CN1850913A - Bright yellow combined disperse dye - Google Patents
Bright yellow combined disperse dye Download PDFInfo
- Publication number
- CN1850913A CN1850913A CN 200610050832 CN200610050832A CN1850913A CN 1850913 A CN1850913 A CN 1850913A CN 200610050832 CN200610050832 CN 200610050832 CN 200610050832 A CN200610050832 A CN 200610050832A CN 1850913 A CN1850913 A CN 1850913A
- Authority
- CN
- China
- Prior art keywords
- formula
- bright yellow
- grades
- disperse dye
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000000986 disperse dye Substances 0.000 title claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 36
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000000975 dye Substances 0.000 abstract description 15
- 238000004043 dyeing Methods 0.000 abstract description 13
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 238000007639 printing Methods 0.000 abstract description 4
- 229920000728 polyester Polymers 0.000 abstract description 3
- 239000001046 green dye Substances 0.000 abstract 1
- 239000010865 sewage Substances 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000002270 dispersing agent Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920005552 sodium lignosulfonate Polymers 0.000 description 3
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 2
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 description 1
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- -1 alkyl naphthalene sulfonic acid formaldehyde Chemical compound 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Coloring (AREA)
Abstract
The invention discloses a bright yellow combined disperse dye suitable for printing and dyeing polyester materials, which comprises the following components: at least one or more compounds represented by formula (1) and at least one or more compounds represented by formula (2): wherein the substituents are shown in the specification. The dye can produce bright yellow products with higher concentration, reduces dyeing sewage, is a green dye meeting the environmental and ecological requirements of Oeko-Tex Standard 100, has excellent build-up, dye-uptake and level-dyeing property, and has good dyeing repeatability and better dyeing fastness.
Description
Technical field
The present invention relates to a kind of dispersed dye, is the combined disperse dye that is applicable to a kind of bright yellow of printing and dyeing polyester material.
Background technology
In the printing and dyeing of polyester material, C.I.DISP.YELLOW 134# is widely used high temperature modification bright yellow dispersed dye, but because the lifting force of its dyestuff is not fine, can't satisfy the needs of printing and dyeing.Seek the substitute that substitutes this dyestuff, must satisfy environmental requirement, and can compatibleness preferably be arranged with other dyestuff (as C.I.DISP BLUE 56# and C.I.DISP.RED 60#, C.I.DISP.RED50#, C.I.DISP.BLUE 183#, C.I.DISP.BLUE 60#).
Summary of the invention
The invention provides a kind of combined disperse dye of bright yellow, solve the lifting force problem of C.I.DISP.YELLOW134#, and can satisfy environmental requirement.
A kind of combined disperse dye of bright yellow comprises following component by weight percentage:
At least a or more than one compounds as the formula (1)
Wherein Y is H, CH
3, CH
2CH
3Or
Compound as the formula (1) can be preferably the compound of formula (3)～formula (4)
With at least a or more than one compounds as the formula (2):
R wherein
1Be H, Cl, Br, NO
2R
2Be H, Cl, Br, NO
2
R
3Be H, Cl, Br; And R
1, R
2, R
3Be not H simultaneously
Compound as the formula (2) can be preferably the compound suc as formula (5)～formula (20)
A kind of combined disperse dye of bright yellow, comprise following component by weight percentage: 5.5～43.0% at least suc as formula (1) one or more compound and 0.5～23.5% at least suc as formula (2) one or more compound, surplus is an auxiliary agent.
Above-mentioned composition preferably comprises following component: 6.05～41.44% at least suc as formula (1) one or more compound and 0.75～21.65% at least suc as formula (2) one or more compound, surplus is an auxiliary agent.
Auxiliary agent described in the present invention is common dispersants, diffusant and the tensio-active agents thereof etc. of dispersed dye when composite, preferably includes one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.As condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate etc.
