CN1641007A - Natural acetic acid cleaning agent for tableware and its manufacturing method - Google Patents
Natural acetic acid cleaning agent for tableware and its manufacturing method Download PDFInfo
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- CN1641007A CN1641007A CN 200410081564 CN200410081564A CN1641007A CN 1641007 A CN1641007 A CN 1641007A CN 200410081564 CN200410081564 CN 200410081564 CN 200410081564 A CN200410081564 A CN 200410081564A CN 1641007 A CN1641007 A CN 1641007A
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- acetic acid
- tableware
- cleaning agent
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Abstract
The natural acetic tableware cleaning agent is compounded with: alkyl glycoside 20-30 wt%, EDTA 0.1-0.5 wt%, edible modified acetic acid 0.1-0.5 wt%, edible essence 0.1-0.2 wt%, polyacrylic acid 1-3 wt% and uncontaminated water 66-79 wt%. The product of the present invention is biodegradable, high in surface activity and high in detergency, and has no toxic side effect on human body, low cost, wide material source, high sterilizing effect and simple production process.
Description
Technical field:
The present invention relates to a kind of dish washing detergent and production method thereof, especially a kind of natural acetic acid cleaning agent for tableware and production method thereof.
Background technology:
Raising along with people's living standard and quality of life, the dish washing detergent consumption is increasing, it is tensio-active agent that at present commercially available and people's dish washing detergent used in everyday generally adopts Sodium dodecylbenzene sulfonate and polyoxyethylenated alcohol sodium sulfate, and EDTA, Sodium sulfate anhydrous.min(99), sanitas, essence are that auxiliary agent produces.Mainly there is following defective in this series products; The one, Sodium dodecylbenzene sulfonate and fatty alcohol-polyoxyethylene ether are to be the product that starting material are produced with the oil, influenced by the global oil price and on the high side, have increased the washing composition production cost.The 2nd, contaminate environment, biodegradation rate is slow, Sodium dodecylbenzene sulfonate, polyoxyethylenated alcohol sodium sulfate and sanitas very easily cause rivers, lake foam to spread unchecked with the wash water discharging, and these materials are residual as having on the tableware of washing simultaneously, can produce harm to human body; The 3rd, the dish washing detergent pH value that contains Sodium dodecylbenzene sulfonate is generally higher, and washing person's skin is had pessimal stimulation, easily causes xerosis cutis, coarse.
Summary of the invention:
The objective of the invention is to overcome the deficiencies in the prior art, provide a kind of washing effect good, to the natural acetic acid cleaning agent for tableware and the production method thereof of human body safety, non-environmental-pollution, purpose of the present invention realizes by following technical proposals:
The present invention is formulated by following component and weight ratio:
Alkyl glycoside (APG) 20-30
EDTA????????????????????????????0.1-0.5
Edible modification acetic acid 0.1-0.5
Food flavour 0.1-0.2
Polyacrylic acid 1-3
Clean water 66-79
Concrete preparation method is as follows:
Earlier clean water is heated to 50-65 ℃, after the adding alkyl glycoside is fully dissolved, adds EDTA, transfer ph to 6.0-7.0 with citric acid or sodium hydroxide solution, add modification acetic acid and polyacrylic acid again, be cooled to 30-40 ℃, add essence, packing gets final product after filtering.
Said alkyl glycoside (APG) structural formula is:
Said edible modification acetic acid molecule formula is:
Its polymerization degree of said polyacrylic acid is 4500-5500, and its structural formula is:
Said clean water is distilled water or deionized water.
Compared with prior art the present invention has following advantage:
1, the used tensio-active agent alkyl glycoside of the present invention is that the derivative with native starch and vegetable and animals oils is the intermediate synthetic; It has biological degradation rapidly thoroughly, surfactivity is high, soil release characteristics is strong, foam is abundant, exquisiteness and stablizing, nontoxic advantage such as non-stimulated.
2, the alkylbenzene glucosides is raw materials used is resourceful regeneration data, is inexhaustible cheapness regeneration organic raw material, can reduce product cost greatly, compare with Sodium dodecylbenzene sulfonate, no matter this tensio-active agent is price, or performance all has clear superiority.
3, the used modification alimentary acetic acid of the present invention, sterilization is strong, and is nontoxic to human body.
4, the pH value of this product is between 6-7, for slightly acidic or neutral and the human body skin pH value is approaching, can not produce pessimal stimulation to human body skin during washing.
5, wash dining set of the present invention very easily cleans up, and tangible water-saving result is arranged.
6, contained polyacrylic acid in the product of the present invention is the clean bright composition of a kind of crust, and it can prevent the secondary deposition of organic dirt, and is clean bright as new behind the dishwashing detergent.
We compare the test contrast product to product salient features of the present invention with domestic and international other dish washing detergent performance has-the cat dish washing detergent ,-board dish washing detergent and-dish washing detergent ,-strong dish washing detergent.(1) detergency test, experiment method: it is as follows to press GB9986-2000 " hand washing use dish washing detergent " experimental result:
The detergency test result
| Test products | -cat | -board | -Bai | -strong | Spring flies |
| The dishwashing number | ??4.7 | ??3.5 | ??4.4 | ??4.0 | ????6.5 |
Annotate: the spring flies to be product of the present invention, and its detersive power is best
(2), pungency compares relatively
Test conditions: 20 people, detergent concentration 1%; Once sealing, 24 hours time.
