CN1870973A - Antidandruff shampoo composition - Google Patents
Antidandruff shampoo composition Download PDFInfo
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- CN1870973A CN1870973A CNA2004800316013A CN200480031601A CN1870973A CN 1870973 A CN1870973 A CN 1870973A CN A2004800316013 A CNA2004800316013 A CN A2004800316013A CN 200480031601 A CN200480031601 A CN 200480031601A CN 1870973 A CN1870973 A CN 1870973A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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Abstract
A shampoo composition comprising: an anti-dandruff agent in an amount of from 0.01% to 10% by weight; beeswax in an amount of from 0.01% to 10% by weight; and a silicone in an amount of from 0.01% to 10% by weight.
Description
The present invention relates to the purposes of the component of shampoo composite and said composition.
There's a widespread conviction that for people, and Malassezia yeasts is the main cause that produces the dandruff as malassezia furfur (Malasseziafurfur).Be used for the treatment of the main of the dandruff in the market, if not only, Intervention Strategy is the local application antifungal, as Zinc Pyrithione (ZnPTO), climbazole (climbazole), octopirox and ketoconazole, they discharge from shampoo usually.These antifungal are removed (or reducing its amount at least) horse traction color and are belonged to fungus (Malassezia) from scalp, and the effective treatment to dandruff conditions is provided.
Some compositions that is used for the treatment of the dandruff is felt it is very coarse on hair, make the hair drying handled, coarse and be difficult to combing.
CA 2078375 has described a kind of shampoo composite that is used for the treatment of headache and pain, and it comprises the natural anti-pain of specified quantitative and oil and the Cera Flava and the silicone oil of headache.In CA2078375, do not mention the dandruff agent or disclose the effect of relevant Cera Flava or silicone oil.
EP 0502616 discloses a kind of make-up composition of gentleness, and it comprises the poly-sugar surfactant of joining of alkyl, wax and choosing any one kind of them or multiple thickening agent, and wherein said composition has specified viscosity.Described wax can be Cera Flava.But EP 0502616 does not describe any dandruff compositions or comprises the compositions of siloxanes.
EP 0413417 has described a kind of hair conditioning shampoo, it comprises specific anionic detergent, water-insoluble hair conditioning auxiliary agent such as siloxanes, polyethylene, paraffin hydrocarbon, isoparaffin, paraffin oil, microwax, C18-36 (mixing) fatty acid and/or triglyceride, stearic acid stearyl and Cera Flava, stabilizing agent and water-bearing media.Be considered to owing to comprised due to the specified anionic detergent for the improvement of hair conditioning.
EP 0471606 discloses stable liquid fiber-and composition for processing skin, and it has been owing to comprised stabilizing agent, a kind of long-chain alcohol or its suitable derivatives and have improved high-temperature stability.Said composition also comprises liquid medium, emulsifying agent and insoluble fiber or skin treatment material in liquid medium in addition.The example of described skin treatment material comprises: paraffinic base paraffin; Isoparaffin; Mineral oil; Microwax; Cera Flava; Organo-silicon compound comprise siloxanes and amodimethicone; Polyethylene; C
18-36Triglyceride; Spice; Sunscreen and dandruff agent.
Especially, EP 0471606 has described the dandruff compositions, and it comprises the anionic detergent of specified quantitative, water-insoluble dandruff agent, long-chain alcohol and water.
Also need effectively to be used for the treatment of the shampoo composite of the dandruff, it can provide improved foam quality (foam quality), can make the hair of handling have improved conditioning performance, as, more slick sensation, more fluffy, easier dried comb and can not damage the effectiveness of dandruff treatment.
Also need to have the gentle degree of increase and/or the shampoo composite of improved foam quality and/or smoothness and/or conditioning effect.
According to a first aspect of the invention, provide a kind of shampoo composite, it comprises: content is the dandruff agent of 0.01 weight %-10 weight %; Content is the Cera Flava of 0.01 weight %-10 weight %; With content be the siloxanes of 0.01 weight %-10 weight %.
Another aspect of the present invention, the purposes in the shampoo composite of being combined in of Cera Flava and siloxanes is provided, and it is selected from following performance in order to one or more to be provided: the gentle degree of increase, improved foam quality, improved conditioning effect and the easily processing effect of improved hair.Term " improved " meaning is meant that the shampoo composite of the combination that the present invention includes Cera Flava and siloxanes is better than the shampoo composite that those do not comprise the combination of Cera Flava and siloxanes.
One side more of the present invention provides Cera Flava and the siloxanes purposes in the dandruff shampoo composite, and it is in order to provide improved foaming properties and dandruff removing agent is effectively deposited.
The present invention relates to wonderful discovery to a certain extent, be in the shampoo composite combination of Cera Flava and siloxanes can make such as, the gentleness degree, foam quality, performances such as conditioning and the easy treatment effect of hair such as slickness, easy cardability, hair volume reduction obtain exceeding unexpected improvement.
Especially, compositions of the present invention can provide such shampoo, and gentle still but can formation has as exceeding the foam of unexpected creaminess performance in described shampoo.As everyone knows, gentle shampoo composite produces the foam with low-qualityer sensation and outward appearance usually, and therefore, gentle shampoo may be not too attractive to consumer.Do not wish to be entangled in theory, we believe to have synergism between Cera Flava and siloxanes, can make compositions of the present invention have the easy treatment effect of improved hair.
