CN1311656A - Hair treatment compositions - Google Patents

Hair treatment compositions Download PDF

Info

Publication number
CN1311656A
CN1311656A CN 99809297 CN99809297A CN1311656A CN 1311656 A CN1311656 A CN 1311656A CN 99809297 CN99809297 CN 99809297 CN 99809297 A CN99809297 A CN 99809297A CN 1311656 A CN1311656 A CN 1311656A
Authority
CN
China
Prior art keywords
hair
polysiloxane polymer
polymer
described compositions
cationic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 99809297
Other languages
Chinese (zh)
Inventor
P·费尔利
C·M·菲内尔
D·C·斯蒂尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever NV filed Critical Unilever NV
Publication of CN1311656A publication Critical patent/CN1311656A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5422—Polymers characterized by specific structures/properties characterized by the charge nonionic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Hair treatment compositions containing a particular combination of silicone and hydrocarbon materials can impart surprisingly improved fullness, body and volume to the hair, when compared with compositions utilising either of these materials alone. A particularly preferred combination is cross-linked silicone gum and polyisobutylene resin.

Description

Hair-treatment composition
Invention field
The present invention relates to give the hair-treatment composition of hair with improved plumpness, solid sense and bulkiness, said composition contains the specific mixture of a kind of polysiloxanes and hydrocarbons.
The background of invention and prior art
Application conditioner such as polysiloxane polymer, cation opsonizing agent and oily matter are known for people and extensively are reported in the patent documentation in hair-treatment composition.Yet the problem relevant with this type of material is that it may make the hair jewelry, expensive clothing and other valuables and be difficult for combing for obtaining the necessary consumption application of good sense of touch and/or appearance.
So, after hair washing and/or conditioning, usually obtain plumpness, solid sense and the bulkiness of hair usually by film forming matter to hair coating mousse, gel or hair spray form.Yet the binding agent and/or the resinousness material that are usually used in the hair style maintenance may damage the dried characteristic of sending out, and especially send out sense and do the difficulty or ease of combing.In addition, many people need to a certain degree improve hair plumpness, solid sense and bulkiness but not have inconvenience and the cost of an independent step.
For example, EP-A-240 350 and US 4902499 (Procter ﹠amp; Gamble) application of certain stiffness polysiloxane polymer in improved hair style retentivity is provided that is dissolved in the volatile vehicle material disclosed.
WO 96/31188 discloses the polysiloxane polymer by emulsion polymerisation, and this polysiloxane polymer is crosslinked with the emulsified body form, is used to provide improved hair caring effect and does not impair conditioning character when being formulated as hair-treatment composition.
EP 0 498 119 and EP 567 326 disclose the application of high molecular weight resin all alkyl (thiazolinyl) hydrocarbons in giving hair solid sense and hair caring.
The present inventor finds that at present when contrasting with the compositions of utilizing these materials separately, the hair-treatment composition that contains the specific mixture of a kind of polysiloxanes and hydrocarbons is given hair astoundingly with improved plumpness, solid sense and bulkiness.
The definition of invention
The invention provides a kind of hair-treatment composition of giving the improved plumpness of hair, solid sense and bulkiness, wherein in aqueous medium, contain the emulsified particles of (ⅰ) high viscosity polysiloxane polymer and (ⅱ) emulsified particles of high-molecular weight hydrocarbon material.Detailed Description Of The Invention (ⅰ) emulsifying high viscosity polysiloxane polymer
Hair-treatment composition of the present invention contains the granule of high viscosity polysiloxane polymer.This polysiloxane polymer is insoluble in the aqueous medium of this hair-treatment composition and with the emulsifying form and exists, and this polysiloxane polymer is to exist as discrete particles simultaneously.
So-called " high viscosity polysiloxane polymer " is meant that the viscosity of polysiloxane polymer (not being emulsified body or final hair-treatment composition) itself is 500000cst (centistoke) at least.The viscosity of polysiloxane polymer itself is suitably for 1000000cst at least.In order to be easy to preparation, preferably this viscosity is no more than 109cst.Utilize the device of glass capillary tube viscometer to measure viscosity according to the described method of Dow corning Corporate Test Method CTM004 (on July 20th, 1970).
Suitable polysiloxane polymer comprises polydiorganosiloxanepolyurea, polydimethylsiloxane particularly, its CTFA called after polydimethylsiloxane.Other are applicable to that hair-treatment composition of the present invention is the polydimethylsiloxane with hydroxyl end groups, its CTFA called after dimethiconol.
Be specially adapted to emulsifying of the present invention, high viscosity polysiloxane polymer in conjunction with crosslinked so that the network structure of polydiorganosiloxanepolyurea chain to be provided.
Can determine the degree of cross linking according to the unitary percentage ratio of branched monomer in the polysiloxane polymer.This numerical value is suitably about 0.001% to about 35%, and is preferred 0.002 to 10%, and more preferably 0.003 to 10%, the best is 0.004 to 2%.Find to improve and crosslinkedly can improve the fluffyization effect of hair and do not reduce a little conditioning performance, therefore select suitable (crosslinked) level in different situations, to be fit to user's hobby according to character.The degree of cross linking is about 0.6% (being the unitary percentage ratio of branched monomer) can obtain good overall performance.
