CN1821313B - 具有还原稳定性的铁酸锌颜料、其制备方法及其用途 - Google Patents
具有还原稳定性的铁酸锌颜料、其制备方法及其用途 Download PDFInfo
- Publication number
- CN1821313B CN1821313B CN2006100040358A CN200610004035A CN1821313B CN 1821313 B CN1821313 B CN 1821313B CN 2006100040358 A CN2006100040358 A CN 2006100040358A CN 200610004035 A CN200610004035 A CN 200610004035A CN 1821313 B CN1821313 B CN 1821313B
- Authority
- CN
- China
- Prior art keywords
- pigment
- zinc ferrite
- zinc
- lithium
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 83
- 238000000034 method Methods 0.000 title claims abstract description 13
- 230000009467 reduction Effects 0.000 title abstract description 14
- 229910001308 Zinc ferrite Inorganic materials 0.000 claims abstract description 68
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 claims abstract description 68
- 229920001903 high density polyethylene Polymers 0.000 claims description 31
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 30
- 239000004700 high-density polyethylene Substances 0.000 claims description 30
- 238000012360 testing method Methods 0.000 claims description 25
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 24
- 229910052744 lithium Inorganic materials 0.000 claims description 23
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 21
- 238000001354 calcination Methods 0.000 claims description 16
- 229910052742 iron Inorganic materials 0.000 claims description 15
- 239000011787 zinc oxide Substances 0.000 claims description 12
- 238000005259 measurement Methods 0.000 claims description 10
- 229920003023 plastic Polymers 0.000 claims description 7
- 239000004033 plastic Substances 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000011455 calcium-silicate brick Substances 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 210000003298 dental enamel Anatomy 0.000 claims description 3
- 238000005304 joining Methods 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims description 2
- 235000013305 food Nutrition 0.000 claims description 2
- 239000000976 ink Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- 239000003826 tablet Substances 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 3
- 238000001914 filtration Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 150000002642 lithium compounds Chemical class 0.000 description 6
- 239000002893 slag Substances 0.000 description 6
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Chemical compound [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 210000002706 plastid Anatomy 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000001052 yellow pigment Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001062009 Indigofera Species 0.000 description 1
- 229910000502 Li-aluminosilicate Inorganic materials 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 238000001636 atomic emission spectroscopy Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- PSHMSSXLYVAENJ-UHFFFAOYSA-N dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate Chemical compound [Li+].[Li+].O=BOB([O-])OB([O-])OB=O PSHMSSXLYVAENJ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 description 1
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium hydroxide monohydrate Substances [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 1
- 229940040692 lithium hydroxide monohydrate Drugs 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- -1 lithium salt compound Chemical class 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 229910052912 lithium silicate Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002900 organolithium compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000003918 potentiometric titration Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229940071182 stannate Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/0018—Mixed oxides or hydroxides
- C01G49/0063—Mixed oxides or hydroxides containing zinc
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/22—Compounds of iron
- C09C1/24—Oxides of iron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Compounds Of Iron (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005003356.3 | 2005-01-25 | ||
| DE102005003356A DE102005003356A1 (de) | 2005-01-25 | 2005-01-25 | Reduktionsstabile Zinkferrit-Farbpigmente, Verfahren zu ihrer Herstellung sowie deren Verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1821313A CN1821313A (zh) | 2006-08-23 |
| CN1821313B true CN1821313B (zh) | 2012-11-14 |
Family
ID=36295406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100040358A Active CN1821313B (zh) | 2005-01-25 | 2006-01-25 | 具有还原稳定性的铁酸锌颜料、其制备方法及其用途 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20060162613A1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP1683840B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5122075B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN1821313B (cg-RX-API-DMAC7.html) |
| AU (1) | AU2006200051B2 (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0600127B1 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2533748A1 (cg-RX-API-DMAC7.html) |
| CO (1) | CO5770110A1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE102005003356A1 (cg-RX-API-DMAC7.html) |
| DK (1) | DK1683840T3 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2791676T3 (cg-RX-API-DMAC7.html) |
| MX (1) | MXPA06000881A (cg-RX-API-DMAC7.html) |
| PL (1) | PL1683840T3 (cg-RX-API-DMAC7.html) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2005206927C1 (en) * | 2004-01-16 | 2011-05-19 | Battelle Memorial Institute | Methods and apparatus for producing ferrate(VI) |
| DE602005027490D1 (de) * | 2004-11-12 | 2011-05-26 | Battelle Memorial Inst Columbus | Dekontaminationsmittel |
| US8663607B2 (en) | 2007-03-09 | 2014-03-04 | Battelle Memorial Institute | Ferrate(VI)-containing compositions and methods of using ferrate(VI) |
| EP2268345A1 (en) * | 2008-03-26 | 2011-01-05 | Battelle Memorial Institute | Apparatus and methods of providing diatomic oxygen (o2) using ferrate(vi)-containing compositions |
| WO2010045657A1 (en) * | 2008-10-17 | 2010-04-22 | Battelle Memorial Institute | Corrosion resistant primer coating |
| CN107032611A (zh) * | 2016-11-05 | 2017-08-11 | 江苏省宜兴彩陶工艺厂 | 低温烧成蟹青釉及其制备方法 |
| CN110560070B (zh) * | 2019-08-09 | 2020-09-25 | 红河学院 | 一种用含铁废料制备掺杂纳米铁酸锌的方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1554712A (zh) * | 2003-12-23 | 2004-12-15 | 长沙矿冶研究院 | 一种铁酸锌颜料粉体的制备方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2734034A (en) * | 1956-02-07 | Magnetic compositions | ||
| US2904395A (en) | 1955-02-24 | 1959-09-15 | Columbian Carbon | Method for producing zinc ferrite pigment |
| GB1071611A (en) * | 1964-06-15 | 1967-06-07 | Sumitomo Special Melts Company | Process for producting ferrites |
| FR1530609A (fr) * | 1967-05-18 | 1968-06-28 | Cie Des Ferrites Electroniques | Composition de ferrites de lithium pour éléments de mémoires magnétiques et procédé de fabrication de ces éléments |
| US3832455A (en) | 1972-10-25 | 1974-08-27 | Smith G Labor | Preparation of zinc ferrite yellow pigments |
| US4222790A (en) | 1979-03-23 | 1980-09-16 | Cities Service Company | Calcination of ferrite tans |
| JPS5943406B2 (ja) | 1980-06-23 | 1984-10-22 | 戸田工業株式会社 | 黄色系顔料 |
| DE3136279A1 (de) * | 1981-09-12 | 1983-03-24 | Bayer Ag, 5090 Leverkusen | Halogenarme zinkferrit-pigmente, verfahren zu ihrer herstellung und ihre verwendung |
| DE3409722A1 (de) * | 1984-03-16 | 1985-09-26 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von gelbbraunen zinkferritpigmenten |
| DE3819626A1 (de) | 1988-06-09 | 1989-12-14 | Bayer Ag | Thermostabile zinkferrit-farbpigmente, verfahren zu ihrer herstellung sowie deren verwendung |
| DE19642534C2 (de) * | 1996-10-15 | 1998-10-15 | Bayer Ag | Magnetitteilchen, bestehend aus magnetischen Eisenoxid, Verfahren zur Herstellung und dessen Verwendung |
| DE10349810A1 (de) * | 2003-10-24 | 2005-05-25 | Bayer Chemicals Ag | Thermostabile Zinkferrit-Farbpigmente, Verfahren zu ihrer Herstellung sowie deren Verwendung |
-
2005
- 2005-01-25 DE DE102005003356A patent/DE102005003356A1/de not_active Ceased
-
2006
- 2006-01-06 AU AU2006200051A patent/AU2006200051B2/en not_active Ceased
- 2006-01-11 EP EP06000443.9A patent/EP1683840B1/de active Active
- 2006-01-11 PL PL06000443T patent/PL1683840T3/pl unknown
- 2006-01-11 ES ES06000443T patent/ES2791676T3/es active Active
- 2006-01-11 DK DK06000443.9T patent/DK1683840T3/da active
- 2006-01-12 US US11/330,513 patent/US20060162613A1/en not_active Abandoned
- 2006-01-23 MX MXPA06000881A patent/MXPA06000881A/es active IP Right Grant
- 2006-01-23 JP JP2006014159A patent/JP5122075B2/ja active Active
- 2006-01-24 BR BRPI0600127-0A patent/BRPI0600127B1/pt active IP Right Grant
- 2006-01-24 CA CA002533748A patent/CA2533748A1/en not_active Abandoned
- 2006-01-25 CO CO06006801A patent/CO5770110A1/es active IP Right Grant
- 2006-01-25 CN CN2006100040358A patent/CN1821313B/zh active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1554712A (zh) * | 2003-12-23 | 2004-12-15 | 长沙矿冶研究院 | 一种铁酸锌颜料粉体的制备方法 |
Non-Patent Citations (2)
| Title |
|---|
| US 4,681,637 A,1987.07.21,说明书第1栏第18-23行，第3-4栏实施例1. |
| US 4,985,078 A,1991.01.15,说明书第3栏第13-17行,第3-4栏实施例1-2. |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0600127B1 (pt) | 2021-03-02 |
| ES2791676T3 (es) | 2020-11-05 |
| EP1683840A3 (de) | 2008-08-06 |
| EP1683840A2 (de) | 2006-07-26 |
| PL1683840T3 (pl) | 2020-10-19 |
| CO5770110A1 (es) | 2007-06-29 |
| BRPI0600127A (pt) | 2006-09-19 |
| EP1683840B1 (de) | 2020-04-08 |
| MXPA06000881A (es) | 2006-07-24 |
| AU2006200051B2 (en) | 2012-03-01 |
| DK1683840T3 (da) | 2020-07-06 |
| CA2533748A1 (en) | 2006-07-25 |
| JP2006206432A (ja) | 2006-08-10 |
| CN1821313A (zh) | 2006-08-23 |
| DE102005003356A1 (de) | 2006-07-27 |
| AU2006200051A1 (en) | 2006-08-10 |
| JP5122075B2 (ja) | 2013-01-16 |
| US20060162613A1 (en) | 2006-07-27 |
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