CN1675252B - 大单体组合物及其制备方法 - Google Patents
大单体组合物及其制备方法 Download PDFInfo
- Publication number
- CN1675252B CN1675252B CN038197243A CN03819724A CN1675252B CN 1675252 B CN1675252 B CN 1675252B CN 038197243 A CN038197243 A CN 038197243A CN 03819724 A CN03819724 A CN 03819724A CN 1675252 B CN1675252 B CN 1675252B
- Authority
- CN
- China
- Prior art keywords
- composition
- big
- acid
- monomer
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
- G02B1/043—Contact lenses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/04—Polymers provided for in subclasses C08C or C08F
- C08F290/046—Polymers of unsaturated carboxylic acids or derivatives thereof
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/183,765 US6936641B2 (en) | 2002-06-25 | 2002-06-25 | Macromer forming catalysts |
US10/183,765 | 2002-06-25 | ||
PCT/US2003/019700 WO2004000888A1 (en) | 2002-06-25 | 2003-06-23 | Macromer forming catalysts |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1675252A CN1675252A (zh) | 2005-09-28 |
CN1675252B true CN1675252B (zh) | 2010-05-12 |
Family
ID=29779195
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN038197243A Expired - Fee Related CN1675252B (zh) | 2002-06-25 | 2003-06-23 | 大单体组合物及其制备方法 |
Country Status (9)
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7052131B2 (en) * | 2001-09-10 | 2006-05-30 | J&J Vision Care, Inc. | Biomedical devices containing internal wetting agents |
US6822016B2 (en) | 2001-09-10 | 2004-11-23 | Johnson & Johnson Vision Care, Inc. | Biomedical devices containing internal wetting agents |
US20070138692A1 (en) * | 2002-09-06 | 2007-06-21 | Ford James D | Process for forming clear, wettable silicone hydrogel articles |
US9248614B2 (en) * | 2004-06-30 | 2016-02-02 | Novartis Ag | Method for lathing silicone hydrogel lenses |
JP2006057025A (ja) * | 2004-08-20 | 2006-03-02 | Sanyo Chem Ind Ltd | 活性エネルギー線硬化型ウレタン(メタ)アクリレート組成物 |
KR100612960B1 (ko) | 2005-04-20 | 2006-08-16 | 한국화학연구원 | 가교 가능한 포스핀옥사이드 화합물 및 이를 이용한광중합성 조성물 |
TWI402280B (zh) * | 2005-08-09 | 2013-07-21 | Coopervision Int Holding Co Lp | 用於製造矽氧水凝膠隱形眼鏡之組合物與方法 |
US8013409B2 (en) | 2005-09-27 | 2011-09-06 | Canon Kabushiki Kaisha | Photoelectric conversion device and fabrication method therefor |
US20070222095A1 (en) * | 2006-03-23 | 2007-09-27 | Diana Zanini | Process for making ophthalmic lenses |
US8414804B2 (en) | 2006-03-23 | 2013-04-09 | Johnson & Johnson Vision Care, Inc. | Process for making ophthalmic lenses |
TWI441835B (zh) | 2006-07-12 | 2014-06-21 | Novartis Ag | 新穎聚合物 |
US7842762B2 (en) * | 2007-08-08 | 2010-11-30 | Ppg Industries Ohio, Inc. | Electrodepositable coating composition containing a cyclic guanidine |
EP2316867B1 (de) * | 2009-10-31 | 2012-05-09 | Bayer MaterialScience AG | Zinnfreie, wässrige Polyurethandispersionen |
KR102411923B1 (ko) | 2010-07-30 | 2022-06-22 | 알콘 인코포레이티드 | 수분이 풍부한 표면을 갖는 실리콘 히드로겔 렌즈 |
US8722076B2 (en) | 2010-09-30 | 2014-05-13 | Surmodics, Inc. | Photochrome- or near IR dye-coupled polymeric matrices for medical articles |
US8563560B2 (en) | 2011-02-25 | 2013-10-22 | Ppg Industries Ohio, Inc. | Preparation of bicyclic guanidine salts in an aqueous media |
HUE029018T2 (en) | 2011-10-12 | 2017-02-28 | Novartis Ag | A method for producing UV absorbing contact lenses by coating |
US8956682B2 (en) | 2012-04-02 | 2015-02-17 | Surmodics, Inc. | Hydrophilic polymeric coatings for medical articles with visualization moiety |
US9629945B2 (en) | 2012-12-12 | 2017-04-25 | Surmodics, Inc. | Stilbene-based reactive compounds, polymeric matrices formed therefrom, and articles visualizable by fluorescence |
MY172901A (en) | 2012-12-17 | 2019-12-13 | Alcon Inc | Method for making improved uv-absorbing ophthalmic lenses |
US9068089B2 (en) | 2013-03-15 | 2015-06-30 | Ppg Industries Ohio, Inc. | Phenolic admix for electrodepositable coating composition containing a cyclic guanidine |
US9688874B2 (en) | 2013-10-25 | 2017-06-27 | Ppg Industries Ohio, Inc. | Method of making a bicyclic guanidine-cured acrylic coating |
MY180543A (en) | 2013-12-17 | 2020-12-01 | Novartis Ag | A silicone hydrogel lens with a crosslinked hydrophilic coating |
SG10201901379TA (en) | 2014-08-26 | 2019-03-28 | Novartis Ag | Method for applying stable coating on silicone hydrogel contact lenses |
EP3391101B1 (en) | 2015-12-15 | 2020-07-08 | Alcon Inc. | Method for applying stable coating on silicone hydrogel contact lenses |
WO2019116139A1 (en) | 2017-12-13 | 2019-06-20 | Novartis Ag | Weekly and monthly disposable water gradient contact lenses |
JP6850268B2 (ja) * | 2018-02-09 | 2021-03-31 | 信越化学工業株式会社 | (メタ)アクリルシリコーン系グラフト共重合体及びその製造方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5534559A (en) * | 1993-03-18 | 1996-07-09 | Ciba-Geigy Corporation | Daylight curing compositions containing bisacylphosphine oxide photoinitiators |
EP0849296A2 (en) * | 1996-12-20 | 1998-06-24 | Takeda Chemical Industries, Ltd. | A photocurable resin composition and a method for producing the same |
Family Cites Families (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3808178A (en) * | 1972-06-16 | 1974-04-30 | Polycon Laboratories | Oxygen-permeable contact lens composition,methods and article of manufacture |
US3806178A (en) | 1972-12-20 | 1974-04-23 | D Greytak | Door latch construction |
SE432426B (sv) * | 1976-05-12 | 1984-04-02 | Cpc International Inc | Sett att framstella en vattenuppslamning av sterkelse |
US4120570A (en) * | 1976-06-22 | 1978-10-17 | Syntex (U.S.A.) Inc. | Method for correcting visual defects, compositions and articles of manufacture useful therein |
US4136250A (en) * | 1977-07-20 | 1979-01-23 | Ciba-Geigy Corporation | Polysiloxane hydrogels |
US4153641A (en) * | 1977-07-25 | 1979-05-08 | Bausch & Lomb Incorporated | Polysiloxane composition and contact lens |
JPS584327B2 (ja) | 1978-07-15 | 1983-01-26 | 東洋コンタクトレンズ株式会社 | コンタクトレンズ |
JPS5455455A (en) * | 1977-10-12 | 1979-05-02 | Toyo Contact Lens Co Ltd | Contact lens |
JPS5466853A (en) * | 1977-11-08 | 1979-05-29 | Toyo Contact Lens Co Ltd | Soft contact lens |
US4605712A (en) * | 1984-09-24 | 1986-08-12 | Ciba-Geigy Corporation | Unsaturated polysiloxanes and polymers thereof |
US4665123A (en) * | 1985-12-13 | 1987-05-12 | Ciba-Geigy Corporation | Polyvinyl alcohol derivatives containing pendant (meth)acryloylvinylic monomer reaction product units bound through urethane groups and hydrogel contact lenses made therefrom |
US4670506A (en) * | 1985-12-23 | 1987-06-02 | Ciba-Geigy Corporation | Polyvinyl alcohol derivatives containing pendant (meth)acryloyl units bound through urethane groups and crosslinked hydrogel contact lenses made therefrom |
US4720187A (en) * | 1985-12-23 | 1988-01-19 | Ciba-Geigy Corporation | Polyvinyl alcohol derivatives containing pendant (meth)acryloyl units bound through urethane groups and crosslinked hydrogel contact lenses made therefrom |
US4740533A (en) * | 1987-07-28 | 1988-04-26 | Ciba-Geigy Corporation | Wettable, flexible, oxygen permeable, substantially non-swellable contact lens containing block copolymer polysiloxane-polyoxyalkylene backbone units, and use thereof |
US4837289A (en) * | 1987-04-30 | 1989-06-06 | Ciba-Geigy Corporation | UV- and heat curable terminal polyvinyl functional macromers and polymers thereof |
US4978713A (en) | 1987-12-16 | 1990-12-18 | Ciba-Geigy Corporation | Polyvinyl alcohol derivatives containing pendant vinylic monomer reaction product units bound through ether groups and hydrogel contact lenses made therefrom |
US4910277A (en) * | 1988-02-09 | 1990-03-20 | Bambury Ronald E | Hydrophilic oxygen permeable polymers |
FR2634641A1 (fr) * | 1988-07-28 | 1990-02-02 | Michel Jean Pierre | Dispositif de visee pour le positionnement d'au moins un organe de fixation a travers un implant, du type clou centro-medullaire |
US5070215A (en) * | 1989-05-02 | 1991-12-03 | Bausch & Lomb Incorporated | Novel vinyl carbonate and vinyl carbamate contact lens material monomers |
US5034461A (en) * | 1989-06-07 | 1991-07-23 | Bausch & Lomb Incorporated | Novel prepolymers useful in biomedical devices |
US5244981A (en) * | 1990-04-10 | 1993-09-14 | Permeable Technologies, Inc. | Silicone-containing contact lens polymers, oxygen permeable contact lenses and methods for making these lenses and treating patients with visual impairment |
US5314960A (en) * | 1990-04-10 | 1994-05-24 | Permeable Technologies, Inc. | Silicone-containing polymers, oxygen permeable hydrophilic contact lenses and methods for making these lenses and treating patients with visual impairment |
US5314961A (en) * | 1990-10-11 | 1994-05-24 | Permeable Technologies, Inc. | Silicone-containing polymers, compositions and improved oxygen permeable hydrophilic contact lenses |
US5371147A (en) * | 1990-10-11 | 1994-12-06 | Permeable Technologies, Inc. | Silicone-containing acrylic star polymers, block copolymers and macromonomers |
US5410016A (en) * | 1990-10-15 | 1995-04-25 | Board Of Regents, The University Of Texas System | Photopolymerizable biodegradable hydrogels as tissue contacting materials and controlled-release carriers |
US5310779A (en) * | 1991-11-05 | 1994-05-10 | Bausch & Lomb Incorporated | UV curable crosslinking agents useful in copolymerization |
US5358995A (en) * | 1992-05-15 | 1994-10-25 | Bausch & Lomb Incorporated | Surface wettable silicone hydrogels |
WO1993024545A1 (en) * | 1992-05-29 | 1993-12-09 | Union Carbide Chemicals & Plastics Technology Corporation | Aqueous latexes containing macromonomeres |
US5260000A (en) * | 1992-08-03 | 1993-11-09 | Bausch & Lomb Incorporated | Process for making silicone containing hydrogel lenses |
US5349004A (en) * | 1992-09-18 | 1994-09-20 | Minnesota Mining And Manufacturing Company | Fluoroalkyl siloxane/vinyl copolymer dispersions and pressure-sensitive adhesives having improved solvent resistance prepared therefrom |
TW272976B (US06936641-20050830-C00008.png) | 1993-08-06 | 1996-03-21 | Ciba Geigy Ag | |
US5405888A (en) * | 1993-12-28 | 1995-04-11 | Three Bond Co, Ltd. | Curable silicone composition |
US5760100B1 (en) * | 1994-09-06 | 2000-11-14 | Ciba Vision Corp | Extended wear ophthalmic lens |
TW585882B (en) * | 1995-04-04 | 2004-05-01 | Novartis Ag | A method of using a contact lens as an extended wear lens and a method of screening an ophthalmic lens for utility as an extended-wear lens |
JP3625094B2 (ja) * | 1995-11-24 | 2005-03-02 | 住友精化株式会社 | 吸水性樹脂およびその製造方法 |
JP2001518061A (ja) * | 1995-12-07 | 2001-10-09 | ボシュ アンド ロム インコーポレイテッド | シリコーンヒドロゲルのモジュラスを低減するために有用なモノマーユニット |
GB9624482D0 (en) * | 1995-12-18 | 1997-01-15 | Zeneca Phaema S A | Chemical compounds |
JPH10231340A (ja) * | 1996-12-20 | 1998-09-02 | Takeda Chem Ind Ltd | 光硬化性樹脂組成物およびその製造方法 |
US5998498A (en) * | 1998-03-02 | 1999-12-07 | Johnson & Johnson Vision Products, Inc. | Soft contact lenses |
US5962548A (en) * | 1998-03-02 | 1999-10-05 | Johnson & Johnson Vision Products, Inc. | Silicone hydrogel polymers |
US6822016B2 (en) * | 2001-09-10 | 2004-11-23 | Johnson & Johnson Vision Care, Inc. | Biomedical devices containing internal wetting agents |
US6367929B1 (en) * | 1998-03-02 | 2002-04-09 | Johnson & Johnson Vision Care, Inc. | Hydrogel with internal wetting agent |
US6007833A (en) * | 1998-03-19 | 1999-12-28 | Surmodics, Inc. | Crosslinkable macromers bearing initiator groups |
US6031059A (en) * | 1998-09-30 | 2000-02-29 | Johnson & Johnson Vision Products, Inc. | Optically transparent hydrogels and processes for their production |
WO2000024734A1 (en) * | 1998-10-26 | 2000-05-04 | The Research Foundation Of State University Of New York | Lipoic acid derivatives and their use in treatment of disease |
US6353057B1 (en) | 1999-02-10 | 2002-03-05 | King Industries, Inc. | Catalyzing cationic resin and blocked polyisocyanate with bismuth carboxylate |
US20010049400A1 (en) * | 1999-10-25 | 2001-12-06 | Azaam Alli | Method of making an optical polymer |
US6414049B1 (en) * | 2000-03-22 | 2002-07-02 | Johnson & Johnson Vision Care, Inc. | Stable initiator system |
US6535057B2 (en) * | 2000-05-29 | 2003-03-18 | Stmicroelectronics Ltd. | Programmable glitch filter |
US7879267B2 (en) * | 2001-08-02 | 2011-02-01 | J&J Vision Care, Inc. | Method for coating articles by mold transfer |
US6908978B2 (en) * | 2001-11-02 | 2005-06-21 | Bausch & Lomb Incorporated | High refractive index polymeric siloxysilane compositions |
-
2002
- 2002-06-25 US US10/183,765 patent/US6936641B2/en not_active Expired - Lifetime
-
2003
- 2003-06-23 DE DE60329191T patent/DE60329191D1/de not_active Expired - Lifetime
- 2003-06-23 AU AU2003243724A patent/AU2003243724B2/en not_active Ceased
- 2003-06-23 JP JP2004516119A patent/JP2005530896A/ja active Pending
- 2003-06-23 EP EP03761246A patent/EP1534759B1/en not_active Expired - Fee Related
- 2003-06-23 WO PCT/US2003/019700 patent/WO2004000888A1/en active Application Filing
- 2003-06-23 CN CN038197243A patent/CN1675252B/zh not_active Expired - Fee Related
- 2003-06-23 CA CA002490808A patent/CA2490808A1/en not_active Abandoned
-
2005
- 2005-07-14 US US11/181,510 patent/US7429623B2/en not_active Expired - Lifetime
- 2005-10-19 HK HK05109224.4A patent/HK1077309A1/xx not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5534559A (en) * | 1993-03-18 | 1996-07-09 | Ciba-Geigy Corporation | Daylight curing compositions containing bisacylphosphine oxide photoinitiators |
EP0849296A2 (en) * | 1996-12-20 | 1998-06-24 | Takeda Chemical Industries, Ltd. | A photocurable resin composition and a method for producing the same |
Also Published As
Publication number | Publication date |
---|---|
CA2490808A1 (en) | 2003-12-31 |
US7429623B2 (en) | 2008-09-30 |
AU2003243724B2 (en) | 2008-11-20 |
WO2004000888A1 (en) | 2003-12-31 |
HK1077309A1 (en) | 2006-02-10 |
US6936641B2 (en) | 2005-08-30 |
EP1534759A1 (en) | 2005-06-01 |
DE60329191D1 (de) | 2009-10-22 |
US20060004119A1 (en) | 2006-01-05 |
AU2003243724A1 (en) | 2004-01-06 |
EP1534759B1 (en) | 2009-09-09 |
CN1675252A (zh) | 2005-09-28 |
US20040002556A1 (en) | 2004-01-01 |
JP2005530896A (ja) | 2005-10-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100512 Termination date: 20160623 |
|
CF01 | Termination of patent right due to non-payment of annual fee |