CN1926984A - Biological-chemical synergic bactericide composition and its application - Google Patents

Biological-chemical synergic bactericide composition and its application Download PDF

Info

Publication number
CN1926984A
CN1926984A CN 200610096424 CN200610096424A CN1926984A CN 1926984 A CN1926984 A CN 1926984A CN 200610096424 CN200610096424 CN 200610096424 CN 200610096424 A CN200610096424 A CN 200610096424A CN 1926984 A CN1926984 A CN 1926984A
Authority
CN
China
Prior art keywords
biological
agent
adopts
tebuconazole
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 200610096424
Other languages
Chinese (zh)
Other versions
CN100518509C (en
Inventor
罗昌炎
谭瑞成
王江柱
刘智忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Rotam Chemical Co Ltd
Original Assignee
Jiangsu Rotam Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Rotam Chemical Co Ltd filed Critical Jiangsu Rotam Chemical Co Ltd
Priority to CNB2006100964248A priority Critical patent/CN100518509C/en
Publication of CN1926984A publication Critical patent/CN1926984A/en
Application granted granted Critical
Publication of CN100518509C publication Critical patent/CN100518509C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

This invention involves a kind of biological-chemical synergistic fungicide combination and its application. It demonstrates strong bactericidal activity and can be used for the prevention and treatment of various diseases on apple trees, grapes, tomatoes, cucumbers, strawberries and wheat. The invention is characterized in that the active ingredients of the fungicide combination comprise ether-methyl and tebuconazole. The weight percent of ingredients for the preparation of fungicide combination is ethyl-ether 5~45%, tebuconazole 2~43%, accessory ingredient 2~25%, packing material 10~91%. They are made into wettable powdersuspensions.

Description

A kind of biological-chemical synergic bactericide composition and application thereof
Technical field
What the present invention relates to is a kind of biological-chemical synergic bactericide composition and application thereof; show extremely strong antibiotic and bactericidal activity; be applied to agricultural plant chemoproection field; be mainly used in control apple tree, grape, tomato, cucumber, strawberry, all kinds of diseases of wheat and use; crops are had protective effect and therapeutic action, and the said composition bactericide is different from existing other microbicide compositions, can suspension of pesticide resistance generation; safe in utilization, be convenient to promote.
Background technology
Kresoxim-methyl; Chinese is a kresoxim-methyl; English common name: kresoxim-methyl; it is a kind of antibiotics bactericide of bionical synthesizing new; kresoxim-methyl acts on the cytochrome compound; the electron transfer process of blocking-up germ mitochondrial respiratory chain; suppress the supply of germ cellular energy; make the germ cell lack energy death; to imperfect fungus; sac fungi; basidiomycetes; fungus-caused multiple diseases such as Oomycete has good active; has excellent protection; treat and root out activity; to crop; the people; poultry and beneficial organism safety, pollution-free substantially to environment, but the intrinsic resistance risk of this series bactericidal agent is high-caliber; be easy to develop immunity to drugs, and the cost height.Tebuconazole, English common name: tebuconazole is a systemic fungicide, suppresses the sterol demethylation, the disease that control Rust that can be fabulous, Erysiphe, Rhynchosporium spp, nuclear cavity Pseudomonas and Septoria cause, but to phytophthora, dry rot fungus weak effect.
Summary of the invention
The objective of the invention is at above-mentioned weak point, a kind of biological-chemical synergic bactericide composition and application thereof are provided, kresoxim-methyl and Tebuconazole are composite, have obvious synergistic effect, enlarged fungicidal spectrum simultaneously, to using in apple tree, grape, tomato, cucumber, all kinds of diseases of wheat, control efficiency is good, be better than kresoxim-methyl, two medicament lists of Tebuconazole usefulness, can reduce farming simultaneously originally, do not have cross resistance between the two.
A kind of biological-chemical synergic bactericide composition and application thereof take following scheme to realize: biological-chemical synergic bactericide composition, it is characterized in that microbicide compositions active ingredient is made up of kresoxim-methyl, Tebuconazole, it is kresoxim-methyl 5～45%, Tebuconazole 2～43%, auxiliary agent 2～25%, filler 10～91% that microbicide compositions prepares raw material weight percentage.
A kind of biological-chemical synergic bactericide composition can be made into wetting powder or suspending agent.
The auxiliary agent of wetting powder is made up of dispersant 1.95～20%, wetting agent 0.05～5%, and percentage is preparation raw material weight percentage.Dispersant adopts lignosulfonates, NNO, draws back a kind of or mixture in the powder in the wetting powder, and wherein lignosulfonates are selected calcium lignosulfonate, sodium lignin sulfonate for use; Wetting agent adopts alkyl benzene calcium sulfonate or sodium alkyl benzene sulfonate; That filler adopts is silica-based, a kind of or mixture in the precipitated calcium carbonate, white carbon black.Silica-based potter's clay, kaolin, the diatomite etc. selected for use.
The auxiliary agent of suspending agent is made up of dispersion moisture agent 0.5～15%, antifreeze 0.45～3%, thickener 1～5%, defoamer 0.05～2%, and percentage is preparation raw material weight percentage.Dispersion moisture agent in the suspending agent adopts polyoxyethylene triphenyl phosphorus hydrochlorate, alkylnaphthalene sulfonate, a kind of or mixture in the alkylphenol polyoxyethylene; Antifreeze adopts alcohols, selects propane diols or glycerine or ethylene glycol for use; Thickener adopts xanthans or aluminium-magnesium silicate; Defoamer adopts silicone defoaming agent; Filler adopts water, a kind of or mixture in the white carbon black.
A kind of biological-chemical synergic bactericide composition preparation technology method: composition is by said ratio weighing kresoxim-methyl and Tebuconazole, the product form that makes as required is wetting powder or suspending agent, and auxiliary agent and filler that employing is filled a prescription separately, fully mix, pulverize or after sand mill grinds through airslide disintegrating mill, mix, promptly obtain finished product, finished product meets the every index request of country to wetting powder or suspending agent.
A kind of biological-chemical synergic bactericide composition is used in control apple tree, grape, tomato, cucumber, strawberry, all kinds of diseases of wheat.
A kind of biological-chemical synergic bactericide composition is used in control apple tree, grape, cucumber, strawberry, wheat diseases, to crop safety, cost is low, preventive effect good.Be better than kresoxim-methyl, two medicament lists of Tebuconazole usefulness, can reduce farming simultaneously originally, do not have cross resistance between the two.Prove that after tested microbicide compositions chemical property of the present invention is stable, synergy is remarkable, has enlarged fungicidal spectrum, and controlling object is shown obvious synergistic effect and energy suspension of pesticide resistance generation.Biological-chemical synergic bactericide composition of the present invention is safe in utilization, is convenient to promote.
Embodiment
Specific embodiments and effect
Embodiment:
Further specify the present invention below with reference to embodiment, following embodiment only is used to the present invention is described and to the present invention without limits.
Embodiment 1:88% kresoxim-methyl Tebuconazole wetting powder
Kresoxim-methyl 45%
Tebuconazole 43%
NNO (dispersant) 1%
Sodium lignin sulfonate (dispersant) 0.95%
Sodium alkyl benzene sulfonate (wetting agent) 0.05%
White carbon black (filler) 10%
1500～2500 times of liquid of the preparation that is made into according to the above ratio about 80%, are better than single usefulness to the preventive effect of apple tree ring spot.
88% kresoxim-methyl Tebuconazole WP prevents and treats 7 days preventive effects (%) (Feng County, Jiangsu) behind the ring rot of apple medicine
Handle I II III IV On average
1500 times 90.12 94.52 92.96 93.65 93.06
2000 times 85.38 86.82 85.32 87.21 86.18
2500 times 78.47 77.21 76.89 77.88 77.61
2000 times of 50% kresoxim-methyl SC 72.38 73.52 72.42 73.60 72.98
2000 times of 25% Tebuconazole EW 58.81 57.93 56.88 60.12 58.44
88% kresoxim-methyl Tebuconazole WP prevents and treats fortnight preventive effect (%) (Feng County, Jiangsu) behind the sick medicine of apple scab
Handle I II III IV On average
2000 times 86.11 87.17 88.04 89.05 87.59
2500 times 73.86 75.33 78.18 76.54 75.98
3000 times 70.08 71.33 68.54 69.24 69.79
2500 times of 50% kresoxim-methyl SC 63.88 62.58 68.07 67.44 65.49
2000 times of 25% Tebuconazole EW 54.13 50.09 54.76 52.38 52.84
Embodiment 2:7% kresoxim-methyl Tebuconazole wetting powder
Kresoxim-methyl 5%
Tebuconazole 2%
NNO (dispersant) 1%
Draw back powder (dispersant) 0.95%
Alkyl benzene calcium sulfonate (wetting agent) 0.05%
White carbon black (filler) 12%
Diatomite (filler) 79%
600～800 times of liquid of the preparation that is made into according to the above ratio more than 70%, are better than single usefulness to the preventive effect of gray mold of cucumber.
7% kresoxim-methyl Tebuconazole wetting powder control gray mold of cucumber preventive effect (Yixing, Jiangsu)
Handle The sub-district Disease refers to before the medicine Behind the medicine 7 days for the second time Behind the medicine 7 days for the third time
Disease refers to Proofread and correct preventive effect (%) Disease refers to Proofread and correct preventive effect (%)
600 times of kresoxim-methyl Tebuconazoles I 0.32 0.61 65.9 0.78 73.2
II 0.28 0.54 73.2 0.67 75.0
III 0.19 0.48 63.4 0.53 70.6
IV 0.25 0.54 61.9 0.72 66.8
V 0.26 0.54 66.1 0.68 71.4
700 times of kresoxim-methyl Tebuconazoles I 0.21 0.32 72.8 0.26 86.3
II 0.16 0.36 68.7 0.38 75.2
III 0.19 0.38 71.0 0.42 76.7
IV 0.36 0.51 75.0 0.62 80.1
V 0.23 0.39 71.9 0.42 79.6
800 times of kresoxim-methyl Tebuconazoles I 0.30 0.38 77.4 0.30 81.2
II 0.18 0.23 82.2 0.62 81.6
III 0.45 0.51 83.6 0.26 85.5
IV 0.26 0.42 71.5 0.47 29.6
V 0.30 0.39 78.7 0.52 82.2
2500 times of 25% Tebuconazole EC I 0.18 0.28 72.3 0.52 68.0
II 0.38 0.74 72.9 0.84 76.9
III 0.25 0.46 73.2 0.52 78.0
IV 0.41 0.65 72.1 0.92 74.1
V 0.31 0.53 72.7 0.70 74.2
2000 times of 50% kresoxim-methyl WP I 0.32 0.61 65.9 0.78 73.0
II 0.21 0.51 62.8 1.01 60.3
III 0.19 0.48 63.4 0.53 70.6
IV 0.37 0.58 71.2 0.82 67.1
V 0.27 0.54 65.8 0.82 67.7
The agent of embodiment 3:40% kresoxim-methyl Tebuconazole wettable
Tebuconazole 20%
Kresoxim-methyl 20%
Calcium lignosulfonate (dispersant) 20%
Alkyl benzene calcium sulfonate (wetting agent) 5%
Potter's clay (filler) 15%
Precipitated calcium carbonate (filler) 20%
1000～2000 times of liquid of the preparation that is made into according to the above ratio more than 70%, are better than single usefulness to the preventive effect of fruit white rot of grape.
40% kresoxim-methyl Tebuconazole wetting powder is prevented and treated fruit white rot of grape preventive effect (Changli, Hebei)
Handle Repeat Disease refers to before the medicine Behind the medicine 7 days for the third time Behind the 4th medicine 10 days
Disease refers to Preventive effect (%) Disease refers to Preventive effect (%)
1000 times of 40% kresoxim-methyl Tebuconazole WP 1 1.81 1.83 77.2 2.37 83.1
2 1.8 1.61 81.6 2.52 83.4
3 2.15 1.78 82.2 2.81 83.1
4 1.99 1.89 79.8 2.47 85.1
On average 1.9 1.8 80.2 2.5 83.7
40% kresoxim-methyl Tebuconazole 1 1.65 2.11 71.1 2.96 76.9
2 1.89 1.72 81.2 2.81 82.4
1500 times of WP 3 2.06 2 79.2 3.21 79.8
4 1.89 2.17 75.6 3.06 80.6
On average 1.9 2.0 76.8 3.0 79.9
2000 times of 40% kresoxim-methyl Tebuconazole WP 1 1.84 2.94 63.9 4.2 70.5
2 1.82 2.78 68.5 4 74.0
3 2.01 2.94 68.6 4.35 72.0
4 1.91 2.89 67.8 4.1 74.2
On average 1.9 2.9 67.8 4.1 74.2
1000 times of 80% mancozeb WP 1 1.98 1.78 79.7 2.47 83.9
2 1.75 1.78 79.7 2.47 83.9
3 1.97 1.89 79.4 2.86 81.2
4 1.78 1.83 78.1 7.52 83.0
On average 1.9 1.8 79.1 2.6 82.9
The clear water contrast 1 1.88 8.33 14.57
2 1.81 8.78 15.31
3 1.98 9.22 15.31
4 1.82 8.56 15.16
On average 1.9 8.7 15.1
Embodiment 4:60% kresoxim-methyl tebuconazole suspension concentrates
Tebuconazole 30%
Kresoxim-methyl 30%
Polyoxyethylene nonylphenol ether (NP-9) (dispersion moisture agent) 15%
Propane diols (antifreeze) 0.45%
Xanthans (thickener) 1%
Silicone defoaming agent (SAG612) 2%
Water (filler) 21.55%
2000～3000 times of liquid of the preparation that is made into according to the above ratio more than 70%, are better than single usefulness to the preventive effect of wheat powdery mildew.
7 days preventive effects (%) (Yancheng, Jiangsu) behind the 60% kresoxim-methyl Tebuconazole SC control wheat powdery mildew medicine
30 days investigation preventive effect tables behind the secondary medicine
Handle Disease index Control efficiency % Average preventive effect (%)
I II III IV I II III IV
3000 times 3.11 3.63 3.77 3.54 61.27 61.26 56.62 54.56 58.43
2500 times 2.06 2.54 2.37 1.71 74.34 72.89 72.73 78.04 74.50
2000 times 1.46 1.43 1.14 1.80 81.81 84.74 86.88 76.89 82.58
600 times of 50% carbendazim SC 2.29 2.37 1.94 2.29 71.48 74.71 77.68 70.60 73.62
The clear water contrast 8.03 9.37 8.69 7.79
Embodiment 5:50% kresoxim-methyl tebuconazole suspension concentrates
Tebuconazole 5%
Kresoxim-methyl 45%
Polyoxyethylene triphenyl phosphoric acid calcium (dispersion moisture agent) 6%
Ethylene glycol (antifreeze) 1%
Aluminium-magnesium silicate (thickener) 3%
Silicone defoaming agent (Sag587) 0.6%
White carbon black (filler) 2%
Water (filler) 31.4%
2000～3000 times of liquid of the preparation that is made into according to the above ratio more than 80%, are better than single usefulness to the preventive effect of graw mold of tomato.
10 days preventive effect tables behind three medicines of 50% kresoxim-methyl Tebuconazole SC control graw mold of tomato preventive effect (Hefei ,Anhui)
Handle Control efficiency (%) Average preventive effect (%)
I II III IV
2000 times 97.35 95.36 85.45 84.85 90.35
2500 times 76.12 90.0 87.27 75.93 82.33
3000 times 56.36 54.06 49.19 62.92 55.32
50% kresoxim-methyl WP3000 doubly 74.42 70.2 68.4 49.60 65.66
2500 times of 25% Tebuconazole EC 84.85 81.63 72.17 87.27 81.48
Embodiment 645% kresoxim-methyl tebuconazole suspension concentrates
Tebuconazole 43%
Kresoxim-methyl 2%
Negel (soprophor FL) (dispersion moisture agent) 8%
Glycerine (antifreeze) 2%
Xanthans (thickener) 4%
Silicone defoaming agent (Sag722) 0.3%
Water (filler) 45.7%
1000～2000 times of liquid of the preparation that is made into according to the above ratio more than 70%, are better than single usefulness to the preventive effect of powdery mildew of strawberry disease.
The sick drug effect (Jurong, Jiangsu) of 45% kresoxim-methyl Tebuconazole SC control powdery mildew of strawberry
10 days preventive effect tables behind the medicine for the third time
Handle Repeat Disease refers to (%) before the medicine Disease refers to behind the medicine Proofread and correct preventive effect (%)
1000 times 1 0.03 0.02 83.33
2 0.02 0.02 88.89
3 0.02 0.02 87.50
4 0.02 0.02 80.00
On average 0.023 0.02 84.93
1500 times 1 0.02 0.03 62.5
2 0.02 0.03 83.23
3 0.02 0.04 75.00
4 0.02 0.02 80.00
On average 0.02 0.03 75.21
2000 times 1 0.01 0.02 50.00
2 0.02 0.04 77.78
3 0.02 0.04 77.78
4 0.01 0.03 40.00
On average 0.015 0.03 62.25
600 times of 80% mancozeb WP 1 0.01 0.02 80.25
2 0.02 0.04 41.00
3 0.02 0.03 63.25
4 0.02 0.03 51.05
On average 0.015 0.03 58.88
50% kresoxim-methyl WP2000 doubly 1 0.02 0.03 62.50
2 0.01 0.04 55.56
3 0.02 0.05 68.75
4 0.02 0.04 60.00
On average 0.018 0.04 61.72
The clear water contrast 1 0.02 0.08
2 0.01 0.09
3 0.01 0.08
4 0.02 0.10
On average 0.015 0.88
Embodiment 7:30% kresoxim-methyl tebuconazole suspension concentrates
Tebuconazole 15%
Kresoxim-methyl 15%
Alkyl naphthalene sulfonic acid calcium (soprophor FL) (dispersion moisture agent) 0.5%
Propane diols (antifreeze) 3%
Xanthans (thickener) 5%
Silicone defoaming agent (Sag72) 0.05%
White carbon black (filler) 10%
Water (filler) 51.45%
1000～2000 times of liquid of the suspending agent that is made into according to the above ratio more than 70%, are better than single usefulness to the preventive effect of graw mold of tomato.
7 days preventive effect tables behind 30% kresoxim-methyl Tebuconazole SC control graw mold of tomato preventive effect (Nantong) medicine
Handle Control efficiency (%) Average preventive effect (%)
I II III IV
1000 times 85.46 80.09 84.12 82.68 83.08
1500 times 80.28 79.01 74.09 76.25 77.40
2000 times 69.80 72.01 65.08 74.00 70.22
2000 times of 50% kresoxim-methyl SC 60.58 62.89 70.24 62.56 64.06
2500 times of 25% Tebuconazole EW 70.04 69.82 72.08 68.58 70.13
Embodiment 8:47% kresoxim-methyl tebuconazole suspension concentrates
Kresoxim-methyl 45%
Tebuconazole 2%
Negel (soprophor FL) (dispersion moisture agent) 6%
Glycerine (antifreeze) 3%
Aluminium-magnesium silicate (thickener) 5%
Silicone defoaming agent (Sag22) 0.1%
White carbon black (filler) 10%
Water (filler) 28.9%
1500～2500 times of liquid of the suspending agent that is made into according to the above ratio more than 80%, are better than the conventional carbendazim medicament that uses to the preventive effect of wheat powdery mildew disease.
5 days preventive effect tables behind 47% kresoxim-methyl Tebuconazole SC control wheat powdery mildew preventive effect (Jiangdu, the Jiangsu) medicine
Handle Control efficiency (%) Average preventive effect (%)
I II III IV
1500 times 87.63 85.23 82.32 80.09 83.81
2000 times 78.65 80.02 75.68 74.28 77.15
2500 times 68.90 75.86 72.49 70.54 71.94
400 times of 50% carbendazim SC 68.45 70.58 58.98 65.42 65.85

Claims (5)

1, a kind of biological-chemical synergic bactericide composition, it is characterized in that microbicide compositions active ingredient is made up of kresoxim-methyl, Tebuconazole, it is kresoxim-methyl 5～45%, Tebuconazole 2～43%, auxiliary agent 2～25%, filler 10～91% that microbicide compositions prepares raw material weight percentage.
2,, it is characterized in that the microbicide compositions with biological-chemical synergic effect makes wetting powder or suspending agent according to the described a kind of biological-chemical synergic bactericide composition of claim 1.
3, according to claim 1 or 2 described a kind of biological-chemical synergic bactericide compositions, it is characterized in that the auxiliary agent of wetting powder is made up of dispersant 1.95～20%, wetting agent 0.05～5%, percentage is preparation raw material weight percentage; Dispersant adopts lignosulfonates, NNO, draws back a kind of or mixture in the powder, and wherein lignosulfonates are selected calcium lignosulfonate, sodium lignin sulfonate for use; Wetting agent adopts alkyl benzene calcium sulfonate or sodium alkyl benzene sulfonate; That filler adopts is silica-based, a kind of or mixture in the precipitated calcium carbonate, white carbon black, silica-based potter's clay, kaolin, the diatomite selected for use.
4, according to claim 1 or 2 described a kind of biological-chemical synergic bactericide compositions, the auxiliary agent that it is characterized in that suspending agent is made up of dispersion moisture agent 0.5～15%, antifreeze 0.45～3%, thickener 1～5%, defoamer 0.05～2%, and percentage is preparation raw material weight percentage; Dispersion moisture agent in the suspending agent adopts a kind of or mixture in polyoxyethylene triphenyl phosphorus hydrochlorate, alkylnaphthalene sulfonate, the alkylphenol polyoxyethylene; Antifreeze adopts alcohols, and alcohols is selected propane diols or glycerine or ethylene glycol for use; Thickener adopts xanthans or aluminium-magnesium silicate; Defoamer adopts silicone defoaming agent; Filler adopts a kind of or mixture in water, the white carbon black.
5, the described a kind of biological-chemical synergic bactericide composition of claim 1 is used in control apple tree, grape, tomato, cucumber, strawberry, all kinds of diseases of wheat.
CNB2006100964248A 2006-09-26 2006-09-26 Biological-chemical synergic bactericide composition and its application Expired - Fee Related CN100518509C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2006100964248A CN100518509C (en) 2006-09-26 2006-09-26 Biological-chemical synergic bactericide composition and its application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2006100964248A CN100518509C (en) 2006-09-26 2006-09-26 Biological-chemical synergic bactericide composition and its application

Publications (2)

Publication Number Publication Date
CN1926984A true CN1926984A (en) 2007-03-14
CN100518509C CN100518509C (en) 2009-07-29

Family

ID=37857240

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2006100964248A Expired - Fee Related CN100518509C (en) 2006-09-26 2006-09-26 Biological-chemical synergic bactericide composition and its application

Country Status (1)

Country Link
CN (1) CN100518509C (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101578980A (en) * 2008-05-16 2009-11-18 上海禾本药业有限公司 Preparation method of tebuconazole suspension concentrates
CN102027936A (en) * 2010-12-05 2011-04-27 弥华锋 Water dispersible granule containing kresoxim-methyl and tebuconazole
WO2011109927A1 (en) * 2010-03-11 2011-09-15 四川蜀峰化工有限公司 Method for mixed preparation of pesticides to reduce pesticide residues on agricultural produce
CN102763656A (en) * 2012-07-13 2012-11-07 王学权 Fungicide containing tebuconazole
CN102835401A (en) * 2012-09-24 2012-12-26 天津市汉邦植物保护剂有限责任公司 Bactericidal composition containing kresoxim-methyl and tebuconazole and application
CN104336021A (en) * 2014-10-22 2015-02-11 江苏东宝农药化工有限公司 Bactericide composition with synergistic effect

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101578980A (en) * 2008-05-16 2009-11-18 上海禾本药业有限公司 Preparation method of tebuconazole suspension concentrates
WO2011109927A1 (en) * 2010-03-11 2011-09-15 四川蜀峰化工有限公司 Method for mixed preparation of pesticides to reduce pesticide residues on agricultural produce
CN102027936A (en) * 2010-12-05 2011-04-27 弥华锋 Water dispersible granule containing kresoxim-methyl and tebuconazole
CN102763656A (en) * 2012-07-13 2012-11-07 王学权 Fungicide containing tebuconazole
CN102835401A (en) * 2012-09-24 2012-12-26 天津市汉邦植物保护剂有限责任公司 Bactericidal composition containing kresoxim-methyl and tebuconazole and application
CN102835401B (en) * 2012-09-24 2014-05-07 天津市汉邦植物保护剂有限责任公司 Bactericidal composition containing kresoxim-methyl and tebuconazole and application
CN104336021A (en) * 2014-10-22 2015-02-11 江苏东宝农药化工有限公司 Bactericide composition with synergistic effect

Also Published As

Publication number Publication date
CN100518509C (en) 2009-07-29

Similar Documents

Publication Publication Date Title
CN1833503A (en) Bactericide compsns, with synergistic effect
CN1926984A (en) Biological-chemical synergic bactericide composition and its application
CN100473277C (en) Synergistic sterilizing composition containing tricyclazole and tebuconazole
CN100473279C (en) Germicide composition containing thiophanate and tricyclazole
CN1461590A (en) Sterilizing composition contg. ethylicin
CN1255830A (en) Fungicidal combinations comprising 4-phenoxyquinoline
CN101288407A (en) Bactericial composition containing propineb and tebuconazole
CN1261026C (en) Bacteridal composition containing alkene oxime amine and triazole kind compound
CN1759677A (en) Sterilization composition containing carbendazim of multiple antimycin
CN1759674A (en) Composition of fungicide for preventing and curing graw mold of tomato
CN1244275C (en) Cnidiadin and its built composition for preventing and controlling crop powdery mildew
CN101036461A (en) Eugenol, osthol complex biological bactericide
CN1608467A (en) Bactericide composition containing SYP-Zo48
CN101822264B (en) Bactericidal composition with pyriproxyfen and thiophanate-methyl
CN1853483A (en) Green trichodermin enoyl morpholine water dispersion tablet or granule and production thereof
CN1265708C (en) Bactericide composition of SYP-Zo48 and thiocarbamate
CN110679598A (en) Bactericide composition containing tebuconazole and fludioxonil for preventing and treating pitaya brown rot and application thereof
CN101379999A (en) Composition containing propineb and hexaconazole with bactericidal action
CN1745630A (en) Fructus cnidii complex composition
CN1257669C (en) Bactericide composition containing enostroburin
CN101755823A (en) Fungicidal composition containing flusilazole and pyrimethanil
CN1060014C (en) Germicide composite for prevention and control of plant diseases
CN109380251A (en) One kind having synergic bactericide composition
CN101779649B (en) Bactericidal composition containing phenol cycloheximide and thiophanate-methyl
CN1915027A (en) Mancozeb.bordenaux mixture composition bactericide, preparation method and application

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20090729

CF01 Termination of patent right due to non-payment of annual fee