CN1736196A - Herbicidal compositions for cornfields - Google Patents

Herbicidal compositions for cornfields Download PDF

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Publication number
CN1736196A
CN1736196A CN 200510044675 CN200510044675A CN1736196A CN 1736196 A CN1736196 A CN 1736196A CN 200510044675 CN200510044675 CN 200510044675 CN 200510044675 A CN200510044675 A CN 200510044675A CN 1736196 A CN1736196 A CN 1736196A
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compound
agent
weed
common name
herbicidal combinations
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李美
高兴祥
高宗军
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Abstract

The invention relates to four kinds of herbicidal compositions for cornfields including fluroxypyr and acetochlor composition, fluroxypyr and prometryne composition, fluroxypyr and fenoxaprop-p-ethyl composition, and fluroxypyr and isoproturon composition, the compositions have the advantages of high activity, small amount of administration, low cost, wide weeding spectrum and higher safety.

Description

Wheat field herbicide composition
Technical field the present invention relates to four kinds of Herbicidal combinations of wheat weeds, i.e. fluroxypyr and acetochlor composition, fluroxypyr and prometryn composition, fluroxypyr and smart Evil azoles diclofop-methyl composition, fluroxypyr and isoproturon composition.
Background technology is along with the development of chemical weed control technology, China's chemical weed control area rapid growth, and the initial stage nineties is 2,300 ten thousand hm2, now nearly 6,100 ten thousand hm2.But along with long-term, the large scale application of weed killer herbicide, many outstanding problems appear in the farmland weed chemical harnessing, and weeds resistance, population succession and drug injury problem are more and more serious.At present, there is such-and-such drawback in medicament commonly used in the wheatland.Green sulphur is grand, metsulfuron-methyl etc., because the longevity of residure is long, very easily succession crop is caused poisoning; 2,4-D, methoxone medication period is improper or consumption is higher, very easily to causing poisoning when a stubble wheat, and easily broad leaf crop is on every side caused the drift poisoning, and pollute sprayer; The tribenuron-methyl consumption is too high, party causes poisoning to back stubble peanut, soybean etc. excessively.In addition, because certain weed killer herbicide of single use all the year round cause susceptible weeds quantity to descend, and insensitive weeds quantity rises, and causes that weed community changes.Many drug resistance weeds also rise to the field main weeds gradually, become emerging malignant weed.Before 2000, Shandong Province wheat paddock weeds are dominant population with descurainia sophia (l.) webb ex prantl, shepherd's purse, many emerging malignant weeds appear now, as clearvers, wartwort, corn gromwell, Arabic Veronica, wild oat, amur foxtail, Wang grass, candle grass, rescuebrome, hard grass,  hold, humulus grass etc., medicament commonly used is difficult to prevent and kill off, and seriously reduces crop yield and influence results.At present, research broad weed-killing spectrum, safety, efficient, low consumption, low cost, wield weed killer herbicide new varieties are an urgent demands of current agricultural production.
The objective of the invention is to seek a kind of novel wheat field herbicide composition that can overcome above-mentioned defective, both had the advantage that activity is high, consumption is few, cost is low, have broad weed-killing spectrum, good, the tangible characteristics of synergistic effect of safety again, to overcome the problem that occurs in the present production, provide available disposable herbicide conscientiously for the northern China wheatland simultaneously.
Summary of the invention the present invention is by compound (I) fluroxypyr and compound (II) Acetochlor, or compound (I) fluroxypyr and compound (III) prometryn, or compound (I) fluroxypyr and the smart Evil azoles of compound (IV) diclofop-methyl, or compound (I) fluroxypyr and compound (V) isoproturon are formed to be mixed and are realized.Chinese and English common name and the structural formula of compound (I), (II), (III), (IV), (V) are as follows:
Compound (I):
Chinese common name: fluroxypyr
English common name: fluroxypyr
Chemical structural formula:
Figure A20051004467500051
Compound (II):
Chinese common name: Acetochlor
English common name: acetochlor
Chemical structural formula:
Compound (III)
Chinese common name: prometryn
English common name: prometryn
Chemical structural formula:
Figure A20051004467500053
Compound (IV)
Chinese common name: smart Evil azoles diclofop-methyl
English common name: fenoxaprop-ethyl
Chemical structural formula:
Compound (V)
Chinese common name: isoproturon
English common name: isoproturon
Chemical structural formula:
The Herbicidal combinations of control of weed in wheat field of the present invention can become missible oil, aqua, pulvis, soluble powder, wetting powder, microemulsion, aqueous suspension agent, dry suspending agent, oil-suspending agent, water dispersible granules, suspended emulsion with hybrid process such as compound (I) and compound (II) and filler, auxiliary agent, wetting agent, emulsifier.
The Herbicidal combinations of control of weed in wheat field of the present invention can become missible oil, aqua, pulvis, soluble powder, wetting powder, microemulsion, aqueous suspension agent, dry suspending agent, oil-suspending agent, water dispersible granules, suspended emulsion with hybrid process such as compound (I) and compound (III) and filler, auxiliary agent, wetting agent, emulsifier.
The Herbicidal combinations of control of weed in wheat field of the present invention can become missible oil, aqua, pulvis, soluble powder, wetting powder, microemulsion, aqueous suspension agent, dry suspending agent, oil-suspending agent, water dispersible granules, suspended emulsion with hybrid process such as compound (I) and compound (IV) and filler, auxiliary agent, wetting agent, emulsifier.
The Herbicidal combinations of control of weed in wheat field of the present invention can become missible oil, aqua, pulvis, soluble powder, wetting powder, microemulsion, aqueous suspension agent, dry suspending agent, oil-suspending agent, water dispersible granules, suspended emulsion with hybrid process such as compound (I) and compound (V) and filler, auxiliary agent, wetting agent, emulsifier.
The Herbicidal combinations of control of weed in wheat field of the present invention is that elementary cell is re-dubbed Herbicidal combinations in per hectare with active ingredient compound (I) 7.5~375 grams and compound (II) 15~1500 grams.
The Herbicidal combinations of control of weed in wheat field of the present invention is that elementary cell is re-dubbed Herbicidal combinations in per hectare with active ingredient compound (I) 7.5~375 grams and compound (III) 15~1500 grams.
The Herbicidal combinations of control of weed in wheat field of the present invention is that elementary cell is re-dubbed Herbicidal combinations in per hectare with active ingredient compound (I) 7.5~375 grams and compound (IV) 7.5~375 grams.
The Herbicidal combinations of control of weed in wheat field of the present invention is that elementary cell is re-dubbed Herbicidal combinations in per hectare with active ingredient compound (I) 7.5~375 grams and compound (V) 15~2250 grams.
Advantage of the present invention
1. herbicidal composition of the present invention, no any antagonism between each composition can enlarge and kill the grass spectrum, and synergistic effect is remarkable.Weeds in the dispenser controlled wheat whole growing.
2. herbicidal composition of the present invention, the agent of amount ratio list use and significantly reduce, and can save drug cost.
3. herbicidal composition of the present invention all is easy to degraded in environment, belong to the environmental friendliness weed killer herbicide, has overcome the defective of many long residual effect weed killer herbicides to the succession crop poor stability, to working as stubble wheat and succession crop safety.
4. herbicidal composition of the present invention all can use to the wheat period of seedling establishment from one heart stage of wheat one leaf, and the operating period is wide, is convenient to promote the use of.
Following the present invention is described in detail in conjunction with specific embodiments, so that advantage of the present invention is more obvious.
Embodiment 1:(water dispersible granules)
Fluroxypyr 19%, Acetochlor 41%, diffusion agent N 5%, K-123%, op-10 5%, stabilizing agent 5%, disintegrant 5%, sodium sulphate 2%, white carbon black 15% is made 60% water dispersible granules.
Embodiment 2:(aqueous suspension agent)
Fluroxypyr 10%, prometryn 40%, agricultural newborn 600#10%, OT-10 10%, white carbon black 0.2%, wooden calcium 2%, water supplies 100%, makes 50% aqueous suspension agent.
Embodiment 3:(dry suspending agent)
Fluroxypyr 24%, smart Evil azoles diclofop-methyl 12%, agricultural newborn 600#5%, OT-105%, calcium salt 5%, lignosulfite 10%, ammonium nitrate 39% is made 36% dry suspending agent.
Embodiment 4:(wetting powder)
Fluroxypyr 10%, isoproturon 30%, diffusion agent N 5%, detergent LS 5%, K-123%, precipitated calcium carbonate 47% is made 40% wetting powder.
Embodiment 5: the herbicidal effect of compound (I) and compound (II) and composition thereof sees Table 1:
The herbicidal effect of table 1 compound (I) and compound (II) and composition thereof
Handle medicament Consumption (g a.i./ha) To monocotyledon weed preventive effect (%) To broadleaf weed preventive effect (%) Estimate
Compound (I) 180 0 78 Only prevent and kill off broadleaf weed
Compound (II) 750 85 0 Only prevent and kill off monocotyledon weed
Compound (I)+compound (II) 120+300 87 82 Reduce cost, enlarge grass spectrum extremely
Compound (I)+compound (II) 120+400 91 95 Reduce cost, enlarge grass spectrum extremely
More than handle the equal safety of wheat.
Embodiment 6: the herbicidal effect of compound (I) and compound (III) and composition thereof sees Table 2:
The herbicidal effect of table 2 compound (I) and compound (III) and composition thereof
Handle medicament Consumption (g a.i./ha) To monocotyledon weed preventive effect (%) To broadleaf weed preventive effect (%) Estimate
Compound (I) 180 0 78 Only prevent and kill off broadleaf weed
Compound (III) 720 68 59 All effective to single, double cotyledon weeds, but preventive effect is all lower
Compound (I)+compound (III) 120+400 80 88 Reduce cost, enlarge grass spectrum extremely
Compound (I)+compound (III) 120+480 91 93 Reduce cost, enlarge grass spectrum extremely
More than handle the equal safety of wheat.
Embodiment 7: the herbicidal effect of compound (I) and compound (IV) and composition thereof sees Table 3:
The herbicidal effect of table 3 compound (I) and compound (IV) and composition thereof
Handle medicament Consumption (g a.i./ha) To monocotyledon weed preventive effect (%) To broadleaf weed preventive effect (%) Estimate
Compound (I) 180 0 78 Only prevent and kill off broadleaf weed
Compound (IV) 150 83 0 Only prevent and kill off monocotyledon weed
Compound (I)+compound (IV) 120+70 85 80 Reduce cost, enlarge grass spectrum extremely
Compound (I)+compound (IV) 120+85 95 90 Reduce cost, enlarge grass spectrum extremely
More than handle the equal safety of wheat.
Embodiment 8: the herbicidal effect of compound (I) and compound (V) and composition thereof sees Table 4:
The herbicidal effect of table 4 compound (I) and compound (V) and composition thereof
Handle medicament Consumption (g a.i./ha) To monocotyledon weed preventive effect (%) To broadleaf weed preventive effect (%) Estimate
Compound (I) 180 0 78 Only prevent and kill off broadleaf weed
Compound (V) 1150 65 55 All effective to single, double cotyledon weeds, but preventive effect is all lower
Compound (I)+compound (V) 120+650 89 90 Reduce cost, enlarge grass spectrum extremely
Compound (I)+compound (V) 120+800 96 94 Reduce cost, enlarge grass spectrum extremely
More than handle the equal safety of wheat.

Claims (8)

1. the Herbicidal combinations of a control of weed in wheat field is characterized in that: be made up of compound (I) and compound (II), it is characterized in that containing percentage by weight compound (I) 0.1%~99% and compound (II) 0.1%~99%.
2. the Herbicidal combinations of a control of weed in wheat field is characterized in that: be made up of compound (I) and compound (III), it is characterized in that containing percentage by weight compound (I) 0.1%~99% and compound (III) 0.1%~99%.
3. the Herbicidal combinations of a control of weed in wheat field is characterized in that: be made up of compound (I) and compound (IV), it is characterized in that containing percentage by weight compound (I) 0.1%~99% and compound (IV) 0.1%~99%.
4. the Herbicidal combinations of a control of weed in wheat field is characterized in that: be made up of compound (I) and compound (V), it is characterized in that containing percentage by weight compound (I) 0.1%~99% and compound (V) 0.1%~99%.Chinese and English common name and the structural formula of compound (I), (II), (III), (IV), (V) are as follows:
Compound (I):
Chinese common name: fluroxypyr
English common name: fluroxypyr
Chemical structural formula:
Figure A2005100446750002C1
Compound (II):
Chinese common name: Acetochlor
English common name: acetochlor
Chemical structural formula:
Compound (III)
Chinese common name: prometryn
English common name: prometryn
Chemical structural formula:
Figure A2005100446750003C1
Compound (IV)
Chinese common name: smart Evil azoles diclofop-methyl
English common name: fenoxaprop-ethyl
Chemical structural formula:
Compound (V)
Chinese common name: isoproturon
English common name: isoproturon
Chemical structural formula:
5. the Herbicidal combinations of control of weed in wheat field according to claim 1, it is characterized in that, hybrid process such as compound (I) and compound (II) and filler, auxiliary agent, wetting agent, emulsifier are become missible oil, aqua, pulvis, soluble powder, wetting powder, microemulsion, aqueous suspension agent, dry suspending agent, oil-suspending agent, water dispersible granules, suspended emulsion.
6. the Herbicidal combinations of control of weed in wheat field according to claim 2, it is characterized in that, hybrid process such as compound (I) and compound (III) and filler, auxiliary agent, wetting agent, emulsifier are become missible oil, aqua, pulvis, soluble powder, wetting powder, microemulsion, aqueous suspension agent, dry suspending agent, oil-suspending agent, water dispersible granules, suspended emulsion.
7. the Herbicidal combinations of control of weed in wheat field according to claim 3, it is characterized in that, hybrid process such as compound (I) and compound (IV) and filler, auxiliary agent, wetting agent, emulsifier are become missible oil, aqua, pulvis, soluble powder, wetting powder, microemulsion, aqueous suspension agent, dry suspending agent, oil-suspending agent, water dispersible granules, suspended emulsion.
8. the Herbicidal combinations of control of weed in wheat field according to claim 4, it is characterized in that, hybrid process such as compound (I) and compound (V) and filler, auxiliary agent, wetting agent, emulsifier are become missible oil, aqua, pulvis, soluble powder, wetting powder, microemulsion, aqueous suspension agent, dry suspending agent, oil-suspending agent, water dispersible granules, suspended emulsion.
CN 200510044675 2005-09-09 2005-09-09 Herbicidal compositions for cornfields Pending CN1736196A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102318632A (en) * 2011-07-18 2012-01-18 广西田园生化股份有限公司 Synergistic weeding composition containing fluroxypyr
CN103636620A (en) * 2013-11-28 2014-03-19 北京燕化永乐生物科技股份有限公司 Weeding composition
CN103960272A (en) * 2014-05-24 2014-08-06 南通顺阳化工有限公司 Novel weedicide fpr Gramineae weeds
US8894878B2 (en) 2011-05-12 2014-11-25 T&H Usa Group, Inc. Nanopolymetalic reducing agent filler
CN108684695A (en) * 2018-08-24 2018-10-23 扬州大学 A kind of Herbicidal combinations and its application containing trichlopyr and isoproturon

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8894878B2 (en) 2011-05-12 2014-11-25 T&H Usa Group, Inc. Nanopolymetalic reducing agent filler
CN102318632A (en) * 2011-07-18 2012-01-18 广西田园生化股份有限公司 Synergistic weeding composition containing fluroxypyr
CN103636620A (en) * 2013-11-28 2014-03-19 北京燕化永乐生物科技股份有限公司 Weeding composition
CN103960272A (en) * 2014-05-24 2014-08-06 南通顺阳化工有限公司 Novel weedicide fpr Gramineae weeds
CN108684695A (en) * 2018-08-24 2018-10-23 扬州大学 A kind of Herbicidal combinations and its application containing trichlopyr and isoproturon
CN108684695B (en) * 2018-08-24 2020-10-16 扬州大学 Herbicidal composition containing triclopyr and isoproturon and application thereof

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