraying glass sheet that comprises 0.15% sorbic acid.Glass stack after will applying under the situation of not using partition gathers into folds.A laminated glass sheet that piles up is protected with cotton at each angle.It is folded to seal this glass sheet with polyethylene film then.After removing air, seal this big envelope fully.
From above as can be seen; the invention provides packing and packing method: the integraty of the coating that (1) protection available water is removed with following feature; (2) prevent this coating bonding; (3) reduce the mutual action of the glassy zone of water and uncoated, (4) are eliminated or can be controlled growth of microorganism at least.
Although described and explained the specific embodiment of the present invention, it will be apparent to one skilled in the art that and under the prerequisite that does not deviate from spirit and scope of the invention, to change and to revise.Therefore, following claims comprise the specific embodiment and change, modification and the content of equal value that this paper lifts.

Claims (22)

1. a packaging glass substrates, method to store and/or to transport, described substrate has the surface of two substantially flats separately, is coated with the protective coat that available water is removed on the surface, and described method may further comprise the steps successively:
(A) glass substrate after will applying is stacked into one folded;
(B) described glass substrate stacked package is contained in the container, the Packed internal environment of described vessel, the protective coat that this environment can protect described available water to remove makes it avoid being degraded by moisture.
2. the method for claim 1 is characterized in that, described substrate has the angle and the edge of exposure when piling up, and described method comprises: use the angle of vibration-absorptive material protection substrate exposure and/or the edge that at least a portion exposes before in step (B).
3. method as claimed in claim 2 is characterized in that, uses vibration-absorptive material to protect the angle of described substrate exposure and the edge that at least a portion exposes simultaneously.
4. the method for claim 1 is characterized in that, described container is bubble-tight polymer pouches or poly-mer big envelope.
5. the method for claim 1 is characterized in that, when the glass substrate after will applying piles up, uses partition between substrate.
6. the method for claim 1 is characterized in that, before sealing, the inner space of described container is evacuated.
7. the method for claim 1 is characterized in that, before sealing, fills unreactable gas or noble gas mixtures in the inner space of described container.
8. the method for claim 1 is characterized in that, the inner space within described bag or the big envelope is in check humidity environment lower seal.
9. method as claimed in claim 8 is characterized in that, described in check humidity environment is: temperature is lower than 50 ℃, and relative humidity is less than 50%.
10. the method for claim 1 is characterized in that, the protective coat that described available water is removed is protected, and can not degrade at least 6 months under 50 ℃, the conventional environment of relative humidity 90%.
11. the method for claim 1, this method also comprises other step:
From described container, take out glass substrate;
Make the use ablution remove the protective coat that available water is removed from glass substrate.
12. method as claimed in claim 11 is characterized in that, it is to clean glass substrate in 25-80 ℃ the aqueous solution of alkaline detergent that the water-based ablution is included in temperature.
13. the packing of a glass substrate, it comprises:
(A) be stacked into folded a large amount of glass substrates, described substrate has the surface of two substantially flats separately, is coated with the protective coat that available water is removed on the surface;
(B) surround the folded airtight container of described substrate, described container forms the leak free internal environment, and the protective coat that the protection available water is removed avoids degrading because of moisture.
14. the packing of glass substrate as claimed in claim 13 is characterized in that, described substrate has the angle and the edge of exposure when piling up, and described packing also comprises the vibration-absorptive material at the angle and/or the edge that at least a portion exposes of the exposure that is applied to described substrate.
15. packing as claimed in claim 14 is characterized in that, simultaneously vibration-absorptive material is applied to the angle of exposure of substrate and the edge that at least a portion exposes.
16. packing as claimed in claim 13 is characterized in that, described container is bubble-tight polymer pouches or poly-mer big envelope.
17. packing as claimed in claim 13, this method also are included in partition are set between the substrate.
18. packing as claimed in claim 13 is characterized in that, the pressure of described leak free internal environment is lower than bar pressure.
19. packing as claimed in claim 13 is characterized in that, described leak free internal environment comprises unreactable gas or noble gas mixtures.
20. packing as claimed in claim 13 is characterized in that, described leak free internal environment comprises air, and its temperature is lower than 50 ℃, relative humidity less than 50%.
21. packing as claimed in claim 13 is characterized in that, the protective coat that described available water is removed is protected, and can not degrade at least 6 months under 50 ℃, the conventional environment of relative humidity 90%.
22. packing as claimed in claim 13 is characterized in that, described glass substrate is the LCD glass substrate.
CNA2005800069843A 2004-03-08 2005-02-25 Method and apparatus for packaging glass substrates Pending CN1930055A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/795,590 2004-03-08
US10/795,590 US20050194279A1 (en) 2004-03-08 2004-03-08 Method and apparatus for packaging glass substrates

Publications (1)

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CN1930055A true CN1930055A (en) 2007-03-14

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US (1) US20050194279A1 (en)
JP (1) JP2007527830A (en)
KR (1) KR20060128046A (en)
CN (1) CN1930055A (en)
TW (1) TW200600433A (en)
WO (1) WO2005092740A1 (en)

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JP2007527830A (en) 2007-10-04
US20050194279A1 (en) 2005-09-08
WO2005092740A1 (en) 2005-10-06
TW200600433A (en) 2006-01-01

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