In addition, the present invention relates to following discovery to a certain extent, promptly, siloxanes and Cera Flava may not can disturb the dandruff agent to deposit from the dandruff shampoo composite that wherein above-mentioned two kinds of materials are all included, therefore provide to have, for example the dandruff compositions of improved foaming properties.
The dandruff agent can suitably be to well known to a person skilled in the art to treat and/or prevent any dandruff agent that forms the dandruff.Especially, described dandruff agent can be any antimicrobial that is suitable for treating and/or preventing the dandruff.
The dandruff agent can be the mixture of unification compound or two or more chemical compounds.
The preferred amount of dandruff agent is 0.05 weight %-5 weight %, more preferably 0.5 weight %-2 weight %, especially preferred 0.5 weight %-1 weight %.
The dandruff agent can suitably be a granule or non-particulate, and can be water-fast, that is, under 25 ℃, be insoluble in the compositions, or water miscible, that is, under 25 ℃, be dissolved in the compositions.
If the dandruff agent is the dandruff agent of granule shape, then it can choose wantonly have multiple known in the art in order to promote it to deposit to the size on hair and/or the skin.
In one embodiment, the dandruff agent can comprise the insoluble particles of metal pyrithione, wherein at least about the particle size of 90 weight % be 5 microns or below.
Preferably, the dandruff agent is selected from: 1-hydroxyl-2-pyridone, Zinc Pyrithione, selenium sulfide, sulfur, ketoconazole, the luxuriant alkane of Dichlorobenzene base imidazo two , clotrimazole, chlorobenzene first chlorine imidazoles, his health azoles of clothing, miconazole, climbazole, oxygen health azoles, tioconazole (tioconazole), sulconazole (sulconazole), butoconazole, fluconazol, piroctone olamine and its mixture.
Preferably, the dandruff agent is dissolved in the described compositions.
In a further preferred embodiment, the dandruff agent comprises the azoles ring.Preferably, the dandruff agent is selected from ketoconazole and climbazole and composition thereof.
In particularly preferred embodiments, the dandruff agent is a climbazole.
Compositions of the present invention comprises Cera Flava.Mellisic color can become yellow from white, by the brown black that becomes, this depend on produce mellisic Apis with pollen types.Any form all is applicable to the present invention.
Term " Cera Flava " is intended to comprise the natural Cera Flava and the Cera Flava synthetic and that replace of the unpurified or preferred purified state that obtains from honeycomb, and has been modified, for example by organically-modified Cera Flava.Term " synthetic and replacement " Cera Flava comprises the material that has with natural Cera Flava similarity.
Suitable organically-modified Cera Flava comprises, for example, the PEG-8 Cera Flava, polyglycerol-3 Cera Flava and silication Cera Flava, as contain the polydimethylsiloxane Cera Flava (dimethicone copolyol beeswax) of polyoxyethylene or polyoxypropylene side chain.
Preferably, the amount of Cera Flava in compositions is 0.1 weight %-5 weight % of composition total weight, more preferably 0.2 weight %-2.0 weight %, preferred especially 0.5 weight %-1.5 weight %.
In a preferred embodiment of the invention, Cera Flava is suspended in the compositions with the form of solid particle.
Be particularly preferred for mellisic form of the present invention through processing, purified or white beeswax.
In particularly preferred embodiments, Cera Flava is the Cera Flava through processing, as, those that can obtain from KosterKeunen company.
Siloxanes is insoluble in the aqueous matrix of shampoo composite of the present invention usually, therefore exists with emulsive form, and the siloxanes of existence is the form of dispersed particle.
The preferred amount of siloxanes is 0.05 weight %-5 weight % of composition total weight, more preferably 0.1 weight %-2 weight % of composition total weight.
Preferably, Cera Flava and the siloxanes total amount in compositions is greater than 1.0 weight % of composition total weight, more preferably greater than 1.1 weight %, as 1.2 weight %-5 weight %.
Preferably, the weight ratio of Cera Flava and siloxanes is 1: 4-3: 1, more preferably 1.5: 1-2.5: 1.In particularly preferred embodiments, the weight ratio of Cera Flava and siloxanes is approximately 2: 1.
The whole bag of tricks that is used for preparation siloxane particles emulsion of the present invention all is that this area is available, and is well-known, and the file record is arranged.For example, emulsion can perhaps be passed through siloxanes and water and emulsifying agent emulsifying (for example, siloxanes being mixed in the emulsifier solution of heating), perhaps by the combined preparation of machinery with chemical emulsification by with siloxanes and the mixed preparation of water high shear machinery.The other applicable technology that is used to prepare the siloxane particles emulsion is emulsion polymerisation.The siloxanes of emulsion polymerisation itself is referring to United States Patent (USP) 2,891,820 (Hyde), United States Patent (USP) 3,294,725 (Findlay) and United States Patent (USP) 3,360,491 (Axon).
The viscosity of siloxanes itself (not being the viscosity of emulsion or final shampoo composite) is preferably 10, in 000cps to the 5 1,000,000 cps scopes.Described viscosity can be by use glass capillary tube viscometer, according to as further in the step measurements described in the Dow Corning Corporate test method CTM004 (on July 20th, 1970).
Suitable siloxanes comprises polydiorganosiloxanepolyurea (polydiorganosiloxanes), and particularly its CTFA name is called the dimethione of polydimethylsiloxane.Example be viscosity under 25 ℃ up to the diformazan silicone liquid of 100,000 centistokes, it can be Viscasil series that is purchased from General Electric Co. Limited and DC 200 series that are purchased from Dow Corning.
Being suitable for equally in the present composition is the siloxanes of hydroxyl-functional, the polydimethylsiloxane that particularly has hydroxyl end groups, and its CTFA name is called dimethyl siloxane alcohol.
Be applicable to that the another kind of siloxanes that is included in the shampoo of the present invention is the siloxanes of amino-functional." amino-functional " meaning be meant comprise at least one primary, the second month in a season or tertiary amine group, or the siloxanes of quaternary ammonium group.
The siloxanes that is suitable for amino-functional of the present invention will have the mole % amine degree of functionality in the about 8.0 moles of % scopes of about 0.1-, the about 5.0 moles of % of preferably about 0.1--, the most preferably from about about 2.0 moles of % of 0.1-usually.
The viscosity of the siloxanes of amino-functional is not crucial especially, and it is can be suitably about 500 at about 100-, in the 000cst scope.
The example of the siloxanes of suitable amino-functional comprises that its CTFA name is called the polysiloxanes of " amino-terminated polydimethylsiloxane ".
The particular instance that is suitable for the siloxanes of amino-functional of the present invention is amodimethicone oil DC2-8220, DC2-8166, DC2-8466 and DC2-8950-114 (all these are all available from DowCorning) and GE1149-75 (available from General Electric Silicones).
Same suitable siloxane glue in addition." siloxane glue " expression molecular weight is 200,000-1,000,000 polydiorganosiloxanepolyurea, its specific example comprises polydimethylsiloxane glue, poly dimethyl silanol glue, polydimethylsiloxane/diphenyl/methyl ethylene silicone copolymers, dimethione/methyl ethylene silicone copolymers and composition thereof.Example comprises United States Patent (USP) 4,152, described in 416 (Spitzer) and those materials on the silicone rubber products tables of data SE30 of General Electric, SE 33, SE 54 and SE 76.
Be suitable for equally among the present invention have lightly crosslinked, the siloxane glue described in WO 96/31188.These materials can make hair tangible, fluffy and can finalize the design, and make hair have the good wet two kinds of conditioning effects of doing.
Be preferred for the emulsive siloxanes in the present composition, its average siloxanes particle diameter in compositions preferably is lower than 30 microns for being lower than 100 microns, more preferably 20 microns, most preferably is lower than 10 microns.
Particle diameter can use the 2600D ParticleSizer of Ma Erwen instrument company to measure by laser scattering method.
Suitable be used for silicone emulsion of the present invention and can have bought from the market with pre-emulsified form.Because preformed emulsion can be incorporated in the cleaning compositions by simple mixing, so this is particularly preferred.
The example of suitable preformed emulsion comprises emulsion DC2-1766 and the DC2-1784 that derives from Dow Corning.These are poly dimethyl silanol emulsions.Crosslinked siloxane glue equally also can obtain with pre-emulsified form, and it helps preparation.Preferred examples is can be with the material of DCX2-1787 from Dow Corning acquisition, and it is crosslinked poly dimethyl silanol latex solution.
Being particularly preferred for siloxanes of the present invention is SM 555, and it can obtain from GE Silicones.SM 555 is combinations of poly dimethyl silanol and triethylamine (TEA) dodecyl benzene sulfonate.Other combinations of siloxanes and sulfonate also can be used for compositions of the present invention.
Compositions of the present invention preferably includes the cleansing surfactants that hair can be accepted and be suitable for being locally applied to one or more cosmetics.
If be used for any emulsive component of compositions, as the emulsifying agent of emulsifying siloxanes be not enough to provide cleaning purpose, can have the surfactant of other component form.
Preferably, compositions of the present invention comprises at least a in order to the surfactant of cleaning effect to be provided.
Preferably, described other surfactant is an anion surfactant.
The suitable cleansing surfactants that can be used alone or in combination is selected from anionic, amphoteric and zwitterionic surfactant, and composition thereof.Cleansing surfactants can be the surfactant identical with emulsifying agent, or can be different with it.
In one embodiment of the invention, provide a kind of shampoo composite, it comprises: the anion surfactant of 1 weight %-50 weight %; 0.1 the amphoteric surfactant of weight %-10 weight %; 0.1 the Cera Flava of weight %-10 weight %; Siloxanes with 0.1 weight %-10 weight %.
The example of anion surfactant is alkyl sulfate, alkyl ether sulfate, alkylaryl sulfonate, alkanoyl isethionate, alkyl succinate, alkyl sulfo succinate, N-alkyl sarcosine salt, alkylphosphonic, alkyl ether phosphate, alkyl ether carboxy acid salt and alpha-olefins sulfonate, especially their sodium salt, magnesium salt, ammonium salt and monoethanolamine salt, diethanolamine salt and triethanolamine salt.Alkyl and acyl group contain 8-18 carbon atom and can be unsaturated usually.Each molecule of alkyl ether sulfate, alkyl ether phosphate and alkyl ether carboxy acid salt can contain 1-10 oxygen ethylene or oxypropylene unit.
The anion surfactant that is generally used in the present composition comprises oil base sodium succinate, lauryl 2-Sulfosuccinic acid ammonium, ammonium lauryl sulfate, dodecylbenzene sodium sulfonate, DBSA triethanolamine, cocoyl sodium isethionate, lauryl sodium isethionate and N-sodium lauryl sarcosinate.Most preferred anion surfactant is sodium lauryl sulfate, single lauryl nitranol, sodium laureth sulfate 1EO, 2EO and 3EO, ammonium lauryl sulfate and Zetesol AP 1EO, 2EO and 3EO.
The example of both sexes and zwitterionic surfactant comprises alkyl amine oxide, alkyl betaine, alkylamide propyl-betaine, alkyl sulfobetaines (sulfobetaines), alkyl glycinate, alkyl carboxyl glycinate, alkyl both sexes propionate (alkyl amphopropionates), alkyl both sexes glycinate, alkylamide propyl hydroxyl sulfo betaine, acyl taurine salt and acyl glutamate, and wherein alkyl and acyl group contain 8-19 carbon atom.The both sexes and the zwitterionic surfactant that are generally used for shampoo of the present invention comprise lauryl amine oxide, coco dimethyl azochlorosulfonate propyl lycine and preferred lauryl betaine, cocamidopropyl propyl amide (cocamidopropyl) betanin, cocos nucifera oil both sexes sodium propionate (sodium cocamphapropionate).Compositions of the present invention can comprise that also cosurfactant helps give described compositions aesthetic feeling, outward appearance or clean-up performance, and preferred embodiment is a non-ionic surface active agent, and its content can be up to the about weight 5% of 0 weight %-of composition total weight.
Preferred compositions sodium laureth sulfate (SLES) 2EO that is used for surfactant of the present invention, cocamido propyl betaine (CAPB) and cocos nucifera oil both sexes sodium acetate.The preferred amount of SLES is 5-20 weight %, and the preferred amount of CAPB is 1-5 weight %, and the preferred amount of cocos nucifera oil both sexes sodium acetate is 1-5 weight %.
For example, the representational ionic surfactant pack that can be included in the present composition is drawn together aliphatic series (C
8-C
18) alcohol of uncle or secondary, straight or branched or the condensation substance of phenol and alkylene oxide (being generally oxygen ethylene) and contain 6-30 oxyethylene group group usually.
Other representational ionic surfactant pack are drawn together monoalkyl-or dialkyl group alkanolamide.Example comprises the single isopropanol amide of coconut monoethanol amide or cocos nucifera oil diglycollic amide and cocos nucifera oil.
Other non-ionic surface active agent that can comprise in the present composition is APG (APGs).Usually APG contains with one or more glycosyl blocks the alkyl of link to each other (the optional abutment that passes through).Preferred APGs is defined by following formula:
RO-(G)
n
Wherein R is a branched-chain or straight-chain alkyl, and it can be saturated or unsaturated, and G is a glycosyl.
R can be the about C of average chain length
5-C
20Alkyl.R is preferably the about C of average chain length
8-C
12Alkyl.The R value is 9.5-about 10.5 most preferably from about.G can be selected from C
5Or C
6Monosaccharide residue and be preferably glucoside.G can be selected from glucose, xylose, lactose, fructose, mannose and derivant thereof.G is preferably glucose.
Polymerization degree n can be about 1-about 10 or bigger.The preferably about 1.1-about 2 of n.N is 1.3-about 1.5 most preferably from about.
Be applicable to that APG of the present invention has supply of commodities and comprises following material: available from the Oramix NS10 of Seppic; Plantaren 1200 and Plantaren2000 available from Henkel.
The total amount of surfactant in the present composition is generally (comprising any cosurfactant and/or any emulsifying agent) the 0.1-50 weight % of composition total weight, is preferably 5-30 weight %, more preferably 10-25 weight %.
The cationic deposition polymer is the preferred ingredient of the present composition, for example strengthens the conditioning effect of the present composition." deposited polymer " is meant in use and can promotes that for example siloxanes or antidandruff component are deposited into desired location from shampoo composite, i.e. agent on hair and/or the scalp.
Deposited polymer can form for homopolymer or by two or more monomers.The molecular weight of described polymer is generally 5000 to 10,000,000, is generally at least 10000 and be preferably 100,000 to about 2,000,000.Described polymer will have nitrogenous cation group such as quaternary ammonium or protonated amino or its mixture.
Nitrogenous cation group will exist with the substituent form on the whole monomeric unit parts of deposited polymer usually.Therefore when described polymer was not homopolymer, it can comprise non-cationic monomeric unit at interval.These polymer are described in CTFA Cosmetic IngredientDirectory, the 3rd edition.Thereby select the cation and the ratio of non-cationic monomeric unit to make the cationic charge density of polymer reach required scope.
Suitable cationic deposition polymer comprises, as, have the vinyl monomer of cationic amine or quaternary ammonium functional group and water solublity spacer monomers copolymer as (methyl) acrylamide, alkyl and dialkyl group (methyl) acrylamide, (methyl) alkyl acrylate, vinyl caprolactone and ethylene pyrrolidine.The monomer that alkyl and dialkyl group replace preferably contains the C1-C7 alkyl, more preferably the C1-3 alkyl.Other suitable interval base comprises vinyl acetate, vinyl alcohol, maleic anhydride, propylene glycol and ethylene glycol.
According to the pH of particular type and compositions, cationic amine can be primary amine, secondary amine or tertiary amine.Generally speaking preferred secondary amine and tertiary amine, especially preferred tertiary amine.
Vinyl monomer that amine replaces and amine can amine the form polymerization, and be converted into ammonium by quaternization subsequently.