The crosslinked polysiloxane polymer can for example add in polymerization process then and there, forms polysiloxane polymer by its structure monomeric unit, but should contain the trifunctional and the four functional silane monomeric units of requirement, for example formula RSi (OH) 3Those, wherein R represents alkyl, alkenyl (as vinyl), alkaryl, aralkyl or aryl (for example phenyl), preferable methyl.
In addition, can adopt the polysiloxanes cross-linking chemistry of other types to prepare and be applicable to cross linking polysiloxane polymer of the present invention.Used cross-linking agent can be an organosilicon cross-linking agent in described method, and is listed as EP 0473039, or the non-silicone cross-linking agent, and its typical example is US 5654362 described cross linking polysiloxane polymer.Crosslinked body used herein is α, the ω-aliphatic diolefine of following structure: CH 2=CH (CH 2) xCH=CH 2, wherein X is 1-20.Addition by the laterally two keys of the crosslinked and Si-H in α, the ω-aliphatic diolefine generates gel.
Other examples that are applicable to suitable cross linking polysiloxane polymer of the present invention comprise the material DC 3-2365 that DowCorning sells, polysiloxanes-urethane copolymers Polyderm PPI-SI-100 with Akzo Incorporated (Matawan, New Jersey) sale.
The cross linking polysiloxane polymer that the present composition especially preferably adopts be have low crosslinking degree as WO 96/31188 described silicone gums.These materials can be given hair plumpness, solid sense and bulkiness, and good dried wet conditioning property.
Can adopt the diverse ways preparation to be applicable to the particulate emulsified body of high viscosity polysiloxane polymer of the present invention, these methods are known and open in the prior art.For example, prepare emulsified body by high shear machine mixing polysiloxane polymer and water, or by water and emulsifying agent emulsifying polysiloxane polymer (polysiloxane polymer being blended in the hot solution of emulsifying agent), or the mixed method of employing machinery and chemical emulsification.For some material such as US 5654362 described cross linking polysiloxane polymer, can adopt at first they are mixed with hydrophilic or hydrophobic diluents such as PPG-2 myristyl ether propionic ester or Cyclomethicone, to be easy to emulsifying step subsequently.
The particularly preferred proper technology of the preparation particulate emulsified body of polysiloxane polymer is an emulsion polymerization.The polysiloxane polymer of emulsion polymerisation for example is disclosed in US2891820 (Hyde), US 3294725 (Findlay) and US 3360491 (Axon).
Be applicable to that average polysiloxanes granularity that the emulsifying high viscosity polysiloxane polymer of hair-treatment composition of the present invention has is less than 30 microns in compositions.Can be by laser scattering technology, utilize the 2600D particle size analyzer determination granularity of Malvern Instruments.
The particle mean size of polysiloxane polymer in described hair-treatment composition can for example be 2 to 30 microns, preferred 2-20 micron, more preferably 3-10 micron.
In addition, polysiloxane polymer can be present in this hair-treatment composition with the emulsified particles form of small grain size, and for example granularity is less than 2 microns.Reduce granularity in some cases and can improve conditioning performance.
The polysiloxane polymer emulsified body of average polysiloxanes granularity≤0.15 micron generally is called the microemulsified body.Usually, the particulate granularity of this microemulsified is≤0.15 micron, be suitably 0.01 to 0.15 micron.These are preferred, because they can guarantee that the compositions for preparing has high stability and good optical characteristics, as translucent or transparent preparation.
Be applicable to that polysiloxane polymer emulsified body of the present invention is to buy with pre-emulsifying form.This is suitable especially, because preformed emulsified body can be incorporated in the hair-treatment composition by direct mixing.Pre-formation emulsified body can be available from supplier such as Dow Corning, GeneralElaectric, Union Carbide, Wacker Chemie, Shin Etsu, Toshiba, Toyo Beauty Co and the Toray Silicone Co. of silicone oil
The suitable pre-example that forms emulsified body comprises emulsified body DC2-1766 and the DC2-1784 available from Dow Corning.These all are emulsified body of dimethiconol, and wherein the viscosity of polysiloxanes itself is about 1000000cst.
The preferred cross linking polysiloxane glue that is applicable to the present composition also is to buy with pre-emulsifying form, and it is suitable for preparation.Particularly preferred example is the material available from the DC X2-1787 of Dow Corning, and it is the emulsified body of crosslinked dimethiconol glue, and wherein the viscosity of polysiloxane polymer itself is about 2 * 107cst.Another preferred embodiment is the material available from the DCX2-1391 of DowCorning, and it is the microemulsified body of crosslinked dimethiconol glue, and wherein the viscosity of polysiloxane polymer self is about 1000000cst.
The content that is blended in the emulsifying high viscosity polysiloxane polymer in the hair-treatment composition of the present invention depends on that the opsonic water of expection is gentle raw materials used.Preferred content be the said composition total amount 0.01 to about 10% (weight), but these qualifications are not absolute.We find that suitable especially polysiloxane polymer consumption is 0.05 to 1.0% (weight) of said composition total amount.
When polysiloxane polymer was sneaked into as above-mentioned pre-formation emulsified body, the accurate consumption of emulsified body depended on the concentration of emulsified body certainly, and should be chosen in the polysiloxane polymer that desired amount can be provided in final compositions.(ⅱ) emulsified particles of high-molecular weight hydrocarbon material
So-called " high molecular " is meant that the weight average molecular weight of emulsifying hydrocarbons is 20000 at least.Suitable scope is 20000 to 1000000, preferred 20000 to 500000, first-selected 40000 to 200000; These materials adopt the improvement that plumpness, solid sense and the bulkiness of hair are provided especially effectively when share with above-mentioned high viscosity polysiloxanes.
The preferred high-molecular weight hydrocarbon material of one class is the basic hydrocarbon resins of full alkane (alkene).These terms " resin " comprise under those room temperatures being solid or semisolid material, and those have the liquid of high or moderate viscosity.This term does not comprise oil or viscosity material, hydrocarbon-type oil for example, known they can be blended in the cosmetic emulsions, as described in EP0610407 in affiliated technical field because of its conditioning characteristic.
EP 56732 and EP 498119 have described the suitable basic hydrocarbon resins of full alkane (alkene) of giving hair hair caring and height solid sense.The preferred complete basic hydrocarbon materials of alkane (alkene) is butylene, isoprene, terpenes and cinnamic polymer, copolymer with these monomer combination in any, butyl rubber (polyisobutylene-copolymerization-isoprene) for example, natural rubber (suitable-1, the 4-polyisoprene) and hydrocarbon resins as in " chemical technology complete works " (the 3rd edition that Kirk and Othmer showed, the 8th the volume, the 852-869 page or leaf) in pointed, for example aliphatic series and aromatic resin and terpene resin.
The polyisobutylene material of preferred especially following formula:
H 3C-[C (CH 3) 2-CH 2-] m-R wherein m is 1-5000, and preferred 2-2500 and R are
-CH (CH 3) 2Or-C (CH 3)=CH 2These materials are available from Preperse, and the product of Inc. commodity PERMETHYL by name is available from the product of the trade name OPANOL of the product of the trade name VISTANEX of Exxon Chemical and BASF.Preference comprises VISTANEX LM-MH and OPANOL B 15.
The method that is fit to the particulate emulsified body of preparation high-molecular weight hydrocarbon material such as polyisobutylene resin is disclosed among EP 567326 and the EP 498119.Preferred EP 567326 described methods, because it is with water and the suitable direct emulsive method of surfactant emulsifiers, it is avoided adopting and may dissolve or the solvent or the carrier of dispersed polymer amount hydrocarbons.This kind solvent or carrier (for example low molecular weight hydrocarbons) in the course of processing on safety dangerous property, and the final preparation stabilization removal that it is sneaked into.
Be suitable for the particle mean size that the emulsifying high-molecular weight hydrocarbon material of hair-treatment composition of the present invention has and be generally about 0.01 to about 100 microns in compositions, more typical is about 0.1 to about 10 microns, this is not had special provision.By laser scattering technology, utilize the 2600D particle size analyzer determination granularity of MalvernInstruments.
Being suitable for high-molecular weight hydrocarbon emulsified body of the present invention is to buy with pre-emulsifying form.This is suitable especially, can mix in the hair-treatment composition by direct mixing because form emulsified body in advance.
The pre-formation emulsified body example that is suitable for is the material PIB96/003 available from Basildon Chemical.This is the moisture emulsified body OPANOL B 15 (BASF product) of a kind of polyisobutylene material and anion and non-ionic surface active agent emulsifying agent.
The consumption that is blended in the high-molecular weight hydrocarbon material in the present composition depends on the plumpness of expection, solid sense and bulkiness level and used certain material.Preferred consumption is about 0.01 to about 2% (weight), and in the said composition gross weight, but these qualifications are not absolute.Measure lower limit by the floor level that obtains plumpness, solid sense and bulkiness enhancement effect, and by prevent hair unacceptably the top level of hardening measure the upper limit.We find that the consumption of high-molecular weight hydrocarbon material is that 0.2 to 0.5% (weight) of said composition total amount is particularly preferred.
When the high-molecular weight hydrocarbon material mixed as above-mentioned pre-formation emulsified body, the accurate consumption of emulsified body depended on the concentration of emulsified body certainly, and should be chosen in the high-molecular weight hydrocarbon material that desired amount can be provided in final compositions.(ⅲ) polysiloxanes: hydro carbons ratio
The emulsified particles of the emulsified particles of high viscosity polysiloxane polymer (ⅰ) and high-molecular weight hydrocarbon material (ⅱ) is suitable to especially 1: 20 to 2: 1, preferably with 1: 10 to 1: 1, first-selected polysiloxanes with 1: 4 to 1: 2: the hydro carbons part by weight is blended in the compositions of the present invention.The present inventor finds, makes polysiloxanes increase the fluffy effect of hair that will impair this hair-treatment composition to 2: 1 weight ratios that surpass above-mentioned qualification with respect to the amount of hydro carbons.On the other hand, if when hydro carbons is too high with respect to the amount of polysiloxanes, hair will be felt to harden, and make us and can't accept.(ⅳ) product form
Hair-treatment composition of the present invention is fit to take the form of shampoo, conditioner, hair spray, mousse or washing liquid.Preferred hair-treatment composition form is shampoo and conditioner.Shampoo composite
The particularly preferred hair-treatment composition of the present invention is a shampoo composite.-cleansing surfactants
Described shampoo composite contains one or more and make up to go up acceptable and be suitable for the cleansing surfactants of local coating on hair.If when oiliness that exists for typical case in the shampoo as emulsifying agent or hydrophobicity composition (for example polysiloxanes compounds) can't provide enough cleaning action, other surfactants can be used as annexing ingredient and exist.
Preferred shampoo composite of the present invention contains at least a other surfactant (except as the surfactant of emulsifying agent) so that cleaning effect to be provided.
Can be separately or the suitable cleansing surfactants of share be selected from anion, both sexes and amphoteric ionic surfactant and their mixture.Cleansing surfactants can be with as the identical surfactant of emulsifying agent, or can be different.
The example of anion surfactant is alkyl sulfate, alkyl ether sulfate, alkylaryl sulfonate, alkanoyl isethionate; alkyl succinate; alkyl sulfo succinate; the N-alkyl sarcosine salt; alkylphosphonic, alkyl ether phosphate, alkyl ether carboxy acid salt; and alpha-alkene sulfonate, especially its sodium, magnesium, ammonium and-, two-and triethanolamine salt.Alkyl and acyl group contain 8-18 carbon atom usually and can be undersaturated.Can contain 1-10 oxirane or propylene oxide units in each molecule of alkyl ether sulfate, alkyl ether phosphate and alkyl ether carboxy acid salt.
The typical anionic surfactants that is suitable for shampoo of the present invention comprises the oil base sodium succinate, dodecyl 2-Sulfosuccinic acid ammonium, ammonium lauryl sulfate, dodecylbenzene sodium sulfonate, DBSA triethanolamine, cocoyl hydroxyethyl sulfonate, dodecyl hydroxyethyl sulfonate and N-sarcosyl.First-selected anion surfactant is sodium lauryl sulphate, onodoidecyl phosphonic acid triethanolamine, sodium lauryl tri(oxyethyl) sulfate 1EO 2EO and 3EO, ammonium lauryl sulfate and ammonium dodecyl ether sulfate 1EO, 2EO and 3EO.
The example of both sexes and zwitterionic surfactant comprises alkyl amine oxide, alkyl betaine, alkyl amido CAB, alkyl sulfobetaines (sulfobetaines), alkyl glycinate, alkyl carboxyl glycinate, alkyl both sexes propionate, alkyl both sexes glycinate, alkyl amido propyl hydroxy sulfobetaines, acyl taurine salt and acyl glutamate, and wherein alkyl and acyl group have 8-19 carbon atom.The typical both sexes and the zwitterionic surfactant that are suitable for shampoo of the present invention comprise dodecyl amine oxide, coco dimethyl sulfopropyl betaine and preferred empgen BB, cocamidopropyl betaine and cocos nucifera oil both sexes sodium propionate.
Shampoo composite also can contain cosurfactant, helps compositions that aesthetics, physics or cleaning properties are provided.Preferred embodiment is a non-ionic surface active agent, and its content can be 0% to about 5% (weight), based on the gross weight meter.
For example, the representative ionic surfactant pack that can contain in the shampoo composite of the present invention is drawn together aliphatic series (C 8-C 18) uncle or the condensation substance of secondary straight or branched alcohol or phenol and oxyalkylene (generally being oxirane), and have 6-30 Oxyranyle usually.
Other representational ionic surfactant pack draw together one-or two-alkyl alkanolamide.Example comprises cocoyl one-or two-glycollic amide and cocoyl one isopropanol amide.
Other non-ionic surface active agents that can be contained in the shampoo composite of the present invention are alkyl poly glucoside (APG classes).Usually, APG is a kind of alkyl that links to each other with the block of (randomly passing through bridging group) one or more glycosyls that contains.Preferred APG is as shown in the formula definition:
R0-(G) nWherein R is that saturable or undersaturated branched-chain or straight-chain alkyl and G are glycosyls.
R can represent about C 5-Yue C 20Mean alkyl chain long.The about C of preferred R representative 8-Yue C 12Mean alkyl chain long.First-selected R value is about 9.5 to about 10.5.G can be selected from C 5Or C 6Monosaccharide residue and glucoside preferably.G can be selected from and comprise glucose, xylose, lactose, fructose, mannose and their derivant.Preferred G is a glucose.
Polymerization all n can be about 1 to about 10 or higher numerical value.The numerical value of preferred n about 1.1 in about 2.The numerical value of first-selected n about 1.3 in about 1.5.
Be suitable for alkyl poly glucoside of the present invention and can buy and comprise for example Oramix NS10 of those materials: Seppic sale; Plantaren 1200 and P1antaren2000 that Henkel sells.
In shampoo composite of the present invention, the total amount of surfactant (comprising any cosurfactant and/or any emulsifying agent) generally is 0.1 to 50% (weight) of shampoo composite total amount, preferred 5 to 30% (weight), more preferably 10%-25% (weight).-cationic polymer
Cationic polymer is a preferred ingredients in the shampoo composite of the present invention, is used to improve the conditioning performance of shampoo.Typically, this polymer strengthens in the shampoo composite conditioning component in use such as polysiloxanes deposits on desirable position, i.e. hair and/or scalp.
Cationic polymer can be homopolymer or be formed by two or more monomers that the molecular weight of this polymer generally is 5000 to 10000000, typically is 10000 and preferably 100000 to about 2000000 at least.Polymer should have cation nitrogen-containing group such as quaternary ammonium or protonated amino, or their mixed group.
The cation nitrogen-containing group generally is present on the total monomer units of a part of cationic polymer as substituent group.Therefore, when this polymer was not homopolymer, it can contain basic non-cationic monomeric unit at interval.This base polymer is disclosed in the CTFA components of cosmetics dictionary (the 3rd edition).The ratio of cation and non-cationic monomeric unit is chosen in the cationic charge density that this polymer is had and is in the preset range.
Suitable cationic polymer comprises, for example, the basic monomeric copolymer of vinyl monomer and water solublity interval with cationic amine or quaternary ammonium degree of functionality, described water solublity basic monomer at interval for example is (methyl) acrylamide, alkyl and dialkyl group (methyl) acrylamide, alkyl (methyl) acrylate, vinyl decalactone and ethenyl pyrrolidone.Alkyl and dialkyl group substituted monomer preferably have more preferably C1-3 alkyl of C1-C7 alkyl.Other proper spacing bases comprise vinyl esters, vinyl alcohol, maleic anhydride, propylene glycol and ethylene glycol.
Cationic amine can be primary, the second month in a season or tertiary amine, depends on the particular types and the pH of compositions.Usually, the preferred second month in a season and tertiary amine, especially tertiary amine.
Amine substituted ethylene base monomer and aminated compounds can be with the polymerizations of amine form and subsequently by the quaternized ammonium that is converted into.
Cationic polymer can contain derived from amine-and/or the monomeric unit of quaternary ammonium-substituted monomer and/or the compatibility basic monomeric mixture at interval.
The cationic polymer that is suitable for comprises, for example: the copolymer of-1-vinyl-2-pyrrolidine and 1-vinyl-3-methyl-imidazoline salt (for example villaumite) is called polyquaternium-16 in " cosmetics, washing product and fragrance association " industry (CTFA).This material can be available from BASF WyandotteCorp. (Parsippany, NJ, USA) product of selling with trade name LUVIQUAT (for example LUVIQUAT FC 370); The copolymer of-1-vinyl-2-pyrrolidine and dimethylaminoethyl methacrylate is called Polyquaternium-11 in the industry (CTFA).This material is available from GafCorporation (Wayne, NJ, USA) product of selling with trade name GAFQUAT (for example GAFQUAT 755N);-cation diallyl contains quaternary ammonium polymer, comprise, for example the copolymer of dimethyl diallyl ammonium chloride homopolymer and acrylamide and dimethyl diallyl ammonium chloride is called Polyquaternium 6 and Polyquaternium 7 respectively in industry (CTFA);-have homopolymerization-and the inorganic acid salt of copolymerization-polymer of amino-Arrcostab of the unsaturated carboxylic acid of 3-5 carbon atom, (as described in a United States Patent (USP) 4009256);-PAMC compounds (as described in WO 95/22311).
Other cationic polymer that is suitable for comprises the cationic polysaccharide polymer, for example cationic cellulose analog derivative, cationic starch analog derivative and cationic guar gum analog derivative.
The cationic polysaccharide base polymer that is applicable to the present composition comprises those of following formula:
A-O-[R-N+ (R1) is (R3) X-(R2)], wherein: A is the dewatered grape saccharide residue, for example starch or cellulose dehydration glucose residue.R is alkylidene, oxyalkylene, polyoxy alkylidene or hydroxy alkylidene, or their mixture.R1, R2 and R3 represent alkyl, aryl, alkaryl, aralkyl, alkoxyalkyl or alkoxy aryl independently, and each group contains about at the most 18 carbon atoms.For each cationic moiety, the sum of carbon atom (being the carbon atom sum among R1, R2 and the R3) preferably be equal to or less than about 20 and X be anionic counter-ion.
Cationic cellulose is available from Amerchol Corp. (Edison, NJ, the polymer of polymer JR (trade mark) USA) and LR (trade mark) series is the salt of hydroxyethyl-cellulose and trimethyl ammonium substituted epoxide reaction, is called Polyquaternium 10 in the industry (CTFA).Another kind of cationic cellulose comprises the polymeric quaternary ammonium salts of hydroxyethyl-cellulose and the reaction of dodecyl dimethyl ammonium substituted epoxide, is called Polyquaternium 24 in industry (CTFA).(Edison, NJ is USA) with trade name PolymerLM-200 product sold available from Amerchol Corp. for these materials.
Other cationic polysaccharide polymer that is suitable for comprises the copolymer (for example, as United States Patent (USP) 3958581 as described in) of the cellulose ether (for example, described in United States Patent (USP) 3962418) that contains quaternary nitrogen and etherified cellulose and starch.
Adoptable suitable especially cationic polysaccharide polymer is the cationic guar gum analog derivative, for example guar gum hydroxypropyl trimonium chloride (Rhone-Poulenc sells with trade mark JAGUAR series).
Example is JAGUAR C13S, and it has the cation group and the high viscosity of low degree of substitution.JAGUAR C15 has medium substitution value and low viscosity, JAGUAR C17 (high substituted degree, high viscosity), JAGUAR C16 is that the hydroxypropylation cationic guar gum analog derivative and the JAGUAR 162 that contain low-level substituted radical and cationic quaternary ammonium group are the guar gums with the high grade of transparency, medium-viscosity and low degree of substitution.
The preferred cationic polymer is selected from cationic cellulose and cationic guar gum analog derivative.Particularly preferred cationic polymer is JAGUAR C13S, JAGUAR C15, JAGUARC17, JAGUAR C16 and JAGUAR C162.Conditioner
Compositions of the present invention can also be formulated as and be used for treatment of hair (usually after hair washing) and with the conditioner of post rinse.-conditioning surfactant
Described conditioner can comprise the conditioning surfactant of the acceptable and suitable local coating of one or more cosmetics on hair.
Suitable conditioning surfactant is selected from single cationic surfactant of using or share.Example comprises quaternary ammonium hydroxide or its salt, for example hydrochlorate.
The cationic surfactant that is applicable to hair conditioner of the present invention comprises the cetyl trimethyl ammonium chloride, INCROQUAT TMC-80 ECONOL TM22, hexadecylpyridinium chloride, tetramethyl ammonium chloride, tetraethylammonium chloride, the octyl group trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, the octyldimethyl benzyl ammonium chloride, the decyl dimethyl benzyl ammonium chloride, the stearyl dimethyl benzyl ammonium chloride, two lauryl alkyl dimethyl ammonium chlorides, dioctadecyl dimethyl ammonium chloride, the Adeps Bovis seu Bubali trimethyl ammonium chloride, cocoyl trimethyl ammonium chloride and their corresponding hydroxide.Other cationic surfactant that is suitable for comprises the material of those CTFA called afters Quaternium-5, Quaternium-31 and Quaternium-18.Also be fit to adopt above-mentioned any mixtures of material.The cationic surfactant that is specially adapted to hair conditioner of the present invention is the cetyl trimethyl ammonium chloride, available from for example DEHYQUART of Henkel sale.
In conditioner of the present invention, the level of cationic surfactant is 0.01 to 10% (weight) of composition total weight preferably, more preferably 0.05 to 5% (weight), first-selected 0.1 to 2% (weight).-aliphatic alcohol
The suitable aliphatic alcohol that is mixed with of conditioner of the present invention.Aliphatic alcohol raw material and cationic surfactant share in care composition is especially suitable, because this can form lamellar phase, wherein cationic surfactant is dispersive.
Representative fatty alcohols contains 8 to 22 carbon atoms, preferably contains 16 to 20 carbon atoms.Suitably the example of aliphatic alcohol comprises spermol, stearyl alcohol and their mixture.The application of these materials is suitably total conditioning characteristic of the present composition and makes contributions.
The concentration of aliphatic alcohol raw material in conditioner of the present invention is generally 0.01 to 10% (weight) of composition total weight, preferred 0.1 to 5% (weight).The weight proportion of cationic surfactant and aliphatic alcohol is suitably for 10: 1 to 1: 10, and preferred 4: 1 to 1: 8, the best was 1: 1 to 1: 4.(ⅴ) optional components
Compositions of the present invention can contain any other hair treatment preparation component commonly used.These other components can comprise viscosity modifier, antiseptic, coloring agent, polyhydric alcohol such as glycerol and polypropylene glycol, chelating agen such as EDTA, antioxidant such as Vitamin E acetate, spice, antimicrobial and sunscreen.These components exist with the effective dose of realizing its target separately.Usually, to divide other content be about 5% (weight) of composition total weight to these optional components at the most.
The also suitable adjuvant that is fit to hair nursing that contains of compositions of the present invention.Usually this type of component content separately is 2% (weight) in composition total weight at the most, preferably 1% (weight) at the most.
In suitable hair nursing adjuvant, be: (ⅰ) natural root of hair nutrient, for example aminoacid and sugar.Suitable amino acid whose example comprises arginine, cysteine, glutamine, glutamic acid, isoleucine, leucine, methionine, serine, valine and/or its precursor and derivant.Aminoacid can add separately, or adds with mixture, or adds as the form of peptide (as two-and tripeptides).Aminoacid also can add with the form of protein hydrolysate, for example keratin or collagen hydrolysate.The saccharide that is suitable for is glucose, dextrose and fructose.These can add separately or add with the form of for example fruit extract.(ⅱ) hair fiber beneficial agent, for example :-ceramide is used for fiber and preserves moisture and keep cuticular integrity.Ceramide is to obtain by extracting natural material, or synthetic ceramide and pseudo-neural amide.Preferred ceramide is ceramide (Quest sale).Also be fit to adopt the mixture of ceramide, for example ceramide LS (Laboratories Serobiologiques sale).-fatty acid is used for cuticular reparation and prevents infringement.Example is: branched chain fatty acid, as other analog of 18-methyl arachic acid and this series; Straight chain fatty acid is as stearic acid, myristic acid and Palmic acid; And unsaturated fatty acid, as oleic acid, linoleic acid, linolenic acid and arachidonic acid.Preferred fatty acid is an oleic acid.Fatty acid can add separately, or adds as mixture, or adds with the form of mixtures derived from the extract of for example lanoline.
Can also adopt the mixture of any above-mentioned active component.
The present invention further specifies by following non-limiting examples:
Embodiment
By being mixed with described consumption, following ingredients prepares a kind of shampoo composite: composition weight % sodium lauryl tri(oxyethyl) sulfate 2EO 14.0 cocamido propyl betaine 2.0Jaguar C13S 0.2CARBOPOL 980 0.4 polysiloxanes (1) 0.2 polyisobutylene (2) 0.5 antiseptic, coloring agent, the spice suitable quantity of water, on a small quantity to 100% (1) polysiloxanes emulsified body DC2-1787, the moisture emulsified body that contain 50% active component of crosslinked dimethiconol in the anionic/nonionic surfactant, Dow Corning sells.(2) PIB 96/003, the moisture emulsified body that contain 50% active component of polyisobutylene resin in the anionic/nonionic surfactant, and Basildon Chemicals sells.

Claims (8)

1. give the hair-treatment composition of hair for one kind, wherein in aqueous medium, contain the emulsified particles of (ⅰ) high viscosity polysiloxane polymer and (ⅱ) emulsified particles of high-molecular weight hydrocarbon material with improved plumpness, solid sense and bulkiness.
2. according to the described compositions of claim 1, wherein said polysiloxane polymer (ⅰ) is crosslinked and the percentage ratio of branched monomer unit in polysiloxane polymer (ⅰ) is 0.003 to 10%.
3. according to the described compositions of claim 2, wherein polysiloxane polymer (ⅰ) is crosslinked dimethiconol glue and has 0.004% to 2% branched monomer unit.
4. according to each described compositions of claim 1 to 3, wherein hydrocarbons (ⅱ) is the basic hydrocarbon resins of full alkane (alkene).
5. according to the described compositions of claim 4, the wherein complete basic hydrocarbon resins of alkane (alkene) is the polyisobutylene material of following formula:
H 3C-[C (CH 3) 2-CH 2-] m-R wherein m is 1-5000, and preferred 2-2500 and R are
-CH (CH 3) 2Or-C (CH 3)=CH 2
6. require each described compositions according to aforesaid right, the emulsified particles of the emulsified particles of its medium-high viscosity polysiloxane polymer (ⅰ) and high-molecular weight hydrocarbon material (ⅱ) is with polysiloxanes: the part by weight of hydro carbons is to be blended in the compositions of the present invention in 1: 20 to 2: 1.
7. require each described compositions according to aforesaid right, wherein the hair shampoo compositions contains one or more cleansing surfactants.
8. according to the described compositions of claim 6, further contain 0.01 deposition aid to about 5% (weight) of having an appointment, it is the cationic polymer that is selected from hydroxyalkyl cellulose ether compounds, cationic guar gum analog derivative and PAMC compounds.
CN 99809297 1998-08-03 1999-07-14 Hair treatment compositions Pending CN1311656A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9816870.1A GB9816870D0 (en) 1998-08-03 1998-08-03 Hair treatment compositions
GB9816870.1 1998-08-03

Publications (1)

Publication Number Publication Date
CN1311656A true CN1311656A (en) 2001-09-05

Family

ID=10836618

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 99809297 Pending CN1311656A (en) 1998-08-03 1999-07-14 Hair treatment compositions

Country Status (11)

Country Link
EP (1) EP1102574A1 (en)
JP (1) JP2002522365A (en)
CN (1) CN1311656A (en)
AR (1) AR024508A1 (en)
AU (1) AU5505399A (en)
BR (1) BR9912730A (en)
CA (1) CA2336684A1 (en)
GB (1) GB9816870D0 (en)
ID (1) ID28380A (en)
PL (1) PL345806A1 (en)
WO (1) WO2000007551A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0019493D0 (en) * 2000-08-08 2000-09-27 Unilever Plc Hair styling compositions
JP4751516B2 (en) * 2001-02-22 2011-08-17 東レ・ダウコーニング株式会社 Emulsion and production method thereof
BRPI0607354A2 (en) * 2005-04-20 2009-09-01 Avon Prod Inc long lasting cosmetic makeup
US8377425B2 (en) 2005-12-30 2013-02-19 Avon Products, Inc. Long wearing cosmetic compositions
US9198849B2 (en) 2013-07-03 2015-12-01 The Procter & Gamble Company Shampoo composition comprising low viscosity emulsified silicone polymers
JP2016533340A (en) 2013-09-27 2016-10-27 ザ プロクター アンド ギャンブル カンパニー Hair conditioning composition comprising low viscosity emulsifying silicone polymer
JP7059196B2 (en) * 2016-10-31 2022-04-25 株式会社 資生堂 Oil-in-water type external composition for skin

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995023581A2 (en) * 1994-03-01 1995-09-08 The Procter & Gamble Company Hair care compositions providing hair conditioning and style retention
ATE204738T1 (en) * 1995-10-16 2001-09-15 Procter & Gamble HAIR CARE SHAMPOO
DE69620011D1 (en) * 1995-10-16 2002-04-25 Procter & Gamble CONDITIONING SHAMPOO COMPOSITIONS WITH IMPROVED STABILITY

Also Published As

Publication number Publication date
ID28380A (en) 2001-05-17
CA2336684A1 (en) 2000-02-17
PL345806A1 (en) 2002-01-02
BR9912730A (en) 2001-05-02
GB9816870D0 (en) 1998-09-30
WO2000007551A1 (en) 2000-02-17
JP2002522365A (en) 2002-07-23
EP1102574A1 (en) 2001-05-30
AR024508A1 (en) 2002-10-16
AU5505399A (en) 2000-02-28

Similar Documents

Publication Publication Date Title
CN1146392C (en) Shampoo compositions
EP1058531B1 (en) Shampoo compositions containing silicone
EP1981472B1 (en) Use of hair treatment compositions for conditioning bleached hair
US7988954B2 (en) Hair treatment composition comprising sugar lactone
JP4307848B2 (en) Hair treatment composition containing silicone
CN1165288C (en) detergent composition
JP2000505805A (en) Shampoo compositions and methods
CN1345220A (en) Shampoo compositions
JP2001525352A (en) Hair treatment composition
EP1503724B1 (en) Hair conditioning compositions
CN1311656A (en) Hair treatment compositions
EP1482899B1 (en) Hair treatment compositions
CN1870973A (en) Antidandruff shampoo composition
CN1359284A (en) Hiar treatment compositions
WO2003092638A1 (en) Improved hair conditioning compositions containing silicone blend
MXPA00006795A (en) Shampoo compositions containing silicone
MXPA00007486A (en) Shampoo compositions

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication