CN1628520A - Externally used preparation for household pet disinsection and sterilization - Google Patents
Externally used preparation for household pet disinsection and sterilization Download PDFInfo
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- CN1628520A CN1628520A CN 200410040747 CN200410040747A CN1628520A CN 1628520 A CN1628520 A CN 1628520A CN 200410040747 CN200410040747 CN 200410040747 CN 200410040747 A CN200410040747 A CN 200410040747A CN 1628520 A CN1628520 A CN 1628520A
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Abstract
The invention discloses an externally used preparation for household pet disinsection and sterilization, which employs ketoconazole or/and chlorhexidine acetate as the active constituents, and balancing auxiliary materials. wherein the effective composition of bactericide in the external preparation comprises 0.1-20.0% of ketoconazole and 0.04% of chlorhexidine acetate, the effective composition of pesticide in the external preparation comprises 0.001-20.0% of natural insecticidal cyhalothrin and balancing additive auxiliary materials, the effective composition of sterilizing complexing agent in the external preparation comprises 0.001-20.0% of natural insecticidal cyhalothrin, 0.04% of chlorhexidine acetate, and 0.1-20.0% of ketoconazole.
Description
Technical field:
The present invention relates to a kind of external preparation that is used for house pet desinsection and sterilization, more specifically relating to a kind of is that insecticide raw material and ketoconazole, chlorhexidine acetate are desinsection, the washing lotion of sterilization external preparation, shampoo, perfumed soap, spray with natural plant insect killing chrysanthemum fat.Fungi, Escherichia coli, staphylococcus aureus that is applicable to animal body surfaces such as directly killing house pet such as dog, cat etc. is common to parasites such as germ and flea, louse.
Technical background:
Human numerous disease is propagated by hematophagus, the lice flea can be propagated dangerous diseases such as LBT, the plague, relapsing fever, whole world every year due to illness insect pest cause with a toll of 1,200 hundred million dollars, eliminate vector " lice flea " is the key link of control disease always.
Louse can be subjected to the influence of insecticide, normally used chemical insecticide is mainly organic phosphorus compound and intends chrysanthemum lipid, use these insecticides and not only killed insect, also killed the natural enemy of useful insect and insect simultaneously, and other living resources have been destroyed to a certain extent, caused ecological balance damage, chemical insecticide also produces certain harm to people and animals simultaneously.
Middle fifties, medicine delousing flea widespread organochlorine insecticide such as hexachlorcyclohexane, two or two is third-class, but owing to produced pesticide resistance, insecticidal effect is not good.After the sixties, there is new insecticide to promote again, as organophosphorus insecticide chlorophos, dichlorvos etc., harmful in view of the organochlorine medicine pollutes the environment to people and animals, stopped at present producing and using.The cruel class of carbamic acid, it is fast to intend insecticide chrysanthemum lipid insecticidal effect, but the cost height, and still poisonous.Although synthetic plan desinsection chrysanthemum vinegar is more effective than natural 4-Chloro-on the antagonism louse, to higher toxicity usually being arranged by the treatment acceptor.
Bad hygienic habit has been propagated significant effect to louse.The lice flea is a findable parasite on nearly all mammalian fauna, and the lice flea bites and causes stimulating, and can cause stimulation face to infect but stimulate.Pet enters ten million family, has both brought the joyful worry of also bringing, and the dangerous infectious diseases that cat and dog lice flea on one's body makes the city become extinct already probably is revivable.Killing animal for display lice flea on one's body, cut off popular link, is the requisite measure of protection social public security.Searching is to the nontoxic medicine of efficiently killing the lice flea again of people and animals, and is particularly important.For this reason, the present invention adopts the combination of pure natural plant extract and makes this external preparation.
Desinsection chrysanthemum formal name used at school: Chrysanthemnm cinera riacefolium, another name: spend the desinsection chrysanthemum in vain, department: composite family form: perennial herb.High by one, two chis, greyish white, the light green of complete stool, the main root taper shape, the lateral root majority, the elongated palpus shape that is, filbert.Five, high by one, two chis of stem between June, cephaloid is given birth on branch top, adularescent ligulate corolla on every side, central authorities are the tubular corolla of yellow.Fruit maturation between July.The place of production: all there is cultivation in provinces such as former Jiangsu, Zhejiang, Jiangxi, Shandong, at present only in Jiangsu, Yunnan finds.Medicinal part: spend preferably, stem, leaf take second place.The flower of flower when half-open renderd a service best, and it is poor that the flower of opening is renderd a service.Adopt that the flower that gets off should in time dry or low temperature under heat drying (below 60 ℃), make water content between 6-12%.
Common said desinsection chrysanthemum element is meant the mixture of several desinsection chrysanthemum elements, and its content in spending is generally about 0.9-1.3%.Various desinsection chrysanthemum elements through purifying all are light yellow viscous liquids, and are water insoluble and be dissolved in the organic solvents such as benzinum, gasoline, benzene, acetone, ethanol, contact daylight, high temperature, humidity or alkaline matter, all easy decomposition failure.
The desinsection chrysanthemum has very strong action of contace poison to insect, benumbs rapidly in a few minutes, is poisoned to death behind the insect contact medicament.19 beginnings of the century, the plain control of human desinsection chrysanthemum louse is arranged, flea, house pests such as cockroach. studies show that desinsection chrysanthemum element has the insecticidal effect of high-efficiency broad spectrum, the desinsection chrysanthemum element of one of 100,000 concentration has fine desinsection fruit to nearly all pest and house pest.Boy M.G.ct.al (2000) prevents and treats cat louse on one's body with desinsection chrysanthemum element, and DrydenM.ctal (1999) is sprayed at desinsection chrysanthemum element on one's body the pet, and the louse rate of going down is 48.9% after 7 days.Yang Shaohong sprays about 1 second with desinsection chrysanthemum ester spray treatment pediculosis pubis nine examples, can repeat to spray medicine behind the 3d 1 time.Follow up a case by regular visits to after 1 week, all cure (wherein 8 examples are only sprayed medicine 1 time, repeat to spray medicine 1 time behind the 1 routine 3d).All there is not obvious adverse reaction, nontoxic to human body.
Meaningfully, desinsection chrysanthemum element does not just reach before the nervous centralis by metabolism and drains in dried meat breast animal body, and in insect bodies, can reach its nervous system, causes excitement and paralysis, causes knocking down and death.The desinsection chrysanthemum element of Nong Suoing is not almost non-toxic to the people, uses very safely, plant is not had poisoning yet, big white mouse per os LD
50Be 1500mg/kg.
The pet body surface is except parasites such as flea, louse, also have pathogenic bacteria such as a large amount of fungies, Escherichia coli, staphylococcus aureus, can cause that pet infects, again can be because of pet and people, particularly children contact closely with the elderly and cause infecting, and existing both at home and abroad many reports cause enteritis, ringworm of the body because raising pet such as cat, dog, illnesss such as meningitis are serious even cause death.
The treatment fungi is more effective both at home and abroad at present, toxicity is lower, the medicine that price is also lower is exactly a ketoconazole, it is by suppressing the synthetic of the liquor-saturated and relevant vinegar compounds of bacterial cell wall surface ergot reputation, cause cell wall defective, the permeability that changes film causes fungi sex change death, so all better to skin surface fungal infection curative effect.
Summary of the invention
The objective of the invention is to avoid the deficiency of above-mentioned delousing flea medicine and bactericide, and provide a kind of with natural plant extracts desinsection chrysanthemum element+chlorhexidine acetate, natural desinsection chrysanthemum ester+ketoconazole or+that chlorhexidine acetate, ketoconazole+chlorhexidine acetate are made is safe, be used for the external preparation of house pet desinsection and sterilization efficiently, particularly the above-mentioned material component of stating is used to kill and colonizes in house pet lice flea on one's body.
The present invention also may carry the characteristic of pathogenic bacteria at pet, provide a series of efficient, safe antibiotic pets to use washing, nursing materials such as conditioning liquid, shampoo, bath foam, perfumed soap, spray.
The objective of the invention is to finish like this: a kind of external preparation that is used for house pet desinsection and sterilization, it is characterized in that active ingredient that this external preparation contains Pesticidal and sterilizing in essence is natural desinsection chrysanthemum ester, ketoconazole or/and chlorhexidine acetate, all the other are for adding auxiliary material; This external preparation can be made into conditioning liquid, shampoo, bath foam, perfumed soap, spray; The bactericidal agent effective ingredient that contains in the external preparation is made up of ketoconazole and 0.04% chlorhexidine acetate of 0.1-20.0%, and its surplus is for adding auxiliary material; The insecticide effective ingredient that contains in the external preparation is the natural 4-Chloro-by 0.001-20.0%, and its surplus is for adding auxiliary material; The Pesticidal and sterilizing complexing agent effective ingredient that contains in the external preparation is made of jointly the ketoconazole of natural 4-Chloro-, 0.04% chlorhexidine acetate and the 0.1-20.0% of 0.001-20.0%, and its surplus is an auxiliary material.
A kind of external preparation that is used for house pet desinsection and sterilization is characterized in that with the active ingredient that contains Pesticidal and sterilizing be natural desinsection chrysanthemum ester, ketoconazole or/and chlorhexidine acetate, and all the other use as pet desinsection and bactericidal agent for the external preparations that add auxiliary material.
The auxiliary material of indication comprises among the present invention: piperonyl butoxide; lauryl sodium sulfate; glycol stearate; peregal EO; sodium acetate; CMC; 2-hydroxyl C14 alkyl phosphoric acid sodium; sodium laurate; cocamidopropyl betaine; Cocoamidopropyl betaine; C13 alkyl ether ammonium sulfate; Tween20; the stearyl sodium glutamate; C14 alkyl methyl aminoethyl phosphonic acid sodium; C16 alkyl methyl aminoethyl phosphonic acid sodium; C18 alkyl methyl aminoethyl phosphonic acid sodium triethanolamine; the C9-11 alkyl glycoside; lauric acid diethyl amide; lauric acid; PEG-20 ten thousand; the lauroyl imidazoline; sulfosuccinic acid list bay alkyl; the lauric acid triethanolamine salt; the C12 sodium alkylether sulphate; C18 alkyl dimethyl propionic acid ammonium; C18 alkyl trihydroxyethyl ammonium chloride; cationic cellulose; the rilanit special APEO; EO-PO type polyethers; coconut oil potassium; glycerine; lauric acid diethyl amide etc.
The ketoconazole that the present invention is used for the external preparation of house pet desinsection and sterilization can directly be killed common pathogens such as the fungi, Escherichia coli, staphylococcus aureus of pet body surfaces such as dog, cat; Natural 4-Chloro-can effectively be killed the flea and the louse of pet body surfaces such as dog, cat.Since safety, delousing flea and antibacterial action are efficiently arranged, thereby have great society and economic benefit, but wide popularization and application, for human health is made contributions.
Embodiment
By specific embodiment given below and experimental data material, can further be well understood to external preparation of the present invention and application of the present invention.But they are not limitation of the invention.
Embodiment 1 Pesticidal shampoo (composition is % by weight percentage):
Desinsection chrysanthemum ester 0.001
Chlorhexidine acetate 0.04
Piperonyl butoxide 0.001
Lauryl sodium sulfate 50.0
Glycol stearate 2.0
Peregal EO 6.0
Sodium acetate 2.0
CMC?????????????????????0.5
Water 39.46
Embodiment 2 Pesticidal shampoos
Desinsection chrysanthemum ester 20.0
Piperonyl butoxide 20.0
Chlorhexidine acetate 0.04
2-hydroxyl C14 alkyl phosphoric acid sodium 10.0
Sodium laurate 3.0
Cocamidopropyl betaine 3.0
Water 43.96
Embodiment 3 Pesticidal shampoos
Desinsection chrysanthemum ester 1.0
Piperonyl butoxide 1.0
Chlorhexidine acetate 0.04
Cocoamidopropyl betaine 17.1
C13 alkyl ether ammonium sulfate 8.3
Tween20?????????????????15.0
Water 57.56
Embodiment 4 antibiotic shampoos
Ketoconazole 0.1
Chlorhexidine acetate 0.04
Stearyl sodium glutamate 15.0
C14 alkyl methyl aminoethyl phosphonic acid sodium 25.0
C16 alkyl methyl aminoethyl phosphonic acid sodium 2.5
C18 alkyl methyl aminoethyl phosphonic acid sodium triethanolamine 1.0
Water 56.36
Embodiment 5 antibiotic shampoos
Ketoconazole 20.0
Chlorhexidine acetate 0.04
C9-11 alkyl glycoside 10.0
Lauric acid diethyl amide 3.0
Lauric acid 1.0
PEG-20 10,000
Water 65.95
Embodiment 6 antibiotic shampoos
Ketoconazole 3.0
Chlorhexidine acetate 0.04
Lauroyl imidazoline 10.0
Sulfosuccinic acid list bay alkyl 10.0
Lauric acid triethanolamine salt 1.0
Water 75.96
Embodiment 7 composite bactericidal Pesticidal shampoos
Ketoconazole 2.0
Desinsection chrysanthemum ester 0.5
Chlorhexidine acetate 0.04
Piperonyl butoxide 0.4
C12 sodium alkylether sulphate 20.0
C18 alkyl dimethyl propionic acid ammonium 8.0
C18 alkyl trihydroxyethyl ammonium chloride 0.2
Cationic cellulose 1.0
Water 67.86
Embodiment 8 composite bactericidal Pesticidal shampoos
Ketoconazole 20.0
Desinsection chrysanthemum ester 20.0
Chlorhexidine acetate 0.04
Piperonyl butoxide 0.4
C12 sodium alkylether sulphate 20.0
C18 alkyl dimethyl propionic acid ammonium 8.0
C18 alkyl trihydroxyethyl ammonium chloride 0.2
Cationic cellulose 1.0
Water 30.36
Embodiment 9 composite bactericidal Pesticidal shampoos
Ketoconazole 0.1
Desinsection chrysanthemum ester 0.001
Chlorhexidine acetate 0.04
Piperonyl butoxide 0.4
C12 sodium alkylether sulphate 20.0
C18 alkyl dimethyl propionic acid ammonium 8.0
C18 alkyl trihydroxyethyl ammonium chloride 0.2
Cationic cellulose 1.0
Water 70.26
Embodiment 10 antibiotic desinsection perfumed soaps
Ketoconazole 2.0
Desinsection chrysanthemum ester 0.4
Chlorhexidine acetate 0.04
Piperonyl butoxide 0.4
Rilanit special APEO 40.0
EO-PO type polyethers 2.0
Coconut oil potassium 20.0
Glycerine 5.0
Lauric acid diethyl amide 1.0
Water 29.16
Following experimental data is to obtain with the minimum sampling test of Pesticidal and sterilizing agent content, and the Pesticidal and sterilizing agent content of all the other prescriptions all is higher than time content, and its Pesticidal and sterilizing effect also should be stronger.
Composite bactericidal Pesticidal shampoo sterilization experiment
Along with the raising of city life level, housing condition is constantly improved, the continuous variation that family population constitutes, and the family that raises cat, dog class pet is more and more, and pet and people's life is close day by day, and its health status also is subjected to raising pets master's attention day by day.Thing diseases such as dermatitis, itch, pathologic depilation are perplexing the raising pets master.The pet fur is infected with the more direct health that is threatening the raising pets master of the various pathogens of carrying.For this reason, we have developed a kind of special-purpose disinfection nursing shampoo of pet with potent sterilization and insecticidal action, measure its killing action to microorganism.Now research method and result are reported as follows.
1 material and method
1.1 test strain: adopt sterilizing test representative strain staphylococcus aureus CMCC26003 strain, Escherichia coli CMCC44103 strain, Candida albicans CMCC98001 strain.
1.2 composite bactericidal Pesticidal shampoo: the liquid preparation (prescription is seen embodiment 9) that contains ketoconazole, chlorhexidine acetate and desinsection chrysanthemum ester disinfectant composition.
I.3 laboratory quantitative disinfecting test: adopt the suspension quantitative disinfecting test.The preparation bacteria containing amount is 5 * 10
5,-5 * 10
6The cfu/ml bacteria suspension is used for test.5.0ml places test tube with disinfectant, puts 20 ℃, water-bath 5 minutes, adds 0.1ml bacteria suspension mixing, acts on 0.5,1,2,5 respectively, 10 minutes, draws this mixed liquor.Shake up 0.5ml advance in the 4.5ml neutralizer test tube, act on 10 minutes respectively after, get 0.5ml respectively and do viable bacteria counting with tilt-pour process.Test sample is all put to train in 37 ℃ of incubators and was held concurrently 48 hours. observe final result.
1.4 field trial: get 30 of new zealand white rabbits, mark 5 * 5cm square in its ridge portion adjacent regions, be respectively experimental group and control group, during test the control group rabbit hair is cut, put into and contain 10ml neutralizer test tube, experimental group spray disinfectant 3ml uses the wooden comb combing, makes it all to be distributed in the surface, after 10 minutes the rabbit hair is cut, put into and contain 10ml neutralizer test tube and after 10 minutes, rapping is evenly analyzed, observe its result after 48 hours.
1.5 stability test: adopt accelerated test, the composite bactericidal Pesticidal shampoo is placed in 54 ℃ of water-baths 14 days, before placing and place back its killing action of mensuration to Candida albicans ATCC10231 strain.
2.1 laboratory bactericidal assay result (table 1)
Table 1: disinfectant bactericidal assay result
| Killing rate (%) experimental strain (cfu/ml) 0.5 125 10 of viable bacteria contrast different time (branch) |
| Candida albicans 3.5 * 10 699.99 100 100 100 95.99 (CMCC98001) staphylococcus aureus 5.32 * 10 699.99 99.99 100 100 92.52 (CMCC26003) Escherichia coli 3.86 * 10 6???94.12??98.54??99.99??99.99??100 ??(CMCC44103) |
As can be seen from Table 1, the special-purpose disinfection nursing shampoo of pet effect can be killed Candida albicans strain (CMCC98001) and reach 100% in 2 minutes, acted on 1 minute and can reach 99.99.% with respectively staphylococcus aureus strain (CMCC26003) and Escherichia coli (CMCC26003) strain being killed in 2 minutes
2.2 site test results
Be sprayed on experimental group zone, rabbit back with composite bactericidal Pesticidal shampoo 10ml, and even with the wooden comb combing, and 10 minutes energy are on average killed the natural bacteria that carries in the rabbit hair and are reached 90.50%.
2.3 stability test result:
Sample is placed on 54 ℃ descends 14, day its killing action of mensuration to Candida albicans strain CMCC98001, the killing rate that begins preceding sample with accelerated test compares.Found that killing rate does not have obvious reduction before and after placing.Disinfectant reaches time of 99.9% to Candida albicans strain CMCC98001 killing rate and is 5 minutes (table 2) before and after placing.Effective storage period of this disinfectant, can be 1 year.
Table 2 disinfectant is placed front and back to the oidiomycetic killing effect of white
| According to average bacterium effect different time (branch) average kill ratio (%) the group number of group (cfu/ml) 35 10 15 |
| Place preceding 4,253,323 99.89 99.97 99.99 99.99 and place back 1,480,000 99.89 99.96 99.99 99.99 |
Pet infected by microbes does not on one's body obtain people's extensive attention for a long time.Family's " shampoo " class bath article commonly used is done cleaning to pet, but this can only play cleaning action, and the pathogenic bacteria of carrying for most of pets do not have killing action.Make that pet is ill or give the people with transmission of infection.The special-purpose disinfection nursing shampoo of this pet has the effect of sterilization and combing pet fur concurrently, can bring into play lasting effect, can reduce the bacterium amount of taking in the pet fur greatly, ensure pet health, prevent disease takes place, and to dermatitis, phlegm that infection causes itch, disease such as pathologic depilation has therapeutic action.Believe that the consciousness theory of pet health health care will be accepted by the raising pets master.
Composite bactericidal Pesticidal shampoo insecticidal test
It is the 15cm specimen jar that 5 diameters are got in laboratory simulation test, drops into 20 fleas in every wooden cylinder of mark, covers cylinder cap, pulicida and water are mixed at 1: 2, be mixed with dilution, to bottom spray composite bactericidal Pesticidal shampoo (prescription is seen embodiment 9), observe killing effect with miniaturised nebuliser.
Table 1 pet depulization washing agent is to the killing effect of laboratory flea
| Dosage (g/ml) | Throw flea number (only) | Different time (min) is knocked down number (only) | 24h lethality (%) |
| ????1.5????30????60 | |||
| ??0.5 ??1.0 ??2.0 ??4.0 ??6.0 | ????20 ????20 ????20 ????20 ????20 | ????4??????10????11 ????7??????15????14 ????15?????18????17 ????19?????20????20 ????20?????20????20 | ????55 ????70 ????85 ????100 ????100 |
Zoopery shows that pet cat uses 15ml, dog to use the 20ml pulicida, and the depulization rate reaches 100%. soups does not have obvious influence to animal skin, only in the higher environment of temperature, behind personnel hand contact soup, and when touching the face of perspiring, slight spicy sensation is arranged.
The special-purpose shampoo of this pet also can with atomizers spray method kill fleas, can have good effect equally after other has movable easily institute's water of flea to dilute with 1: 10.
Claims (7)
1, a kind of external preparation that is used for house pet desinsection and sterilization is characterized in that active ingredient that this external preparation contains Pesticidal and sterilizing in essence is natural desinsection chrysanthemum ester, ketoconazole or/and chlorhexidine acetate, and all the other are for adding auxiliary material.
2, the external preparation that is used for house pet desinsection and sterilization according to claim 1 is characterized in that this external preparation can be made into conditioning liquid, shampoo, bath foam, perfumed soap, spray.
3, according to claim 1 and the 2 described external preparations that are used for house pet desinsection and sterilization, it is characterized in that the bactericidal agent effective ingredient that contains in the external preparation is made up of ketoconazole and 0.04% chlorhexidine acetate of 0.1-20.0%, its surplus is for adding auxiliary material.
4, according to claim 1 and the 2 described external preparations that are used for house pet desinsection and sterilization, it is characterized in that the insecticide effective ingredient that contains in the external preparation is the natural 4-Chloro-by 0.001-20.0%, its surplus is for adding auxiliary material.
5, according to claim 1 and the 2 described external preparations that are used for house pet desinsection and sterilization, it is characterized in that the Pesticidal and sterilizing complexing agent effective ingredient that contains in the external preparation is made of jointly the ketoconazole of natural 4-Chloro-, 0.04% chlorhexidine acetate and the 0.1-20.0% of 0.001-20.0%, its surplus is an auxiliary material.
6, according to claim 1 and the 2 described external preparations that are used for house pet desinsection and sterilization, it is characterized in that with the active ingredient that contains Pesticidal and sterilizing be natural desinsection chrysanthemum ester, ketoconazole or/and chlorhexidine acetate, all the other use as pet desinsection and bactericidal agent for the external preparations that add auxiliary material.
7; according to claim 1 and the 2 described external preparations that are used for house pet desinsection and sterilization, it is characterized in that the auxiliary material of this external preparation indication comprises: piperonyl butoxide; lauryl sodium sulfate; glycol stearate; peregal EO; sodium acetate; CMC; 2-hydroxyl C14 alkyl phosphoric acid sodium; sodium laurate; cocamidopropyl betaine; Cocoamidopropyl betaine; C13 alkyl ether ammonium sulfate; Tween20; the stearyl sodium glutamate; C14 alkyl methyl aminoethyl phosphonic acid sodium; C16 alkyl methyl aminoethyl phosphonic acid sodium; C18 alkyl methyl aminoethyl phosphonic acid sodium triethanolamine; the C9-11 alkyl glycoside; lauric acid diethyl amide; lauric acid; PEG-20 ten thousand; the lauroyl imidazoline; sulfosuccinic acid list bay alkyl; the lauric acid triethanolamine salt; the C12 sodium alkylether sulphate; C18 alkyl dimethyl propionic acid ammonium; C18 alkyl trihydroxyethyl ammonium chloride; cationic cellulose; the rilanit special APEO; EO-PO type polyethers; coconut oil potassium; glycerine; lauric acid diethyl amide.
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| CN 200410040747 CN1278610C (en) | 2004-09-22 | 2004-09-22 | Externally used preparation for household pet disinsection and sterilization |
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|---|---|---|---|
| CN 200410040747 CN1278610C (en) | 2004-09-22 | 2004-09-22 | Externally used preparation for household pet disinsection and sterilization |
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| CN1628520A true CN1628520A (en) | 2005-06-22 |
| CN1278610C CN1278610C (en) | 2006-10-11 |
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| CN102763692A (en) * | 2012-08-15 | 2012-11-07 | 李国� | Mosquito-repellent incense |
| CN102763692B (en) * | 2012-08-15 | 2014-05-28 | 李国� | Mosquito-repellent incense |
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| CN109221111A (en) * | 2018-09-14 | 2019-01-18 | 柯林森·哈德罗·休 | It is a kind of for treating the drug of poultry louse |
| CN109464390A (en) * | 2018-12-29 | 2019-03-15 | 上海汉维生物医药科技有限公司 | Compound Permethrin composition and preparation method thereof |
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