CN1667109A - Food detergent with ocean active matters - Google Patents

Food detergent with ocean active matters Download PDF

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Publication number
CN1667109A
CN1667109A CNA2005100331611A CN200510033161A CN1667109A CN 1667109 A CN1667109 A CN 1667109A CN A2005100331611 A CNA2005100331611 A CN A2005100331611A CN 200510033161 A CN200510033161 A CN 200510033161A CN 1667109 A CN1667109 A CN 1667109A
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China
Prior art keywords
food
extract
seawater
bittern
seawater bittern
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CNA2005100331611A
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CN1290990C (en
Inventor
孙恢礼
翁世兵
李君�
郑建禄
孙大儒
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South China Sea Institute of Oceanology of CAS
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South China Sea Institute of Oceanology of CAS
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Abstract

This invention relates to a food detergent that contains ocean active matter. it is constituted by following components as quality portions sea water bittern extract 10~70%, baking sldap 1.5~85% and food additive 0~20%. The sea water bittern extract by wet basis quality portion main contains NaCl 16~86%, MgSO4 2~21%, MgCl 1~25%. Preparation method is that sea water bittern is purified first, then concentration by evaporation at 120 ~ 1560C and crystallisation by cooling and the crystal is crushed. This invention can react with pesticides, insecticide, organic and inorganic pollution, even harmful microorganism, bacteria, and virus, so it can be used to purify fruit, vegetable, poultry and poultry internal organs, or other food of foreign flavor face and mucilage, it is propitious to ensure food safety.

Description

A kind of food detergent that contains ocean active matters
Technical field
The present invention relates to a kind of food detergent, especially relate to a kind of food detergent that contains ocean active matters, be applicable to and clean vegetables, fruit and pluck etc.
Background technology
Now objectionable impurities such as agricultural chemicals to the pollution of vegetable and fruit and other food serious threat to human existence and health, and potential safety problems such as the caused secondary pollution of chemical classes vegetable and fruit washing composition in the market are also a lot, make most of people no longer be ready to use these chemical classes washing composition.Therefore, the exploitation of natural food washing composition seems very urgent.
Seawater bittern (Bittern) is meant the mother liquor behind the natural sea-water system sodium-chlor.Seawater bittern contains active substance in the seawater, and promptly all inorganic elementss comprise Cl 1-, SO 4 2-, Br 1-, I 1-, Na +, Mg 2+, Ca 2+, K +, Sr 2+, CO 3 2-, HCO 3 -, BO 3 3-Deng the natural inorganic thing, and organism such as a small amount of Sargassum polysaccharides.Existing a lot of bibliographical information seawater bitterns have germ-resistant effect.
Summary of the invention
The objective of the invention is to utilize the ocean bittern to prepare a kind of natural and food detergent efficiently.
Technological processs such as the present invention passes through filtration, purification, heating evaporation is concentrated, crystallization is pulverized, allotment mixing are extracted the active substance in the bitterns of ocean, add sodium bicarbonate again, the food detergent that obtains can be decomposed into harmless material with the objectionable impurities that is attached on the food to greatest extent, thereby has realized purpose of the present invention.
The food detergent that contains ocean active matters of the present invention, it is characterized in that by massfraction, by seawater bittern extract 10%~97%, sodium bicarbonate 1.5%~85% and foodstuff additive 0~20% are formed, always consist of 100%, wherein said seawater bittern extract mainly contains NaCl 16%~86%, MgSO by the wet basis massfraction 42%~21%, MgCl 21%~25%, and obtain by following preparation method: earlier seawater bittern is purified, then 120~156 ℃ of evaporation concentration, then crystallisation by cooling, and get crystallization and pulverize, obtain the seawater bittern extract.
Described seawater bittern extract is except described main component, also contain water such as crystal water, calcium cpd, strontium compound, boron compound, lithium compound, carbonate and other inorganic microelement, also contain micro-content organisms such as Sargassum polysaccharides, sodium alginate.
Described sodium bicarbonate can act synergistically with the seawater bittern extract, accelerates the decomposition of agricultural chemicals and objectionable impurities; Described foodstuff additive are generally used for food, can strengthen washing effect, and are fresh-keeping, and the additive of increase flavour of food products etc. is as sucrose fat, Trisodium Citrate etc.
In the described seawater bittern preparation method of extract, conventional centrifugal separation or filtration method etc. are adopted in described purification, as bittern is passed through sand filter or charcoal filtering layer or gac filtering layer or stone filtering layer etc., be intended to remove pollution substances such as oil in the bittern, agricultural chemicals, heavy metal, according to differences such as raw material sources, pollutent, pollution levels, can select different purifying methods for use; Described evaporation concentration adopts conventional method, can be open under the normal pressure and carry out, also can carry out under negative pressure or vacuum, preferably adopt under the normal pressure and carry out, this moment is froth breaking preferably, so that raising productive rate, froth breaking adopts conventional method, can use the method for chemistry, also can use the method for physics, preferably adopt the method for physics, for example no dirty debubbling method such as mechanical stirring, pneumatic, ultrasonic wave; Crystallisation by cooling adopts conventional method, preferably adopts the open type naturally cooling; When the temperature of evaporation concentration was 120~149 ℃, cooled crystallization adopted the ordinary method solid-liquid separation to obtain, and for example centrifugation, pressure filtration, vacuum filtration etc. preferably will obtain isolating mother liquor and be transported to evaporating pot recycle after purifying.
The preparation method who contains the food detergent of ocean active matters of the present invention is by massfraction, with seawater bittern extract 10%~97%, and sodium bicarbonate 1.5%~85%, foodstuff additive 0~20% mix promptly.
The ratio of above-mentioned food detergent of the present invention in massfraction 1%~5% is dissolved in the fresh water, obtains the multifunctional food washing and use liquid.Fruit or vegetables were soaked in this solution about 10~30 minutes, with clean fresh water flushing 2~3 times, just can remove the most remains of pesticide of vegetables and fruits foodstuff surface (mainly being organic phosphates and objectionable impurities) then.
Directly will above-mentioned food detergent be sprinkling upon on the intestines, abdomen of domestic birds and animals, wash by rubbing with the hands 2~3 times, then with the clean fresh water flushing, obtain totally, odorless, tasteless, nontoxic pig abdomen, chitling.
Organism co-precipitation such as ionogen and trehalose have been initiated in the seawater bittern preparation method of extract of the present invention, make full use of the active substance of ocean, add coordinative role with sodium bicarbonate, can be to greatest extent and nuisances such as various agricultural chemicals, sterilant, inorganic and organic pollutant, even complicated physical and chemical effect takes place in harmful microorganism, bacterium, virus etc., therefore can be used for purifying fruit, vegetables, domestic birds and animals internal organ intestines and stomach etc., perhaps other appearance has raw meat, peculiar smell and mucous food such as smelly, helps ensuring food safety.
Embodiment
Following embodiment further specifies of the present invention, is not limitation of the present invention.
Embodiment 1:
By behind the sand filter, charcoal filtering layer filtration, purification, the normal pressure heating evaporation is concentrated into 149 ℃ with seawater bittern, stirs natural cooling crystallization behind the froth breaking, just obtains solid seawater bittern extract through centrifugation again, contains NaCl 20%, MgSO by massfraction 416%, MgCl 222%, KCl 7.0%, NaBr 1.0%, sodium alginate 0.01%, surplus are water (comprising crystal water), the compound of calcium, strontium, boron, and the inorganic and organic trace element of carbonate and other etc., all content is the wet basis massfraction.Isolating mother liquor is transported to evaporating pot after purifying recycle.
97g seawater bittern extract and sodium bicarbonate 2g mix, and add sucrose fat 1g, promptly obtain containing the food detergent of ocean active matters.
Embodiment 2:
After seawater bittern centrifugation purification, the normal pressure heating evaporation is concentrated into 142 ℃, and natural cooling crystallization behind the ultrasonic wave froth breaking just obtains solid seawater bittern extract through vacuum filtration again, contains NaCl 36%, MgSO by massfraction 418%, MgCl 215%, KCl 5.0%, NaBr 0.80%, sodium alginate 0.007%, surplus are water (comprising crystal water), the compound of calcium, strontium, boron, and the inorganic and organic trace element of carbonate and other etc., all content is the wet basis massfraction.Isolating mother liquor is transported to evaporating pot after purifying recycle.
Seawater bittern extract 60g and sodium bicarbonate 38g mix, and add sucrose fat 1g, and Trisodium Citrate 1g promptly obtains containing the food detergent of ocean active matters.
Embodiment 3:
With seawater bittern by behind the sand filter, charcoal filtering layer filtration, purification, the normal pressure heating evaporation is concentrated into 139 ℃, natural cooling crystallization behind stirring and the pneumatic froth breaking just obtains solid seawater bittern extract through centrifugation again, contains NaCl45%, MgSO by massfraction 419%, MgCl 211%, KCl 5.0%, NaBr 0.70%, sodium alginate 0.01%, surplus are water (comprising crystal water), the compound of calcium, strontium, boron, and the inorganic and organic trace element of carbonate and other etc., all content is the wet basis massfraction.Isolating mother liquor is transported to evaporating pot after purifying recycle.
Seawater bittern extract 65g and sodium bicarbonate 35g mix, and promptly obtain containing the food detergent of ocean active matters.
Embodiment 4:
With seawater bittern halogen centrifugation impurity, behind the active carbon layer filtration, purification, normal pressure also uses oils froth breaking heating evaporation to be concentrated into 136 ℃, back natural cooling crystallization, just obtain solid seawater bittern extract through centrifugation again, contain NaCl 52%, MgSO by massfraction 420%, MgCl 26.0%, KCl 3.0%, NaBr 0.50%, sodium alginate 0.0022%, surplus are water (comprising crystal water), the compound of calcium, strontium, boron, and the inorganic and organic trace element of carbonate and other etc., all content is the wet basis massfraction.Isolating mother liquor is transported to evaporating pot after purifying recycle.
Seawater bittern extract 60g and sodium bicarbonate 39g mix, and add Trisodium Citrate 1g, promptly obtain containing the food detergent of ocean active matters.
Embodiment 5:
By behind the active carbon layer filtration, purification, the normal pressure heating evaporation is concentrated into 128 ℃ with seawater bittern, and natural cooling crystallization behind the stirring froth breaking just obtains solid seawater bittern extract through centrifugation again, contains NaCl 72%, MgSO by massfraction 412%, MgCl 22.1%, KCl 0.50%, NaBr 0.30%, sodium alginate 0.0015%, surplus are water (comprising crystal water), the compound of calcium, strontium, boron, and the inorganic and organic trace element of carbonate and other etc., all content is the wet basis massfraction.Isolating mother liquor is transported to evaporating pot after purifying recycle.
Seawater bittern extract 50g and sodium bicarbonate 30g mix, and add sucrose fat 20g, promptly obtain containing the food detergent of ocean active matters.
Embodiment 6:
With seawater bittern by behind the sand filter, gac filtering layer filtration, purification, the normal pressure heating evaporation is concentrated into 125 ℃, natural cooling crystallization behind the pneumatic froth breaking just obtains solid seawater bittern extract through centrifugation again, contains NaCl 78%, MgSO by massfraction 48.0%, MgCl 21.5%, KCl 0.90%, NaBr 0.20%, sodium alginate 0.0015%, surplus are water (comprising crystal water), the compound of calcium, strontium, boron, and the inorganic and organic trace element of carbonate and other etc., all content is the wet basis massfraction.Isolating mother liquor is transported to evaporating pot after purifying recycle.
Seawater bittern extract 60g and sodium bicarbonate 39g mix, and add sucrose fat 1g, promptly obtain containing the food detergent of ocean active matters.
Embodiment 7:
Behind impurity such as the grit in the centrifugal separation separation seawater bittern, organic debris, it is passed through sand filter, charcoal filtering layer filtration, purification, the normal pressure heating evaporation is concentrated into 120 ℃, natural cooling crystallization behind the stirring froth breaking, just obtain solid seawater bittern extract through centrifugation again, contain NaCl 86%, MgSO by massfraction 42.8%, MgCl 21.2%, KCl 0.20%, NaBr 0.20%, sodium alginate 0.001%, surplus are water (comprising crystal water), the compound of calcium, strontium, boron, and the inorganic and organic trace element of carbonate and other etc., all content is the wet basis massfraction.Isolating mother liquor is transported to evaporating pot after purifying recycle.
Seawater bittern extract 10g and sodium bicarbonate 85g mix, and add sucrose fat 5g, promptly obtain containing the food detergent of ocean active matters.
Embodiment 8:
After will passing through sand filter, charcoal filtering layer filtration, purification from the bittern of natural sea-water, heating evaporation is concentrated into 120 ℃ under 62kPa pressure, natural cooling crystallization just obtains solid seawater bittern extract through centrifugation again, contains NaCl 56%, MgSO by massfraction 415%, MgCl 24.6%, KCl 3.3%, NaBr 0.60%, sodium alginate 0.0019%, surplus are water (comprising crystal water), the compound of calcium, strontium, boron, and the inorganic and organic trace element of carbonate and other etc., all content is the wet basis massfraction.Isolating mother liquor is transported to evaporating pot after purifying recycle.
Seawater bittern extract 10g and sodium bicarbonate 85g mix, and add sucrose fat 5%, promptly obtain containing the food detergent of ocean active matters.
Embodiment 9:
By behind the sand filter, charcoal filtering layer filtration, purification, the normal pressure heating evaporation is concentrated into 156 ℃ with seawater bittern, stir froth breaking after, all concentrated solution natural cooling crystallization obtain solid seawater bittern extract, contain NaCl 18%, MgSO by massfraction 420%, MgCl 222%, KCl 8.0%, NaBr 1.3%, sodium alginate 0.01%, surplus are water (comprising crystal water), the compound of calcium, strontium, boron, and the inorganic and organic trace element of carbonate and other etc., all content is the wet basis massfraction.
Seawater bittern extract 93.5g and sodium bicarbonate 1.5g mix, and add sucrose fat 5g, promptly obtain containing the food detergent of ocean active matters.
Embodiment 10:
The washing of cabbage mustard: a kind of food detergent that contains ocean active matters that embodiment 7 is obtained is dissolved in the clean fresh water in 3% ratio, obtains the washing of multi-functional vegetable and fruit food and uses liquid.Cabbage mustard was soaked in this solution about 20 minutes, with clean fresh water flushing 3 times, just can removes the cabbage mustard remains of pesticide that the surface is polluted by SD-1750 just then, make its residual quantity reach the pollution-free food safety standards (≤0.2mg/Kg, NY5215-2004).
Embodiment 11:
The washing of citrus: a kind of food detergent that contains ocean active matters that embodiment 4 is obtained is dissolved in the clean fresh water in 5% ratio, obtains the citrus washing and uses liquid.Citrus was soaked in this solution about 5 minutes, with clean fresh water flushing 3 times, just can removes the citrus remains of pesticide that the surface is polluted by Rogor just then, make its residual quantity reach state food maximum residue limit standard (1.0mg/Kg, GB5127-1998) below.

Claims (3)

1. food detergent that contains ocean active matters, it is characterized in that by massfraction, by seawater bittern extract 10%~97%, sodium bicarbonate 1.5%~85% and foodstuff additive 0~20% are formed, always consist of 100%, wherein said seawater bittern extract mainly contains NaCl 16%~86%, MgSO by the wet basis massfraction 42%~21%, MgCl 21%~25%, and obtain by following preparation method: earlier seawater bittern is purified, then 120~156 ℃ of evaporation concentration, then crystallisation by cooling, and get crystallization and pulverize, obtain the seawater bittern extract.
2. according to a kind of food detergent that contains ocean active matters of claim 1, it is characterized in that described foodstuff additive are sucrose fat or Trisodium Citrate.
3. according to a kind of food detergent that contains ocean active matters of claim 1 or 2, it is characterized in that in the described seawater bittern preparation method of extract, described evaporation concentration temperature is 150~156 ℃, under unlimited normal pressure, carry out, and carry out froth breaking; Described crystallisation by cooling adopts the open type naturally cooling.
CNB2005100331611A 2005-02-06 2005-02-06 Food detergent with ocean active matters Expired - Fee Related CN1290990C (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101449696B (en) * 2008-11-26 2010-06-02 宾永桂 Preparation method of livestock and poultry intestine tripe cleaning agent
CN103468438A (en) * 2013-09-29 2013-12-25 上海心动能科技有限公司 Environment-friendly ion fabric detergent
CN103468437A (en) * 2013-09-29 2013-12-25 上海心动能科技有限公司 Anti-bacteria tableware washing agent
CN104450288A (en) * 2014-11-07 2015-03-25 舟山赛莱特海洋科技有限公司 Fruit and vegetable detergent based on concentrated saltwater and preparation method thereof
CN104804900A (en) * 2015-03-27 2015-07-29 天津科技大学 Universal fruit and vegetable washing salt composition and preparation method
CN105211253A (en) * 2015-08-25 2016-01-06 郎溪县睿智生产力促进中心有限公司 A kind of pig, cattle and sheep tripe cleaning agent
CN106386998A (en) * 2016-07-27 2017-02-15 柳州市柳南区安顺养殖协会 Preparation method of cow tripe cleaning agent
CN106386999A (en) * 2016-07-27 2017-02-15 柳州市柳南区安顺养殖协会 Preparation method of Nubia goat tripe cleaning agent
CN106434067A (en) * 2016-07-27 2017-02-22 柳州市柳南区安顺养殖协会 Xinjiang brown cattle tripe washing agent preparation method
CN106417551A (en) * 2016-07-27 2017-02-22 柳州市柳南区安顺养殖协会 Preparation method of Boer goat abdomen cleaning agent
CN108192762A (en) * 2018-01-23 2018-06-22 合肥百绿盛农业科技有限公司 A kind of fruits and vegetables special purpose detergent
CN110760394A (en) * 2019-11-04 2020-02-07 黑龙江省普帅农业科技有限公司 Cleaning preparation for removing pesticide residues

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101449696B (en) * 2008-11-26 2010-06-02 宾永桂 Preparation method of livestock and poultry intestine tripe cleaning agent
CN103468438A (en) * 2013-09-29 2013-12-25 上海心动能科技有限公司 Environment-friendly ion fabric detergent
CN103468437A (en) * 2013-09-29 2013-12-25 上海心动能科技有限公司 Anti-bacteria tableware washing agent
CN104450288B (en) * 2014-11-07 2017-12-01 舟山赛莱特海洋科技有限公司 A kind of fruits and vegetables detergent based on strong brine and preparation method thereof
CN104450288A (en) * 2014-11-07 2015-03-25 舟山赛莱特海洋科技有限公司 Fruit and vegetable detergent based on concentrated saltwater and preparation method thereof
CN104804900A (en) * 2015-03-27 2015-07-29 天津科技大学 Universal fruit and vegetable washing salt composition and preparation method
CN105211253A (en) * 2015-08-25 2016-01-06 郎溪县睿智生产力促进中心有限公司 A kind of pig, cattle and sheep tripe cleaning agent
CN106386998A (en) * 2016-07-27 2017-02-15 柳州市柳南区安顺养殖协会 Preparation method of cow tripe cleaning agent
CN106434067A (en) * 2016-07-27 2017-02-22 柳州市柳南区安顺养殖协会 Xinjiang brown cattle tripe washing agent preparation method
CN106417551A (en) * 2016-07-27 2017-02-22 柳州市柳南区安顺养殖协会 Preparation method of Boer goat abdomen cleaning agent
CN106386999A (en) * 2016-07-27 2017-02-15 柳州市柳南区安顺养殖协会 Preparation method of Nubia goat tripe cleaning agent
CN108192762A (en) * 2018-01-23 2018-06-22 合肥百绿盛农业科技有限公司 A kind of fruits and vegetables special purpose detergent
CN110760394A (en) * 2019-11-04 2020-02-07 黑龙江省普帅农业科技有限公司 Cleaning preparation for removing pesticide residues

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Assignee: Shenzhen Magier Co.,Ltd.

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Denomination of invention: Food detergent with ocean active matters

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