The cationic deposition polymer can contain by amine-and/or the monomer of quaternary ammonium-substituted and/or compatible interval base monomer derived and mixture of the monomeric unit that comes.
Suitable cationic deposition polymer comprise as:
The copolymer of-1-vinyl-2-pyrrolidine and 1-vinyl-3-methyl-imidazole salts (as chloride salt) is called polyquaternium-16 on cosmetics, toilet articles and fragrance association (CTFA).This material can be by BASF Wyandotte Corp. (Parsippany, NJ, the LUVIQUAT that USA) provides (trade name) (as LUVIQUAT FC370);
The copolymer of-1-vinyl-2-pyrrolidine and dimethylaminoethyl methacrylate, (CTFA) in the field of business is called Polyquaternium-11.This material can be by GafCorporation (Wayne, NJ, the GAFQUAT that USA) provides (trade name) (as GAFQUAT 755N);
-contain the cationic polymer of diallyl quaternary ammonium salt, comprise the copolymer as dimethyl diallyl ammonium chloride homopolymer and acrylamide and dimethyl diallyl ammonium chloride, (CTFA) in the field of business is called Polyquaternium 6 and Polyquaternium 7;
-have an inorganic acid salt (as described in United States Patent (USP) 4009256) of the amino-Arrcostab of the homopolymer of unsaturated carboxylic acid of 3-5 carbon atom and copolymer;
-PAMC (as described in WO95/22311).
Operable other cationic deposition polymer comprises the cationic polysaccharide polymer, as cationic cellulose derivative, cationic starch derivative and cationic guar gum derivant.
The cationic polysaccharide polymer that is applicable to the present composition comprises the material shown in the following formula:
A-O-[R-N
+(R
1)(R
2)(R
3)X
-]
Wherein: A is dehydration glucose residue such as starch or cellulose dehydration glucose residue.R is alkylidene, oxy alkylene, polyoxy thiazolinyl or hydroxy alkenyl or its combination.R
1, R
2And R
3Independently represent alkyl, aryl, alkaryl, aralkyl, alkoxyalkyl or alkoxy aromatic yl, each group to contain up to about 18 carbon atoms.The total carbon atom number of each cationic moiety (is R
1, R
2And R
3The carbon number sum) preferably be about 20 or be lower than 20, X is cloudy type counter ion.
Cationic cellulose is by Amerchol Corp. (Edison, NJ, the polymer of polymer JR (trade mark) that USA) provides and LR (trade mark) series, they are the epoxide reactive salt that hydroxyethyl-cellulose and trimethyl ammonium replace, and are called Polyquaternium10 in industry (CTFA).Another kind of cationic cellulose comprises the polymer quaternary ammonium salt of the epoxide reaction gained that is replaced by hydroxyethyl-cellulose and lauryl dimethyl ammonium, is called Polyquaternium 24 in industry (CTFA).These materials can be for by Amerchol Corp. (Edison, NJ, the commodity Polymer LM-200 that USA) provides.
Other suitable cationic polysaccharide polymer comprises the cellulose ether (as described in United States Patent (USP) 3962418) that contains quaternary nitrogen and the copolymer (as described in United States Patent (USP) 3958581) of etherified cellulose and starch.
Operable especially suitable cationic polysaccharide polymer is the cationic guar gum derivant, as chlorination guar gum hydroxypropyl three salt (JAGUAR (trade mark) series by Rhodia (Rhone-Poulenc in the past) obtains commercial offers).
Example has JAGUAR C13S, and the replacement rate of its cation group is low, the viscosity height, JAGUAR C15 has medium replacement rate, and viscosity is low, JAGUAR C17 (high replacement rate, high viscosity), JAGUAR C16, it is the hydroxypropyl cationic guar gum derivant that contains a small amount of substituent group and cationic quaternary ammonium group, JAGUAR 162, it is low replacement rate, high transparent, moderately viscous guar gum and JAGUAR CHT, and it is transparent Jaguar.
The cationic deposition polymer is preferably selected from cationic cellulose and cationic guar gum derivant.
Especially preferred deposited polymer is JAGUARCHT, JAGUAR C13S, JAGUAR C15, JAGUAR C17, JAGUAR C16 and JAGUAR C162.
The common amount of cationic deposition polymer will be the 0.001-5 weight % of composition total weight, preferably about 0.01-1 weight %, more preferably from about 0.02-0.5 weight %.
The suitable solid activator that can be incorporated in the present composition comprises granules of pigments, as is suitable for being applied to solid dye or coloring agent on the hair, and metallic colloid.
Thereby hair-treatment composition such as shampoo are often improved captivation to client by shadingization or pearly-lustreization.
The example of opacifier comprises high fatty alcohol (as hexadecanol, stearyl alcohol, the pure and mild behenyl alcohol of arachidyl), solid ester (cetyl palmitate, glyceryl laurate ester, stearmide MEA-stearate), high-molecular weight fatty acid amide and alkanolamide and various derivative of fatty acid such as propylene glycol ester and macrogol ester.The inorganic material that is used for the shading hair-treatment composition comprises Magnesiumaluminumsilicate, zinc oxide and titanium dioxide.
Pearling agent forms the crystal that serves as micro mirror thin, the sheet type usually in described compositions.It provides pearl effect.Above-mentioned some opacifiers of listing also can become pearling agent according to the medium that uses and the condition crystallization of use.
