CN1768243A - Method for suddenly cooling high-temperature gas - Google Patents

Method for suddenly cooling high-temperature gas Download PDF

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Publication number
CN1768243A
CN1768243A CNA2004800091931A CN200480009193A CN1768243A CN 1768243 A CN1768243 A CN 1768243A CN A2004800091931 A CNA2004800091931 A CN A2004800091931A CN 200480009193 A CN200480009193 A CN 200480009193A CN 1768243 A CN1768243 A CN 1768243A
Authority
CN
China
Prior art keywords
quenching
water
area
equipment
cooling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2004800091931A
Other languages
Chinese (zh)
Inventor
贡特尔·H·基斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Thermoselect AG
Original Assignee
Thermoselect AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thermoselect AG filed Critical Thermoselect AG
Publication of CN1768243A publication Critical patent/CN1768243A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28CHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
    • F28C3/00Other direct-contact heat-exchange apparatus
    • F28C3/06Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/04Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C10K1/06Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials combined with spraying with water
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28CHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
    • F28C3/00Other direct-contact heat-exchange apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28CHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
    • F28C3/00Other direct-contact heat-exchange apparatus
    • F28C3/06Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour
    • F28C3/08Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour with change of state, e.g. absorption, evaporation, condensation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/0075Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for syngas or cracked gas cooling systems

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Heat Treatment Of Articles (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Industrial Gases (AREA)
  • Furnace Details (AREA)

Abstract

The invention relates to a quench device for suddenly cooling a hot gas stream with the aid of quench water. The inventive quench device comprises a gas supply line and a gas drainage pipe. Said quench water is at least partially cooled by means of a heat exchanger. In addition, said quench device is provided with a cooling water circuit for cooling the first area of the gas stream and with a second separate cooling circuit which cools a second area of the gas stream and is arranged downstream.

Description

The method of quenching of high-temperature gas
Technical field
Equipment according to claim 1 and method according to claim 9 the present invention relates to the quenching to high-temperature gas.In addition, according to claim 15, the present invention relates to the use in the high temperature circulation process according to equipment of the present invention and the method according to this invention.
Background technology
In the extensive application of high-temperature technology technology, waste gas is cooled rapidly by adding the liquid such as water.This is called " quenching " process; The equipment that is used for this process is called " quenching equipment ".
Water circulates by means of the quenching pump.Between water inlet and delivery port, quenching water has heated about 10 to 30 ℃.This heat energy distributes from system by means of the quenching heat exchanger.
Described process is characterised in that: except refrigerating gas, the impurity that is arranged in gas also is deposited in liquid.To pollute the device of heat exchanger, pipeline and all carrying quenching water inevitably.Therefore must clean repeatedly.
Summary of the invention
The objective of the invention is to propose a kind of equipment and a kind of method, wherein, at first gas is cooled very effectively, and secondly cleaning can reduce to minimum.In addition, the objective of the invention is to propose the usage of a kind of like this equipment and such a kind of method.
The usage of the described equipment of claim 1, the described method of claim 9 and claim 15 has realized this purpose of the present invention.
The specific embodiment
Therefore, the present invention is to have proposed the such improvement of two stage quenching processes for the solution of the quenching problem of high-temperature gas.In two stages or zone of high temperature gas flow, cooling is to be undertaken by two cooling circuits that separate, and these two stages or zone are along flow direction continuous distributed of high-temperature gas.Therefore, quenching water circulates in two loops that separate.
Loop 1 is used for carry out actual quenching along the high-temperature gas in the first area of gas flow direction, and the solid particle that is included in the gas also precipitates herein; Loop 2 is used for the high-temperature gas along the second area of gas flow direction is cooled to final temperature at last.
According to the present invention, the usage of a kind of like this equipment or correlation method is provided, be used for cooling off the forming gas that occurs in the high temperature circulation process.
The invention has the beneficial effects as follows: solid particle is located, is deposited in the finite region of cooling by quenching.In conjunction with embodiment described below, can avoid of the pollution of precipitated solid particle fully to heat exchanger.
The quenching heat exchanger preferably only is arranged in the scavenger circuit 2.The energy that is included in the high-temperature gas dissipates by means of these quenching heat exchangers.Therefore, loop 1, i.e. Shi Ji quenching loop, being implemented as does not have heat exchanger.Therefore got rid of pollution basically to first cooling circuit.
Preferably a kind of elongate device of quenching equipment, it has an interior pipe that is provided with one heart, pipe and flow through described quenching equipment from the top to the bottom in hot gas enters from the top.In lower area, gas under the effect of a transfer and turn to, the outside annular gap and leave described quenching equipment in the upper end of upwards flowing through afterwards.In interior pipe, preferably be cooled to 95 ℃~70 ℃ from 1000 ℃~2000 ℃, especially be preferably 85 ℃, and be cooled to 70 ℃~40 ℃ from 85 ℃ in the annular gap externally, be preferably 60 ℃.
In the preferred variants of described equipment, quenching water is discharged by freely overflowing to the loop 1 from loop 2.
In a further advantageous embodiment, the water level of the quenching water in loop 1 and loop 2 is by the water level control of the quenching water in the loop 1.The device that is used for regulating water level is preferably by providing water or 1 discharge water realizes from the loop to loop 1.
In the method according to the invention, preferably to being in 1000 ℃ to 2000 ℃, the waste gas that is preferably 1200 ℃ carries out quenching.In the first area that preferably includes pipe in, quenching makes high-temperature gas drop to 95 ℃~70 ℃ from being higher than 1200 ℃, is preferably 85 ℃.
Described method is applicable to that preferably the percent by volume of water content is 10% to 70%, and preferably percent by volume is 30% waste gas.

Claims (15)

1, a kind of quenching equipment is used for by means of quenching water thermal current being carried out quenching, and described quenching equipment has a steam line and a discharge duct, and this quenching water cools off by a heat exchanger at least in part, it is characterized in that:
Described quenching equipment is provided with a chilled(cooling) water return (CWR), and it is used for the first area of cooling blast; And second chilled(cooling) water return (CWR) that separates, be used to cool off the zone that this air-flow is positioned at this downstream, first area.
2, equipment as claimed in claim 1 is characterized in that, only second cooling circuit is provided with the heat exchanger that is used to cool off quenching water.
3, as each described equipment in the above-mentioned claim, it is characterized in that having a overflow from second cooling circuit to first cooling circuit.
4, as each described equipment in the above-mentioned claim, it is characterized in that, be provided with a device, be used for controlling the water level of the quenching water of first cooling circuit.
5, equipment as claimed in claim 4 is characterized in that, the described device that is used for controlling the water level of the first cooling circuit quenching water comprises by to first loop supply quenching water with discharge the water level that quenching water is regulated quenching water from first loop.
As each described equipment in the above-mentioned claim, it is characterized in that 6, the first area of air-flow is limited by the inwall of pipe in the upright cylinder, the steam line of quenching equipment is positioned at the upper end of this pipe.
7, equipment as claimed in claim 6 is characterized in that, the second area of air-flow is limited by the inwall of the outer wall of pipe in this and the outer tube that pipe is provided with one heart in this.
8, equipment as claimed in claim 7 is characterized in that, a transfer that is installed on the lower area of described interior pipe is used for the air-flow that interior pipe flows downward is turned to the airflow flowing that makes progress in outer tube.
9, a kind of method of thermal current being carried out quenching by adding quenching water, it is characterized in that, by the quenching water in first cooling circuit first area of this air-flow is cooled off, by the quenching water in second chilled(cooling) water return (CWR) that separates with first chilled(cooling) water return (CWR) and the second area that this air-flow is positioned at the downstream, first area is cooled off.
10, method as claimed in claim 9 is characterized in that, only the quenching water in second cooling circuit cools off by means of a heat exchanger.
As claim 9 or 10 described methods, it is characterized in that 11, gas in the first area of air-flow flows along the direction opposite with gas in the second area of air-flow.
12, as each described method in the claim 9 to 11, it is characterized in that the initial temperature of the gas in the first area of air-flow before cooling is 1000 ℃ to 2000 ℃, be preferably 1200 ℃, and cooled temperature is 95 ℃ to 70 ℃, is preferably 85 ℃.
As each described method in the claim 9 to 12, it is characterized in that 13, the initial temperature of gas before cooling in the second area of air-flow is 95 ℃ to 70 ℃, is preferably 85 ℃, and cooled temperature is 70 ℃ to 40 ℃, is preferably 60 ℃.
As each described method in the claim 9 to 13, it is characterized in that 14, the percent by volume of the water content of gas to be cooled is 10% to 70%, percent by volume preferably is 30%.
15, a kind of as each described equipment in the claim 1 to 8 and as the purposes of each described method in the claim 9 to 14, the forming gas that is used for the high temperature circulation process is occurred carries out quenching.
CNA2004800091931A 2003-04-11 2004-02-25 Method for suddenly cooling high-temperature gas Pending CN1768243A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10316874.5 2003-04-11
DE10316874A DE10316874B4 (en) 2003-04-11 2003-04-11 Process for the shock cooling of high-temperature gases

Publications (1)

Publication Number Publication Date
CN1768243A true CN1768243A (en) 2006-05-03

Family

ID=33103347

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2004800091931A Pending CN1768243A (en) 2003-04-11 2004-02-25 Method for suddenly cooling high-temperature gas

Country Status (11)

Country Link
EP (1) EP1613912B1 (en)
JP (1) JP2006522911A (en)
KR (1) KR20060004662A (en)
CN (1) CN1768243A (en)
AT (1) ATE430295T1 (en)
DE (2) DE10316874B4 (en)
DK (1) DK1613912T3 (en)
ES (1) ES2323640T3 (en)
PT (1) PT1613912E (en)
SI (1) SI1613912T1 (en)
WO (1) WO2004090447A1 (en)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2352561C2 (en) * 1973-10-19 1983-02-17 Linde Ag, 6200 Wiesbaden Method for dissipating the compression heat that arises when compressing a gas mixture
DE2416167A1 (en) * 1974-04-03 1976-02-05 Werner Ing Grad Minkler Cooling and partial drying of hot moist gases - by direct cooling with pre-cooled condensate
DE2538611C2 (en) * 1975-08-29 1983-09-08 Linde Ag, 6200 Wiesbaden Process for cooling a raw gas mixture containing different boiling hydrocarbons
GB2065500B (en) * 1979-12-19 1983-09-28 Heat Extractor Corp Heat extractor
US5765546A (en) * 1996-05-30 1998-06-16 Sofame Direct contact water heater with dual water heating chambers
DE19633830C2 (en) * 1996-08-22 2002-01-17 Intensiv Filter Gmbh Cooling device based on the evaporation principle for hot, dusty gases
SE514866C2 (en) * 1997-09-23 2001-05-07 Svensk Roekgasenergi Intressen Device for cooling gases
DE10004138C2 (en) * 2000-01-31 2002-05-16 Thermoselect Ag Vaduz Process and device for the disposal and recycling of waste goods

Also Published As

Publication number Publication date
DE502004009424D1 (en) 2009-06-10
DK1613912T3 (en) 2009-06-22
KR20060004662A (en) 2006-01-12
EP1613912B1 (en) 2009-04-29
SI1613912T1 (en) 2009-10-31
ATE430295T1 (en) 2009-05-15
DE10316874A1 (en) 2004-11-04
ES2323640T3 (en) 2009-07-22
JP2006522911A (en) 2006-10-05
DE10316874B4 (en) 2008-04-03
EP1613912A1 (en) 2006-01-11
WO2004090447A1 (en) 2004-10-21
PT1613912E (en) 2009-06-09

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C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication