CN1915576A - Soft soldering material with no lead - Google Patents
Soft soldering material with no lead Download PDFInfo
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- CN1915576A CN1915576A CN 200610113052 CN200610113052A CN1915576A CN 1915576 A CN1915576 A CN 1915576A CN 200610113052 CN200610113052 CN 200610113052 CN 200610113052 A CN200610113052 A CN 200610113052A CN 1915576 A CN1915576 A CN 1915576A
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- lead
- soft soldering
- consumption
- alloy
- lead soft
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Abstract
A non-lead soft solder with high binding strength, high stability of soldered joint, and high corrosion resistance contains Zn (3-11 Wt%), Ag (0.1-3.), Cu and/or Ti (0.1-3.0) and Sn (rest).
Description
Technical field
The present invention relates to a kind of no-lead soft soldering, belong to welding material.
Technical background
Along with being gradually improved and strictness of environmental regulation, though tin-lead solder has excellent advantages such as wetability, weldability, good mechanical performance and low price, but lead and compound thereof are the poisonous and harmful substance of harm humans health and contaminated environment, so no-lead soft soldering will increase greatly in microelectronics surface installation technique Application for Field.
The lead-free solder that uses mainly is SnCu, SnAg, SnZn binary alloy system and SnAgCu ternary alloy system at present, or more multicomponent alloy solder based on this, but the cost height that has, the fusing point height that has.
Summary of the invention
Purpose of the present invention just for the shortcoming that overcomes above-mentioned prior art with not enough and provide a kind of and have that cost is low, the bond strength height of soldered fitting, no-lead soft soldering that the soldered fitting structure stability is good, thereby unleaded for realizing electronics and IT products, make unleaded soft fine scolder obtain broader applications.
The objective of the invention is to realize by following technical proposal:
A kind of no-lead soft soldering is characterized in that it is made up of following by weight percentage:
Zn 3～11%, Ag 0.1～3.0%, Cu or Ti 0.1～3.0% and surplus Sn.
Cu or Ti also can be Cu and Ti in the described no-lead soft soldering, and its consumption is respectively 0.1～3.0%.
The preferred weight percent of described Ag is 0.1～1.0%,
The preferred weight percent of described Cu is 0.1～1.5%,
The preferred weight percent of described Ti is 0.2～1.0%.
The Zn consumption is controlled between 3～11% in the no-lead soft soldering of the present invention, and the alloy melting temperature range is little, and the soldering processes performance is better.The Zn consumption is less than 3% or surpass 11%, all can make alloy away from eutectic composition, and it is big that molten temperature region becomes, and makes welding that difficulty take place.
The Ag consumption is controlled between 0.1～3.0% in the no-lead soft soldering of the present invention, and along with the increase of Ag consumption, the adhesion of solder joint enlarges markedly when beginning, but the trend of Zeng Daing just slows down subsequently, if the Ag consumption surpasses 3%, cost of alloy rises on the one hand, will cause Ag on the other hand
3The Sn intermetallic compound increases, and has a strong impact on the mechanical property of solder and joint, reduces Joint Reliability, also ELECTROMIGRATION PHENOMENON might take place simultaneously.So the most preferred scope of Ag consumption is 0.1～1.0%.
No-lead soft soldering Cu consumption is controlled between 0.1～3.0%, the interpolation of Cu can be brought into play and improve solder mechanical intensity and extensibility, suppressing copper in Copper Foil or the copper conductor melts to brazing alloy, and make welding point produce the concentration gradient of a rational copper, improve its electric conductivity, the adding of copper also improves the conduction of whole lead-free solder, heat conductivility, if the Cu consumption is below 0.1%, then its effect is low excessively, as surpassing 3.0%, the fusing point of scolder is increased, also can produce the intermetallic compound of Cu and Sn simultaneously, can cause its mechanical strength to reduce so on the contrary.So the most preferred scope of Cu consumption is 0.1～1.5%.
No-lead soft soldering Ti consumption is controlled between 0.1～3.0%, and Ti is a kind of advantage that scolder is welded with oxide easily that has, and the interpolation of Ti in addition can strengthen the decay resistance of alloy.If the Ti consumption is below 0.1%, then its effect is low excessively, and as surpassing 3.0%, then the hardness of scolder itself increases, thereby causes its operation variation.So the most preferred scope of Ti consumption is 0.2～1.0%.