Common pearling agent can be selected from C16-C22 fatty acid (as stearic acid, myristic acid, oleic acid and behenic acid), the C16-C22 fatty acid adds the ester that generates as the aklylene glycol unit with ester and the C16-C22 fatty acid that alcohol generates.Suitable aklylene glycol unit can comprise ethylene glycol and propylene glycol.Yet, can adopt higher alkylidene chain length glycol, suitable higher aklylene glycol comprises Polyethylene Glycol and polypropylene glycol.
Example is to contain the Polyethylene Glycol monoesters of C16-C22 fatty acid of 1-7 oxygen ethylene unit or the glycol ester of diester and C16-C22 fatty acid.Preferred ester comprises polyglycol distearate and glycol distearate.The polyglycol distearate of commercial offers is EUPERLAN PK900 (available from Henkel) or GENAPOL TS (available from Hoechst).An example of glycol distearate is EUPERLAN PK3000 (available from Henkel).
Other pearling agent comprises the alkanolamide (as stearic acid monoethanolamide, Stearic acid diethanolamine salt, stearic acid list isopropanol amide and stearic acid monoethanolamide stearate) of the fatty acid that contains 16-22 carbon atom; The long-chain ester of long-chain fatty acid (as stearyl stearate, cetyl palmitate); Glyceride (as distearin); Long-chain ester of long-chain alkanolamide (as stearmide DEA distearate, stearmide MEA stearate) and alkyl (C18-C22) dimethyl oxidation amine (as stearyl dimethyl amine oxide).
Other suitable pearling agent comprises inorganic material, as the pearlescent pigment based on the natural mica ore deposit.An example is the titanium dioxide that Muscovitum coats.The change of granularity scope of this material is 2-150 micron (diameter).In a word, granule produces pearlescent appearance, and the granule of big average diameter produces the compositions of flicker.
The titanium dioxide granule commodity that suitable Muscovitum on sale coats are TIMIRON (available from Merck, trade name) or FLAMENCO (available from Mearl, trade name).
The use amount of opacifier and pearling agent is generally the 0.01-20 weight % of composition total weight in the present composition, preferred 0.01-0.5 weight %, more preferably 0.02-0.2 weight %.
The representative of gas (as air) bubble is another kind of can be incorporated into the suspended phase that is used for purpose attractive in appearance in the shampoo composite.When big or small homogeneous and when being dispersed in the compositions, they can strengthen the captivation to client.
The present composition can comprise any other usual component that is used for hair treatment formulations.These other components can comprise that viscosity modifier, antiseptic, coloring agent, many alcohol are as glycerol and polypropylene glycol, chelating agen such as EDTA, antioxidant, spice and sunscreen.These components exist with the effective dose that reaches its purpose separately.Usually, these optional components that comprise are separately up to about 5 weight % of the gross weight of compositions.
Preferably, compositions of the present invention also comprises the auxiliary agent that is suitable for hair nursing.Usually, this composition amount of comprising separately is 2 weight % up to composition total weight, preferably up to 1 weight %.
Wherein, suitable hair nursing auxiliary agent is:
(i) natural root of hair nutrient is as aminoacid and sugar.Suitable amino acid whose example comprises arginine, cysteine, glutamine, glutamic acid, isoleucine, leucine, methionine, serine and valine, and/or its precursor and derivant.Aminoacid can add separately, adds with the form of mixture, or is peptide, as dipeptides-and the form of tripeptides.Aminoacid also can be with protein hydrolysate, as the form adding of keratin or collagen hydrolysate.Suitable sugar is glucose, D-glucose (dextrose) and fructose.These can add separately or add with the form of for example fruit extract.The particularly preferred natural root of hair nutrient combination that is included in the present composition is isoleucine and glucose.Particularly preferred aminophenol nutrient is an arginine.
(ii) hair fiber beneficial agent (hair fibre benefit agent).Example is:
-ceramide is used to make fiber to preserve moisture and keeps horny layer complete.Ceramide can obtain by extracting from natural source, perhaps is that synthetic ceramide and false vitalility are through amide.Preferred ceramide is the ceramide II (Ceramide II) of ex Quest company.The mixture of ceramide also may be suitable, as the ceramide LS (Ceramides LS) of Laboratoires Serobiologiques.
(iii) natural or artificial oil is as the fatty acid that comprises 12-30 carbon atom in ester and/or the ester of aliphatic alcohol.An example of artificial oil is an isopropyl myristate.An example of natural oil is an Oleum Helianthi.
Compositions of the present invention comprises water, preferred distilled water or deionized water, and preferably its amount is 30 weight %-99.97 weight % of composition total weight, more preferably 50 weight %-95 weight %, preferred especially 60 weight %-90 weight %.
Now, will be by the present invention is further illustrated with reference to the restrictive embodiment of following not tool.Except as otherwise noted, embodiment and description in the whole text in, all percentage ratio is all by weight.
Embodiment:
The test of smoothness and combing easness:
In following embodiment, send out in the thread experimental study in double blinding, by 12 evaluation and test members relatively the present composition and correlated grouping of commodities thing send out character aspect thread smoothness and the combing easness at hair, carry out record by the evaluation and test member then.
The smoothness test method
Make assessor group member hold the paired low-density hair that is used to compare and send out thread with the present composition or Comparative composition processing.
The assessor is required " to clamp " between forefinger and middle finger and sends out thread, strokes each thread downwards along its length and does not see them, and judge which is sent out thread and feels the most smooth.Equipment
1.6.67g/25cm the hair strands of making by Red Tie Yugoslavian hair (each compositions has 3 threads).
2. be used to the horizontal bar that has clip of hair strands of slinging.
3. test matrix.
4. appraisal group.
5. plastic comb (8 teeth/centimetre, facewidth 0.025cm).
Operator's deviation
Test should be carried out in double blinding, influences the probability of assessor's (concluding the personnel of different product) decision to avoid Test Operator (personnel that test).
Method
1. before testing, will send out the thread balance in the middle of test, to guarantee not having " mixing " to send out thread.SLES 2EO with 2 * 0.5ml 16% washs each thread, and makes its drying, perhaps dry 1 hour or dried overnight at room temperature in 50 ℃ baking oven.
2. according to test matrix, will send out thread and suspend (first thread is in the left side) in pairs in midair with horizontal bar.
3. require the evaluation and test member to close their eyes, and will send out its non-writing of thread " being clipped in ", and stroke each thread successively with between the forefinger and middle finger of hands.Then, require the assessor to judge which is sent out thread and feels more smooth.Do not allow the judged result of " not having difference ".
4. with computer program VITRO analysis result.
5. if send out at 3 and find there is not significant difference in detail between the combination, just carry out step 6.If find to have significant difference, determine " mixing " thread.Repeat to carry out the equilibrium process of washing for the second time with the SLES 2EO of 2 * 0.5ml 16%.If find difference again, need so with the new thread of sending out.
6. according to like this, handle a thread and a repeating step 2-4 with compositions of the present invention and Comparative composition.
Basic components:
| Component | Amount, by weight |
| SLES?2EO | 14％ |
| The cocoyl amido propyl betaine | 2％ |
| Cocoyl both sexes sodium acetate | 2％ |
| Synthalan?K(Carbopol) | 0.4％ |
| Jaguar?CHT | 0.2％ |
| Jaguar?C13S | 0.2％ |
| Propylene glycol | 4.0％ |
| Climbazole | 1.0％ |
| Spice | 0.75％ |
| EDTA | 0.045％ |
| Glydant?Plus | 0.3％ |
| Water | Surplus |
Embodiment 1:
Cera Flava 0.5% (finished Cera Flava derives from Koster Keunen Inc.) and 1.0% SM 555 siloxanes (deriving from GE Silicones) join in the basic components.
| Compositions | Smoothness | Dry combing easness |
| Embodiment 1 | 46 | 52 |
| Contrast | 26 | 20 |
Embodiment 2:
Cera Flava 0.5% (finished Cera Flava derives from Koster Keunen Inc.) and 2.0% SM 555 siloxanes (deriving from GE Silicones) join in the basic components.
| Compositions | Smoothness | Dry combing easness |
| Embodiment 2 | 51 | 53 |
| Contrast | 21 | 19 |
Embodiment 3:
Cera Flava 1.0% (finished Cera Flava derives from Koster Keunen Inc.) and 0.5% SM 555 siloxanes (deriving from GE Silicones) join in the basic components.
| Compositions | Smoothness | Dry combing easness |
| Embodiment 3 | 53 | 51 |
| Contrast | 19 | 21 |
Embodiment 4:
Cera Flava 0.5% (finished Cera Flava derives from Koster Keunen Inc.) and 0.5% SM 555 siloxanes (deriving from GE Silicones) join in the basic components.
| Compositions | Smoothness | Dry combing easness |
| Embodiment 4 | 19 | 19 |
| Contrast | 53 | 53 |
Claims (13)
1. shampoo composite, it comprises: the dandruff agent of 0.01 weight %-10 weight %; 0.01 the Cera Flava of weight %-10 weight %; Siloxanes with 0.01 weight %-10 weight %.
2. according to the compositions of claim 1, wherein the weight ratio of Cera Flava and siloxanes is 1: 4-3: 1.
2. according to the compositions of claim 1 or 2, wherein the weight ratio of Cera Flava and siloxanes is 1.5: 1-2.5: 1.
4. according to any one compositions of claim 1-3, wherein the weight ratio of Cera Flava and siloxanes is about 2: 1.
5. according to any one compositions of claim 1-4, wherein the dandruff agent is dissolved in the compositions.
6. according to the compositions of claim 5, wherein the dandruff agent is selected from ketoconazole, climbazole and composition thereof.
7. according to any one compositions of claim 1-6, wherein the dandruff agent is a climbazole.
8. according to any one compositions of claim 1-7, it comprises anion surfactant.
9. according to any one compositions of claim 1-8, wherein Cera Flava is suspended in the compositions with solid particulate form.
10. according to any one compositions of claim 1-9, wherein in the compositions total amount of Cera Flava and siloxanes greater than 1.0 weight % of composition total weight.
11. Cera Flava and siloxanes be combined in purposes in the shampoo composite, it is used to provide one or more to be selected from following character: improved pliability, improved foam quality, improved conditioning effect and improved hair are easily handled benefit.
12. Cera Flava and the siloxanes purposes in the dandruff shampoo composite, it is used to provide improved foam property and dandruff removing agent is effectively deposited.
13. according to the purposes of claim 11 or 12, wherein the weight ratio of Cera Flava and siloxanes is 1: 4-3: 1.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03256770.3 | 2003-10-27 | ||
| EP03256770 | 2003-10-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1870973A true CN1870973A (en) | 2006-11-29 |
Family
ID=34585912
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800313674A Expired - Fee Related CN100502832C (en) | 2003-10-27 | 2004-09-16 | Hair care composition |
| CNA2004800316013A Pending CN1870973A (en) | 2003-10-27 | 2004-10-01 | Antidandruff shampoo composition |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800313674A Expired - Fee Related CN100502832C (en) | 2003-10-27 | 2004-09-16 | Hair care composition |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1677750A1 (en) |
| JP (1) | JP2007509183A (en) |
| CN (2) | CN100502832C (en) |
| AR (1) | AR046203A1 (en) |
| BR (1) | BRPI0415163A (en) |
| MX (1) | MXPA06004594A (en) |
| TW (1) | TW200518778A (en) |
| WO (1) | WO2005046629A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104135989A (en) * | 2012-02-29 | 2014-11-05 | 莱雅公司 | Use of porphyrin-type catalytic oxidation compounds as an anti-dandruff agent |
| CN106924074A (en) * | 2017-05-08 | 2017-07-07 | 福建华夏蓝新材料科技有限公司 | A kind of colorful washing product and preparation method thereof |
| CN107334653A (en) * | 2017-07-12 | 2017-11-10 | 南雄鼎成新材料科技有限公司 | A kind of antibacterial anti-dandruff and itching-relieving shampoo with treatment containing organosilicon quaternary ammonium salt |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8263053B2 (en) | 2005-11-22 | 2012-09-11 | Access Business Group International | Hair treatment compositions |
| JP2007277227A (en) * | 2006-03-14 | 2007-10-25 | Mochida Pharmaceut Co Ltd | Azole-based antifungal agent-formulated cleaning composition |
| CN102421408B (en) * | 2009-04-23 | 2014-05-28 | 荷兰联合利华有限公司 | Composition comprising azole fungicide and water soluble metal salt |
| JP2013534231A (en) * | 2010-08-18 | 2013-09-02 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Anti-dandruff shampoo |
| KR20130136966A (en) * | 2010-08-18 | 2013-12-13 | 유니레버 엔.브이. | Anti-dandruff shampoo |
| MX2016013894A (en) * | 2014-04-24 | 2017-02-02 | Procter & Gamble | Scalp care composition. |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4002734A (en) * | 1973-10-29 | 1977-01-11 | Pickford Melcina H | Hair grooming composition |
| US4843097A (en) * | 1984-06-13 | 1989-06-27 | Groupement D'interet Economique Dit: Centre International De Recherches Dermatologiques C.I.R.D. | 10-aryl-1,8-dihydroxy-9-anthrones and their esters, process for preparing same, and use of same in human and veterinary medicine and in cosmetics |
| US4867971A (en) * | 1988-04-22 | 1989-09-19 | Colgate-Palmolive Company | Low pH shampoo containing climbazole |
| US5348736A (en) * | 1989-06-21 | 1994-09-20 | Colgate-Palmolive Company | Stabilized hair-treating compositions |
| US5213716A (en) * | 1989-06-21 | 1993-05-25 | Colgate-Palmolive Company | Hair conditioning shampoo containing long chain alcohol component |
| US6635702B1 (en) * | 2000-04-11 | 2003-10-21 | Noveon Ip Holdings Corp. | Stable aqueous surfactant compositions |
-
2004
- 2004-09-16 CN CNB2004800313674A patent/CN100502832C/en not_active Expired - Fee Related
- 2004-10-01 EP EP04790116A patent/EP1677750A1/en not_active Withdrawn
- 2004-10-01 MX MXPA06004594A patent/MXPA06004594A/en not_active Application Discontinuation
- 2004-10-01 JP JP2006537098A patent/JP2007509183A/en not_active Withdrawn
- 2004-10-01 CN CNA2004800316013A patent/CN1870973A/en active Pending
- 2004-10-01 WO PCT/EP2004/011083 patent/WO2005046629A1/en not_active Application Discontinuation
- 2004-10-01 BR BRPI0415163-1A patent/BRPI0415163A/en not_active Application Discontinuation
- 2004-10-19 TW TW093131611A patent/TW200518778A/en unknown
- 2004-10-27 AR ARP040103901 patent/AR046203A1/en unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104135989A (en) * | 2012-02-29 | 2014-11-05 | 莱雅公司 | Use of porphyrin-type catalytic oxidation compounds as an anti-dandruff agent |
| CN104135989B (en) * | 2012-02-29 | 2016-12-14 | 莱雅公司 | Porphyrin-type catalysis oxidized compound is as the purposes of dandruff removing agent |
| CN106924074A (en) * | 2017-05-08 | 2017-07-07 | 福建华夏蓝新材料科技有限公司 | A kind of colorful washing product and preparation method thereof |
| CN107334653A (en) * | 2017-07-12 | 2017-11-10 | 南雄鼎成新材料科技有限公司 | A kind of antibacterial anti-dandruff and itching-relieving shampoo with treatment containing organosilicon quaternary ammonium salt |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1677750A1 (en) | 2006-07-12 |
| JP2007509183A (en) | 2007-04-12 |
| TW200518778A (en) | 2005-06-16 |
| CN100502832C (en) | 2009-06-24 |
| BRPI0415163A (en) | 2006-11-28 |
| AR046203A1 (en) | 2005-11-30 |
| CN1870970A (en) | 2006-11-29 |
| WO2005046629A1 (en) | 2005-05-26 |
| MXPA06004594A (en) | 2006-06-27 |
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