Test method: Duhring-Chamber method
Test result
| Test products | -cat | -board | -Bai | -strong | Spring flies |
| Relative pungency % | ??100 | ??120 | ??90 | ??90 | ??10 |
(3), biological degradability test:
Test method: GB/T15818-1995 " negatively charged ion and nonionogenic tenside biological degradation biological degradability test method "
Test result:
| Test products | -cat | -board | -Bai | -strong | Spring flies |
| Biological degradation rate | ??95％ | ??92％ | ??93％ | ??93％ | ??99.9％ |
(4), to the human safety simultaneous test:
The clean small white mouse LD50 of natural acetic acid tableware is 3000-7000mg/kg (acute oral), meets human body and Environmental Safety requirement index fully.The small white mouse LD50 of other brand is about 500mg/kg, and is harmful.
In sum, the objective of the invention is to realize, product of the present invention is easily by biology degraded fully rapidly, surperficial quiet property height, strong detergency has no side effect to human body, and its cost is lower, and raw material is extensive, bactericidal properties is strong, and washing effect is good, and production technique is simple.
Embodiment:
Embodiment 1, gets the raw materials ready by following component and weight:
Alkyl glycoside (APG) 20kg
EDTA??????????????????????????0.1kg
Edible modification acetic acid 0.5kg
Food flavour 0.1kg
Polyacrylic acid 1kg
Remove dried up 66kg
Concrete preparation method is as follows:
Earlier clean water is heated to 50 ℃, after the adding alkyl glycoside is fully dissolved, adds EDTA, transfer PH to 6.0 with citric acid or sodium hydroxide solution, add modification acetic acid and polyacrylic acid again, it is 4500 polyacrylic acid that present embodiment is selected the polymerization degree for use, is cooled to 30 ℃, add food flavour, essence can be lemon flavour, apple flavour, grapefruit essence etc. any or several mixture, present embodiment is selected lemon flavour for use, filters the back packing and gets final product.
Embodiment 2, get the raw materials ready by following component and weight
Alkyl glycoside (APG) 30kg
EDTA????????????????????????????0.5kg
Edible modification acetic acid 0.1kg
Food flavour 0.2kg
Polyacrylic acid 3kg
Distilled water 79kg
Concrete preparation method is as follows:
Earlier clean water is heated to 65 ℃, after the adding alkyl glycoside is fully dissolved, add EDTA, transfer ph to 6.5 with citric acid or sodium hydroxide solution, add modification acetic acid and polyacrylic acid again, it is 5000 polyacrylic acid that present embodiment is selected the polymerization degree for use, be cooled to 35 ℃, add food flavour, present embodiment is selected apple flavour for use, filters the back packing and gets final product.
Embodiment 3:
Alkyl glycoside (APG) 25kg
EDTA???????????????????????????0.4kg
Edible modification acetic acid 0.3kg
Food flavour 0.15kg
Polyacrylic acid 2kg
Remove dried up 70kg
Concrete preparation method is as follows:
Earlier clean water is heated to 60 ℃, after the adding alkyl glycoside is fully dissolved, add EDTA, transfer ph to 7.0 with citric acid or sodium hydroxide solution, add modification acetic acid and polyacrylic acid again, it is 5500 polyacrylic acid that present embodiment is selected the polymerization degree for use, be cooled to 40 ℃, add essence, present embodiment is selected grapefruit essence for use, filters the back packing and gets final product.
Claims (2)
1, a kind of natural acetic acid cleaning agent for tableware is characterized in that by following component and weight ratio formulated:
Alkyl glycoside (APG) 20-30
EDTA?????????????????????????0.1-0.5
Edible modification acetic acid 0.1-0.5
Food flavour 0.1-0.2
Polyacrylic acid 1-3
Clean water 66-79
2, the production method of the said natural acetic acid cleaning agent for tableware of a kind of claim 1, it is characterized in that: earlier clean water is heated to 50-65 ℃, after the adding alkyl glycoside is fully dissolved, add EDTA, transfer ph to 6.0-7.0 with citric acid or sodium hydroxide solution, add modification acetic acid and polyacrylic acid again, be cooled to 30-40 ℃, add essence, filter the back packing and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410081564 CN1641007A (en) | 2004-12-17 | 2004-12-17 | Natural acetic acid cleaning agent for tableware and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410081564 CN1641007A (en) | 2004-12-17 | 2004-12-17 | Natural acetic acid cleaning agent for tableware and its manufacturing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1641007A true CN1641007A (en) | 2005-07-20 |
Family
ID=34869178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410081564 Pending CN1641007A (en) | 2004-12-17 | 2004-12-17 | Natural acetic acid cleaning agent for tableware and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1641007A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103379825A (en) * | 2011-02-25 | 2013-10-30 | 萨尔弗科公司 | Biocidal materials |
-
2004
- 2004-12-17 CN CN 200410081564 patent/CN1641007A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103379825A (en) * | 2011-02-25 | 2013-10-30 | 萨尔弗科公司 | Biocidal materials |
| CN103379825B (en) * | 2011-02-25 | 2016-05-04 | 萨尔弗科公司 | Biocidal material |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |