CN1887252A - Composition for skin - Google Patents
Composition for skin Download PDFInfo
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- CN1887252A CN1887252A CN 200510082401 CN200510082401A CN1887252A CN 1887252 A CN1887252 A CN 1887252A CN 200510082401 CN200510082401 CN 200510082401 CN 200510082401 A CN200510082401 A CN 200510082401A CN 1887252 A CN1887252 A CN 1887252A
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- skin
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Abstract
The composition for skin includes one kind of high concentration protein fiber dispersed homogeneously in an emulsifier system with at least one kind of non-siloxane surfactant. The emulsifier system without silicon component is superior to known emulsifier system and suitable for application for cosmetics and externally applied medicine. Or, the composition for skin may have its high concentration protein fiber dispersed homogeneously in an emulsifier system of wax oil and at least one kind of non-siloxane surfactant.
Description
Technical field
The relevant a kind of composition for skin of the present invention, particularly relevant a kind of composition for skin that contains the emulsifier system of being formed by at least one non-silicone surfactants (non-silicone surfactant) (emulsifier system).
Background technology
Collagen protein (collagen) also is called collagen, is the most important composition branch of extracellular matrix, also is the topmost constructivity protein of animal connective tissue simultaneously, mainly is that the form with insoluble fibrin exists.In the composition of human body, each organ-tissue of collagen protein and human body and cell have indivisible relation, can be used for the repairing (repair) and the regeneration (regeneration) of human organ tissue.
Form by collagen protein by 70% in the human body skin composition, so collagen protein has all multi-purposes to skin.At first, the powerful moistening effect of collagen protein tool can be strengthened skin lock water function, is the important person who has rendered outstanding service that skin connective tissue is preserved moisture.Secondly, collagen protein accounts for 1/3rd of protein component in the cell, in the dermis of skin layer tissue, mainly is to be combined by institutes such as collagen fiber and elastic fiberss.Moreover the collagen protein number influences the elasticity and the gloss of skin.In addition, collagen protein makes skin be tending towards neutral, can improve secretor state under its water-retaining property and the compactibility reciprocal action, and oiliness skin pore is shunk, and the dryness skin is possessed moisture, allows skin tend to the careful neutral skin of consolidation.And collagen protein can effectively be repaired impaired skin such as acne and wrinkle.
Collagen protein is the main constituent of keeping the skin and the elasticity of muscle, but along with the age increases, the moisture in skin and the muscle can reduce and begin to wear out.At this moment, it is tiny that collagen fabric gradually becomes, and the elasticity of elastin laminin also can lower, and collagen protein and the disintegrate gradually of the mutual well-regulated mesh structure of formation of elastin laminin cause wrinkle, cutis laxa, dark and gloomy, mottle, coarse at last in original corium.Can suitably replenish the collagen protein of skin by diet, cosmetics or external preparation for skin pharmaceuticals.
By and large, cosmetics circle are according to cosmetic property, application target function, can generally be divided into for example cosmeceutical (medicine cosmetics) etc. of cleaning (cleansing), maintenance (skin care), color make-up (make up), fragrance (fragranced), hair nursing (hair care) and specific purposes, and wherein maintenance, color make-up and specific purposes apply some make up and are the main flow of cosmetics sales now.The effect of cosmetics depends on the object of its composition, manufacture process and use.Under the continuous progressive situation of now color make-up science and technology, cosmetics have dropped to very low to the injury of skin, even some cosmetics also added the maintenance composition, with when using, more can have the effect of maintenance concurrently.
Generally speaking, collagen protein in the solution that is soluble in the aqueous phase earlier usually, mixes with other cosmetic compositions when being applied to have the cosmetics of maintenance concurrently again.Yet, in various forms of collagen protein, only have water-solubility collagen to can be applicable to cosmetics, and the concentration that water-solubility collagen is soluble in the aqueous phase in the solution is also limited, its concentration is no more than about 1 percentage by weight, more increases the step and the time of cosmetics processing procedure simultaneously.
On the other hand, with regard to composition, cosmetics generally comprise cosmetics base raw material, surfactant and cosmetics additive (for example essence, colorant, glutinous agent, antioxidant and antibacterial etc.) three major types composition, wherein are chosen as key with the composition of base raw material again.Generally speaking, base comprises oil-phase component, water-phase component and emulsifying agents such as vegetable oil, mineral oil, fatty acid, wax, synthetic ester.Yet, the fatty acid that part is arranged in the base, for example caprylic acid (capric acid), oleyl alcohol (oleyl alcohol) or partial synthesis ester such as Witconol 2310 (isopropyl isostearate), infiltrate skin easily, not only skin being caused easily stimulates and burden, and has causing danger property of pimples.And used emulsifying agent in the base, and of long duration, just have the phenomenon of floating powder.
Recently, with silicon-containing surfactant for example siloxanes (silicone) polymer be the cosmetics of substrate owing to be difficult for more not injured skin, can be used for replacing synthetic ester and emulsifying agent by skin absorbs, reduce above-mentioned puzzlement whereby.Yet, silicon-containing surfactant blocks pore easily, though can cause sliding suitable sense of touch, but because the water-fast characteristic of siloxane polymer, when using next time, the siloxane polymer of thoroughly cleaning in original pore on the contrary can be along with the increase of the number of times that uses, and blocks pore gradually and causes and can't breathe.
In view of the above, be necessary to develop a kind of composition for skin in fact, to improve the various shortcoming of known emulsifier system.
Summary of the invention
One of purpose of the present invention is to disclose a kind of composition for skin, and it comprises the high concentration protein fiber, and this high concentration protein fiber is dispersed in the emulsifier system of being made up of at least one non-silicone surfactants.Owing to there is no siliceous composition in the emulsifier system, can improve the shortcoming of known emulsifier system, and be applied to the raw material of cosmetics or external pharmaceuticals.
Another object of the present invention then is to disclose a kind of composition for skin, it comprises the high concentration protein fiber, this high concentration protein fiber is dispersed in oily wax and reaches in the emulsifier system of being made up of at least one non-silicone surfactants, with the raw material as cosmetics or external pharmaceuticals.
The above-mentioned purpose according to the present invention proposes a kind of composition for skin, and this composition for skin comprises emulsifier system at least and is dispersed in wherein protein fibre.The mentioned emulsifier system is made up of at least one non-silicone surfactants, and wherein the structural formula of this non-silicone surfactants (I) is as follows:
X
m1[-O-(C
m2)
n]H
m3 (I)
Wherein X can include but not limited to C8-C24 fatty acid carbonyl (C7-CO-to C23-CO-), C8-C24 aliphatic alcohol polyether [(C8-O-)
pTo (C24-O-)
p], C8-C24 fatty acid-polyglycerol ester base [C7-COO-(CH
2CH
2OHCH
2-)
qTo C23-COO-(CH
2CH
2OHCH
2-)
q] and derivant, m1 is 1 or 2, and m2 is 2 or 3, and m3 is 0 or 1, m
1+ m
3Equal 2, n is the integer between 10 to 100, and p is the integer between 1 to 20, and q is the integer between 1 to 3.
According to a preferred embodiment of the present invention, the content of above-mentioned protein fibre can be for example between 0.5 percentage by weight to 40 percentage by weight.
According to a preferred embodiment of the present invention, above-mentioned protein fibre can include but not limited to collagen protein (hydrolyzed collagen), water-solubility collagen and the water-insoluble collagen protein of collagen protein, hydrolysis.
According to a preferred embodiment of the present invention, the content of mentioned emulsifier system can be for example between 0.1 percentage by weight to 90 percentage by weight.
According to a preferred embodiment of the present invention, above-mentioned fatty acid can include but not limited to mono fatty acid, bis-fatty acid and derivant thereof.
According to a preferred embodiment of the present invention, above-mentioned aliphatic alcohol can include but not limited to single aliphatic alcohol, double fatty alcohol ethers and derivant thereof.
According to a preferred embodiment of the present invention, above-mentioned skin uses the constituent of emulsion-type applicable to cosmetics or external pharmaceuticals.
The above-mentioned purpose according to the present invention, other proposes a kind of composition for skin, and this composition for skin wraps gatch at least, with the mixed uniformly emulsifier system of oily wax and be dispersed in protein fibre in the emulsifier system.The mentioned emulsifier system is made up of at least one non-silicone surfactants, and wherein the structural formula of this non-silicone surfactants (I) is shown below:
X
m1[-O-(C
m2)
n-O-]H
m3 (I)
Wherein X can include but not limited to C8-C24 fatty acid carbonyl (C7-CO-to C23-CO-), C8-C24 aliphatic alcohol polyether [(C8-O-)
pTo (C24-O-)
p], C8-C24 fatty acid-polyglycerol ester base [C7-COO-(CH
2CH
2OHCH
2-)
qTo C23-COO-(CH
2CH
2OHCH
2-)
q] and derivant, m1 is 1 or 2, and m2 is 2 or 3, and m3 is 0 or 1, m
1+ m
3Equal 2, n is the integer between 10 to 100, and p is the integer between 1 to 20, and q is the integer between 1 to 3.
According to a preferred embodiment of the present invention, the content of above-mentioned oily wax can be for example between 10 percentage by weight to 90 percentage by weights.
According to a preferred embodiment of the present invention, above-mentioned skin uses the constituent of emulsion-type applicable to cosmetics or external pharmaceuticals, and this composition for skin can be for example between 1 percentage by weight to 100 percentage by weight in the content of cosmetics or external pharmaceuticals.
When using above-mentioned composition for skin,, can improve the shortcoming of known emulsifier system, to be applied to the raw material of cosmetics or external pharmaceuticals owing to there is no siliceous composition in the employed emulsifier system of composition for skin.
The specific embodiment
Composition for skin of the present invention is that protein fibre is dispersed in the emulsifier system of being made up of at least one non-silicone surfactants, with the raw material as cosmetics or external pharmaceuticals.Below describe composition for skin of the present invention in detail.
Particularly, the emulsifier system of indication of the present invention is made up of at least one non-silicone surfactants.(I) is as follows for the structural formula of aforesaid non-silicone surfactants:
X
m1[-O-(C
m2)
n-O-]H
m3 (I)
Wherein X can include but not limited to C8-C24 fatty acid carbonyl (C7-CO-to C23-CO-),, the C8-C24 aliphatic alcohol polyether [(C8-O-)
pTo (C24-O-)
p], C8-C24 fatty acid-polyglycerol ester base [C7-COO-(CH
2CH
2OHCH
2-)
qTo C23-COO-(CH
2CH
2OHCH
2-)
q] and derivant, m1 is 1 or 2, and m2 is 2 or 3, and m3 is 0 or 1, m
1+ m
3Equal 2, n is the integer between 10 to 100, and p is the integer between 1 to 20, and q is the integer between 1 to 3.
For example, this non-silicone surfactants can include but not limited to Polyethylene Glycol (PEG)-fatty acid ester, Polyethylene Glycol-poly alkyl alcohol ethers, Polyethylene Glycol-fatty acid-polyglycereol lipid, polypropylene glycol-fatty acid ester, polypropylene glycol-poly alkyl alcohol ethers and polypropylene glycol-fatty acid-polyglycereol lipid.According to a preferred embodiment of the present invention, the degree of polymerization of above-mentioned Polyethylene Glycol and polypropylene glycol (degree of polymerization; D.p.) be advisable with low polymerization degree, can be for example between 10 to 100.Above-mentioned fatty acid generally is advisable with the C8-C24 fatty acid, can be mono fatty acid, bis-fatty acid or derivatives thereof, for example lauric acid (C12), myristic acid (C14), Palmic acid (C16), stearic acid (C18) etc.Above-mentioned aliphatic alcohol generally then is advisable with the C8-C24 aliphatic alcohol, can be single aliphatic alcohol, double fatty alcohol ethers or derivatives thereof.Only for illustrating usefulness, yet the present invention is not limited to this to above-mentioned each composition.The present invention utilizes above-mentioned at least one non-silicone surfactants to form emulsifier system, can reduce stimulation and the burden of known emulsifying agent to skin, and prepared thus cosmetics do not have the phenomenon of floating powder, and can significantly improve the concentration of protein fibre in the composition for skin.
The protein fibre of indication of the present invention can include but not limited to collagen protein, water-solubility collagen and the water-insoluble collagen protein of collagen protein, hydrolysis.Collagen protein of the present invention mainly is as the maintenance and the composition of preserving moisture, and with when using, more can have the effect of maintenance concurrently.
In a preferred embodiment, composition for skin of the present invention comprises emulsifier system at least and is dispersed in wherein protein fibre, wherein the content of protein fibre can be for example between 0.5 percentage by weight to 40 percentage by weight, and the content of emulsifier system can be for example between 0.1 percentage by weight to 90 percentage by weight.In another preferred embodiment, composition for skin of the present invention also wraps gatch at least, with the mixed uniformly emulsifier system of oily wax and be dispersed in protein fibre in the emulsifier system, wherein the content of protein fibre can be for example between 0.5 percentage by weight to 40 percentage by weight, the content of emulsifier system can be for example between 0.1 percentage by weight to 80 percentage by weight, and the content of oily wax can be for example between 10 percentage by weight to 90 percentage by weights.
According to a preferred embodiment of the present invention, composition for skin of the present invention can be used as the raw material of cosmetics or external pharmaceuticals, with cosmetics or external pharmaceuticals in the external composition merge to use.This composition for skin is applied to when cosmetics or external pharmaceuticals, and its content can be for example between 1 percentage by weight to 100 percentage by weight.The external composition that is suitable for generally can include but not limited to other whitening agents, wetting agent, antioxidant, UV absorbent, surfactant, thickening agent, colorant, skin-nourishing agent etc.
When composition for skin of the present invention is applied to cosmetics or external pharmaceuticals, also can arrange in pairs or groups other known whitening function agent and/or other active component are such as vitamin C, Arbutin, kojic acid, slack skin ketone (quercetin) and catechin Tyrosine ferment inhibitor such as (catechin), anti-pox agent, antibacterial, analgesics, anesthetis, anti-chafing agent, pruritus, antiinflammatory agents, resisted keratinization agent (antihyperkeratolytic agents), anti-dry skin agent (anti-dry skin agents), anti-diaphoretic (antipsoriatic agents), age resister, anti-creasing agent (antiwrinkleAgents), seborrhea goes out agent (antiseborrheic agents), U.S. black agent (self-tanning agents), Wound healing and bone regeneration agent (wound-healing agents), corticosteroid (corticosteroids) or hormone (hormones) etc.
In addition, when composition for skin of the present invention was applied to cosmetics or external pharmaceuticals, the prescription of these cosmetics or external pharmaceuticals also comprised adjuvant and other compositions at least.Adjuvant generally can include but not limited to hydrophilic or hydrophobic gellant (gelling agent), hydrophilic or hydrophobic activating agent (active agent), preservative agent (preserving agent), antioxidant (antioxidant), solvent, spice (fragrance), filler (filler), screening agent (screening agent), chelating agen (chelating agents), odour absorbents (odor absorbers) and dyestuff.Other compositions generally can include but not limited to the carbohydrate of lactose and glucose, excipient such as glucosan, cellulose, silicate and calcium carbonate, be formed at together in the prescription of required cosmetics or external pharmaceuticals then such as the adhesive of cellulose, starch, gelatin, carbohydrate, and such as the disintegrating agent of agar powder, gelatin powder, sodium alginate, cellulose derivative and calcium carbonate.Have in the technical field as for the consumption of above-mentioned adjuvant and other compositions for this reason and to know that usually the knowledgeable knows, and does not give unnecessary details in addition at this.
Moreover, when composition for skin of the present invention was applied to cosmetics or external pharmaceuticals, its form generally can include but not limited to compound emulsion (emulsions), cream (cream), ointment (ointment), breast (milk), emulsion (lotion), serum (serum), ointment (paste) or dispersion liquid (dispersion) etc. such as W/O (water-in-oil-in-water) type or W/O medium oil (oil-in-water-in-oil) type in oil-in-water (oil-in-water) type or Water-In-Oil (water-in-oil) type or the water.Except above-mentioned form, when composition for skin of the present invention is applied to cosmetics, its form is for example the cleaning breast of lip gloss (lip colors), foundation cream (foundations), skin breast (milk), facial cream (cream), facial film (masks), gel (gel), aerosol (aerosol), creamy emulsion (milky lotions), Mu Si (mousse), dispersion liquid, cream (cream), patch (packs) and makeup removing usefulness, facial soap with soap dish (washsoap) etc. also, and the present invention is not limited to above-mentioned the act.
Below enumerate several preferred embodiments, the more application of elaboration composition for skin of the present invention whereby, however it is not in order to limiting the present invention, so protection scope of the present invention is when looking accompanying being as the criterion that the application's claim scope defined.
Embodiment one
The water-insoluble collagen protein of dough shape that weight is about 680 g is dissolved in 1650 g the aqueous phase liquid, and again that weight is the about 550 g oil phase liquid of 2-Methylpentadecane more than 90% that contains adds wherein and stirs.Afterwards, it is even to add in the about 115 g emulsifier system of weight emulsifying, with the raw material as cosmetics, wherein aforesaid emulsifier system is made up of weight about 60 g Polyethylene Glycol-30 dimerization hydroxy stearic acid ester (PEG-30 dipolyhydroxystearate) and the about 55 g stearic fat alcohol ether of polypropylene glycol-15 (PPG-15 stearyl ether) of weight.
Embodiment two
The collagen protein aqueous solution of the hydrolysis that weight is about 340 g is dispersed in the about 120 g emulsifier system of the about 600 g oily wax of weight and weight, with the raw material as cosmetics, wherein aforesaid emulsifier system is made up of to about 60 g PPG-20 oleyl ether between about 90 g to about 60 g PEG-40 olive oil glyceride and weight between about 30 g weight.
Embodiment three
The water-insoluble collagen protein of dough shape that weight is about 500 g is dissolved in 1200 g the aqueous phase liquid, and again that weight is the about 550 g oil phase liquid of zamene (squalene) more than 90% that contains adds wherein and stirs.Afterwards, it is even to add in about 145 g emulsifier system emulsifying, with the raw material as the external preparation for skin pharmaceuticals, wherein aforesaid emulsifier system is made up of to about 45 g stearic fat alcohol ether of polypropylene glycol-15 for about 65 g to about 50 g Polyethylene Glycol-30 dimerization hydroxy stearic acid esters and weight for about 30 g weight.
Embodiment four
With about 550 g the containing in the collagen protein aqueous solution that the oil phase liquid of zamene more than 90% adds about 1000 g hydrolysis and stir of weight.Afterwards, add in about 140 g emulsifier system, with the raw material as the external preparation for skin pharmaceuticals, wherein aforesaid emulsifier system is made up of to about 70 g PEG-40 glyceryl cocoate (PEG-40 glyceryl cocoate) for about 105 g to about 70 g PPG-4 ceteareth-12 (PPG-4 ceteareth-12) and weight for about 35 g weight.
In brief, composition for skin of the present invention is characterized in that the high concentration protein fiber is dispersed in the emulsifier system of being made up of at least one non-silicone surfactants.Compared to the processing technology of known cosmetics or external pharmaceuticals, only the water-solubility collagen of low concentration (being no more than about 1 percentage by weight) can be soluble in the aqueous phase earlier behind the solution, other compositions with cosmetics or external pharmaceuticals mix again.Composition for skin of the present invention is characterised in that the mentioned emulsifier system is not only applicable to the various forms of collagen protein of dissolving, collagen protein, water-solubility collagen and water-insoluble collagen protein such as collagen protein, hydrolysis, but also the collagen protein of solubilized higher concentration, its concentration can be up between 0.5 percentage by weight to 40 percentage by weight, the step and the time of more simplifying external pharmaceuticals or process for producing cosmetic simultaneously.In addition,, except the shortcoming that can improve known emulsifier system, also can be applicable to the raw material of cosmetics or external pharmaceuticals owing to there is no siliceous composition in the emulsifier system of the present invention, this be known techniques far away from part of the present invention.
By the invention described above preferred embodiment as can be known, use composition for skin of the present invention, its advantage is the high concentration protein fiber is dispersed in the emulsifier system of being made up of at least one non-silicone surfactants, perhaps protein fibre is dispersed in oily wax and the emulsifier system formed by at least one non-silicone surfactants in.Owing to there is no siliceous composition in the emulsifier system of the present invention, can improve the shortcoming of known emulsifier system, to be applied to the raw material of cosmetics or external pharmaceuticals.
Though the present invention discloses as above with several preferred embodiments; yet it is not in order to limit the present invention; in every technical field any have know the knowledgeable usually; without departing from the spirit and scope of the present invention; when the change that can do various equivalences or replacement, so protection scope of the present invention is when looking accompanying being as the criterion that the application's claim scope defined.
Claims (13)
1. composition for skin comprises at least:
One emulsifier system, this emulsifier system is made up of at least one non-silicone surfactants, and wherein the structural formula of this non-silicone surfactants (I) is shown below:
X
m1[-O-(C
m2)
n-O-]H
m3 (I)
Wherein X is selected from by C8-C24 fatty acid carbonyl (C7-CO-to C23-CO-), C8-C24 aliphatic alcohol polyether [(C8-O-)
pTo (C24-O)
p], C8-C24 fatty acid-polyglycerol ester base [C7-COO-(CH
2CH
2OHCH
2-)
qTo C23-COO-(CH
2CH
2OHCH
2-)
q] and the group that forms of derivant, m1 is 1 or 2, and m2 is 2 or 3, and m3 is 0 or 1, m
1+ m
3Equal 2, n is the integer between 10 to 100, and p is the integer between 1 to 20, and q is the integer between 1 to 3; And
One protein fibre, this protein fibre is dispersed in this emulsifier system.
2. composition for skin as claimed in claim 1, the content that it is characterized in that this protein fibre are between 0.5 percentage by weight to 40 percentage by weight.
3. composition for skin as claimed in claim 1 is characterized in that this protein fibre is selected from a group that is made up of collagen protein, water-solubility collagen and the water-insoluble collagen protein of collagen protein, hydrolysis.
4. composition for skin as claimed in claim 1, the content that it is characterized in that this emulsifier system are between 0.1 percentage by weight to 90 percentage by weight.
5. composition for skin as claimed in claim 1 is characterized in that this skin is applicable to cosmetics or external pharmaceuticals with the constituent of emulsion-type.
6. composition for skin as claimed in claim 5 is characterized in that this composition for skin is between 1 percentage by weight to 100 percentage by weight in the content of these cosmetics or these external pharmaceuticals.
7. composition for skin comprises at least:
One oily wax;
One emulsifier system, this emulsifier system formed by at least one non-silicone surfactants and with this oil wax uniform mixing, wherein the structural formula of this non-silicone surfactants is as shown in the formula shown in (I):
X
m1[-O-(C
m2)
n-O-]H
m3 (I)
Wherein X is selected from by C8-C24 fatty acid carbonyl (C7-CO-to C23-CO-), C8-C24 aliphatic alcohol polyether [(C8-O-)
pTo (C24-O-)
p], C8-C24 fatty acid-polyglycerol ester base [C7-COO-(CH
2CH
2OHCH
2-)
qTo C23-COO-(CH
2CH
2OHCH
2-)
q] and the group that forms of derivant, m1 is 1 or 2, and m2 is 2 or 3, and m3 is 0 or 1, m
1+ m
3Equal 2, n is the integer between 10 to 100, and p is the integer between 1 to 20, and q is the integer between 1 to 3; And
One protein fibre, this protein fibre is dispersed in this emulsifier system.
8. composition for skin as claimed in claim 7, the content that it is characterized in that this protein fibre are between 0.5 percentage by weight to 40 percentage by weight.
9. composition for skin as claimed in claim 7 is characterized in that this protein fibre is selected from a group that is made up of collagen protein, water-solubility collagen and the water-insoluble collagen protein of collagen protein, hydrolysis.
10. composition for skin as claimed in claim 7, the content that it is characterized in that this emulsifier system are between 0.1 percentage by weight to 80 percentage by weight.
11. composition for skin as claimed in claim 7, the content that it is characterized in that this oil wax are between 10 percentage by weight to 90 percentage by weights.
12. composition for skin as claimed in claim 7 is characterized in that this composition for skin is applicable to cosmetics or external pharmaceuticals.
13. composition for skin as claimed in claim 12 is characterized in that this composition for skin is between 1 percentage by weight to 100 percentage by weight in the content of these cosmetics or these external pharmaceuticals.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510082401 CN1887252A (en) | 2005-06-30 | 2005-06-30 | Composition for skin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510082401 CN1887252A (en) | 2005-06-30 | 2005-06-30 | Composition for skin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1887252A true CN1887252A (en) | 2007-01-03 |
Family
ID=37576531
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510082401 Pending CN1887252A (en) | 2005-06-30 | 2005-06-30 | Composition for skin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1887252A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110114061A (en) * | 2016-12-28 | 2019-08-09 | 小林制药株式会社 | Topical composition |
-
2005
- 2005-06-30 CN CN 200510082401 patent/CN1887252A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110114061A (en) * | 2016-12-28 | 2019-08-09 | 小林制药株式会社 | Topical composition |
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Open date: 20070103 |