CN1712632A - Pretreatment of cotton fabrics by composite enzyme rolling and pilling up - Google Patents
Pretreatment of cotton fabrics by composite enzyme rolling and pilling up Download PDFInfo
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- CN1712632A CN1712632A CN 200510040957 CN200510040957A CN1712632A CN 1712632 A CN1712632 A CN 1712632A CN 200510040957 CN200510040957 CN 200510040957 CN 200510040957 A CN200510040957 A CN 200510040957A CN 1712632 A CN1712632 A CN 1712632A
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Abstract
The invention provided a fore treatment process of the enzyme rolling pile for the fabric which belongs to the fore treatment process of the dyeing and finishing field. The process is: first to fore treatment of the loom stare using the boiling water, then dipping into the the mixture of the alkali pectinase liquid, neutral proteinase liquid and xylanase liquid, then to wash with the hot water ( killing the enzyme) and the cool water, last to dry in the air. the best pectinase is produced by the Bacillus subtilis WSHB04-03. the process has many merits such as high efficiency, low work output and the energy conservation and so on.
Description
Technical field
The present invention relates to a kind of pretreatment of cotton fabrics by composite enzyme rolling and pilling up, be specifically related to a kind of cotton fabrics alkaline pectase, neutral cellulase, neutral proteinase and zytase compound biological enzyme infusion process refining process, belong to the pre-treatment process technical field of knitted dyeing and finishing industry.
Background technology
Cotton fiber is in growth course; content of cellulose increases with the increase of maturity; also has a certain amount of material that in the cotton fiber growth, plays protective effect in addition; and the impurity that generates in the bio-metabolic process; long altogether with the cellulose symbiosis, these materials are called cellulosic commensal or accompaniment.The cellulose commensal mainly contains pectin substance, protein, waxy substance, natural colouring matter etc., the cotton seed hulls fragment of carrying secretly in addition when stripping cotton fiber.The shared ratio of commensal reduces with the raising of maturity of cotton fiber.
Cotton fiber is a hydrophilic fibre from chemical constitution, and good hygroscopicity should be arranged.But because the existence of commensal makes that the hygroscopicity of cotton fiber is very poor, can not satisfy the needs of printing and dyeing processing, can influence dyeing qualities such as dyefastness, dyeing uniformity and colour brightness, and can't embody the good wearability of cotton fabrics.
Be intended to remove the commensal of cotton fiber, improve the moisture pick-up properties of cotton fabrics, the pre-treatment of dying of satisfying the needs of dyeing and finishing processing is commonly referred to as kiering or concise.Printing and dyeing both at home and abroad always and adopting traditional alkali pretreatment that COTTON FABRIC is carried out pre-treatment in the processing, to remove various cotton fiber commensal impurity such as pectic substance, cotton wax, improve the wettability and the outward appearance of COTTON FABRIC, follow-up dyeing, stamp and arrangement processing are carried out smoothly.Traditional alkaline scouring method is to be the main agent of practicing with NaOH, be aided with scouring agent (surfactant), sodium metasilicate, sodium sulfite, sodium phosphate etc. and help experienced agent, under the acting in conjunction of these digesting agents, make natural impurity on the cotton fiber that a series of physicochemical change take place and removed wholly or in part.This technology exists water consumption, energy consumption big, waste discharge alkalescence big (pH＞11), dark, the poor disadvantages such as (COD are up to thousands of mg/L) of biodegradable of colourity, the pollution sources of dyeing maximum have been become, severe contamination ecological environment, simultaneously also cotton fiber is caused bigger damage, influence the quality of COTTON FABRIC.
Except chemical method, the present also commensal in research and utilization biological method removal cotton fiber to reduce the damage of chemical reagent to cotton fiber, alleviates the pollution of kiering waste water to environment.
Abroad started the upsurge of biology enzyme since nineteen nineties in research aspect the cotton pretreatment, Denmark Novozymes Company and Osaka, Japan university develop respectively after alkaline pectase and the protopectinase, and the biology enzyme pretreatment technology is further developed.The selection of enzyme is paid attention in the research of relevant Bio-Enzyme Pretreatment of Cotton Fabric at first both at home and abroad, and single enzyme is to improving the effect of cotton fiber wettability emphatically.Began to turn to the different enzymes of research to mix the complex enzyme of back composition in recent years to improving the synergy of cotton fiber wettability, its emphasis is pectase and cellulase, or add protease, lipase, at, piece together with the back cotton pretreatment is had certain synergy, can remove the impurity on the cotton fiber effectively, also there is a certain distance on the effect but compare, still remains on the enzyme preparation kind is selected, to be furtherd investigate with alkali treatment.Domestic multiple so-called commercial complex enzyme formulation appearred in recent years, but these products mostly are biology enzyme pieces together the product that mixes mutually with chemicals (the especially mixture of alkali), that have even just do not have any enzyme preparation composition at all, and must use (100%H when using up to 10g/L～15g/L
2O
2) hydrogen peroxide carry out oxygen and float processing, its alkali consumption height, the oxidation fierceness easily makes fabric impaired.In addition, although these complex enzyme kinds are a lot, on producing, applied as yet.And the alkaline pectase that Novozymes Company released also is difficult to adapt to the characteristics of China's COTTON FABRIC, also is among the application study.
Summary of the invention
(1) technical problem to be solved
Solve the optimized technical problem of process conditions of a kind of cotton fabrics alkaline pectase, neutral cellulase, neutral proteinase and zytase compound biological enzyme infusion process refining process.
(2) technical scheme
A kind of cotton fabrics alkaline pectase, neutral cellulase, neutral proteinase and zytase compound biological enzyme infusion process refining process, adopt step compound biological enzyme pre-treatment process, its technological process is: the first boiling water preliminary treatment of cotton knitted fabric, maceration enzyme liquid then, insulation is handled a period of time after hot water wash (the double enzyme that goes out), cold wash is dried.
1) all-cotton knitting cloth: this technology is applicable to various types of all-cotton knitting cloth, as interlock fabric, single jersey, FIGURED CLOTH, two-sided eyelet fabric, rib fabric etc.
2) boiling water preliminary treatment: the wax on cotton fiber surface and lipids fusing point are lower than 100 ℃ more, the processing of boiling water short time can make these compound fusions, and redistribute at fiber surface, or part is distributed in the pretreated water-bath, enzyme and auxiliary agent are increased at the accessibility of fiber surface, thereby scouring result is improved, and wetting property of the fabric improves.Obviously, to carry out the boiling water preliminary treatment before concise be necessary to the cotton fabrics enzyme.The boiling water pretreatment time is 1-60min among the present invention.
3) maceration enzyme liquid: the complex enzyme of selecting for use is the various combination of alkaline pectase, neutral proteinase, neutral cellulase and zytase, during enzyme is handled and is bathed, or add the polyoxyethylene-type non-ionic surface active agent and/or anion surfactant is made wetting and penetrating agent, or do not add any wetting and penetrating agent; Enzyme liquid consists of: alkaline pectase 0.5-10g/L, neutral cellulase 0.1-1.0g/L, neutral proteinase 0-5g/L, zytase 0-5g/L, wetting and penetrating agent 0-1g/L; Maceration enzyme treatment fluid temperature is a room temperature to 60 ℃, handle and bathe pH8.6-10.0, cotton fabrics than maceration enzyme bath of liquid than 1: 20, dip time 30-90min.
It is excellent that used alkaline pectase produces alkaline pectate lyase with Bacillus subtilis WSHB04-03 (open among the application number 200410065807.X, deposit number is CCTCC NO:M204082) especially.
4) hot water wash: 95～100 ℃ of hot water wash temperature, time 5～10min; Enzyme generally carries out hot water wash earlier, 95～100 ℃ of temperature, time 5～10min after handling.Purpose is to remove impurity catabolites such as pectin on the one hand, also plays enzyme deactivation (enzyme goes out) effect simultaneously, stops enzyme to proceed catalytic action.
5) cold wash: will fully wash behind the enzyme that goes out, can adopt cold water, further the concise middle catabolite of eccysis enzyme.
(3) beneficial effect
The pretreatment of cotton fabrics by composite enzyme rolling and pilling up that the present invention adopts belongs to batch (-type) dyeing and finishing processing mode, meets knitted fabric actual production requirement.The biology enzyme that is adopted is the various combination that Bacillus subtilis WSHB04-03 produces alkaline pectate lyase, neutral proteinase, neutral cellulase and zytase.Adopt cotton fabrics by composite enzyme pre-treatment process treatment effect of the present invention better, concise back absorbent time can≤10s, concise bleaching (oxygen floats) again back absorbent time can≤5s.In addition, technology of the present invention also has advantages such as fabric damage little (strength loss is less than 10%), fabric quality are improved, the waste water environmental pollution is little, is a kind of pre-treatment processing that cleans.
The specific embodiment
Pretreatment of cotton fabrics by composite enzyme rolling and pilling up is given an example:
The textile interlock fabric of embodiment 1:14.5tex
Technological process: the cotton knitted fabric boiling water bath processing 40min of elder generation, extract fabric then, flood complex enzyme liquid certain hour again, take out fabric and carry out hot water wash (the double enzyme that goes out), cold wash, room temperature is dried.
Wherein, the biology enzyme treatment fluid consists of: alkaline pectase 4g/L, neutral cellulase 0.5g/L.Handle and bathe pH8.6-10.0, cotton fabrics compared 1: 20 than maceration enzyme bath of liquid, dip time 70min.Handle the back in 95～100 ℃ of washing 5min enzymes that go out down, carry out abundant cold wash at last.
Cotton fabrics after the concise processing of above-mentioned complex enzyme, concise back wettability 9.0s, bleaching back wettability 4.8s, concise back R457 whiteness value Wr63.42%, bleaching back Wr is 77.24%, the loss of fabric bursting strength is 7.8%.Textile dyeing K/S value (color depth value) REACTIVE DYES is 24.60 after the refining, reducing dye is 21.47.Do, fastness to wet rubbing and soaping fastness all meet the demands.
The textile interlock fabric of embodiment 2:18.7tex
Technological process: the cotton knitted fabric boiling water bath processing 30min of elder generation, extract fabric then, flood complex enzyme liquid certain hour again, take out fabric and carry out hot water wash (the double enzyme that goes out), cold wash, room temperature is dried.
Wherein, the biology enzyme treatment fluid consists of: Bacillus subtilis WSHB04-03 produces alkaline pectate lyase 1g/L, neutral cellulase 1.0g/L; Neutral proteinase 4g/L handles and bathes pH8.6-10.0, and cotton fabrics compared 1: 20 than maceration enzyme bath of liquid, dip time 80min.Handle the back in 95～100 ℃ of washing 5min enzymes that go out down, carry out abundant cold wash at last.
Cotton fabrics after the concise processing of above-mentioned complex enzyme, concise back wettability 8.5s, bleaching back wettability 2.6s, concise back R457 whiteness value Wr63.21%, bleaching back Wr is 78.10%, the loss of fabric bursting strength is 8.9%.
Concise back textile dyeing K/S value (color depth value) REACTIVE DYES is 23.06, reducing dye is 21.22.Do, fastness to wet rubbing and soaping fastness all meet the demands.
The textile FIGURED CLOTH of embodiment 3:14.5tex
Technological process: the cotton knitted fabric boiling water bath processing 10min of elder generation, extract fabric then, flood complex enzyme liquid certain hour again, take out fabric and carry out hot water wash (the double enzyme that goes out), cold wash, room temperature is dried.
Wherein, the biology enzyme treatment fluid consists of: alkaline pectase 10g/L, neutral cellulase 0.1g/L, zytase 1g/L.Handle and bathe pH8.6-10.0, dip time 40min.Handle the back in 95～100 ℃ of washing 5min enzymes that go out down, carry out abundant cold wash at last.
Cotton fabrics after the concise processing of above-mentioned complex enzyme, concise back wettability 8.2s, bleaching back wettability 4.4s, concise back R457 whiteness value Wr62.41%, bleaching back Wr is 76.52%, the loss of fabric bursting strength is 8.4%.Textile dyeing K/S value (color depth value) REACTIVE DYES is 24.44 after the refining, reducing dye is 23.46.Do, fastness to wet rubbing and soaping fastness all meet the demands.
Claims (7)
1. pretreatment of cotton fabrics by composite enzyme rolling and pilling up, it is characterized in that adopting step compound biological enzyme pre-treatment process, technological process is: the first boiling water preliminary treatment of cotton knitted fabric, maceration enzyme liquid then, a period of time is handled in insulation after hot water wash, cold wash and drying;
(1) boiling water preliminary treatment: the boiling water pretreatment time is 1-60min;
(2) maceration enzyme liquid: the complex enzyme of selecting for use is the various combination of alkaline pectase, neutral proteinase, neutral cellulase and zytase, during enzyme is handled and is bathed, or add the polyoxyethylene-type non-ionic surface active agent and/or anion surfactant is made wetting and penetrating agent, or do not add any wetting and penetrating agent; Enzyme liquid consists of: alkaline pectase 0.5-10g/L, neutral cellulase 0.1-1.0g/L, neutral proteinase 0-5g/L, zytase 0-5g/L, wetting and penetrating agent 0-1g/L; Maceration enzyme treatment fluid temperature is a room temperature to 60 ℃, handle and bathe pH8.6-10.0, cotton fabrics than maceration enzyme bath of liquid than 1: 20, dip time 30-90min;
(3) hot water wash: 95～100 ℃ of hot water wash temperature, time 5～10min;
(4) cold wash: will fully carry out cold wash behind the enzyme that goes out.
2. a kind of pretreatment of cotton fabrics by composite enzyme rolling and pilling up according to claim 1 is characterized in that the complete cotton knitted fabric that is applicable to processing comprises interlock fabric, single jersey, FIGURED CLOTH, two-sided eyelet fabric or rib fabric lining.
3. a kind of pretreatment of cotton fabrics by composite enzyme rolling and pilling up according to claim 1 is characterized in that the alkaline pectase of selecting for use in the enzyme treatment fluid is that Bacillus subtilis WSHB04-03 produces alkaline pectate lyase.
4. a kind of pretreatment of cotton fabrics by composite enzyme rolling and pilling up according to claim 1 is characterized in that the enzyme treatment fluid adopts Bacillus subtilis WSHB04-03 to produce the complex enzyme system of alkaline pectate lyase and neutral cellulase composition.
5. a kind of pretreatment of cotton fabrics by composite enzyme rolling and pilling up according to claim 1 is characterized in that the enzyme of selecting for use in the enzyme treatment fluid is that Bacillus subtilis WSHB04-03 produces the complex enzyme system that alkaline pectate lyase, neutral cellulase and neutral proteinase are formed.
6. a kind of pretreatment of cotton fabrics by composite enzyme rolling and pilling up according to claim 1 is characterized in that the enzyme of selecting for use in the enzyme treatment fluid is that Bacillus subtilis WSHB04-03 produces the complex enzyme system that alkaline pectate lyase, neutral cellulase and zytase are formed.
7. a kind of pretreatment of cotton fabrics by composite enzyme rolling and pilling up according to claim 1, it is characterized in that in the biology enzyme treatment fluid, or add the polyoxyethylene-type non-ionic surface active agent and/or anion surfactant is made wetting and penetrating agent, or do not add any wetting and penetrating agent.
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| CN 200510040957 CN1282798C (en) | 2005-07-06 | 2005-07-06 | Pretreatment of cotton fabrics by composite enzyme rolling and pilling up |
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| CN 200510040957 CN1282798C (en) | 2005-07-06 | 2005-07-06 | Pretreatment of cotton fabrics by composite enzyme rolling and pilling up |
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| CN1712632A true CN1712632A (en) | 2005-12-28 |
| CN1282798C CN1282798C (en) | 2006-11-01 |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974819A (en) * | 2010-09-30 | 2011-02-16 | 福建众和股份有限公司 | Pretreatment, dyeing and finishing process of pepper fiber woven fabric |
| CN104099788A (en) * | 2014-07-04 | 2014-10-15 | 无锡市信达染整机械厂 | Environmental-friendly cotton fabric dyeing |
| CN105155246A (en) * | 2015-08-21 | 2015-12-16 | 泉州市新宏化工贸易有限公司 | Soaping process for natural fiber cotton fabric and soap activator |
| CN105507002A (en) * | 2015-12-18 | 2016-04-20 | 江南大学 | Cotton woven fabric scouring method based on trametes and white-rot fungus combined fermentation crude enzyme liquid |
| CN106012549A (en) * | 2016-05-28 | 2016-10-12 | 湖南细心信息科技有限公司 | Method for processing cotton embroidery threads before dyeing |
| CN107268277A (en) * | 2017-07-27 | 2017-10-20 | 南通金康弘纺织品有限公司 | A kind of cotton fiber pretreating agent and its cotton fiber production technology and product |
| CN107757007A (en) * | 2017-12-04 | 2018-03-06 | 广东名鳄服饰实业有限公司 | A kind of fabric of antibacterial quick-drying |
| CN107933000A (en) * | 2017-12-04 | 2018-04-20 | 广东名鳄服饰实业有限公司 | A kind of multifunction bamboo cotton composite material |
| CN111118909A (en) * | 2020-01-22 | 2020-05-08 | 山东宏业纺织股份有限公司 | Enzyme preparation for refining cotton fabric and refining method and device |
| CN111411527A (en) * | 2020-04-13 | 2020-07-14 | 海宁市春晟经编有限公司 | Ultra-soft white grey cloth and biological enzyme treatment method thereof |
| CN111809397A (en) * | 2020-06-30 | 2020-10-23 | 武汉新华扬生物股份有限公司 | Complex enzyme preparation for low-temperature treatment of ready-made clothes and after-finishing method of cotton-type fabric ready-made clothes |
| CN114592355A (en) * | 2022-04-14 | 2022-06-07 | 厦门谢田守望新材料有限公司 | Dyeing method suitable for cotton fiber textiles |
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2005
- 2005-07-06 CN CN 200510040957 patent/CN1282798C/en not_active Expired - Fee Related
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974819B (en) * | 2010-09-30 | 2012-09-12 | 福建众和股份有限公司 | Pretreatment, dyeing and finishing process of pepper fiber woven fabric |
| CN101974819A (en) * | 2010-09-30 | 2011-02-16 | 福建众和股份有限公司 | Pretreatment, dyeing and finishing process of pepper fiber woven fabric |
| CN104099788A (en) * | 2014-07-04 | 2014-10-15 | 无锡市信达染整机械厂 | Environmental-friendly cotton fabric dyeing |
| CN104099788B (en) * | 2014-07-04 | 2016-01-20 | 无锡市信达染整机械厂 | Eco-friendly cotton fabric dyeing process |
| CN105155246A (en) * | 2015-08-21 | 2015-12-16 | 泉州市新宏化工贸易有限公司 | Soaping process for natural fiber cotton fabric and soap activator |
| CN105507002A (en) * | 2015-12-18 | 2016-04-20 | 江南大学 | Cotton woven fabric scouring method based on trametes and white-rot fungus combined fermentation crude enzyme liquid |
| CN106012549A (en) * | 2016-05-28 | 2016-10-12 | 湖南细心信息科技有限公司 | Method for processing cotton embroidery threads before dyeing |
| CN106012549B (en) * | 2016-05-28 | 2019-05-31 | 上海纳薇服装设计有限公司 | A kind of cotton embroider line pretreatment method for dyeing |
| WO2019019545A1 (en) * | 2017-07-27 | 2019-01-31 | 南通金康弘纺织品有限公司 | Cotton fiber pretreatment agent, cotton fiber production process, and product |
| CN107268277A (en) * | 2017-07-27 | 2017-10-20 | 南通金康弘纺织品有限公司 | A kind of cotton fiber pretreating agent and its cotton fiber production technology and product |
| CN107757007A (en) * | 2017-12-04 | 2018-03-06 | 广东名鳄服饰实业有限公司 | A kind of fabric of antibacterial quick-drying |
| CN107933000A (en) * | 2017-12-04 | 2018-04-20 | 广东名鳄服饰实业有限公司 | A kind of multifunction bamboo cotton composite material |
| CN107933000B (en) * | 2017-12-04 | 2024-03-19 | 广东创时尚智能股份有限公司 | Multifunctional bamboo-cotton composite fabric |
| CN111118909A (en) * | 2020-01-22 | 2020-05-08 | 山东宏业纺织股份有限公司 | Enzyme preparation for refining cotton fabric and refining method and device |
| CN111118909B (en) * | 2020-01-22 | 2024-06-11 | 山东宏业纺织股份有限公司 | Enzyme preparation for refining cotton fabric and refining method and device |
| CN111411527A (en) * | 2020-04-13 | 2020-07-14 | 海宁市春晟经编有限公司 | Ultra-soft white grey cloth and biological enzyme treatment method thereof |
| CN111809397A (en) * | 2020-06-30 | 2020-10-23 | 武汉新华扬生物股份有限公司 | Complex enzyme preparation for low-temperature treatment of ready-made clothes and after-finishing method of cotton-type fabric ready-made clothes |
| CN114592355A (en) * | 2022-04-14 | 2022-06-07 | 厦门谢田守望新材料有限公司 | Dyeing method suitable for cotton fiber textiles |
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