CN1883896B - Wood protective agent - Google Patents
Wood protective agent Download PDFInfo
- Publication number
- CN1883896B CN1883896B CN2006100277058A CN200610027705A CN1883896B CN 1883896 B CN1883896 B CN 1883896B CN 2006100277058 A CN2006100277058 A CN 2006100277058A CN 200610027705 A CN200610027705 A CN 200610027705A CN 1883896 B CN1883896 B CN 1883896B
- Authority
- CN
- China
- Prior art keywords
- bravo
- permethrin
- alkyl
- timber
- dimethyl ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a timber protective agent comprising the following constituents (by weight percent): quaternary ammonium salt 13-15%, chloroguanide 3-5%, tetramethrin 1-3%, emulsifying agent 9-11% and balancing dissolvent.
Description
Technical field
The present invention relates to a kind of protective agent, especially relate to a kind of timber protective agent.
Background technology
The general timber preservative in the world today mainly is copper, chromium, arsenic (CCA), copper amine (ammonia) quaternary ammonium salt (ACQ) and brass file (CA) etc. because the arsenic chromium among the CCA all is noxious material, easily cause damage to human body, during especially indoor use, bigger to the harm of human body.In the prior art, begun to substitute CCA by efficient low toxic and environment-friendly anticorrisive agent such as ACQ, CA.China's wood preservation industry is in new developing period, CCA and ACQ timber preservative are all using simultaneously, antiseptic timber and woodwork greatly part all are used for the open air, because cuprammonium series anticorrisive agent all has color, and the volatilization of its solvent brings harmful effect to environment, so often limiting in the present anticorrosion wooden inlet chamber being extensive use of, therefore, pressing for that a kind of colourless nothing of development is smelt, environment-friendly type, multi-functionally be suitable for the timber protective agent that indoor and outdoor is widely used.
Summary of the invention
Purpose of the present invention mainly is that timber protective agent easily causes harmful effect to environment in the prior art in order to solve, and is not suitable for the deficiency of indoor use, provides that a kind of colourless nothing is smelt, environment-friendly type, multi-functionally is suitable for the timber protective agent that indoor and outdoor is widely used.
For realizing above purpose, the utility model is achieved through the following technical solutions:
A kind of timber protective agent is characterized in that, each component title and weight percentage are:
Quaternary ammonium salt 13-15%
Bravo 3-5%
Permethrin 1-3%
Emulsifying agent 9-11%
The solvent surplus.
Preferably, each component title and percentage by weight are:
Quaternary ammonium salt 13.9-14.7%
Bravo 3.8-4.2%
Permethrin 1.9-2.1%
Emulsifying agent 9.5-10.5%
The solvent surplus.
Most preferably be that each component title and percentage by weight are
Quaternary ammonium salt 14%
Bravo 4%
Permethrin 2%
Emulsifying agent 10%
The solvent surplus.
Wherein, described quaternary ammonium salt is two alkyl-dimethyl ammonium chlorides.
Preferably, the arbitrary alkyl carbon chain length of two alkyl of described pair of alkyl-dimethyl ammonium chloride is C
8-C
18
Described pair of alkyl-dimethyl ammonium chloride is: two octyldimethyl ammonium chlorides; Two nonyl alkyl dimethyl ammonium chlorides; Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides; Two undecyl alkyl dimethyl ammonium chlorides; Two dodecyl dimethyl ammonium chlorides; The double tridecyl alkyl dimethyl ammonium chloride; Two myristyl alkyl dimethyl ammonium chlorides; Varisoft 432PPG; Dioctadecyl dimethyl ammonium chloride; Most preferably be two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides.
Wherein said Bravo (Chlorothalonil), chemical name is: 2,4,5,6-tetrachloro-1, the 3-dicyanobenzenes, molecular formula is: C
8CL
4N
2, can on market, buy acquisition, sharp port, Jiangyin City, Jiangsu Province Fine Chemical Works, all there is production in favorable to the people chemical plant, Xinyi city.
Wherein said Permethrin claims Permanone again, and chemical name is: (3-benzyloxy phenoxy base) cis, trans-(±)-3-(2.2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid fat.
Wherein said solvent is dimethylbenzene or other organic solvents, and the dimethylbenzene molecular formula is C
8H
10Emulsifying agent is an Arlacel-80, and name is called sorbitan monooleate (nonionic surface active agent), can also be other nonionic surface active agent.
Preparation method: at normal pressure, under temperature 15-35 ℃, at first solvent and emulsifying agent are dropped in the preparing tank, drop into Bravo and permethrin then, utilize high-shearing dispersion emulsifying machine to carry out stirring and emulsifying 30-60 minute, drop into quaternary ammonium salt at last and stir mixing in 30-60 minute again, make the creamy timber preservative, can be during use by concentration requirement, dilute with water is that protective liquid adopts methods such as spary, immersion or vacuum pressure impregnating to handle timber.
Timber protective agent among the present invention has following beneficial effect after testing:
1, fungicidal properties:
This agent is carried out mould proof test through indoor to rubber wood timber, and concentration is 1.0%, inhales dose 0.2523kg/m
3, preventing efficiency is 93.07%, than other timber preservatives (CCA and ACQ) for good; Working concentration is 0.4% and 0.8% pair of poplar, the test of masson pine timber, and its anti-mould and aspergillus niger effect are better than penta sodium pentachlorophenate (NaPCP).
2, anti-variable color performance:
This agent prevents that to masson pine timber discoloration test concentration is 0.1%～0.7% through indoor, inhales dose 0.7220～5.6109kg/m
3, preventing efficiency is 100%.
3, antiseptic property:
This agent is the examination material with the populus ussuriensis, and covering bacterium with white rot suede leather serves as that the examination bacterium carries out indoor corrosion-resistanting test, during presentation of results drug concentration 0.5%, keeps inhaling dose 3.8kg/m
3, the sample mass loss late is 7.2%, for good, reaches strong corrosion resistant grade than CCA anticorrisive agent; Carry out the ground with this agent and CCA anticorrisive agent again and be subjected to the open-air simulation comparison test of bacterium, result of the test shows that it is 0.8～1.6kg/m that its toxicity beginning is imitated approximation
3, than the 3.9kg/m of CCA
3For good, the toxicity beginning effect value after running off also remains on 1.6～3.2kg/m
3
4, termite-proof performance:
In the indoor test medicine concentration 0.125,0.25,0.5% o'clock of carrying out, the average quality index of timber moth erosion is respectively 9.3,10,10 (index is to represent that sample lost efficacy at 0 o'clock, represents that sample did not have remarkable moth erosion at 10 o'clock) to yellow limb reticulitermes flavipe in this agent; Bury test underground through the field again, after 1 year, observe, 1.0% and 2.0% concentration, its termite moth erosion performance figure is respectively 8.6 and 9.7, and contrasts (non-processor) examination material, and performance figure has been 6.4.
5, insect protected performance:
Confirm through anti-moth eating test, this agent capsule is stolen by control class and Ambeodontus tristis all very effective, as long as its effective maintenance dose is at 1.0kg/m
3Below can kill these fully and eat into wooden insect.
The specific embodiment
Below in conjunction with specific embodiment component of the present invention is described further:
Embodiment 1: each weight percentages of components is:
Two octyldimethyl ammonium chlorides; 13%
Bravo 3%
Permethrin 1%
Dimethylbenzene 74%
Sorbitan monooleate 9%;
Embodiment 2: each weight percentages of components is:
Two octyldimethyl ammonium chlorides; 15%
Bravo 5%
Permethrin 3%
Dimethylbenzene 66%
Sorbitan monooleate 11%;
Embodiment 3: each weight percentages of components is:
Two myristyl alkyl dimethyl ammonium chlorides; 14%
Bravo 4%
Permethrin 2%
Dimethylbenzene 70%
Sorbitan monooleate 10%;
Embodiment 4: each weight percentages of components is:
Two myristyl alkyl dimethyl ammonium chlorides; 13.7%
Bravo 4.2%
Permethrin 2.1%
Dimethylbenzene 70%
Sorbitan monooleate 10%;
Embodiment 5: each weight percentages of components is:
Two myristyl alkyl dimethyl ammonium chlorides; 13.9%
Bravo 3.8%
Permethrin 1.9%
Dimethylbenzene 70.4%
Sorbitan monooleate 10%;
Embodiment 6: each weight percentages of components is:
Two myristyl alkyl dimethyl ammonium chlorides; 14.5%
Bravo 4.1%
Permethrin 2.0%
Dimethylbenzene 69.4%
Sorbitan monooleate 10%;
Embodiment 7: each weight percentages of components is:
Two dodecyl dimethyl ammonium chlorides; 13%
Bravo 3%
Permethrin 1%
Dimethylbenzene 74%
Sorbitan monooleate 9%;
Embodiment 8: each weight percentages of components is:
Two dodecyl dimethyl ammonium chlorides; 15%
Bravo 5%
Permethrin 3%
Dimethylbenzene 67%
Sorbitan monooleate 10%;
Embodiment 9: each weight percentages of components is:
Two dodecyl dimethyl ammonium chlorides; 14%
Bravo 4%
Permethrin 2%
Dimethylbenzene 70%
Sorbitan monooleate 10%;
Embodiment 10: each weight percentages of components is:
Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides; 13%
Bravo 3%
Permethrin 1%
Dimethylbenzene 74%
Sorbitan monooleate 9%;
Embodiment 11: each weight percentages of components is:
Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides; 15%
Bravo 5%
Permethrin 3%
Dimethylbenzene 66%
Sorbitan monooleate 11%;
Embodiment 12: each weight percentages of components is:
Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides; 13.9%
Bravo 3.8%
Permethrin 1.9%
Dimethylbenzene 70.9%
Sorbitan monooleate 9.5%;
Embodiment 13: each weight percentages of components is:
Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides; 14.7%
Bravo 4.2%
Permethrin 2.1%
Dimethylbenzene 68.5%
Sorbitan monooleate 10.5%;
Embodiment 14: each weight percentages of components is:
Two decyl alkyl dimethyl ammonium chlorides; 13.9%
Bravo 4.2%
Permethrin 1.9%
Dimethylbenzene 70%
Sorbitan monooleate 10%;
Embodiment 15: each weight percentages of components is:
Two decyl alkyl dimethyl ammonium chlorides; 14.2%
Bravo 3.5%
Permethrin 2.3%
Dimethylbenzene 70%
Sorbitan monooleate 10%;
Embodiment 16: each weight percentages of components is:
Two certain herbaceous plants with big flowers base alkyl dimethyl ammonium chlorides; 14%
Bravo 4%
Permethrin 2%
Dimethylbenzene 70%
Sorbitan monooleate 10%;
Embodiment 17: each weight percentages of components is:
Two nonyl alkyl dimethyl ammonium chlorides; 14.3%
Bravo 4.1%
Permethrin 2.0%
Dimethylbenzene 69.6%
Sorbitan monooleate 10%;
Embodiment 18: each weight percentages of components is:
Two undecyl alkyl dimethyl ammonium chlorides; 14.2%
Bravo 4%
Permethrin 2.1%
Dimethylbenzene 70.2%
Sorbitan monooleate 9.5%;
Embodiment 19: each weight percentages of components is:
The double tridecyl alkyl dimethyl ammonium chloride; 14%
Bravo 4%
Permethrin 2%
Dimethylbenzene 70%
Sorbitan monooleate 10%;
Preparation method: at normal pressure, under temperature 15-35 ℃, at first solvent and emulsifying agent are dropped in the preparing tank, drop into Bravo and permethrin then, utilize high-shearing dispersion emulsifying machine to carry out stirring and emulsifying 30-60 minute, drop into quaternary ammonium salt at last and stir mixing in 30-60 minute again, make the creamy timber preservative, can be during use by concentration requirement, dilute with water is that protective liquid adopts methods such as spary, immersion or vacuum pressure impregnating to handle timber.
Above embodiment is made product carries out following Performance Detection:
1, fungicidal properties:
This agent is carried out mould proof test through indoor to rubber wood timber, and concentration is 1.0%, inhales dose 0.2523kg/m
3, preventing efficiency is 93.07%, than other timber preservatives (CCA and ACQ) for good; Working concentration is 0.4% and 0.8% pair of poplar, the test of masson pine timber, and its anti-mould and aspergillus niger effect are better than penta sodium pentachlorophenate (NaPCP).
2, anti-variable color performance:
This agent prevents that to masson pine timber discoloration test concentration is 0.1%～0.7% through indoor, inhales dose 0.7220～5.6109kg/m
3, preventing efficiency is 100%.
3, antiseptic property:
This agent is the examination material with the populus ussuriensis, and covering bacterium with white rot suede leather serves as that the examination bacterium carries out indoor corrosion-resistanting test, during presentation of results drug concentration 0.5%, keeps inhaling dose 3.8kg/m
3, the sample mass loss late is 7.2%, for good, reaches strong corrosion resistant grade than CCA anticorrisive agent; Carry out the ground with this agent and CCA anticorrisive agent again and be subjected to the open-air simulation comparison test of bacterium, result of the test shows that it is 0.8～1.6kg/m that its toxicity beginning is imitated approximation
3, than the 3.9kg/m of CCA
3For good, the toxicity beginning effect value after running off also remains on 1.6～3.2kg/m
3
4, termite-proof performance:
In the indoor test medicine concentration 0.125,0.25,0.5% o'clock of carrying out, the average quality index of timber moth erosion is respectively 9.3,10,10 (index is to represent that sample lost efficacy at 0 o'clock, represents that sample did not have remarkable moth erosion at 10 o'clock) to yellow limb reticulitermes flavipe in this agent; Bury test underground through the field again, after 1 year, observe, 1.0% and 2.0% concentration, its termite moth erosion performance figure is respectively 8.6 and 9.7, and contrasts (non-processor) examination material, and performance figure has been 6.4.
5, insect protected performance:
Confirm through anti-moth eating test, this agent capsule is stolen by control class and Ambeodontus tristis all very effective, as long as its effective maintenance dose is at 1.0kg/m
3Below can kill these fully and eat into wooden insect.
Claims (5)
1. a timber protective agent is characterized in that, each component title and weight percentage are:
Quaternary ammonium salt 13-15%
Bravo 3-5%
Permethrin 1-3%
Emulsifying agent 9-11%
The solvent surplus,
Wherein, described quaternary ammonium salt is two alkyl-dimethyl ammonium chlorides, and described solvent is a dimethylbenzene, and emulsifying agent is a sorbitan monooleate.
2. timber protective agent according to claim 1 is characterized in that, each component title and percentage by weight are:
Quaternary ammonium salt 13.9-14.7%
Bravo 3.8-4.2%
Permethrin 1.9-2.1%
Emulsifying agent 9.5-10.5%
The solvent surplus.
3. timber protective agent according to claim 2 is characterized in that, each component title and percentage by weight are:
Quaternary ammonium salt 14%
Bravo 4%
Permethrin 2%
Emulsifying agent 10%
The solvent surplus.
4. timber protective agent according to claim 1 is characterized in that, the arbitrary alkyl carbon chain length of two alkyl of described pair of alkyl-dimethyl ammonium chloride is C
8-C
18, described pair of alkyl carbon chain length is identical or inequality.
5. timber protective agent according to claim 4 is characterized in that, two alkyl of described pair of alkyl-dimethyl ammonium chloride are two certain herbaceous plants with big flowers bases.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100277058A CN1883896B (en) | 2006-06-13 | 2006-06-13 | Wood protective agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100277058A CN1883896B (en) | 2006-06-13 | 2006-06-13 | Wood protective agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1883896A CN1883896A (en) | 2006-12-27 |
| CN1883896B true CN1883896B (en) | 2010-12-08 |
Family
ID=37582262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100277058A Active CN1883896B (en) | 2006-06-13 | 2006-06-13 | Wood protective agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1883896B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241035B (en) * | 2011-07-23 | 2016-08-31 | 李艳丽 | A kind of Wood protecting agent |
| CN102513280A (en) * | 2011-12-07 | 2012-06-27 | 青岛富臣化工有限公司 | Construction method for preventing transparent polyurethane paint film for outdoor solid wood product from being whity |
| CN102941606A (en) * | 2012-11-27 | 2013-02-27 | 东兴市观福古典红木家具有限公司 | Wood preservative |
| CN103223685A (en) * | 2013-04-11 | 2013-07-31 | 冯勇 | Rubber wood impregnation treatment method |
| CN106217554A (en) * | 2016-06-06 | 2016-12-14 | 杨引利 | A kind of former bamboo protective agent and preparation method thereof |
| CN110091400A (en) * | 2019-01-24 | 2019-08-06 | 南京天诗蓝盾生物科技有限公司 | A kind of environmentally friendly wood preservative and preparation method thereof |
| CN111469242A (en) * | 2020-03-21 | 2020-07-31 | 上海华山家具有限公司 | Furniture section bar processing protection technology |
| CN113854320A (en) * | 2021-10-18 | 2021-12-31 | 阜南县猛发工艺品有限公司 | Insect-proof mildew-proof agent for bamboo rattan woven product and preparation method thereof |
| CN115956573A (en) * | 2022-12-15 | 2023-04-14 | 江苏维尤纳特精细化工有限公司 | Novel bactericidal composition containing chlorothalonil |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001091925A1 (en) * | 2000-05-31 | 2001-12-06 | Board Of Control Of Michigan Technological University | Compositions and methods for wood preservation |
| CN1436465A (en) * | 2002-02-09 | 2003-08-20 | 王文久 | Bamboo and wood protecting agent |
| CN1504087A (en) * | 2002-11-29 | 2004-06-16 | 中国石油天然气股份有限公司 | Composite bactericide |
| CN1727142A (en) * | 2004-12-16 | 2006-02-01 | 龙有前 | Wood protective agent |
-
2006
- 2006-06-13 CN CN2006100277058A patent/CN1883896B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001091925A1 (en) * | 2000-05-31 | 2001-12-06 | Board Of Control Of Michigan Technological University | Compositions and methods for wood preservation |
| CN1436465A (en) * | 2002-02-09 | 2003-08-20 | 王文久 | Bamboo and wood protecting agent |
| CN1504087A (en) * | 2002-11-29 | 2004-06-16 | 中国石油天然气股份有限公司 | Composite bactericide |
| CN1727142A (en) * | 2004-12-16 | 2006-02-01 | 龙有前 | Wood protective agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1883896A (en) | 2006-12-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1883896B (en) | Wood protective agent | |
| CN102349506B (en) | Ultralow-volume solvent containing Flusilazole | |
| CN101284386B (en) | Nano wood antiseptics and manufacturing method thereof | |
| CN102273441B (en) | Ultralow volume liquid containing azoxystronbin | |
| CN105076132B (en) | A kind of oil type agricultural chemicals synergist and preparation method thereof | |
| CN102273442A (en) | Ultralow volume liquid containing epoxiconazole | |
| CN102273440A (en) | Ultralow volume liquid containing clothianidin | |
| CN102273445A (en) | Superlow-capacity liquid reagent containing prochloraz | |
| CN104824013A (en) | Film-spreading oil agent containing chlorantraniliprole and chloronicotinyl insecticide | |
| CN104210001A (en) | Insect and mould inhibitor and application thereof | |
| US20240057594A1 (en) | Solutions for enhancing the effectiveness of insecticides and fungicides on living plants and related methods | |
| EP3285580A1 (en) | Solutions for enhancing the effectiveness of insecticides and fungicides on living plants and related methods | |
| CN106665673A (en) | Wood preservative and preparation method thereof | |
| US11779016B2 (en) | Solutions for enhancing the effectiveness of insecticides and fungicides on living plants and related methods | |
| CN106393348B (en) | A kind of timber preservative containing compound SchiglautoneA | |
| EP0018341B1 (en) | A method and composition for the preservation of plants | |
| CN106378840B (en) | A kind of timber preservative | |
| US4203253A (en) | Process for increasing oleoresin synthesis in pinus species | |
| KR100553007B1 (en) | Composition for Wood Preservation | |
| CN113973835A (en) | Insecticidal composition containing brofenpyrad and cyfluthrin and application thereof | |
| CN110014488A (en) | A kind of timber preservative and its application | |
| CN108656283A (en) | A kind of timber preservative | |
| CN103688955A (en) | Ultra-low volume liquid containing ametoctradin and triazole bactericide composition as well as preparation method and application thereof | |
| CN109042647A (en) | Purposes and repellant of the beta-myrcene as striped rice borer female adult repellant component | |
| CN103719124A (en) | Ultra-low volume liquid containing cycloxaprid and insect growth regulator pesticide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191223 Address after: 214500 No.19 Fukang Road, Xieqiao Town, Jingjiang City, Taizhou City, Jiangsu Province Patentee after: Jingjiang Guolin Wood Co. Ltd. Address before: 200051, building 1, building 518, No. 4 West Zhongshan Road, Shanghai, Changning District Patentee before: Shanghai Dabutong Wood Technology Co., Ltd. |
|
| TR01 | Transfer of patent right |