The combined disperse dye of a kind of bright yellow of the present invention can be preferably combination or the formula (3) and the combination of formula (9) and formula (17) or the combination of formula (3) and formula (5) and formula (17) of formula (3) and formula (9), but is not limited to this three combinations.
The combined disperse dye of a kind of bright yellow of the present invention can prepare in order to the below method:
With above-mentioned weight ratio at least suc as formula (1) one or more compound with mix the back with auxiliary agent, water suc as formula (2) one or more compound at least and grind dispersion, spraying drying then with sand mill.Above-mentioned raw materials all can adopt the commercially available prod.
The formula (1) that the present invention adopts or the dyestuff of formula (2) structure representation are middle warm type dispersed dye, thereby it is broader than the colorant match range of application of C.I.DISP.YELLOW 134#, with other dyestuff (as C.I.DISP BLUE 56# and, C.I.DISP.BLUE 183#, C.I.DISP.BLUE 60#) colorant match, and compatibleness and dyeing circulation ratio are preferably arranged, and can keep washing fastness, the crock fastness of C.I.DISP.YELLOW134#.
Compound described in the present invention all meets environmental protection and the ecological requirement of the Oeko-Tex Standard of the European Community 100, the present invention can produce product greater concn, bright yellow, reduce dyeing waste, become and meet Oeko-Tex Standard 100 environmental protection and the ecological green colouring material that requires, have good lifting force, dye uptake and good level-dyeing property, and good dyeing repeatability and dyefastness are preferably arranged.
Embodiment
The invention will be further described below in conjunction with embodiment and Comparative Examples, but protection scope of the present invention is not limited to this.
Embodiment 1～11
According to data shown in the table 1, will be at least suc as formula (1) one or more compound with at least suc as formula one or more compound and dispersion agent condensation compound of methyl naphthalene sulfonic acid and formaldehyde (MF), diffusant benzyl naphthalene sulfonic formaldehyde condensation compound (CNF), diffusant naphthalene sulfonic acidformaldehyde condensation product (NNO), sodium lignosulfonate of (5)～formula (20) add water piece together mixed after, grind dispersion with sand milling, carry out spraying drying then.
Compound shown in its Chinese style (1) can be selected compound shown in C.I.DISP.YELLOW 120# that Zhejiang Province Runtu intercalated Co., Ltd produces, the formula (2) preferably C.I.DISP.YELLOW 135#, the 119# or the like of Zhejiang Province Runtu intercalated Co., Ltd's production for use.
Table 1
| The embodiment title | Formula (1) compound (gram) | Formula (2) compound (gram) | Dispersant MF (gram) | Dispersing agent CNF (gram) | Dispersing agent NNO (gram) | Sodium lignosulfonate (gram) | Water (gram) | ||
| Embodiment 1 | Formula (3) | 68.8 | Formula (9) | 0.8 | 30.0 | 0 | 20.5 | 50.0 | 240 |
| Embodiment 2 | Formula (3) | 8.7 | Formula (9)+formula (17) | 10.0+26.0 | 60.2 | 20.0 | 32.0 | 0 | 235 |
| Embodiment 3 | Formula (3) | 70.0 | Formula (5)+formula (17) | 5.0+7.75 | 20.5 | 20.0 | 0 | 47.0 | 255 |
| Embodiment 4 | Formula (3) | 10.5 | Formula (10)+formula (13) | 20.0+17.0 | 0 | 30.3 | 40.0 | 55.5 | 260 |
| Embodiment 5 | Formula (3) | 55.0 | Formula (11)+formula (19) | 1.1+1.5 | 40.3 | 10.0 | 30.6 | 29.0 | 250 |
| Embodiment 6 | Formula (4) | 49.0 | Formula (9) | 1.5 | 35.1 | 25.5 | 20.0 | 22.2 | 230 |
| Embodiment 7 | Formula (4) | 21.5 | Formula (6)+formula (8) | 0.8+3.5 | 47.3 | 40.1 | 0 | 57.8 | 245 |
| Embodiment 8 | Formula (4) | 36.5 | Formula (7)+formula (20) | 3.5+1.0 | 50.3 | 35.6 | 30.0 | 0 | 235 |
| Embodiment 9 | Formula (3)+formula (4) | 20.0+ 25.0 | Formula (5)+formula (9)+formula (16) | 1.9+2.6+ 4.5 | 70.5 | 0 | 0 | 40.4 | 247 |
| Embodiment 10 | Formula (3)+formula (4) | 10.0+ 5.5 | Formula (6)+formula (11)+formula (13)+formula (18) | 1.5+1.0+ 0.5+3.5 | 65.1 | 20.9 | 0 | 65.1 | 250 |
| Embodiment 11 | Formula (3)+formula (4) | 15.0+ 15.5 | Formula (5)+formula (12)+formula (13)+formula (18)+formula (20) | 0.5+1.0+ 2.0+0.5+ 1.5 | 75.0 | 10.3 | 10.0 | 45.1 | 254 |
The dispersed dye that the foregoing description is made carry out performance test, and testing method is as follows:
Respectively get the dispersed dye that 0.5 gram embodiment 1～11 makes, water is mixed with the dispersion suspension liquid that concentration is 0.5g/500ml respectively, drawing 20ml mixes with the water of 80ml, regulate dye bath PH to 5 with acetic acid, be warmed up to 60 ℃ then, put into the 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 ℃, be incubated 30 minutes, sampling when being cooled to 80 ℃.Observe cloth specimen coloured light and adopt GB/T3921-1997, GB/T3920-1997, GB/T5718-1997 to measure its dyefastness.Measurement result sees Table 2.
Comparative Examples 1
The dyestuff of getting 0.5 gram DISPERSE YELLOW H-4GL, 100% (primary structure is C.I.DISP.YELLOW 134#) repeats the performance test methods of embodiment 11.Test result sees Table 2.
Table 2
| Embodiment | Color | Washing fastness (60 ℃) | Crock fastness | Sublimation fastness |
| Embodiment 1 | Bright yellow | 4～5 grades | 4～5 grades | 4～5 grades |
| Embodiment 2 | Bright yellow | 4～5 grades | 4～5 grades | 4 grades |
| Embodiment 3 | Bright yellow | 4～5 grades | 4～5 grades | 4～5 grades |
| Embodiment 4 | Bright yellow | 4～5 grades | 4～5 grades | 4～5 grades |
| Embodiment 5 | Bright yellow | 4～5 grades | 4～5 grades | 4 grades |
| Embodiment 6 | Bright yellow | 4～5 grades | 4～5 grades | 4～5 grades |
| Embodiment 7 | Bright yellow | 4～5 grades | 4～5 grades | 4 grades |
| Embodiment 8 | Bright yellow | 4～5 grades | 4～5 grades | 4～5 grades |
| Embodiment 9 | Bright yellow | 4～5 grades | 4～5 grades | 4～5 grades |
| Embodiment 10 | Bright yellow | 4～5 grades | 4～5 grades | 4～5 grades |
| Embodiment 11 | Bright yellow | 4～5 grades | 4～5 grades | 4～5 grades |
| Comparative Examples 1 | Bright yellow | 4 grades | 4 grades | 4 grades |
Claims (8)
1. the combined disperse dye of a bright yellow comprises following component:
At least a or more than one compounds as the formula (1)
Wherein Y is H, CH
3, CH
2CH
3Or
With at least a or more than one compounds as the formula (2):
R wherein
1Be H, Cl, Br, NO
2R
2Be H, Cl, Br, NO
2
R
3Be H, Cl, Br; And R
1, R
2, R
3Be not H simultaneously
2. the combined disperse dye of bright yellow according to claim 1 is characterized in that: as
Compound shown in the formula (1) can be selected from a kind of in formula (3)～formula (4):
3. the combined disperse dye of bright yellow according to claim 1 is characterized in that: as
Optional a kind of from suc as formula in (5)～formula (20) of compound shown in the formula (2):
4. the combined disperse dye of bright yellow according to claim 1 is characterized in that: be made up of suc as formula the compound shown in (3), the formula (9) following:
With
5. the combined disperse dye of bright yellow according to claim 1 is characterized in that: be made up of suc as formula the compound shown in (3), formula (9), the formula (17) following:
With
And:
6. the combined disperse dye of bright yellow according to claim 1 is characterized in that: be made up of suc as formula the compound shown in (3), formula (5), the formula (17) following:
With
And:
7. the combined disperse dye of bright yellow according to claim 1, it is characterized in that: described combined disperse dye, comprise following component by weight percentage: 5.5～43.0% at least suc as formula (1) one or more compound and 0.5～23.5% at least suc as formula (2) one or more compound, surplus is an auxiliary agent.
8. the combined disperse dye of bright yellow according to claim 5, it is characterized in that: described combined disperse dye, comprise following component by weight percentage: 6.05～41.44% at least suc as formula (1) one or more compound and 0.75～21.65% at least suc as formula (2) one or more compound, surplus is an auxiliary agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610050832XA CN100429282C (en) | 2006-05-18 | 2006-05-18 | Bright yellow combined disperse dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200610050832XA CN100429282C (en) | 2006-05-18 | 2006-05-18 | Bright yellow combined disperse dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1850913A true CN1850913A (en) | 2006-10-25 |
| CN100429282C CN100429282C (en) | 2008-10-29 |
Family
ID=37132415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200610050832XA Active CN100429282C (en) | 2006-05-18 | 2006-05-18 | Bright yellow combined disperse dye |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100429282C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101100560B (en) * | 2007-07-24 | 2010-08-11 | 浙江龙盛染料化工有限公司 | Deep color dispersion dyes composition |
| CN101864197A (en) * | 2010-07-07 | 2010-10-20 | 陶国来 | Yellow disperse dye with high sublimation fastness |
| CN102924975A (en) * | 2012-11-12 | 2013-02-13 | 浙江闰土股份有限公司 | Disperse dye composition and disperse dyes, and preparation method and purpose thereof |
| CN103709790A (en) * | 2011-12-20 | 2014-04-09 | 上海安诺其纺织化工股份有限公司 | Dye composition, dye, preparation methods thereof and raw material composition of dye |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101775236A (en) * | 2010-01-29 | 2010-07-14 | 陶国来 | Disperse dye |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3711672B2 (en) * | 1996-12-24 | 2005-11-02 | 三菱化学株式会社 | Thermal transfer sheet |
| JPH10316878A (en) * | 1997-05-19 | 1998-12-02 | Sumitomo Chem Co Ltd | Disperse dye composition |
| JP2004339252A (en) * | 2003-05-12 | 2004-12-02 | Dystar Japan Ltd | Disperse dye mixture suitable for dyeing composite material of polyurethane and polyester |
-
2006
- 2006-05-18 CN CNB200610050832XA patent/CN100429282C/en active Active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101100560B (en) * | 2007-07-24 | 2010-08-11 | 浙江龙盛染料化工有限公司 | Deep color dispersion dyes composition |
| CN101864197A (en) * | 2010-07-07 | 2010-10-20 | 陶国来 | Yellow disperse dye with high sublimation fastness |
| CN103709790A (en) * | 2011-12-20 | 2014-04-09 | 上海安诺其纺织化工股份有限公司 | Dye composition, dye, preparation methods thereof and raw material composition of dye |
| CN102924975A (en) * | 2012-11-12 | 2013-02-13 | 浙江闰土股份有限公司 | Disperse dye composition and disperse dyes, and preparation method and purpose thereof |
| CN102924975B (en) * | 2012-11-12 | 2014-09-10 | 浙江闰土股份有限公司 | Disperse dye composition and disperse dyes, and preparation method and purpose thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100429282C (en) | 2008-10-29 |
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