CN1837295A - Combined blue disperse dye - Google Patents
Combined blue disperse dye Download PDFInfo
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- CN1837295A CN1837295A CN 200610050428 CN200610050428A CN1837295A CN 1837295 A CN1837295 A CN 1837295A CN 200610050428 CN200610050428 CN 200610050428 CN 200610050428 A CN200610050428 A CN 200610050428A CN 1837295 A CN1837295 A CN 1837295A
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- blue disperse
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Abstract
The invention provides a combined blue dispersion dye comprising one or more compounds represented by structural formula (1) and one or more compounds represented by structural formula (2). The dye can be used for the printing and dyeing for polyester materials.
Description
Technical field
The present invention relates to a kind of dispersed dye, is a kind of combined blue disperse dye that is applicable to printing and dyeing polyester material.
Background technology
In the printing and dyeing of polyester material, enhancing rate when the vividness of the blue disperse dye thumping majority color that adopts, PH susceptibility, sublimation fastness, washing fastness, crock fastness, pad-dry-cure dyeing can not be taken into account mutually, though the Chang Yong C.I. Disperse Blue-56 color and luster that when the dyeing of trevira, can obtain to become clear and have good photostabilization for example, but its tinctorial yield is very low, dyeing cost height, and contamination level is big in the production process.
Some enterprises are by making up C.I. Disperse Blue-56 and other azoic dyestuff, as publication number is that the application for a patent for invention of CN1640944A discloses a kind of disperse dye composition, exactly by C.I. Disperse Blue-56 and other two kinds of azoic dyestuffs are made up, reduce the consumption of C.I. Disperse Blue-56, improve dyeing behavior, but still can't take into account various dyeing behavioies.Owing to can decomposite objectionable impuritiess such as arylamine during some composition heating, not meet the environmental protection standard that meets Germany and the Okeo-Tex Standard of European Union 100.
Summary of the invention
The invention provides a kind of combined blue disperse dye, solved environmental issue, and can take into account dyeing behavioies such as consistency, washing fastness, crock fastness and sublimation fastness.
A kind of combined blue disperse dye, it comprises one or more the compound shown in the general structure (1)
N=3,4 or 5
And one or more the compound shown in the general structure (2)
Wherein X=-Cl ,-Br ,-I ,-CN
Y＝-H、-Cl、-Br、-I、-CN、-NO
2
R
2＝R
3＝-CH
2CH
3、-CH
3、-CH
2CH
2CH
3
R
1＝-NHCOCH
3、-NHCOCH
2CH
3
Can be preferably suc as formula the compound shown in (1) general structure
Can be preferably suc as formula the compound shown in (2) general structure
A kind of combined blue disperse dye comprises 1.70～60.30% the compound of the compound shown in general structure (1) and 0.01～17.10% shown in general structure (2) by weight percentage, and surplus is an auxiliary agent.
Auxiliary agent described in the present invention is common dispersants, diffusant and the tensio-active agents thereof etc. of dispersed dye when composite, preferably includes one of following or its composition: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.As condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate etc.
A kind of novel combined blue disperse dye of the present invention can prepare in order to the below method:
With in the formula (1) of above-mentioned weight ratio one or more compound and general formula (2) in one or more compound and auxiliary agent, water combination back grind dispersion with sand mill, spraying drying then.Above-mentioned compound all can adopt the commercially available prod.
Compound described in the present invention all meets environmental protection and the ecological requirement of the Oeko-Tex Standard of the European Community 100, for meeting Oeko-Tex Standard 100 environmental protection and the ecological green colouring material that requires, combination back color and luster is plentiful, be used for the printing and dyeing of polyester material, have higher enhancing rate, sublimation fastness, washing fastness, crock fastness and good premium propertiess such as consistency.
Embodiment
The invention will be further described below in conjunction with embodiment and Comparative Examples, but protection scope of the present invention is not limited to this.
Embodiment 1～17
According to data shown in the table 1, with the compound of the compound of formula (1), formula (2), with dispersion agent condensation compound of methyl naphthalene sulfonic acid and formaldehyde (MF), diffusant benzyl naphthalene sulfonic formaldehyde condensation compound (CNF), diffusant naphthalene sulfonic acidformaldehyde condensation product (NNO), sodium lignosulfonate add water piece together mix after, grind dispersion with sand milling, carry out spraying drying then.
C.I.DISP.BLUE 165#, C.I.DISP.BLUE 183#, C.I.DISP.BLUE 183:1#, C.I.DISP.BLUE 366#, C.I.DISP.BLUE 165:1#, C.I.DISP.BLUE 224# or the like that C.I.DISP.BLUE 60#, the compound in the general formula (2) that the compound of its Chinese style (1) indication can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce.
Table 1
| Embodiment | Compound (gram) shown in the formula (1) | Compound (gram) shown in the formula (2) | Dispersant MF (gram) | Dispersing agent CNF (gram) | Dispersing agent NNO (gram) | Diffusant sodium lignosulfonate (gram) | Water (gram) | ||
| 1 | Formula (21) | 50.0 | Formula (3) | 0.85 | 20.0 | 2.0 | 5.0 | 5.3 | 125 |
| 2 | Formula (21) | 1.2 | Formula (4) | 0.7 | 30.5 | 0 | 15.0 | 19.0 | 105 |
| 3 | Formula (21) | 46.0 | Formula (5) | 13.1 | 7.9 | 5.0 | 0 | 5.0 | 120 |
| 4 | Formula (21) | 1.4 | Formula (6) | 14.2 | 0 | 20.0 | 20.0 | 26.0 | 125 |
| 5 | Formula (22) | 25.0 | Formula (7) | 14.5 | 20.0 | 20.0 | 0 | 10.5 | 135 |
| 6 | Formula (22) | 10.0 | Formula (8) | 8.0 | 15.5 | 0 | 15.6 | 17.2 | 100 |
| 7 | Formula (22) | 5.5 | Formula (9) | 8.4 | 30.5 | 10.0 | 28.02 | 0 | 124 |
| 8 | Formula (22) | 38.8 | Formula (10) | 1.2 | 10 | 10.5 | 17.5 | 10.0 | 132 |
| 9 | Formula (21)+formula (22) | 25.5 | Formula (3)+formula (4) | 13.8 | 15.0 | 25.0 | 10.0 | 0 | 133 |
| 10 | Formula (21)+formula (22) | 1.3 | Formula (3)+formula (9) | 0.9 | 30.0 | 25.0 | 0 | 9.5 | 110 |
| 11 | Formula (21) | 6.7 | Formula (4)+formula (15) | 10.5 | 35 | 0 | 35.0 | 0 | 135 |
| 12 | Formula (21)+formula (22) | 48.0 | Formula (6)+formula (19) | 11.5 | 8.5 | 8.5 | 0 | 5.0 | 120 |
| 13 | Formula (21)+formula (22) | 40.5 | Formula (5)+formula (8)+formula (13)+formula (17)+formula (18) | 1.5 | 15.0 | 5.5 | 15.5 | 13.0 | 130 |
| 14 | Formula (21)+formula (22) | 1.8 | Formula (5)+formula (17) | 16.5 | 25.5 | 20.0 | 10.0 | 10.5 | 130 |
| 15 | Formula (21)+formula (22) | 43.5 | Formula (7)+formula (10) | 1.9 | 15.0 | 20.5 | 15.0 | 0 | 130 |
| 16 | Formula (22 | 9.0 | Formula (3)+formula (11)+formula (16) | 9.0 | 0 | 15.0 | 16.5 | 17.0 | 105 |
| 17 | Formula (21) | 30.0 | Formula (6)+formula (8+formula (11)+formula (20) | 18.5 | 10.0 | 25.5 | 10.5 | 10.5 | 145 |
The dispersed dye that the foregoing description is made carry out performance test, and testing method is as follows:
Respectively get the dispersed dye that 0.5 gram embodiment 1～17 makes, water is mixed with the dispersion suspension liquid that concentration is 0.5g/500ml respectively, draw the water combination of 20m1 and 80ml, regulate dye bath PH to 5 with acetic acid, be warmed up to 60 ℃ then, put into the 2g trevira simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 ℃, be incubated 30 minutes, sampling when being cooled to 80 ℃.Observe cloth specimen coloured light and adopt GB/T3921-1997, GB/T3920-1997, GB/T5718-1997 to measure its dyefastness.Measurement result sees Table 2.
Table 2
| The embodiment title | Color | Washing fastness (60 ℃) | Crock fastness | Sublimation fastness (180 ℃) |
| Embodiment 1 | Gorgeous indigo plant | 5 grades | 4～5 grades | 5 grades |
| Embodiment 2 | Gorgeous indigo plant | 5 grades | 5 grades | 4～5 grades |
| Embodiment 3 | Gorgeous indigo plant | 4～5 grades | 5 grades | 5 grades |
| Embodiment 4 | Gorgeous indigo plant | 5 grades | 4～5 grades | 4～5 grades |
| Embodiment 5 | Gorgeous indigo plant | 5 grades | 5 grades | 5 grades |
| Embodiment 6 | Gorgeous indigo plant | 4～5 grades | 4～5 grades | 4～5 grades |
| Embodiment 7 | Gorgeous indigo plant | 5 grades | 5 grades | 5 grades |
| Embodiment 8 | Gorgeous indigo plant | 4～5 grades | 4～5 grades | 4～5 grades |
| Embodiment 9 | Gorgeous indigo plant | 5 grades | 4～5 grades | 4～5 grades |
| Embodiment 10 | Gorgeous indigo plant | 4～5 grades | 5 grades | 5 grades |
| Embodiment 11 | Gorgeous indigo plant | 4～5 grades | 4～5 grades | 5 grades |
| Embodiment 12 | Gorgeous indigo plant | 5 grades | 5 grades | 4～5 grades |
| Embodiment 13 | Gorgeous indigo plant | 4～5 grades | 5 grades | 5 grades |
| Embodiment 14 | Gorgeous indigo plant | 5 grades | 4～5 grades | 4～5 grades |
| Embodiment 15 | Gorgeous indigo plant | 5 grades | 4～5 grades | 5 grades |
| Embodiment 16 | Gorgeous indigo plant | 4～5 grades | 5 grades | 4～5 grades |
| Embodiment 17 | Gorgeous indigo plant | 5 grades | 4～5 grades | 4～5 grades |
A kind of combined blue disperse dye of the present invention has high level washing fastness, crock fastness and sublimation fastness, and the PH dyeing scope of broad is arranged.
Claims (4)
1. combined blue disperse dye comprises one or more the compound shown in formula (1) general structure
N=3,4 or 5
And one or more the compound shown in formula (2) general structure
Wherein X=-Cl ,-Br ,-I ,-CN
Y＝-H、-Cl、-Br、-I、-CN、-NO
2
R
2＝R
3＝-CH
2CH
3、-CH
3、-CH
2CH
2CH
3
R
1＝-NHCOCH
3、-NHCOCH
2CH
3
2. combined blue disperse dye according to claim 1 is characterized in that: be selected from the compound shown in following formula (21) or formula (22) structural formula suc as formula the compound shown in (1) general structure:
3. combined blue disperse dye according to claim 1 is characterized in that: be selected from a kind of with the compound shown in following formula (3)～(20) structural formula suc as formula the compound shown in (2) general structure:
4. according to the arbitrary described combined blue disperse dye of claim 1～3, it is characterized in that: described combined blue disperse dye comprises 1.70～60.30% the compound of the compound shown in general structure (1) and 0.01～17.10% shown in general structure (2) by weight percentage, and surplus is an auxiliary agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100504282A CN100393817C (en) | 2006-04-19 | 2006-04-19 | Combined blue disperse dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100504282A CN100393817C (en) | 2006-04-19 | 2006-04-19 | Combined blue disperse dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1837295A true CN1837295A (en) | 2006-09-27 |
| CN100393817C CN100393817C (en) | 2008-06-11 |
Family
ID=37014808
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100504282A Active CN100393817C (en) | 2006-04-19 | 2006-04-19 | Combined blue disperse dye |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100393817C (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101671492A (en) * | 2009-10-21 | 2010-03-17 | 张善生 | Composition of cobaly blue dispersed dye |
| CN101974252A (en) * | 2010-07-30 | 2011-02-16 | 江苏亚邦染料股份有限公司 | High-fastness disperse violet dye for direct printing of polyester fiber |
| CN101984002A (en) * | 2010-07-30 | 2011-03-09 | 江苏亚邦染料股份有限公司 | Blue disperse dye with high light fastness for polyester fiber |
| CN101984003A (en) * | 2010-07-30 | 2011-03-09 | 江苏亚邦染料股份有限公司 | High fastness disperse turquoise blue dye for directly printing polyester fibers |
| CN101983999A (en) * | 2010-07-30 | 2011-03-09 | 江苏亚邦染料股份有限公司 | Compound disperse blue dye for direct printing |
| CN102010616A (en) * | 2010-11-01 | 2011-04-13 | 韩耀君 | Dispersing agent for dyeing of polyester fabrics and production process thereof |
| CN103554990A (en) * | 2013-10-30 | 2014-02-05 | 江苏亚邦染料股份有限公司 | Blue disperse dye composition with high washing fastness and high light fastness |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102040864A (en) * | 2010-11-01 | 2011-05-04 | 韩耀君 | Colorant for dyeing and printing polyester fabrics and production process thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1317339C (en) * | 2005-09-16 | 2007-05-23 | 浙江闰土股份有限公司 | Combined disperse dye for printing and dyeing polyester material |
-
2006
- 2006-04-19 CN CNB2006100504282A patent/CN100393817C/en active Active
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101671492A (en) * | 2009-10-21 | 2010-03-17 | 张善生 | Composition of cobaly blue dispersed dye |
| CN101671492B (en) * | 2009-10-21 | 2013-05-08 | 张善生 | Composition of cobaly blue dispersed dye |
| CN101974252A (en) * | 2010-07-30 | 2011-02-16 | 江苏亚邦染料股份有限公司 | High-fastness disperse violet dye for direct printing of polyester fiber |
| CN101984002A (en) * | 2010-07-30 | 2011-03-09 | 江苏亚邦染料股份有限公司 | Blue disperse dye with high light fastness for polyester fiber |
| CN101984003A (en) * | 2010-07-30 | 2011-03-09 | 江苏亚邦染料股份有限公司 | High fastness disperse turquoise blue dye for directly printing polyester fibers |
| CN101983999A (en) * | 2010-07-30 | 2011-03-09 | 江苏亚邦染料股份有限公司 | Compound disperse blue dye for direct printing |
| CN101983999B (en) * | 2010-07-30 | 2014-02-05 | 江苏亚邦染料股份有限公司 | Compound disperse blue dye for direct printing |
| CN101984002B (en) * | 2010-07-30 | 2014-02-05 | 江苏亚邦染料股份有限公司 | Blue disperse dye with high light fastness for polyester fiber |
| CN102010616A (en) * | 2010-11-01 | 2011-04-13 | 韩耀君 | Dispersing agent for dyeing of polyester fabrics and production process thereof |
| CN102010616B (en) * | 2010-11-01 | 2013-04-17 | 韩耀君 | Dispersing agent for dyeing of polyester fabrics and production process thereof |
| CN103554990A (en) * | 2013-10-30 | 2014-02-05 | 江苏亚邦染料股份有限公司 | Blue disperse dye composition with high washing fastness and high light fastness |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100393817C (en) | 2008-06-11 |
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