CN1596151A - 用于二异丙苯烷基转移反应的沸石催化剂 - Google Patents

用于二异丙苯烷基转移反应的沸石催化剂 Download PDF

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Publication number
CN1596151A
CN1596151A CNA028235495A CN02823549A CN1596151A CN 1596151 A CN1596151 A CN 1596151A CN A028235495 A CNA028235495 A CN A028235495A CN 02823549 A CN02823549 A CN 02823549A CN 1596151 A CN1596151 A CN 1596151A
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China
Prior art keywords
component
catalyst composition
zeolite
catalyst
benzene
Prior art date
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Pending
Application number
CNA028235495A
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English (en)
Chinese (zh)
Inventor
M·J·凡德阿尔斯特
M·S·萨姆森
G·R·梅玛
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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Publication of CN1596151A publication Critical patent/CN1596151A/zh
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/16After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007Zeolite Beta
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04Alumina
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08Silica
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10Magnesium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16Clays or other mineral silicates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80Mixtures of different zeolites
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNA028235495A 2001-12-06 2002-10-07 用于二异丙苯烷基转移反应的沸石催化剂 Pending CN1596151A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33835201P 2001-12-06 2001-12-06
US60/338,352 2001-12-06

Publications (1)

Publication Number Publication Date
CN1596151A true CN1596151A (zh) 2005-03-16

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CNA028235495A Pending CN1596151A (zh) 2001-12-06 2002-10-07 用于二异丙苯烷基转移反应的沸石催化剂

Country Status (11)

Country Link
US (1) US20050038307A1 (enExample)
EP (1) EP1455939A1 (enExample)
JP (1) JP2005511285A (enExample)
KR (1) KR20050034633A (enExample)
CN (1) CN1596151A (enExample)
AU (1) AU2002342005A1 (enExample)
BR (1) BR0214658A (enExample)
CA (1) CA2468534A1 (enExample)
MX (1) MXPA04005454A (enExample)
TW (1) TW200300752A (enExample)
WO (1) WO2003049857A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102407156A (zh) * 2010-09-21 2012-04-11 中国石油天然气股份有限公司 一种烷基转移催化剂的制备方法
CN102470353A (zh) * 2009-07-03 2012-05-23 英国石油国际有限公司 改性沸石催化剂
CN110337328A (zh) * 2017-02-28 2019-10-15 埃克森美孚化学专利公司 催化剂组合物及其用于芳族化合物烷基化方法的用途
CN114426451A (zh) * 2020-09-24 2022-05-03 中国石油化工股份有限公司 一种多取代异丙苯烷基转移制备异丙苯的方法及其所得异丙苯

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7919421B2 (en) * 2006-12-21 2011-04-05 Exxonmobil Chemical Patents Inc. Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation
US7626064B1 (en) * 2008-06-26 2009-12-01 Uop Llc Transalkylation process
US8435909B2 (en) * 2010-02-18 2013-05-07 King Fahd University Of Petroleum And Minerals Dual-zeolite catalyst for production of ethylbenzene
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
WO2018160327A1 (en) * 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5243116A (en) * 1987-11-23 1993-09-07 The Dow Chemical Company Alkylation of aromatic compounds
US5240889A (en) * 1991-07-12 1993-08-31 Union Oil Company Of California Hydrated alkylation catalyst
IT1270230B (it) * 1994-06-16 1997-04-29 Enichem Sintesi Composizione catalitica e processo per l'alchilazione di composti aromatici
FR2744650B1 (fr) * 1996-02-09 1998-03-27 Inst Francais Du Petrole Catalyseur composite de dismutation et/ou de transalkylation d'hydrocarbures alkylaromatiques
BR9709381A (pt) * 1996-05-29 1999-08-10 Exxon Chemical Patents Inc Processos de convers o aromática e catalisador de zeólito útil nos mesmos

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102470353A (zh) * 2009-07-03 2012-05-23 英国石油国际有限公司 改性沸石催化剂
CN102407156A (zh) * 2010-09-21 2012-04-11 中国石油天然气股份有限公司 一种烷基转移催化剂的制备方法
CN102407156B (zh) * 2010-09-21 2013-09-04 中国石油天然气股份有限公司 一种烷基转移催化剂的制备方法
CN110337328A (zh) * 2017-02-28 2019-10-15 埃克森美孚化学专利公司 催化剂组合物及其用于芳族化合物烷基化方法的用途
CN110337328B (zh) * 2017-02-28 2022-05-06 埃克森美孚化学专利公司 催化剂组合物及其用于芳族化合物烷基化方法的用途
CN114426451A (zh) * 2020-09-24 2022-05-03 中国石油化工股份有限公司 一种多取代异丙苯烷基转移制备异丙苯的方法及其所得异丙苯

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JP2005511285A (ja) 2005-04-28
WO2003049857A1 (en) 2003-06-19
TW200300752A (en) 2003-06-16
MXPA04005454A (es) 2004-10-11
KR20050034633A (ko) 2005-04-14
EP1455939A1 (en) 2004-09-15
CA2468534A1 (en) 2003-06-19
US20050038307A1 (en) 2005-02-17
AU2002342005A1 (en) 2003-06-23
BR0214658A (pt) 2004-11-03

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