Formula for a product of the present invention, the purity of each raw material of selecting for use: Sn is 99.5%, Cu 〉=99.5%, Ag, Zn, Ti 〉=99.5% are major ingredient with Sn, by following method manufacturing:
(a) at first Sn and Cu, Ag and Ti are made SnAg, SnCu or SnTi intermediate alloy respectively,
(b) tin dropped in the tin stove earlier melt, then Zn is joined in the tin liquor, constantly stir simultaneously, it is melted fully after, again SnAg, SnCu or SnTi intermediate alloy are joined in the tin zinc liquation, constantly stir simultaneously, it is melted fully, be incubated half an hour, make the alloy homogenising
(c) the scolder slag of removal alloy surface becomes product at the casting film top-pour.
Because it is low to take technique scheme to make the technology of the present invention compared with the prior art have a cost; Bond strength height, the soldered fitting structure stability of soldered fitting is good, anti-corrosion property can be used for advantage and the effect that soldering iron carries out soldering well.
The specific embodiment
Embodiment
| Embodiment | Raw material components consumption (Kg) | ||||
| Sn | Zn | Ag | Cu | Ti | |
| 1 | 93.90 | 3.0 | 0.1 | 3.0 | |
| 2 | 89.50 | 8.0 | 2.0 | 0.5 | |
| 3 | 85.90 | 11.0 | 3.0 | 0.1 | |
| 4 | 91.50 | 5.0 | 0.5 | 3.0 | |
| 5 | 90.20 | 7.0 | 2.3 | 0.5 | |
| 6 | 93.40 | 4.0 | 2.5 | 0.1 | |
| 7 | 92.00 | 3.5 | 1.5 | 2.0 | 1.0 |
| 8 | 86.00 | 10.0 | 1.0 | 1.5 | 1.5 |
| 9 | 88.10 | 9.0 | 0.8 | 0.1 | 2.0 |
Claims (5)
1, a kind of no-lead soft soldering is characterized in that it is made up of following weight percentages:
Zn 3～11%, Ag 0.1～3.0%, Cu or Ti 0.1～3.0%
With surplus Sn.
2, no-lead soft soldering according to claim 1 is characterized in that in the described no-lead soft soldering that Cu or Ti also can be Cu and Ti, and its percentage by weight is respectively 0.1～3.0%.
3, no-lead soft soldering according to claim 1 and 2 is characterized in that described Ag percentage by weight is 0.1～1.0%.
4, no-lead soft soldering according to claim 1 and 2 is characterized in that described Cu percentage by weight is 0.1～1.5%.
5, no-lead soft soldering according to claim 1 and 2 is characterized in that described Ti percentage by weight is 0.2～1.0%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610113052A CN100593448C (en) | 2006-09-08 | 2006-09-08 | Soft soldering material with no lead |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610113052A CN100593448C (en) | 2006-09-08 | 2006-09-08 | Soft soldering material with no lead |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1915576A true CN1915576A (en) | 2007-02-21 |
| CN100593448C CN100593448C (en) | 2010-03-10 |
Family
ID=37736721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610113052A Expired - Fee Related CN100593448C (en) | 2006-09-08 | 2006-09-08 | Soft soldering material with no lead |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100593448C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106624430A (en) * | 2016-11-30 | 2017-05-10 | 安徽华众焊业有限公司 | Tin soldering paste |
| CN113399859A (en) * | 2021-05-27 | 2021-09-17 | 西安理工大学 | Sn-Zn-Cu lead-free solder and preparation method thereof |
-
2006
- 2006-09-08 CN CN200610113052A patent/CN100593448C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106624430A (en) * | 2016-11-30 | 2017-05-10 | 安徽华众焊业有限公司 | Tin soldering paste |
| CN113399859A (en) * | 2021-05-27 | 2021-09-17 | 西安理工大学 | Sn-Zn-Cu lead-free solder and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100593448C (en) | 2010-03-10 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100310 Termination date: 20160908 |